CS218886B1 - Method of preparation of the new azodyes containing the silicon - Google Patents
Method of preparation of the new azodyes containing the silicon Download PDFInfo
- Publication number
- CS218886B1 CS218886B1 CS791667A CS166779A CS218886B1 CS 218886 B1 CS218886 B1 CS 218886B1 CS 791667 A CS791667 A CS 791667A CS 166779 A CS166779 A CS 166779A CS 218886 B1 CS218886 B1 CS 218886B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- siloxanes
- radical
- natural
- fibers
- silicon
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 6
- 239000000987 azo dye Substances 0.000 title claims 3
- 229910052710 silicon Inorganic materials 0.000 title claims 2
- 239000010703 silicon Substances 0.000 title claims 2
- -1 siloxanes Chemical class 0.000 claims 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 150000001989 diazonium salts Chemical class 0.000 claims 2
- 239000000835 fiber Substances 0.000 claims 2
- 239000012209 synthetic fiber Substances 0.000 claims 2
- 229920002994 synthetic fiber Polymers 0.000 claims 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 238000004040 coloring Methods 0.000 claims 1
- 239000000470 constituent Substances 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims 1
- 239000000975 dye Substances 0.000 claims 1
- 150000002484 inorganic compounds Chemical class 0.000 claims 1
- 229910010272 inorganic material Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- 239000000985 reactive dye Substances 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 150000004756 silanes Chemical class 0.000 claims 1
- 241000238876 Acari Species 0.000 description 1
- 101100384273 Dictyostelium discoideum clua gene Proteins 0.000 description 1
- 101150096418 Mepe gene Proteins 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 240000003864 Ulex europaeus Species 0.000 description 1
- 101150115538 nero gene Proteins 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/008—Dyes containing a substituent, which contains a silicium atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Silicon Polymers (AREA)
- Coloring (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Description
4 HA3BAHHE Μ30ΒΡΞΤΞΗΗΗ
CnocoÓ nojiyneHMH hobhx xpeMHunco^epacamiix a3OKpacnTejieíí
OBJIACTL ΠΡΚΜΞΗΞΗΠΒ K30EPETEHHH ΜθοδρβτβΗΗβ KacaeTCH KpeMHiiíícoAepsamMX a3OKpacnTejiečí:, κοτορκβMOryT ČHTb MCnOJIi>3OBaHH ΛΠΗ ΟΚρθΙΠΗΒβΗΖΗ nOJTMMepHHX opraHMuec-KHX ΟΟθΛΜΗΘΗΗΜ, ΠρθΛΠΟΠΤΗΤβΛΒΗΟ OpraHO CMJIHKCaHOB MJIM ΠΟΟ-opraHociuiOKcaHOB, a Taxae HeopraHHnecKMX waTepnajioB. 3th aeoKpaΟΙΓΓΘΛΜ HBJIHIOTCH ΟΛΗΟΒρβΜθΗΗΟ ΤδΚΚβ ρβ aKTMBHUMH Κρβ CMTeJIHMH flJXHcMHTeTwxiecKíix μλμ HaTypanbHbix bojiokoh pacTHTejibHoro mjim scmbot-ΗΟΓΟ npOMCXOXAeHMH . KpaCMTeXM MOryT ČiJTb BCTpOeHbl Β ΠΟΛΜΜΘΡ-Hyro MOJieKyjiy c noMoníbio γομθοποληρηομ cbh3M μλη, οοοτβθτοτβθη-ηο , MoryT SbiTb HaneceHu Ha βολοκηθ 6β3 λοπολημτθλβηοχ Φηκοθ-pHM. 4anee cymecTByeT βο3μοηηοοτβ HaHocMTb KpeMHMiíco,a;epacainMííHBe'TOo6pa3ymníMfi κομποηθητ Ha OKpainHBaeMyio noBepxHocTb h eaTewoópa3OBHBaTb a3OKpacHTeJib c noMombX) peaaííHH c apoMaTM^ecKHMpaCTBOpOM COJIIÍ £Ha3OHHH . XÁgAKTEPnCTJffiA H3BECTHHX ΤΕΧΗΤΓΊΕΟΚΗΧ PEHEBHH#
IlojiyneHHe aeoKpacMTejieií na ocHOBe τριίΜβτιιοιίΛΜΛθΗΐυίΜΗΟΒ peaic-ρκβίί 3THX ΟΟβΛΗΗΘΗΗΜ ΚρβΜΗΜΗ C ΛΗ830ΤΗρ0ΒaHHHMH βρΟΜβΤΜΗβCKH-mh aMMHaMM onzcajiM BoHxyp (ahccepTapii.fi 1970, ΤβχΗΚΗββκκϋ ynn-ΒβροΗτβτ ΙΙιορΗχ) μ XamHMOTO (ΗκβΓβΚίΐ 3acmw 80)1960), 1399-1404).3th KpacHTSJtw Ηβ ημθβτ λοοτθτοηηοη aare3ww κ OKpameHHHM cyScT-paTaM, Tas ksk ohm coAepaaT y aTOMa κρβΜΗΚΗ τοληκο ΗββκτΗΒΗκβΜβτΜΛΗΗΗβ rpynnu, w nosTOMy Taoe ohm ηθ MoryT jmen ηημκογοΤθΧΗΗΗβΟΚΟΓΟ 3Η8ΗβΗΙίΗ.
KpeMHHÍícoAepa:amHe a3OKpacwTejiH c rnflpo^H3yeMKMH cnocočcTByso-πμίΜη y^epawBaHHro rpynnaMH onacaHH, HanpnMep, b onucaHHax Η3θδ-ρβτβΗκϋ κ naTeHTaM DIIIA 2 925 313, 2 927 839, 2 931 693, 2 934459, 2 955 898, 2 963 383. B xa^ecTBe hcxo^hux κομποηθητοβwcnojib3OBajiM apujiaMííHo- hjiii aMHHoapmrazrKMjiajiajiKOKCíícKJiaHH.KpameHne θτμμη a30KpacHTejrHMH οτληηθλοοη xopomuMH a^re3neííw npotíHOCTbio Ha CTeidOBOJiOKHax, Ha HaTypanbHHX βολοκηθχ 2 thkhx, Kas mepcTb, πιθλκ, xjiormaToSyMaoKHoe bojiokho, w Ha cwh-ΤβΤΜΗβΟΚΗΧ BOJIOKHaX. OffHQKO, HX ΗθΛΟΟΤΘΤΚΘΜΗ ΗΒΛΗβΤΟΗ ΗΘΠίβBcero ciuiisHoinejroHHOM xapaKTep, a Taoe Aoporoe h czoxHoeΠΟΛΗΗβΗΜβ MCXOAHOrO ΚρβΜΗΗίί ΟΟΛβρΧδΠίβΓΟ ΘΜΗΗΗΟΓΟ ΟΟβΛΗΗΘΗΜίϊ. B οπηοθκη.ίχ Η3θδρβΤθΗΗ“ι κ ποτβΗΤθΜ CLUA 3 888 891, 3 963 744h 3 981 859 οπηοθηη Mešity nponHM a3OKpacHTeJiH, κοτορπβ conep-StaT TpHC-( ΤρΗΜβΤΗΛΟΗΛΗΛ-) ΟΗΛΟΚΟΗΘΛΚΗΛΘΜΗΗΗΗίί paflHKaJI. 3thKpaCHTeJIM OTJIIltiaETCfl Η3ΒβΟΤΗθϋ COBMeCTHMOCTbK C ΟΠρβΛβΛβΗΗΗΜΚΠΟΛΗβρΓβΗΟΟΗΛΟΚΟΘΗΘΜΜ. ΟλΗΘΚΟ, HX HSaKTHBHHÍt ΟΜΛΟΧΟΘΗΟΒΗϋpa^HKaji 3aTpy£HíieT flocraTO^HyK) a£re3yro, BCjreflCTBHe nero c hhmmTaKate HeflOCTwraeTCíi npoHHoe OKpainwBaHHe οτθκλοβολοκοη, HaTy-Ρθλβηηχ w cHHTeTtmeckmx οργθηηηθοκηχ βολοκοη. y othx Kpacw-TeJieíi Ηβ μο»θτ ÓHTb peajiH30BaHa roMeonojiHpHan cBH3b KpacHHíHXΚΟΜΠΟΗβΗΤΟΒ C ΠΟΛΗΜβρΗΟίί MOJieKy.SOÍÍ . UEJIL· M3OEPETEHHfl
IleJIb Η3Ο0ρβΤβΗΗΗ 3ΘΚΛϊΟΠββΤCfl B TOM, HTOÓH HaíÍTM £0 CHX ΠΟρΗβΗ3ΒβΟΤΗΗβ ΚρβΜΗΗΖί ΟΟΛβρϊθΠίΗβ ΘΒΟΚρβΟΗΤβΛΗ, ΚΟΤΟρΗβ MO2CHOnOJty^HTb ΠΡΟΟΤΗΜ CIIOCOÓOM H C ΧΟρΟΙΠΗΜ BHXOflOM H3 ΛβΓΚΟ,ΠΡ CTyn-HHX WCXOAHHX ΒβΙΙξβΌΤΒ. KpaCOTíKe ΚΟΜΠΟΗβΗΤΗ ^ΧΟΛΒΗΗ ÓHTb CIIOCOÓ-hhmh oÓpasoBHBaTb roMenojinpHyio οβη3β c πολημθρηιιμμ cTpyKTypa-mh. KpoMe toto, 3TM KpacwTejiH λολ3κηη no κρβϋΗβϋ Mepe οτβθπθτβTeXHOJIOrHtieCXHM TpeÓOBaHMHM K CHJÍHKOHOBHM npO^yKTSM, ΑΟΛΓΟΒβΗ-HO ΟΚρβΙΠΜΒβΤΈ» ΠΟΛΜΜβρΗΗβ ΜβΤβρΗΘΛΗ H ÓHTb ΠρΗΜβΗΗΜΗΜΜ Β ΚβΠβΟ-ΤΒβ peaKTWBHux κρθοκτβΛβίί. P13JI0HEHftE CyigHOCTH Κ30ΒΡΕΤΕΗ7ιΉ Βηλο oÓHapyaceHO, ητο KpeMHHÍico^epKaimie θβοκρθοΗτβΛΗ oómeň$opMyjtH : 3
MoryT αολγοβθ*ιηο OKpamHBaTb nojiwMepHhie μθτθρμθλη π ocoóeHHoCMJrHKOHOBHe npOflyKTH W πρκ 3TO11 yHOBJíeTBOpflTb ΠρθΑΈΗΒΛββΜΗΜM H3BeCTHHM K CMJIHKOHOBKM ΠρΟβγΚΤΒΜ BHCOKHM ΤρββΟΒδΗΜΗΜ BΟΤΗΟΠβΗΗΜ ΟΠβΙξΜφΜΗβΟΚΜΧ RJIR ΟΗΛΜΚΟΗΟΒ CBOÍÍCTB, KflK HanpMMep,ΤβρΜΟ CTOÍÍKO CTb . B oónjeií <$opMyjie HHAeKCH o6o3HaxiaK)Tcaí X = o^MHaKOBue mjim pa3HHe rMjtpojiH3yeMi)ie rpynnu ηλη cnjiMKca-HOBHM ρβΛΜΚΘΛ, Z = ΛΒγΧΒΘΛβΗΤΗΕΓΗ aJIKMJIbHEIM paflHKaJI C 2 - 10 Ο-ΘΤΟΜβΜΜ, κοτορυίί MOSCBT 3aKaHHWBaTbCa 3T0M0M KHCJIOpOAa, ΜΟΧβΤ 1 2 coflepacaTb pmcjnínecxiie 3Bem>a, πρΜΗβΜ C τβκ se κβκ. m CMoryT o6pa3OBHBaTb θβθηβα pHKjio-ajiKHJibHorq KOJibiía, R = oflHOBaneHTHHií opraHM-qeckmm pa^MKaji,
Ar = 3aMeqeHHHÍt mm HeaaMemeHHHM aTOMaTMnecKHM ρθληκθλ, a = pejrue qwcjia οτ 1 ,n;o 3, η = ΗΗ3ΚΟβ ΪίβΛΟβ ΧΪΜΟΛΟ ·
Hajiee, stm asoKpacirrejiii BcaeACTBze HajHrcna y aTOMa κρθμηηηrnAP0JiH3yeMiix rpynn MoryT 6μτβ πρπΜβΗβΗΗ KaK peaKTMBHueKpacMTejiM. Kpacsnqwe κομποηθητη MoryT 6htb c πομοήβε γομθοπο-JiapHOM CBH3H ΒΟΤρΟβΗΗ B nOJIItMepHyiO MOneKyjiy ΜΛΜ 0ΒΗ3ΗΗΗ cποΛΗΜβρΗοϋ CTpyKTypoií, χιτο πρβΑΠΟΛΟΓββτ BhieoKys iíBeTOCToňKocTbKaK HanpMMep, cbot- m MMrpaiíMOHHyio ctoSkoctb. Ηβλθηηη cMHepe-3MCa Β CHJIMKOHaX Ηβ ΠρΟΗΒΛΗΪΟΤΟΗ. IIOJiyqeHMe HOBHX KpeMHMňcOAep-atanpíx aeoTOKpacMTejieM θβληθτοη οηθηβ npocTHM μ λθγκο peaan3y-eTca peaKijMeíí ομλθηοβ μλμ cíuroKcaHOB οδιμβη $opMyjrn: X - Si - Z - ICH - 2CÍL· - LÍH - Ar a t 1 2
R_ OH 3-a C £Ha3OT ΚρΟΒβΗΗΗΜΜ θρΟΜΗΤΜΧϊβΟΚΗΜΜ ΘΜΜΗΘΜΜ ( COJIflMH AHa3OHWtf)oómeií <£opMyjiH: - Ar 4
Tax xax xpeMHMMCOAepacamMe μοχοληηθ οοβΛΗΗβΗΜίΐ MoryT 6uTbΗΒβτοοόρ a3yioinHMM χομποηθητθμμ npaxTMxiecxM pjisi Bcex jiMaeoTMpy—θμηχ apOMaTHqecKMň θμμηοβ, to θτο xejiaeT βοθμοχηημ οηθηβ mho-rwe BapwaHTH stmx hobkx xpeMHMíícoflepaamMX asoxpacMTejieM. B xanecTBe AMaeoTMpyeMNx apoMaTMnecxMx θμμηοβ MoryT 6ητβ,HanpMMep Μ0ΠΟΛΒ3ΟΒΘΗΚ: ΘΜΜΗθ6βΗ3ΟΛ, l-aMHHO-4-HHTpOÓeH3OJI , l-aHHHO-2, 4-βΗΗΗΤρθ6βΗ-3ΟΛ , l-aMMHO-2-XJIOp6eH3OJI , l-aMHHO-4xjIOp!5eH3OJI , l-aMMHO-2T5—j^nxjiop6eH3OJi, 4-aiíeTiciaMMHO-l-aMMHo6eH3oji, 4-6eH3OMJi-aMHHO--l-aMMH06eH30Ji, l-aMHH06eH3OJi-3-cyjib<£0KMCJi0Ta, l-aMMH06eH30ji--4-CyjIb$OKMCJIOTa, 1-ΘΜΜΗΟ~2-ΜβΤΜΛ0βΗ3ΟΛ , 1-ΘΜΜΗΟ-3-ΜθΤΜΛδβΗ-3OJI, 1-ΘΜΜΗΟ-4-ΜΕΤΜΛ6βΗ3ΟΛ, l-aMMHO-2, 4-ΣξΜΜΘΤΗΛδθΗ3ΟΛ , 1-aMHHO-2, 5-ΛΜΜθΤΜΛ6βΗ3ΟΛ , 1-3ΜΜΗΟ-4-φθΗΜΛ0βΗ3ΟΛ, 4-ΘΜΜΗΟ-1, 1’-θ3θδβΗ3ΟΛ, 2—ΘΜΜΗΟΗθφΤΟΛ , l-aMMHOHaφTOJI-5-CyΛbφOKHCJΪOTa,1-ΘΜΜΗ0ΗθφΤΟΛ-7-^ΛΙ>φθΚΗΟΛΟΤΘ, 2-aMHHOHaφTαΛ-6-CyΛbφOKHCΛOTa,l-aMHHO-2-ΓΖΛΡΟΚΟΜ-4-ΗΜΤρθδβΗ3ΟΛ Μ TsJL· ^HaaoTupoBaHMe θρομθτμηθοκμχ ^waaoTMpyeMHX θμμηοβ μο»θτ 6κτβΠρΟΒβ,ΖξθΗΟ KJXaCCMHeCXMMM , Μ33βΟΤΗΚΜΜ ΜθΤΟΛΘΜΜ ^ΜΘ30ΤΜρ0ΒΘΗΜΗ ·
Tax xax ΜΜθβτ ομκολ οοπβτβΤΒ xpeMHMxcoícepatamMe οοθλμηθημη,co^epacaiqMe rn;npojiM3yeMEte rpynna, β οργθημηθοκμχ pacTBopMTejiax, *htoÓh coxpaHHTb rHApojiM3yeMHe rpynnu, cjie^yeT yace #Ma3OTMpo- ·ΒΘΗΜΘ apOMaTMHe CKMX AMaSOTMpyeMHX COeflMHeHMíi npOBOflMTb B HeBOfl-hom cpe^e. Kax no^xo^HiUMe pacTBopHTejiM MoryT óhtb πρΜΒββθΗκ,HanpMMep, cnnpTH, apeTOH, MypaBbMHaa, yxcycHaa ηλμ προπμοηο-ΒΘΗ ΚΗΟΛΟΤΘ, a ΤΘΚΟΚβ ΛΗΜβΤΜΛφΟρΜΘΜΜΛ;. ΠΟΛΘ3ΗΟ IipOBOflHTb ΟΟΗβ-TaHMe Β OflHOM ΟΛΜΗΘΚΟΒΟ ΠΟΛΧΟίξΗΠξθΜ ΗΘ3ΒΘΗΗΚΜ rpynnaM paCTBO-ρητβΛθ μ pe.aecoo6pa3Ho β οηλβηοκμολομ ορβΛβ. Αθοτοκρθομτθλβ,ΒΚΛβΛΗΜΙξΜΜ CH Β δΟΛΒΙΠΜΗΟΤΒβ CJiynaeB TBepAHM, Ο ΤφΜΛΒΤρΟΒΗΒΘ&Τμ moscho Taxace 3aTeM β cjiynae ΗβοδχοΛΗΜΟοτΜ οημοτμτβ nepexpxc-Taji^MsaqMeíi. IIojrytieHMe KpeMHHňcoAepacamHX μοχοληκχ οοθαμηθημμ jierxo peajiM-3yeTCH peaxnMeň ομλθηοβ oh οηλοκοθηοβ oómeíí φopMyΛH: 5 X - ϋΐ - Za l rL· 3-a c apmji3Mwhqmm očmeíí φορι^Λκ: H2N - Ar ZUh peKpww CMenwBaiOT b CTexwoweTpwqecKOM οοοτηομθηημ snoxcw-φγΗΚςΜΟΗδίΛΒΗΗΘ CMJiaHLI HJII1 CWJIOKCaHH C apMJISMWHaMH. ΡθθΚΙξΗΗ προτβκββτ ΠΟΗΤΗ ΚΟΛΗΠβΟΤΒβΗΗΟ Η saKaHHHBaeTCH Ηβρβ3HecKOJibKo wacoB. JUh yjiy^meHMH pacTBopwMOCTw pejiecoo6pa3HoπροΒΟβΜΤΒ peaKpwio b pacTBopwTewHX, cnocoScTByiomwx pacTBopw-MOCTH Ηβκοτορυχ apHJiaMMHOB. Πο^ΧΟΛΗΜΜΜΜ paCTBOpWTeJIHMZ SBJIH-botcHj Hanpwwep, ajiieaHOjiH, apeTOH, ajibKMjibHLre cjioacHHe θφπρυKapóoHOBBX kwcjiot, ÓeH3OJi, TOJiyow w ^pyrwe. £o6aBKa KaTaww-saTapoB He TpeóyeTcw. Ilocjie ynaneHHíi HeBCTynwBiawx b peaKpwmwcxoahhx BemecTB w, b cjiyqae ηοπολββοβθημη, pacTBopwTeJiH cHDMOiubro, HanpwMep, BaKyyMHoX neperoHXW, npo,n;yKT peaKpww cTa-hobhtch ΓΟΤΟΒΗΜ pjix npwMeHeHHa b xawecTBe pBeTOo6pa3yKmeroΚΟΜΠΟΗβΗΤβ ΑΠΗ flMO 3ΟΤΙίρθΒ3ΗΗΗΧ apOMaTJWeCKHX COeflMHeHMÍÍ ( CO-jieií .AwaaoHMH).
CorwacHo ιοοδρβτβΗΗΐο, ΗΟΒΗβ KpeMHwSco j?epsamwe aaoKpacwTejiwworyT ÓHTb Taxsce nojtyweHH Ha npo^yKTe, sto 03HawaeT, hto ok-pameBaeMHií MaTepwaw προπζτθΗ KpeMHwiico^epsamMMW οοθαμηθημημμ,coAepacamwMM rwflpojiM3yeMhre rpynnu. MMnperHwpoBaHwe μοχθτ óhtbπροΒβ^βΗΟ, HanpwMep, norpyseHweM c nocjre^yoqwM BHcyrawBaHweM.A3OKpacwTejib oópaayeTcw 3θτθμ nocpeACTBOM oópaóoTKw #Ma3OTH-poBaHHMMM apoMaTwnecKWMM aMHHaMW (pacTBopaMW cojieft flwaaoHwa) .3tot BapwaHT ΜΜββτ το npewMymecTBO, πτο npw stom MoryT 6ητβΠρΜΜβΗβΗΗ ΒΟ£ΗΗβ paCTBOpH COJIH £Η33ΗΗΜΗ, WTO ΟΟΟββΗΗΟ OHeHbynoóHO rjir OKpameBaHWH saTypaabHHx w cwHTeTwqecKwx βολοχοη,Taxwx xax raepcTb, ιπβΛΚ, xzonnaTofiyMasHoe, pereHepwpoBaHHoenowwaMMflHoe, ποΛΗθφΜρΗοβ ΒΟΛΟΚΗΟ w t.a. Meswy xpacwTejieM wcyóCTpaTOM Ha^eatHo peawwsymTCH HeoSxoAWMme λλη bhcokož npow-hoctw roMenoaapHHe cbh3w. 6 ΠΡΗΜΕΡΗ OCy%ECTBJIEHHH Η3ΟΕΡΕΤΞΗΗ3 ΠρΜΜβρ 1 18,6 BecoBHX MacTeň amuíMHa cMernnBajin c 56 βθοοβημκ nacTHMn3-rJnmHflOKCMnponiuiTpM3TOKCMciíjiaHa. 3aTeM CMecfa κηπητοκ 6 wac,ΠΟ ΜΟΤβΜβΗΗΗ 3Τ0Γ0 ΒρβΜβΗΗ ΟΤΓΟΗΟΜ npn JíaBJíeHttH 1 τορρ Η3Bomefliune β peaKnnio wcxoflHne προΛγκτυ. Βηχοα aHHJiHHonponaHonoK-cHnpommaTOKCMciíjiaHa οοοτθβμλ 87%. Β §%-ΗΗΜ 3TaHOJIOBHÍÍ paeTBOp aHHJIMHOnponaHOJIOKCMnpOnMJITpH3TO-KcwcKJiaHa norpysann· τβρΜΜτιβοκη pacnwHXTOBHHHyK) CTeooTKaHb, xjion-qaTOÓyMascHue bo-jiokho, uiepcTb, nojinaMH^Hoe, πόΛΗβκρΜΛΟΗΗτρΗΛΒΗΟβ η ποηποφηρ-ηοθ BOjioKHa. OSpaóoTaHHne τβκιω o6pa3ow βολοκηθ OTSHMajin nnpocyuiHBajsw (okomo 60 mhh. npn TeMnepaType 20°C) n odpaóaTht-Ban 3aTeiz pacTBopoM ,n;na3OTnpoBaHHoro apnjiaMHHa. B KanecTBeapmiSMMHa ótuin BaópaHH aHMJiwH n 2, 4-αμημτρο8ημλμη, κοτορκβnna3OTnpoBajin oÓbraHHM cnocoóoM c noMombio CMecn Ηητρητ ΗβτρηΛ-co^HHaíi KMCJioTa mjim HMTpo3ocepHoň khcmótok. Βοηοκηθ, a TaKaeCTeiQiaTKaHb, nponnTaHHBie aHnnnHonponaHojioKcnnponnjiTpnesTOKcn-cnjiaHOM, norpysann b pacTBopu cojieií #ηθ30ηη.η, ciíjisho paefiaB-ΛβΗΗΗΐί ΛβΛΗΗΟΪϊ BOflOM . ΠΒβΤΟΟδρββΟΒΘΗΗΘ npOTeKanO ΜΓΗΟ3ΘΗΙΪΟ ,ταχ ητο yse Ηβρβ3 5-10 cex. ΜθτβρηβΛΗ μογλμ ĎUTb BHHyTH M3pacTBopa cojih ΛΜβ3θΗηη. 3aTew nponanacKMBajui β sose rq npex-pameHna OKpamHBaHHfl npoMMBHoít boah. C xnopncTHM Φμημλαμ330— HKeM nojrynajin χβΛτοβ OKpaniMBaHMe, a c cy.zih<£aTOM 2, 4-βΗΗΜτρο-φβΗΜΛΛΗθβοΗΟΗ-φηοΛβτοΒοβ. ΠρΜΜβρ 2 49,2 BecoBHX nacTen β -3, 4-3ποκοηηηζΛθΓβκοΗΛ3ΤΜΛτρηΜβτο-κοκοοθηθ β 50 μη MeTanona CMemMBaan c 28,8 βθοοβημμ πηοτκμμβ —ηa$THjiaMMHa η κηπητμλη οκολο 8 nac. Πο οκοηηθημμ οτγοηη-^npacpBopwTejib w 3βτβΜ πολ BaxyyMOM Ηβ Borne αιπμχ β ρββκηηκ sno-ΚΟΗΙίΜΚΛΟΓβΚΟΗΛΘΤΗΛΤρΗΜβΤΟΚΟΗΟΜΛ ΘΗ. Πρη 3ΤΟΜ MOSHO ShUO ΒΗ^β^ΚΤΙ»Μ3 peaKpMOHHoň CMecn τολβκο 3 BecoBtie nacTH cnjraHa. Oóhhhhm cnocoÓOM ίζΜθβοτηροΒοπη 27,6 BecoBne xíacTM 4-HMTpoaHMJinHa. 3 pacTBop cojih flnasoHMa octoposho bhocmhm 39,2 BecoBne nacTMnony^íeHHoro ββππθ nponyKTa. ΠροπΒΛΗίοπξββΟίΐ cpaey se oxpamMBaHMe -7.- yKaaHBajio Ha το, πτο n;BeTOo6pa3OBaHMe προΗ3θπυιο. Πο OKOH^a-ηημ nepeMemHBθλμ enje 30 μμη., OTcacuBajiM κριιοτθΛΛίπιβοκΗίΠΡΟΛΥΚΤ Η ΠρΟΜΗΒΘΛΜ βΓΟ ΜΗΟΓΟΚρβΤΗΟ ΜβΤΘΗΟΛΟΜ. 1 r acejiTO-icpacHoro aaoKpacHTejiH ομθιπηβ3λη c 80 γ 70%-ηογοΚΟΜ2ΙΟ4ΒΗΟΓΟ paCTBOpa HpO CTpaHCTBeHHO ΟΙΠΗΤΟΜ ΜβΤΜΛφθΗΙΟΟΗΛΜ-ΚΟΗΟΒΟϋ CMOJIH. 3θΤβΜ Β φθρΜβ ΠρΜ 80 °C paCTBOpH CMJIHKOHOBOÍÍCMOJta noflcyraHBajiH μ nocjie θτογο ocTaBJuuíM OTBepflesaTb οκολο3 qac. npM 250°C. nojiynajm npoepaMHyro, oicpanieHHyro b acejiTo-KpaCHHft ΗΒβΤ OTJIMBKy CHJIHKOHOBOÍÍ CMOJIH. <?
ΦΟΡΓΜΑ PI30BPSTEHHH 1.
Cnocoó nouryxieHiiH hobhx xpeMHHňcoAepaamnx aaoxpacirrejieM αλη oKpamHBaHHfl ποαημθρηηχ opraHimecKHx m HeopraHwxecKux coe- ΛΖΗβΗΗϋ, a Taxae HaTypajibHHX κ οκΗτβτκ^βοχκχ βολοχοη, οτλμ^ϊθ KEJHAcH ΤβΜ, ΗΤΟ CHJI8HH ΜΛΗ CMJIOKCaHH O6iqeÍ5 φΟρωγΛΚ• » X - Si - Z - 1CH - 2CHo - ΝΗ - Ara i f 2
ÍL· OH 3-a nyTeM peaKXíMM C COeAHHeHHflMH apMJIflMaSOHMH OÓmefi φορΜγΛΗ4 - Ar npeBpamarorca b ββοκρθοκτβΛΜ odměň φορωγΛΗ X - Si - Z - ^CH - 2CH-, - KH - Ar - ÍN = N - Árl „ a < i 2 L 4 π
Va 0H r^e pBeTooOpasysauMe κομποηθητη nocpeACTBOM ΓΟΜβοποΛΗρΗκχ cbh3eň coeAMHeHH c aTOMaMW κρθμημη u oČosHatiasiT: X » oAHHaKOBHe ηλη ρβ3Λκ“«ϊΗΗβ rMApomMeyeiatne ‘rpynnn ujím ch-jiOKcaHOBiiií pa^MKaji, Z = AByxBajieHTHHíí ajiKiuibHHň paAHxaji c 2 - 10 θτομθμη yrjie- pofla, χοτορκϋ MoaeT 3axaHHHBaTbCH aTOMSMH XHcmopoAa η/ηλη μοοκθτ coAepataTb anHqnKJnmecxMe 3BeHbji, h Tax2 ae xax m C Moryr odpasoBHBaTb 3BeHbs niixjioajrKHJibHorokojí bu; a, R = oahobaaeHTHErS opraHHqecxHň paAwxaji,
Ar = 3aMemeHHníí ujím He3aMemeHHHň apoMaTHHecxHň paAWxaji, a = ρβΛΗβ nKCjra οτ 1 ao 3 κ n = HH3xoe qejioe hhcjio. 2.
Cnocod no nyHxry 1, OTjumaxmjiíicíi τβΜ, hto οηλθη ujím οηλοκοθη co^epscarr ajiKaHOjroBue rpynmj 3.
Cnocoó no nyHKTy 1, oTJinxiasniníicH τθμ, ητο ομλθη mjih chjiokcaH coflepacaT nHKJioajiKaHOjioBHe rpynnH. 4.
Cnocoó no nyHKTQM 1-3, OTJiKHa®inHiícH τθμ, hto peaKnna προτβκθβτ b npucyTCTBMM HaTypajibHHx hjih οηητθτηηθοκηχ bojiokoh,h 0Ópá3yxmHecfl ρθβκτηβηηθ KpacHTejin TOTnac ace οβηβηβθκτοηC ΒΟΛΟΚΗΘΜΜ. 5.
Cnocoó no nyHKTaM 1-3, oTJiHHaBmHiícH τθμ, ητο προπητθηηηθcooTBeTCTBymmiíMM cmíaHaMH kjik cHjioKcaHaMH HaTypajibHue' hjihcηητθτηηθοκηθ BOJioKHa pearnpyKT c θβοοοθληηθηηημη. 40
AHHQTAIW
KpeMHHiicoBepsamite a30KpacMTe^M oSmeii φορωγΛΗ X - Si - Z - ^-CH - 2CHo - NH - Ar - Γ- N = N - Ar] n .a j , Z u J n
OH 3-a r^e X osHanaeT rwApojiMayeMy© rpynny ho cwjioKcaHOBníi pa^w-Kajx h Z-azcKiuiasHOBafl rpynna, co,nepa:aníaa b jjjaHHOM cjiy^ae hmx-jiM-qecKMe κομποηθητηγ, πρηγοληβιθ τβκκθ η b βμ^θ οττβΗοςΗυχnaCT ΛΛΗ ΟΚρθΙΠΜΒΒΗΜίϊ ΠΟΛΗΜβρΗΗΧ ΟρΓΘΗΗηβCKMX Μ ΗβΟρΓβΗΚΧίβ CKMXοοβΛΜΗβΗΗδ, ocoSeHso cHJiHKOHOBEix npo£yKTOB, a τβκοκβ β KanecT-Ββ peaKTHBHHX ΚρβΟΗΤβΛβϋ ftM HaTypajIhHHX Η ΟΗΗΤβΤΗΠβΟΚΗΧBOJiOKOH. OKpamMBaKmMíi κομποηθητ npw βτομ BCTpaMBaeTCH βnoJiHMepHys> MO-aeKyjiy nocpe^CTBOM roMeonojrapnoii cbash.
HojiyneHne a30KpacnTeJieií jrerieo peanneyeTcsi nocpe^cTBOM peaK-quH cHJianoB hjih cnjioKcaHOB očmeíi ^opMyjiH X -Si - Z - ^CH - 2CHo - KH - Ara í , 2
K3-a OH C flMaSOTMpOBaHHHMM apOM8TH^eCKJOíÍI aMHHaMH ( COJISMH ληθθοηηη) .0Cpa3OBaHMe KpacHTexa MoaceT Shtb τβκχβ προΒβΑβΗο Ha βολοκ-Hax, eCJIM OHM npeflBapHTeJtbHO ΠρΟΠΜΤΒΙΒΗίΟΤΟΗ ΟΗΛβΗΟΒΗΜΙΪ hjihCHJXOKCaHOBHMH ΟΟβ^ΗΗβΗΗΗΜΗ ·
I
Claims (5)
- PŘEDMĚT VYNÁLEZU1. Způsob výroby nových azobarviv obsahujících křemík probarvení polymerních organických a anorganických slou-čenin a rovněž přírodních a syntetických vláken, vyzna-čující se tím, že se silany nebo siloxany obecnéhovzorce X — Si — Z — 1GH — 2CHo - NH - Ara j , 2 R3-a 0H nechávají reagovat aryl s diazoniovými sloučeninamiobecného vzorce - Ar za vzniku azobarviva obecného vzorce I XQ - Si - Z - "^CH - 2CHo - NH - Ar -/N=N-Ar/„a [2 *3-a OH (I) •kde jsou složky tvořící barvivo spojeny homeopolárnímivazbami s atomy křemíku a kde značí X stejné nebo rozdílné hydrolyzovatelné skupiny nebosiloxanový radikál, Z dvojvazný alkylový radikál se 2 až 10 atomi uhlíku, který může být zakončen atomy kyslíku a/nebo může1 2 obsahovat cyklické členy a C jakož i C mohou býtčleny cykloalkylového kruhu. R jednovazný organický radikál, Ar substituovaný nebo nesubstituovaný aromatický radikála celá čísla od 1 do 3,n nízké celé číslo. +2-
- 2. Způsob podle bodu 1, vyznačující se tím, že se používajísílaný nebo siloxany obsahující alkanolové skupiny.
- 3. Způsob podle bodu 1, vyznačující se tím, že se používajísílaný nebo siloxany obsahující cykloalkanolové skupiny.
- 4. Způsob podle bodů 1 až 3, vyznačující se tím, že reakceprobíhá v přítomnosti přírodních neb syntetických vlákena vznikající reaktivní barviva se současně reagují svlákny.
- 5. Způsob podle bodů 1 až 3, vyznačující se tím, že přírod-ní nebo syntetická vlákna impregnovaná silany nebo silo-xany se nechávají reagovat s diazoniovými sloučeninami. Uznáno vynálezem na základě výsledků expertizy, provedenéÚřadem pro vynálezectví a patentnictví, Berlín, DD
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| Application Number | Priority Date | Filing Date | Title |
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| DD20458878A DD141678B1 (de) | 1978-04-05 | 1978-04-05 | Siliziumhaltige nitrofarbstoffe |
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| CS218886B1 true CS218886B1 (en) | 1983-02-25 |
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| Application Number | Title | Priority Date | Filing Date |
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| CS791667A CS218886B1 (en) | 1978-04-05 | 1979-03-12 | Method of preparation of the new azodyes containing the silicon |
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| US (1) | US4405801A (cs) |
| JP (1) | JPS54148023A (cs) |
| BE (1) | BE875160A (cs) |
| CS (1) | CS218886B1 (cs) |
| DD (1) | DD141678B1 (cs) |
| DE (1) | DE2908205A1 (cs) |
| FR (1) | FR2421935A1 (cs) |
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| EP0283206A3 (en) * | 1987-03-12 | 1990-08-22 | Hewlett-Packard Company | Covalently labeled siloxane polymers |
| US5070158A (en) * | 1987-03-12 | 1991-12-03 | Hewlett-Packard Company | Covalently labeled siloxane polymers |
| FR2746102B1 (fr) * | 1996-03-18 | 1998-04-30 | Colorants siloxaniques, compositions les contenant et utilisations | |
| US5789515A (en) * | 1997-03-13 | 1998-08-04 | Milliken Research Corporation | Polysiloxane-poly(oxyalkylene) copolymer-substituted colorant |
| DE102006027533A1 (de) * | 2006-06-14 | 2007-12-20 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Farbige Organopolysiloxane |
| DE102006046465A1 (de) * | 2006-09-29 | 2008-04-03 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Farbige Organopolysiloxane |
| EP2155805A2 (en) * | 2007-05-11 | 2010-02-24 | Basf Se | Polymeric dyes |
| JP5851336B2 (ja) * | 2012-05-09 | 2016-02-03 | オリンパス株式会社 | 複合ゴム材料、成形体、複合ゴム材料の製造方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2756246A (en) * | 1954-02-08 | 1956-07-24 | Gen Electric | Nitro derivatives of organosilicon compounds |
| US2985680A (en) * | 1959-08-03 | 1961-05-23 | Union Carbide Corp | Nitro and nitrito derivatives of organosilicon compounds |
| US3375218A (en) * | 1962-12-07 | 1968-03-26 | Union Carbide Corp | Nitroarylsilanes and siloxanes |
| US3731205A (en) * | 1972-03-23 | 1973-05-01 | Embhart Corp | Sequence detector circuit |
| US4139403A (en) * | 1977-08-19 | 1979-02-13 | The United States Of America As Represented By The Secretary Of The Navy | Dinitroalkyl and fluorodinitroalkyl silicon compounds |
-
1978
- 1978-04-05 DD DD20458878A patent/DD141678B1/de not_active IP Right Cessation
-
1979
- 1979-03-02 DE DE19792908205 patent/DE2908205A1/de not_active Withdrawn
- 1979-03-07 SU SU797770488A patent/SU1017706A1/ru active
- 1979-03-12 CS CS791667A patent/CS218886B1/cs unknown
- 1979-03-23 GB GB7910304A patent/GB2018797B/en not_active Expired
- 1979-03-28 BE BE0/194271A patent/BE875160A/xx unknown
- 1979-04-04 FR FR7908521A patent/FR2421935A1/fr not_active Withdrawn
- 1979-04-05 JP JP4152679A patent/JPS54148023A/ja active Pending
-
1982
- 1982-06-24 US US06/391,657 patent/US4405801A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| GB2018797B (en) | 1982-08-04 |
| GB2018797A (en) | 1979-10-24 |
| US4405801A (en) | 1983-09-20 |
| FR2421935A1 (fr) | 1979-11-02 |
| JPS54148023A (en) | 1979-11-19 |
| DD141678B1 (de) | 1980-12-24 |
| DD141678A1 (de) | 1980-05-14 |
| DE2908205A1 (de) | 1979-10-18 |
| BE875160A (fr) | 1979-07-16 |
| SU1017706A1 (ru) | 1983-05-15 |
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