CS266578B2 - Method of low alcohols continuous production - Google Patents
Method of low alcohols continuous production Download PDFInfo
- Publication number
- CS266578B2 CS266578B2 CS861966A CS196686A CS266578B2 CS 266578 B2 CS266578 B2 CS 266578B2 CS 861966 A CS861966 A CS 861966A CS 196686 A CS196686 A CS 196686A CS 266578 B2 CS266578 B2 CS 266578B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- reactor
- sec
- differential pressure
- ppm
- chloride
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 50
- 150000001298 alcohols Chemical class 0.000 title claims description 6
- 238000010924 continuous production Methods 0.000 title claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 239000003054 catalyst Substances 0.000 claims description 18
- 239000003093 cationic surfactant Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 150000001768 cations Chemical class 0.000 claims description 8
- 230000036571 hydration Effects 0.000 claims description 7
- 238000006703 hydration reaction Methods 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- 150000001336 alkenes Chemical class 0.000 claims description 5
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 4
- PVUBCQXMQPBYKZ-UHFFFAOYSA-N 16,16-dimethylheptadecylazanium;chloride Chemical compound [Cl-].CC(C)(C)CCCCCCCCCCCCCCC[NH3+] PVUBCQXMQPBYKZ-UHFFFAOYSA-N 0.000 claims description 3
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 3
- 125000005541 phosphonamide group Chemical group 0.000 claims 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 30
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 28
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 12
- 239000007789 gas Substances 0.000 description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- HHBZZTKMMLDNDN-UHFFFAOYSA-N 2-butan-2-yloxybutane Chemical compound CCC(C)OC(C)CC HHBZZTKMMLDNDN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007792 gaseous phase Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 230000008092 positive effect Effects 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical class C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical class N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 1
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- -1 amine oxide salts Chemical class 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- OJOSABWCUVCSTQ-UHFFFAOYSA-N cyclohepta-2,4,6-trienylium Chemical class C1=CC=C[CH+]=C[CH]1 OJOSABWCUVCSTQ-UHFFFAOYSA-N 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical class C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000002918 oxazolines Chemical class 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 150000003549 thiazolines Chemical class 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Ultra Sonic Daignosis Equipment (AREA)
- Measurement Of Radiation (AREA)
- Transmission Systems Not Characterized By The Medium Used For Transmission (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853512518 DE3512518A1 (de) | 1985-04-06 | 1985-04-06 | Verfahren zur kontinuierlichen herstellung von niederen alkoholen |
| AU60052/86A AU583137B2 (en) | 1985-04-06 | 1986-07-10 | Process for the continuous production of lower alcohols |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS196686A2 CS196686A2 (en) | 1989-04-14 |
| CS266578B2 true CS266578B2 (en) | 1990-01-12 |
Family
ID=36840752
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS861966A CS266578B2 (en) | 1985-04-06 | 1986-03-20 | Method of low alcohols continuous production |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US4831197A (es) |
| EP (1) | EP0197403B1 (es) |
| JP (1) | JPS61236736A (es) |
| CN (1) | CN86102121B (es) |
| AT (1) | ATE53566T1 (es) |
| AU (1) | AU583137B2 (es) |
| BR (1) | BR8601562A (es) |
| CA (1) | CA1297133C (es) |
| CS (1) | CS266578B2 (es) |
| DD (1) | DD246987A5 (es) |
| DE (1) | DE3512518A1 (es) |
| DK (1) | DK154786A (es) |
| ES (1) | ES8702326A1 (es) |
| FI (1) | FI86710C (es) |
| IN (1) | IN166988B (es) |
| NO (1) | NO163615C (es) |
| PL (1) | PL147138B1 (es) |
| RO (1) | RO93221B (es) |
| SU (1) | SU1400502A3 (es) |
| YU (1) | YU43430B (es) |
| ZA (1) | ZA862486B (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3419392C1 (de) * | 1984-05-24 | 1985-12-05 | Deutsche Texaco Ag, 2000 Hamburg | Verfahren zur kontinuierlichen Herstellung von Isopropylalkohol oder sek. Butylalkohol |
| DE3600274A1 (de) * | 1986-01-08 | 1987-07-09 | Basf Ag | Verfahren zur selektiven regenerierung von mediatoren und katalysator dafuer |
| US4956506A (en) * | 1989-12-21 | 1990-09-11 | Conoco Inc. | Vapor-phase hydration of olefins to alcohols in series reactors with intermediate alcohol removal |
| US5191129A (en) * | 1992-05-01 | 1993-03-02 | The Pritchard Corporation | Method of preparing an isopropanol and diisopropyl ether oxygenate motor fuel additive |
| US5268515A (en) * | 1992-05-01 | 1993-12-07 | The Pritchard Corporation | Process of preparing an isopropanol and diisopropyl ether oxgenate motor fuel additive |
| CN1095819C (zh) * | 1999-09-29 | 2002-12-11 | 中国石油化工集团公司 | 连续生产低碳醇的方法 |
| EP2208719A1 (en) | 2009-01-15 | 2010-07-21 | Sasol Solvents Germany GmbH | Process for the production of lower alcohols by olefin hydration |
| US8558036B2 (en) | 2010-11-15 | 2013-10-15 | Saudi Arabian Oil Company | Dual phase catalysts system for mixed olefin hydrations |
| CN103664520B (zh) * | 2012-09-20 | 2015-08-19 | 中国石油化工股份有限公司 | 一种丙烯水合反应制备异丙醇的方法 |
| EP4059557A3 (en) * | 2017-09-30 | 2022-09-28 | Asahi Intecc Co., Ltd. | Guide wire |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL288077A (es) * | 1962-01-24 | 1900-01-01 | ||
| GB1227144A (es) * | 1967-04-05 | 1971-04-07 | ||
| DE2233967A1 (de) * | 1972-07-11 | 1974-01-31 | Texaco Ag | Verfahren zur kontinuierlichen herstellung von niederen alkoholen, insbesondere isopropanol |
| DE2429770C3 (de) * | 1974-06-21 | 1981-04-16 | Deutsche Texaco Ag, 2000 Hamburg | Verfahren zur Herstellung von niederen Alkoholen durch direkte katalytische Hydratisierung niederer Olefine |
| US4012456A (en) * | 1974-11-19 | 1977-03-15 | Chaplits Donat N | Method for separation of isobutylene from C4 hydrocarbon fractions |
| US4180688A (en) * | 1977-07-29 | 1979-12-25 | Nippon Oil Co., Ltd. | Method for continuously producing tert-butyl alcohol |
| FR2470105A1 (fr) * | 1979-11-20 | 1981-05-29 | Chaplits Donat N | Procede de separation de l'isobutylene de fractions d'hydrocarbures en c4 |
| GB2081254B (en) * | 1980-08-01 | 1984-07-25 | Toa Nenryo Kogyo Kk | Production of tertiary alcohols |
| DE3040997C2 (de) * | 1980-10-31 | 1983-07-21 | Deutsche Texaco Ag, 2000 Hamburg | Verfahren zur kontinuierlichen Herstellung von sek.-Butylalkohol |
| DE3200990A1 (de) * | 1982-01-15 | 1983-07-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von ungesaettigten alkoholen und/oder deren estern |
| DE3419392C1 (de) * | 1984-05-24 | 1985-12-05 | Deutsche Texaco Ag, 2000 Hamburg | Verfahren zur kontinuierlichen Herstellung von Isopropylalkohol oder sek. Butylalkohol |
-
1985
- 1985-04-06 DE DE19853512518 patent/DE3512518A1/de not_active Ceased
-
1986
- 1986-03-17 NO NO861014A patent/NO163615C/no not_active IP Right Cessation
- 1986-03-18 ES ES553124A patent/ES8702326A1/es not_active Expired
- 1986-03-20 CS CS861966A patent/CS266578B2/cs unknown
- 1986-03-22 AT AT86103942T patent/ATE53566T1/de not_active IP Right Cessation
- 1986-03-22 EP EP86103942A patent/EP0197403B1/de not_active Expired - Lifetime
- 1986-03-28 SU SU864027184A patent/SU1400502A3/ru active
- 1986-04-01 YU YU517/86A patent/YU43430B/xx unknown
- 1986-04-01 FI FI861382A patent/FI86710C/fi not_active IP Right Cessation
- 1986-04-02 CN CN86102121A patent/CN86102121B/zh not_active Expired
- 1986-04-03 ZA ZA862486A patent/ZA862486B/xx unknown
- 1986-04-03 JP JP61075647A patent/JPS61236736A/ja active Granted
- 1986-04-04 DD DD86288792A patent/DD246987A5/de not_active IP Right Cessation
- 1986-04-04 PL PL1986258781A patent/PL147138B1/pl unknown
- 1986-04-04 RO RO122885A patent/RO93221B/ro unknown
- 1986-04-04 CA CA000505854A patent/CA1297133C/en not_active Expired - Fee Related
- 1986-04-04 DK DK154786A patent/DK154786A/da not_active Application Discontinuation
- 1986-04-04 BR BR8601562A patent/BR8601562A/pt unknown
- 1986-04-04 IN IN249/MAS/86A patent/IN166988B/en unknown
- 1986-07-10 AU AU60052/86A patent/AU583137B2/en not_active Ceased
-
1987
- 1987-09-02 US US07/092,104 patent/US4831197A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| NO163615B (no) | 1990-03-19 |
| CA1297133C (en) | 1992-03-10 |
| BR8601562A (pt) | 1986-12-09 |
| ZA862486B (en) | 1986-11-26 |
| DK154786D0 (da) | 1986-04-04 |
| EP0197403A2 (de) | 1986-10-15 |
| RO93221B (ro) | 1988-01-01 |
| CN86102121B (zh) | 1988-10-12 |
| DD246987A5 (de) | 1987-06-24 |
| FI861382A (fi) | 1986-10-07 |
| NO861014L (no) | 1986-10-07 |
| IN166988B (es) | 1990-08-18 |
| US4831197A (en) | 1989-05-16 |
| CS196686A2 (en) | 1989-04-14 |
| CN86102121A (zh) | 1986-10-22 |
| RO93221A (ro) | 1987-12-31 |
| YU43430B (en) | 1989-06-30 |
| AU583137B2 (en) | 1989-04-20 |
| FI86710B (fi) | 1992-06-30 |
| FI861382A0 (fi) | 1986-04-01 |
| JPS61236736A (ja) | 1986-10-22 |
| EP0197403B1 (de) | 1990-06-13 |
| ES553124A0 (es) | 1987-01-16 |
| JPS6344732B2 (es) | 1988-09-06 |
| DE3512518A1 (de) | 1986-10-09 |
| AU6005286A (en) | 1986-11-13 |
| DK154786A (da) | 1986-10-07 |
| PL147138B1 (en) | 1989-04-29 |
| SU1400502A3 (ru) | 1988-05-30 |
| ATE53566T1 (de) | 1990-06-15 |
| ES8702326A1 (es) | 1987-01-16 |
| FI86710C (fi) | 1992-10-12 |
| NO163615C (no) | 1990-06-27 |
| EP0197403A3 (en) | 1987-08-26 |
| YU51786A (en) | 1988-02-29 |
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