CN87107909A - 四氟乙烯聚合方法 - Google Patents
四氟乙烯聚合方法 Download PDFInfo
- Publication number
- CN87107909A CN87107909A CN198787107909A CN87107909A CN87107909A CN 87107909 A CN87107909 A CN 87107909A CN 198787107909 A CN198787107909 A CN 198787107909A CN 87107909 A CN87107909 A CN 87107909A CN 87107909 A CN87107909 A CN 87107909A
- Authority
- CN
- China
- Prior art keywords
- chain transfer
- ccl
- cclf
- transfer agent
- tetrafluoroethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 238000006116 polymerization reaction Methods 0.000 title abstract description 19
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 12
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- -1 alkyl vinyl ether Chemical compound 0.000 claims abstract description 9
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000001294 propane Substances 0.000 claims abstract description 5
- 239000012986 chain transfer agent Substances 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 15
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical group FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- 239000000155 melt Substances 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 125000001153 fluoro group Chemical group F* 0.000 claims description 3
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 2
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 39
- 229920000642 polymer Polymers 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000003999 initiator Substances 0.000 description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000004566 IR spectroscopy Methods 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical class FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NHJFHUKLZMQIHN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanoyl 2,2,3,3,3-pentafluoropropaneperoxoate Chemical group FC(F)(F)C(F)(F)C(=O)OOC(=O)C(F)(F)C(F)(F)F NHJFHUKLZMQIHN-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000008707 rearrangement Effects 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- GWTYBAOENKSFAY-UHFFFAOYSA-N 1,1,1,2,2-pentafluoro-2-(1,2,2-trifluoroethenoxy)ethane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)F GWTYBAOENKSFAY-UHFFFAOYSA-N 0.000 description 1
- RKIMETXDACNTIE-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,5,5,6,6-dodecafluorocyclohexane Chemical compound FC1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F RKIMETXDACNTIE-UHFFFAOYSA-N 0.000 description 1
- TXGPGHBYAPBDAG-UHFFFAOYSA-N 1,1,2,2,3,3-hexafluoro-4,4-bis(trifluoromethyl)cyclobutane Chemical compound FC(F)(F)C1(C(F)(F)F)C(F)(F)C(F)(F)C1(F)F TXGPGHBYAPBDAG-UHFFFAOYSA-N 0.000 description 1
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical compound FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 description 1
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 229910001347 Stellite Inorganic materials 0.000 description 1
- NKRHXEKCTWWDLS-UHFFFAOYSA-N [W].[Cr].[Co] Chemical compound [W].[Cr].[Co] NKRHXEKCTWWDLS-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001265 acyl fluorides Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- AHICWQREWHDHHF-UHFFFAOYSA-N chromium;cobalt;iron;manganese;methane;molybdenum;nickel;silicon;tungsten Chemical compound C.[Si].[Cr].[Mn].[Fe].[Co].[Ni].[Mo].[W] AHICWQREWHDHHF-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- BCCOBQSFUDVTJQ-UHFFFAOYSA-N octafluorocyclobutane Chemical compound FC1(F)C(F)(F)C(F)(F)C1(F)F BCCOBQSFUDVTJQ-UHFFFAOYSA-N 0.000 description 1
- 235000019407 octafluorocyclobutane Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
- C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US93361686A | 1986-11-21 | 1986-11-21 | |
| US933,616 | 1986-11-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN87107909A true CN87107909A (zh) | 1988-06-01 |
Family
ID=25464238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN198787107909A Pending CN87107909A (zh) | 1986-11-21 | 1987-11-21 | 四氟乙烯聚合方法 |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0271243B1 (enExample) |
| JP (1) | JPS63150308A (enExample) |
| CN (1) | CN87107909A (enExample) |
| DE (1) | DE3774247D1 (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1294154C (zh) * | 2000-06-19 | 2007-01-10 | 杜邦三井氟化物有限公司 | 用于制备四氟乙烯和全氟代(烷基乙烯基醚)的共聚物的方法 |
| CN101563408B (zh) * | 2006-12-21 | 2013-03-13 | 纳幕尔杜邦公司 | 可发泡含氟聚合物的挤出方法 |
| CN110010283A (zh) * | 2012-03-26 | 2019-07-12 | 索尔维特殊聚合物意大利有限公司 | 井下电缆 |
| CN111349946A (zh) * | 2018-12-21 | 2020-06-30 | 旭化成株式会社 | 阳离子交换膜、含氟系聚合物、含氟系聚合物的制造方法以及电解槽 |
| CN111533929A (zh) * | 2019-02-07 | 2020-08-14 | 富士施乐株式会社 | 含氟树脂粒子、组合物、层状物、电子照相感光体、处理盒及图像形成装置 |
| CN116867814A (zh) * | 2021-02-26 | 2023-10-10 | 大金工业株式会社 | 共聚物、成型体、注射成型体和被覆电线 |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1263955B (it) * | 1993-02-23 | 1996-09-05 | Ausimont Spa | Processo di (co) polimerizzazione radicalica di monomeri olefinici fluorurati |
| DE69421021T2 (de) * | 1993-03-17 | 2000-01-20 | Asahi Glass Co. Ltd., Tokio/Tokyo | Verfahren zur herstellung eines fluorpolymers |
| DE4331971A1 (de) * | 1993-09-21 | 1995-03-23 | Hoechst Ag | Polytetrafluorethylen-Mikropulver, ihre Herstellung und Verwendung |
| AU2003297458A1 (en) | 2002-12-20 | 2004-07-22 | Exxonmobil Chemical Patents Inc. | Polymerization processes |
| ATE469923T1 (de) | 2002-12-20 | 2010-06-15 | Exxonmobil Chem Patents Inc | Polymere mit neuen sequenzverteilungen |
| US7723447B2 (en) | 2002-12-20 | 2010-05-25 | Exxonmobil Chemical Patents Inc. | Polymerization processes |
| US7425601B2 (en) | 2002-12-20 | 2008-09-16 | Exxonmobil Chemical Patents Inc. | Polymers with new sequence distributions |
| WO2006009945A1 (en) | 2004-06-21 | 2006-01-26 | Exxonmobil Chemical Patents Inc. | Impact copolymers |
| WO2006009942A1 (en) | 2004-06-21 | 2006-01-26 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| US7858736B2 (en) | 2004-06-21 | 2010-12-28 | Exxonmobil Chemical Patents Inc. | Polymer recovery method |
| US7981984B2 (en) | 2004-06-21 | 2011-07-19 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| US7799882B2 (en) | 2005-06-20 | 2010-09-21 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| CN117447635A (zh) | 2018-09-28 | 2024-01-26 | 东曹株式会社 | 氟树脂、氟树脂粒子及它们的制造方法 |
| JP7559864B2 (ja) * | 2018-09-28 | 2024-10-02 | 東ソー株式会社 | フッ素樹脂粒子およびその製造方法 |
| US11643516B2 (en) | 2018-12-21 | 2023-05-09 | Asahi Kasei Kabushiki Kaisha | Cation exchange membrane, fluorine-containing polymer, method for producing fluorine-containing polymer, and electrolyzer |
| JP2020128521A (ja) * | 2019-02-07 | 2020-08-27 | 富士ゼロックス株式会社 | フッ素含有樹脂粒子、組成物、層状物、電子写真感光体、プロセスカートリッジ、および画像形成装置 |
| WO2022181229A1 (ja) * | 2021-02-26 | 2022-09-01 | ダイキン工業株式会社 | 共重合体、成形体、射出成形体および被覆電線 |
| JP7177375B2 (ja) * | 2021-02-26 | 2022-11-24 | ダイキン工業株式会社 | 共重合体、成形体、射出成形体および被覆電線 |
| CN118165587A (zh) * | 2024-04-09 | 2024-06-11 | 福建海德福新材料有限公司 | 一种可熔性聚四氟乙烯涂料及其制备方法、涂膜工件 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1072810B (de) * | 1955-12-05 | 1960-01-07 | E. I. Du Pont De Nemours And Company, Wilmington, Del. (V. St. A.) | Verfahren zur Polymerisation oder Mischpolymerisation von perfluorierten olefinisch ungesättigten Verbindungen, besonders von Tetrafluoräthylen |
| US3635926A (en) * | 1969-10-27 | 1972-01-18 | Du Pont | Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers |
-
1987
- 1987-11-20 EP EP19870310275 patent/EP0271243B1/en not_active Expired
- 1987-11-20 DE DE8787310275T patent/DE3774247D1/de not_active Expired - Lifetime
- 1987-11-20 JP JP29220987A patent/JPS63150308A/ja active Granted
- 1987-11-21 CN CN198787107909A patent/CN87107909A/zh active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1294154C (zh) * | 2000-06-19 | 2007-01-10 | 杜邦三井氟化物有限公司 | 用于制备四氟乙烯和全氟代(烷基乙烯基醚)的共聚物的方法 |
| CN101563408B (zh) * | 2006-12-21 | 2013-03-13 | 纳幕尔杜邦公司 | 可发泡含氟聚合物的挤出方法 |
| CN110010283A (zh) * | 2012-03-26 | 2019-07-12 | 索尔维特殊聚合物意大利有限公司 | 井下电缆 |
| CN111349946A (zh) * | 2018-12-21 | 2020-06-30 | 旭化成株式会社 | 阳离子交换膜、含氟系聚合物、含氟系聚合物的制造方法以及电解槽 |
| CN111349946B (zh) * | 2018-12-21 | 2022-04-12 | 旭化成株式会社 | 阳离子交换膜、含氟系聚合物、含氟系聚合物的制造方法以及电解槽 |
| CN111533929A (zh) * | 2019-02-07 | 2020-08-14 | 富士施乐株式会社 | 含氟树脂粒子、组合物、层状物、电子照相感光体、处理盒及图像形成装置 |
| CN116867814A (zh) * | 2021-02-26 | 2023-10-10 | 大金工业株式会社 | 共聚物、成型体、注射成型体和被覆电线 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3774247D1 (de) | 1991-12-05 |
| JPS63150308A (ja) | 1988-06-23 |
| JPH0142966B2 (enExample) | 1989-09-18 |
| EP0271243B1 (en) | 1991-10-30 |
| EP0271243A1 (en) | 1988-06-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |