CN202576250U - Offline temperable low-radiation coated glass - Google Patents

Offline temperable low-radiation coated glass Download PDF

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CN202576250U
CN202576250U CN201220124329.5U CN201220124329U CN202576250U CN 202576250 U CN202576250 U CN 202576250U CN 201220124329 U CN201220124329 U CN 201220124329U CN 202576250 U CN202576250 U CN 202576250U
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silicon nitride
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coated glass
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顾海波
陈颖玺
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JIANGSU AOLAN ARCHITECTURE GLASS CO Ltd
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Abstract

The utility model relates to offline temperable low-radiation coated glass which comprises a glass substrate. A first silicon nitride Si3N4 layer, a metal nickel-chromium NiCr layer, a metal silver Ag layer, a metal nickel-chromium NiCr layer and a second silicon nitride Si3N4 layer are sequentially arranged on the glass substrate; the glass substrate has the thickness of 3mm to 15mm; the first silicon nitride Si3N4 layer has the thickness of 35nm to 45nm; the former metal nickel-chromium NiCr layer has the thickness of 1.5 to 2.5nm; the metal silver Ag layer has the thickness of 6 to 10nm; the latter metal nickel-chromium NiCr layer has the thickness of 2 to 2.5nm; and the second silicon nitride Si3N4 layer has the thickness of 55 to 65nm. The offline temperable low-radiation coated glass has the advantage that on the basis of implementing the low radiance and the low heat transfer property of a coating, the deep processing such as remote heat treatment and the like can also be implemented.

Description

一种离线可钢低辐射镀膜玻璃An off-line steelable low-emissivity coated glass

技术领域 technical field

本实用新型涉及一种玻璃,特别是一种离线可钢低辐射镀膜玻璃。  The utility model relates to a glass, in particular to an off-line steelable low-radiation coated glass. the

背景技术 Background technique

现有普通离线低辐射镀膜玻璃由于膜系配置采用其他的材料,膜层耐侯性、耐酸碱性都较差,膜层质软,容易氧化,且很难实现异地加工。离线可钢低辐射镀膜玻璃,采用氮化硅Si3N4膜层作为保护层,其对氧气具有很低的扩散系数,有较好的稳定性,针孔密度非常低。磁控溅射沉积的氮化硅膜层致密、平整且硬度很高,对可动离子有非常强的阻挡能力,在1200℃时不发生氧化,有较好的抗蚀性,所以,使用Si3N4膜层作为离线可钢低辐射镀膜玻璃的顶层保护膜,实现离线可钢低辐射镀膜玻璃耐高温的性能,从而实现远程异地化的切割、磨边、钢化、中空等后续加工。  The existing common off-line low-emissivity coated glass adopts other materials for the film system configuration, the weather resistance, acid and alkali resistance of the film layer are poor, the film layer is soft, easy to oxidize, and it is difficult to realize off-site processing. Off-line steelable low-emissivity coated glass, using silicon nitride Si 3 N 4 film as a protective layer, which has a very low diffusion coefficient for oxygen, good stability, and a very low pinhole density. The silicon nitride film deposited by magnetron sputtering is dense, flat and has high hardness. It has a very strong blocking ability for mobile ions. It does not oxidize at 1200 ° C and has good corrosion resistance. Therefore, Si The 3 N 4 film layer is used as the top protective film of the offline steelable low-emissivity coated glass to realize the high temperature resistance of the off-line steelable low-emissivity coated glass, so as to realize the subsequent processing such as cutting, edging, tempering and hollowing in remote locations.

发明内容 Contents of the invention

本实用新型的目的是为了克服普通离线低辐射镀膜玻璃不能进行热处理的不足,提供一种够很强的阻隔红外线,具有很好的隔热功效,同时也能实现异地化后续深加工的离线可钢低辐射镀膜玻璃。  The purpose of this utility model is to overcome the deficiency that ordinary off-line low-radiation coated glass cannot be heat-treated, and to provide a kind of off-line steel that is strong enough to block infrared rays, has good heat insulation effect, and can also realize off-site subsequent deep processing. Low-E coated glass. the

本实用新型的目的通过以下技术方案来实现:一种离线可钢低辐射镀膜玻璃,包括玻璃基片,玻璃基片上依次设有第一氮化硅Si3N4层、金属镍铬NiCr层、金属银Ag层、金属镍铬NiCr层、第二氮化硅Si3N4层。玻璃基片的厚度为3mm~15mm,第一氮化硅Si3N4层的厚度为35nm~45nm,金属镍铬NiCr层的厚度为1.5~2.5nm,金属银Ag层的厚度为6~10nm,金属镍铬NiCr层的厚度为2~2.5nm,第二氮化硅Si3N4层的厚度为55~65nm。 The purpose of this utility model is achieved by the following technical solutions: an off-line steelable low-emissivity coated glass, comprising a glass substrate, the glass substrate is successively provided with a first silicon nitride Si3N4 layer, a metal nickel-chromium NiCr layer, Metal silver Ag layer, metal nickel chromium NiCr layer, second silicon nitride Si 3 N 4 layer. The thickness of the glass substrate is 3mm-15mm, the thickness of the first silicon nitride Si 3 N 4 layer is 35nm-45nm, the thickness of the metal nickel-chromium NiCr layer is 1.5-2.5nm, and the thickness of the metal silver Ag layer is 6-10nm , the thickness of the metal nickel chromium NiCr layer is 2-2.5nm, and the thickness of the second silicon nitride Si 3 N 4 layer is 55-65nm.

本实用新型的进一步改进在于:所述玻璃基片的厚度为3mm~15mm,所述第一氮化硅Si3N4层的厚度为37nm,金属镍铬NiCr层的厚度为1.9nm,金属银Ag层的厚度为8nm,金属镍铬NiCr层的厚度为2.1nm,第二氮化硅Si3N4层的厚度为57nm。 The further improvement of the utility model is that: the thickness of the glass substrate is 3 mm to 15 mm, the thickness of the first silicon nitride Si 3 N 4 layer is 37 nm, the thickness of the metal nickel chromium NiCr layer is 1.9 nm, and the metal silver The thickness of the Ag layer is 8 nm, the thickness of the metal nickel chromium NiCr layer is 2.1 nm, and the thickness of the second silicon nitride Si 3 N 4 layer is 57 nm.

本实用新型与现有技术相比具有以下优点:离线可钢低辐射镀膜玻璃的顶层采用扩散系数很低的氮化硅Si3N4作为保护层,能够使膜层在钢化炉中进行热处理而不使膜层破坏,且保持了原有热工性能,同时将原片也进行了钢化处理,而且生产出来的离线可钢低辐射镀膜玻璃能够很强的阻隔红外线、具有很好的隔热功效,同时也能实现异地化后续深加工。 Compared with the prior art, the utility model has the following advantages: the top layer of off-line steelable low-emissivity coated glass adopts silicon nitride Si 3 N 4 with a very low diffusion coefficient as the protective layer, which can make the film layer heat-treated in the tempering furnace It does not damage the film layer, and maintains the original thermal performance. At the same time, the original film is also tempered, and the produced offline steelable low-emissivity coated glass can strongly block infrared rays and has good heat insulation effect. , At the same time, it can also realize the follow-up deep processing of off-site.

附图说明:Description of drawings:

图1为本实用新型的结构示意图; Fig. 1 is the structural representation of the utility model;

图中标号:1-玻璃基片、2-第一氮化硅Si3N4层、3-金属镍铬NiCr层、4-金属银Ag层、5-金属镍铬NiCr层、6-第二氮化硅Si3N4层。 Symbols in the figure: 1-glass substrate, 2-first silicon nitride Si 3 N 4 layer, 3-metal nickel chromium NiCr layer, 4-metal silver Ag layer, 5-metal nickel chromium NiCr layer, 6-second Silicon nitride Si 3 N 4 layer.

具体实施方式:Detailed ways:

    为了加深对发明的理解,下面将结合实施例对本实用新型作进一步详述,该实施例仅用于解释本实用新型,并不构成对本实用新型保护范围的限定。     In order to deepen the understanding of the invention, the utility model will be further described below in conjunction with the examples, which are only used to explain the utility model, and do not constitute a limitation to the protection scope of the utility model.

如图1所示,本实用新型离线可钢低辐射镀膜玻璃的一种实施方式为:离线可钢低辐射镀膜玻璃包括玻璃基片1,玻璃基片1上依次设有第一氮化硅Si3N4层2、金属镍铬NiCr层3、金属银Ag层4、金属镍铬NiCr层5、第二氮化硅Si3N4层6。玻璃基片1的厚度为3mm~15mm,第一氮化硅Si3N4层2的厚度为35nm~45nm,最佳厚度为37nm,金属镍铬NiCr层3的厚度为1.5~2.5nm,最佳厚度为1.9nm,金属银Ag层4的厚度为6~10nm,最佳厚度为8nm,金属镍铬NiCr层5的厚度为2~2.5nm,最佳厚度为2.1nm,第二氮化硅Si3N4层6的厚度为55~65nm,最佳厚度为57nm。 As shown in Figure 1, an embodiment of the off-line steelable low-emissivity coated glass of the present invention is: the off-line steelable low-emissivity coated glass comprises a glass substrate 1, and the first silicon nitride Si is sequentially arranged on the glass substrate 1 3 N 4 layer 2, metal nickel chromium NiCr layer 3, metal silver Ag layer 4, metal nickel chromium NiCr layer 5, second silicon nitride Si 3 N 4 layer 6. The thickness of the glass substrate 1 is 3mm-15mm, the thickness of the first silicon nitride Si 3 N 4 layer 2 is 35nm-45nm, the optimum thickness is 37nm, the thickness of the metal nickel-chromium NiCr layer 3 is 1.5-2.5nm, the optimum The optimum thickness is 1.9nm, the thickness of the metal silver Ag layer 4 is 6-10nm, the optimum thickness is 8nm, the thickness of the metal nickel-chromium NiCr layer 5 is 2-2.5nm, the optimum thickness is 2.1nm, the second silicon nitride The thickness of the Si 3 N 4 layer 6 is 55-65 nm, and the optimum thickness is 57 nm.

实施例1: Example 1:

在双端离线高真空磁控溅射镀膜设备中,使其基础真空达到10?3Pa,线速度为3.5米/分钟时,在6mm玻璃基片上依次溅射: 37nm的氮化硅Si3N4,1.9nm的金属镍铬NiCr,8nm的金属银Ag,2.1nm的金属镍铬NiCr,57nm的氮化硅Si3N4In the double-ended off-line high-vacuum magnetron sputtering coating equipment, make the basic vacuum reach 10?3Pa, and when the line speed is 3.5 m/min, sequentially sputter on a 6mm glass substrate: 37nm silicon nitride Si 3 N 4 , 1.9nm metallic nickel chromium NiCr, 8nm metallic silver Ag, 2.1nm metallic nickel chromium NiCr, 57nm silicon nitride Si 3 N 4 .

本实用新型的顶层采用扩散系数很低的氮化硅Si3N4作为保护层,能够使膜层在钢化炉中进行热处理而不使膜层破坏,且保持了原有热工性能,同时将原片也进行了钢化处理,而且生产出来的离线可钢低辐射镀膜玻璃能够很强的阻隔红外线、具有很好的隔热功效,同时也能实现异地化后续深加工。 The top layer of the utility model adopts silicon nitride Si 3 N 4 with a very low diffusion coefficient as the protective layer, which can make the film layer heat-treated in the tempering furnace without damaging the film layer, and maintains the original thermal performance. The original film has also been tempered, and the produced off-line steelable low-emissivity coated glass can strongly block infrared rays and has good heat insulation effect, and can also realize subsequent deep processing in different places.

Claims (3)

1.一种离线可钢低辐射镀膜玻璃,包括玻璃基片(1),其特征在于:所述玻璃基片(1)上依次设有第一氮化硅Si3N4层(2)、金属镍铬NiCr层(3)、金属银Ag层(4)、金属镍铬NiCr层(5)、第二氮化硅Si3N4层(6)。 1. An off-line steelable low-emissivity coated glass, comprising a glass substrate (1), characterized in that: the glass substrate (1) is sequentially provided with a first silicon nitride Si 3 N 4 layer (2), Metal nickel chromium NiCr layer (3), metal silver Ag layer (4), metal nickel chromium NiCr layer (5), second silicon nitride Si 3 N 4 layer (6). 2.根据权利要求1所述一种离线可钢低辐射镀膜玻璃,其特征在于:所述玻璃基片(1)的厚度为3mm~15mm,所述第一氮化硅Si3N4层(2)的厚度为35nm~45nm,所述金属镍铬NiCr层(3)的厚度为1.5~2.5nm,所述金属银Ag层(4)的厚度为6~10nm,所述金属镍铬NiCr层(5)的厚度为2~2.5nm,所述第二氮化硅Si3N4层(6)的厚度为55~65nm。 2. An off-line steelable low-emissivity coated glass according to claim 1, characterized in that: the thickness of the glass substrate (1) is 3 mm to 15 mm, and the first silicon nitride Si 3 N 4 layer ( 2) has a thickness of 35nm-45nm, the metal nickel-chromium NiCr layer (3) has a thickness of 1.5-2.5nm, the metal silver Ag layer (4) has a thickness of 6-10nm, and the metal nickel-chromium NiCr layer (5) has a thickness of 2-2.5 nm, and the second silicon nitride Si 3 N 4 layer (6) has a thickness of 55-65 nm. 3.根据权利要求1或2所述一种离线可钢低辐射镀膜玻璃,其特征在于:所述玻璃基片的厚度为3mm~15mm,所述第一氮化硅Si3N4层(2)的厚度为37nm,所述金属镍铬NiCr层(3)的厚度为1.9nm,所述金属银Ag层(4)的厚度为8nm,所述金属镍铬NiCr层(5)的厚度为2.1nm,所述第二氮化硅Si3N4层(6)的厚度为57nm。 3. An off-line steelable low-emissivity coated glass according to claim 1 or 2, characterized in that: the thickness of the glass substrate is 3 mm to 15 mm, and the first silicon nitride Si 3 N 4 layer (2 ) thickness is 37nm, the metal nickel chromium NiCr layer (3) has a thickness of 1.9nm, the metal silver Ag layer (4) has a thickness of 8nm, and the metal nickel chromium NiCr layer (5) has a thickness of 2.1 nm, the thickness of the second silicon nitride Si 3 N 4 layer (6) is 57 nm.
CN201220124329.5U 2012-03-29 2012-03-29 Offline temperable low-radiation coated glass Expired - Lifetime CN202576250U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102615877A (en) * 2012-03-29 2012-08-01 江苏奥蓝工程玻璃有限公司 Low-radiation coated glass capable of being toughened off line and production method thereof
CN103847161A (en) * 2013-09-11 2014-06-11 洛阳新晶润工程玻璃有限公司 High-temperature-resistant low-emissivity membrane coated glass with high transparency
WO2018099023A1 (en) * 2016-11-30 2018-06-07 江苏奥蓝工程玻璃有限公司 Offline temperable 50%-transmittance low-radiation coated glass and method for fabrication thereof
WO2018099024A1 (en) * 2016-11-30 2018-06-07 江苏奥蓝工程玻璃有限公司 Offline temperable 60%-transmittance low-radiation coated glass and method for fabrication thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102615877A (en) * 2012-03-29 2012-08-01 江苏奥蓝工程玻璃有限公司 Low-radiation coated glass capable of being toughened off line and production method thereof
CN102615877B (en) * 2012-03-29 2015-06-10 江苏奥蓝工程玻璃有限公司 Low-radiation coated glass capable of being toughened off line and production method thereof
CN103847161A (en) * 2013-09-11 2014-06-11 洛阳新晶润工程玻璃有限公司 High-temperature-resistant low-emissivity membrane coated glass with high transparency
WO2018099023A1 (en) * 2016-11-30 2018-06-07 江苏奥蓝工程玻璃有限公司 Offline temperable 50%-transmittance low-radiation coated glass and method for fabrication thereof
WO2018099024A1 (en) * 2016-11-30 2018-06-07 江苏奥蓝工程玻璃有限公司 Offline temperable 60%-transmittance low-radiation coated glass and method for fabrication thereof

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