CS199271B2 - Process for preparing synthesis gas - Google Patents
Process for preparing synthesis gas Download PDFInfo
- Publication number
- CS199271B2 CS199271B2 CS758215A CS821575A CS199271B2 CS 199271 B2 CS199271 B2 CS 199271B2 CS 758215 A CS758215 A CS 758215A CS 821575 A CS821575 A CS 821575A CS 199271 B2 CS199271 B2 CS 199271B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- tar
- coal
- gas
- solids
- soot
- Prior art date
Links
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 13
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 239000007789 gas Substances 0.000 claims abstract description 67
- 239000003245 coal Substances 0.000 claims abstract description 42
- 238000002485 combustion reaction Methods 0.000 claims abstract description 32
- 239000007787 solid Substances 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims abstract description 25
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 20
- 239000001301 oxygen Substances 0.000 claims abstract description 20
- 239000004071 soot Substances 0.000 claims abstract description 16
- 238000002309 gasification Methods 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000006229 carbon black Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 22
- 229910001868 water Inorganic materials 0.000 abstract description 21
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003830 anthracite Substances 0.000 abstract description 2
- 239000003077 lignite Substances 0.000 abstract description 2
- 239000002802 bituminous coal Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000011269 tar Substances 0.000 description 72
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 26
- 235000019241 carbon black Nutrition 0.000 description 19
- 229910002092 carbon dioxide Inorganic materials 0.000 description 13
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 11
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 11
- 239000002956 ash Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000872198 Serjania polyphylla Species 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 102100031830 Afadin- and alpha-actinin-binding protein Human genes 0.000 description 1
- 101710182459 Afadin- and alpha-actinin-binding protein Proteins 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 239000011286 gas tar Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
- C10J3/64—Processes with decomposition of the distillation products
- C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/78—High-pressure apparatus
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
- C10J2300/0976—Water as steam
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
- C10J2300/1823—Recycle loops, e.g. gas, solids, heating medium, water for synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1892—Heat exchange between at least two process streams with one stream being water/steam
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NLAANVRAGE7415842,A NL189517C (nl) | 1974-12-05 | 1974-12-05 | Werkwijze voor de bereiding van synthesegas. |
Publications (1)
Publication Number | Publication Date |
---|---|
CS199271B2 true CS199271B2 (en) | 1980-07-31 |
Family
ID=19822594
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CS758215A CS199271B2 (en) | 1974-12-05 | 1975-12-03 | Process for preparing synthesis gas |
Country Status (14)
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8322899D0 (en) * | 1983-08-25 | 1983-09-28 | British Gas Corp | Coal gasification process |
DE4226034C1 (de) * | 1992-08-06 | 1994-02-17 | Schwarze Pumpe Energiewerke Ag | Kombiniertes Verfahren zur Vergasung von festen, pastösen und flüssigen Rest- und/oder Abfallstoffen |
DE4226033C2 (de) * | 1992-08-06 | 1995-11-30 | Lausitzer Bergbau Verwalt Gmbh | Verfahren zum Dekontaminieren von Böden und Bauschutt |
DE4226032C1 (de) * | 1992-08-06 | 1994-01-27 | Schwarze Pumpe Energiewerke Ag | Verfahren zur kombinierten Verwertung von feinkörnigen festen und pastösen Abfallstoffen im Prozeß der Festbettdruckvergasung |
EP2205701A4 (en) * | 2007-10-09 | 2011-10-26 | Rentech Inc | SYSTEMS AND METHODS FOR OXIDATION OF SYNTHESIS GAS TARS |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE343815C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | ||||
DD74071A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | ||||
DE447982C (de) * | 1922-12-21 | 1927-08-05 | Naamlooze Vennootschap Handels | Verfahren zur Verschwelung und Vergasung von Torf, Braunkohle, Sapropel und aehnlichen bitumenhaltigen Stoffen |
DE582539C (de) * | 1927-12-07 | 1933-08-16 | Harald Kemmer Dr Ing | Verfahren zur Katalysierung fester stueckiger Brennstoffe |
DE661927C (de) * | 1935-04-28 | 1938-06-30 | E Roser Dr | Verfahren zum Betriebe von Gaserzeugern mit absteigendem Zug fuer Fahrzeuge |
DE895204C (de) * | 1943-06-08 | 1953-11-02 | Basf Ag | Verfahren zur Erzeugung von Wasserstoff-Kohlenoxyd-Gemischen, insbesondere fuer Synthesezwecke |
DE914537C (de) * | 1944-08-11 | 1954-07-05 | Braunkohle Benzin Ag | Verfahren zum Verarbeiten von Briketts aus Abfallteeren, Druckhydrierungsrueckstaenden od. dgl. und teerfreien Brennstoffen, wie Multiklonstaub, Generatorasche u. dgl. |
DE1086000B (de) * | 1953-01-13 | 1960-07-28 | Ruhrgas Ag | Verfahren zur Abfilterung feiner Brennstoffanteile aus dem Gasstrom von Gaserzeugern |
DE2044310C3 (de) * | 1970-09-08 | 1974-01-31 | Texaco Development Corp., New York, N.Y. (V.St.A.) | Verfahren zur Herstellung von Kohlenmonoxid und Wasserstoff aus festem Brennstoff |
DE2130120B2 (de) * | 1971-06-18 | 1980-04-30 | Texaco Development Corp., White Plains, N.Y. (V.St.A.) | Verfahren zur Herstellung von Synthesegas |
NL171435C (nl) * | 1971-06-30 | 1983-04-05 | Shell Int Research | Werkwijze voor de onvolledige verbranding van een vrije en/of gebonden koolstof-bevattende brandstof tot een koolmonoxyde en waterstof-bevattend gas in een bij relatief lage druk bedreven reactor. |
-
1974
- 1974-12-05 NL NLAANVRAGE7415842,A patent/NL189517C/xx not_active IP Right Cessation
-
1975
- 1975-09-16 CA CA235,741A patent/CA1073211A/en not_active Expired
- 1975-09-17 IN IN1783/CAL/1975A patent/IN140976B/en unknown
- 1975-11-26 BE BE1007031A patent/BE835942A/xx not_active IP Right Cessation
- 1975-12-03 JP JP50143031A patent/JPS6020436B2/ja not_active Expired
- 1975-12-03 PL PL1975185203A patent/PL100733B1/pl unknown
- 1975-12-03 ES ES443177A patent/ES443177A1/es not_active Expired
- 1975-12-03 CS CS758215A patent/CS199271B2/cs unknown
- 1975-12-03 FR FR7536989A patent/FR2293483A1/fr active Granted
- 1975-12-03 BR BR7508018*A patent/BR7508018A/pt unknown
- 1975-12-03 IT IT7529974A patent/IT1051040B/it active
- 1975-12-03 DE DE2554419A patent/DE2554419C2/de not_active Expired
- 1975-12-03 DD DD189848A patent/DD121797A5/xx unknown
- 1975-12-03 GB GB49639/75A patent/GB1528368A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB1528368A (en) | 1978-10-11 |
NL189517C (nl) | 1993-05-03 |
ES443177A1 (es) | 1977-04-16 |
JPS5182301A (en) | 1976-07-19 |
CA1073211A (en) | 1980-03-11 |
FR2293483B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1980-05-30 |
NL189517B (nl) | 1992-12-01 |
JPS6020436B2 (ja) | 1985-05-22 |
DE2554419A1 (de) | 1976-06-10 |
FR2293483A1 (fr) | 1976-07-02 |
DD121797A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1976-08-20 |
NL7415842A (nl) | 1976-06-09 |
AU8722775A (en) | 1977-06-09 |
DE2554419C2 (de) | 1984-06-20 |
IN140976B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1977-01-08 |
BR7508018A (pt) | 1976-08-24 |
PL100733B1 (pl) | 1978-11-30 |
IT1051040B (it) | 1981-04-21 |
BE835942A (nl) | 1976-05-26 |
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