CN85101103A - 共聚物的制备方法 - Google Patents
共聚物的制备方法 Download PDFInfo
- Publication number
- CN85101103A CN85101103A CN 85101103 CN85101103A CN85101103A CN 85101103 A CN85101103 A CN 85101103A CN 85101103 CN85101103 CN 85101103 CN 85101103 A CN85101103 A CN 85101103A CN 85101103 A CN85101103 A CN 85101103A
- Authority
- CN
- China
- Prior art keywords
- peroxide
- butyl
- organo
- difunctionality
- multipolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title description 4
- 238000000034 method Methods 0.000 claims abstract description 16
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000012662 bulk polymerization Methods 0.000 claims abstract description 9
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims abstract description 7
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 claims abstract description 7
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 claims abstract description 7
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 7
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 21
- 238000005502 peroxidation Methods 0.000 claims description 19
- -1 butoxy free radical Chemical class 0.000 claims description 17
- 239000003999 initiator Substances 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 7
- YOKNOQAJQSOMKV-UHFFFAOYSA-N 3-butyl-1,1,5-trimethylcyclohexane Chemical group CCCCC1CC(C)CC(C)(C)C1 YOKNOQAJQSOMKV-UHFFFAOYSA-N 0.000 claims description 2
- 230000009466 transformation Effects 0.000 abstract description 12
- 238000006243 chemical reaction Methods 0.000 abstract description 11
- 229920001577 copolymer Polymers 0.000 abstract description 6
- 150000003254 radicals Chemical class 0.000 abstract description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 description 17
- 229920005989 resin Polymers 0.000 description 17
- 238000006116 polymerization reaction Methods 0.000 description 13
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 12
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- ODCCJTMPMUFERV-UHFFFAOYSA-N ditert-butyl carbonate Chemical compound CC(C)(C)OC(=O)OC(C)(C)C ODCCJTMPMUFERV-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 description 4
- 239000001506 calcium phosphate Substances 0.000 description 4
- 229910000389 calcium phosphate Inorganic materials 0.000 description 4
- 235000011010 calcium phosphates Nutrition 0.000 description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 4
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004342 Benzoyl peroxide Substances 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 238000010557 suspension polymerization reaction Methods 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- RSYMCXSNBMYCQX-UHFFFAOYSA-N C(OC(C)(C)C)(OC(C)(C)C)=O.C(CCCC(=O)O)(=O)O Chemical compound C(OC(C)(C)C)(OC(C)(C)C)=O.C(CCCC(=O)O)(=O)O RSYMCXSNBMYCQX-UHFFFAOYSA-N 0.000 description 1
- UIAAMMUJTCPWIP-UHFFFAOYSA-N C(OC(C)(C)C)(OC(C)(C)C)=O.C(CCCCCCCCC(=O)O)(=O)O Chemical compound C(OC(C)(C)C)(OC(C)(C)C)=O.C(CCCCCCCCC(=O)O)(=O)O UIAAMMUJTCPWIP-UHFFFAOYSA-N 0.000 description 1
- VXSADCZMYYQMTB-UHFFFAOYSA-N C(OC(C)(C)C)(OC(C)(C)C)=O.CC(C(C(=O)O)(C)C)CCC(=O)O Chemical compound C(OC(C)(C)C)(OC(C)(C)C)=O.CC(C(C(=O)O)(C)C)CCC(=O)O VXSADCZMYYQMTB-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229960001708 magnesium carbonate Drugs 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 229910000400 magnesium phosphate tribasic Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical group CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
Landscapes
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6306384A JPS60203612A (ja) | 1984-03-29 | 1984-03-29 | 共重合体の製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN85101103A true CN85101103A (zh) | 1987-01-17 |
Family
ID=13218504
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 85101103 Pending CN85101103A (zh) | 1984-03-29 | 1985-04-01 | 共聚物的制备方法 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS60203612A (enExample) |
| CN (1) | CN85101103A (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101072803B (zh) * | 2004-12-11 | 2010-06-16 | Lg化学株式会社 | 一种透明共聚物树脂、其制备方法及包含该透明共聚物树脂的树脂混合物组合物 |
| CN102695729A (zh) * | 2009-12-29 | 2012-09-26 | 第一毛织株式会社 | 具有优良透明度、流动性和耐划擦性能的丙烯酸类树脂 |
| CN102924642A (zh) * | 2012-05-22 | 2013-02-13 | 中国石油集团东北炼化工程有限公司吉林设计院 | 一种提高苯乙烯-丙烯腈共聚反应中丙烯腈转化率的装置 |
| CN101711261B (zh) * | 2007-06-15 | 2013-05-29 | 韩国锦湖石油化学株式会社 | 具有低熔融粘度的基于马来酰亚胺-α-烷基苯乙烯的三元共聚物以及用于生产它的连续本体方法 |
| CN103183762A (zh) * | 2011-12-29 | 2013-07-03 | 奇美实业股份有限公司 | 苯乙烯-α-甲基苯乙烯-丙烯腈系共聚物以及橡胶改性苯乙烯系树脂 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH072814B2 (ja) * | 1986-05-21 | 1995-01-18 | 化薬アクゾ株式会社 | α−メチルスチレン−アクリロニトリル共重合体の製造方法 |
| JPH0717716B2 (ja) * | 1986-05-30 | 1995-03-01 | 日本合成ゴム株式会社 | 共重合体の製造方法 |
| JP6210254B2 (ja) * | 2014-04-25 | 2017-10-11 | エルジー・ケム・リミテッド | 耐熱性スチレン系共重合体及びこれを含むスチレン系樹脂組成物 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS595605B2 (ja) * | 1975-10-02 | 1984-02-06 | 新日鐵化学株式会社 | スチレン−アクリロニトリル共重合体の製造方法 |
| JPS6023685B2 (ja) * | 1976-08-28 | 1985-06-08 | 日本油脂株式会社 | スチレン系重合体の製造法 |
| US4169195A (en) * | 1976-12-29 | 1979-09-25 | Borg-Warner Corporation | Process for preparing alpha-methylstyrene polymers |
| JPS54150493A (en) * | 1978-05-18 | 1979-11-26 | Nippon Oil & Fats Co Ltd | Production of styrene polymer or copolymer |
| JPS55725A (en) * | 1978-06-19 | 1980-01-07 | Denki Kagaku Kogyo Kk | Copolymerization |
| JPS56167706A (en) * | 1980-05-30 | 1981-12-23 | Denki Kagaku Kogyo Kk | Polymerization of styrene type monomer |
-
1984
- 1984-03-29 JP JP6306384A patent/JPS60203612A/ja active Granted
-
1985
- 1985-04-01 CN CN 85101103 patent/CN85101103A/zh active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101072803B (zh) * | 2004-12-11 | 2010-06-16 | Lg化学株式会社 | 一种透明共聚物树脂、其制备方法及包含该透明共聚物树脂的树脂混合物组合物 |
| CN101711261B (zh) * | 2007-06-15 | 2013-05-29 | 韩国锦湖石油化学株式会社 | 具有低熔融粘度的基于马来酰亚胺-α-烷基苯乙烯的三元共聚物以及用于生产它的连续本体方法 |
| CN102695729A (zh) * | 2009-12-29 | 2012-09-26 | 第一毛织株式会社 | 具有优良透明度、流动性和耐划擦性能的丙烯酸类树脂 |
| CN102695729B (zh) * | 2009-12-29 | 2017-03-15 | 第一毛织株式会社 | 具有优良透明度、流动性和耐划擦性能的丙烯酸类树脂 |
| CN103183762A (zh) * | 2011-12-29 | 2013-07-03 | 奇美实业股份有限公司 | 苯乙烯-α-甲基苯乙烯-丙烯腈系共聚物以及橡胶改性苯乙烯系树脂 |
| CN103183762B (zh) * | 2011-12-29 | 2015-08-05 | 奇美实业股份有限公司 | 苯乙烯-α-甲基苯乙烯-丙烯腈系共聚物以及橡胶改性苯乙烯系树脂 |
| CN102924642A (zh) * | 2012-05-22 | 2013-02-13 | 中国石油集团东北炼化工程有限公司吉林设计院 | 一种提高苯乙烯-丙烯腈共聚反应中丙烯腈转化率的装置 |
| CN102924642B (zh) * | 2012-05-22 | 2014-11-26 | 中国石油集团东北炼化工程有限公司吉林设计院 | 一种提高苯乙烯-丙烯腈共聚反应中丙烯腈转化率的装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0125483B2 (enExample) | 1989-05-18 |
| JPS60203612A (ja) | 1985-10-15 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |