CN1915836A - 一种纳米氧化锆粉体的制备方法 - Google Patents
一种纳米氧化锆粉体的制备方法 Download PDFInfo
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- CN1915836A CN1915836A CN 200610112779 CN200610112779A CN1915836A CN 1915836 A CN1915836 A CN 1915836A CN 200610112779 CN200610112779 CN 200610112779 CN 200610112779 A CN200610112779 A CN 200610112779A CN 1915836 A CN1915836 A CN 1915836A
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- 238000000034 method Methods 0.000 title claims abstract description 30
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title claims description 37
- 239000011858 nanopowder Substances 0.000 title description 2
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- 238000002360 preparation method Methods 0.000 claims abstract description 21
- 230000000873 masking effect Effects 0.000 claims abstract description 20
- 150000002500 ions Chemical class 0.000 claims abstract description 18
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- 238000010899 nucleation Methods 0.000 claims abstract description 12
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- 239000000243 solution Substances 0.000 claims description 32
- 239000000843 powder Substances 0.000 claims description 24
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 19
- 239000002243 precursor Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- NGPGDYLVALNKEG-UHFFFAOYSA-N azanium;azane;2,3,4-trihydroxy-4-oxobutanoate Chemical compound [NH4+].[NH4+].[O-]C(=O)C(O)C(O)C([O-])=O NGPGDYLVALNKEG-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 239000002244 precipitate Substances 0.000 claims description 11
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 10
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 10
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 239000011259 mixed solution Substances 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 229910021645 metal ion Inorganic materials 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 239000012716 precipitator Substances 0.000 claims description 4
- 230000032683 aging Effects 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 239000000084 colloidal system Substances 0.000 claims description 3
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- 150000001875 compounds Chemical class 0.000 claims 1
- 238000001556 precipitation Methods 0.000 abstract description 14
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract description 8
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- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
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- 150000004703 alkoxides Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
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- 239000003054 catalyst Substances 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 description 1
- 101710134784 Agnoprotein Proteins 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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- 239000007791 liquid phase Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- -1 oxygen ion Chemical class 0.000 description 1
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- 238000010900 secondary nucleation Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
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- 238000001308 synthesis method Methods 0.000 description 1
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- 230000007704 transition Effects 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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CNB2006101127791A CN100411996C (zh) | 2006-09-01 | 2006-09-01 | 一种纳米氧化锆粉体的制备方法 |
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CN1915836A true CN1915836A (zh) | 2007-02-21 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101704671B (zh) * | 2009-11-27 | 2012-02-08 | 清华大学 | 一种低温制备黑色氧化锆陶瓷的方法 |
CN101717115B (zh) * | 2009-11-24 | 2012-04-18 | 福建省智胜矿业有限公司 | 有机酸法制备超细微部分稳定氧化锆 |
CN105086515A (zh) * | 2014-05-22 | 2015-11-25 | 常州市卓群纳米新材料有限公司 | 一种纳米氧化锆有机分散液的制备方法 |
CN106232526A (zh) * | 2014-04-24 | 2016-12-14 | 第稀元素化学工业株式会社 | 石榴石型化合物的制造方法和石榴石型化合物,以及含有该石榴石型化合物的全固态锂二次电池 |
CN108689431A (zh) * | 2018-07-26 | 2018-10-23 | 北京化工大学 | 一种水相纳米氧化锆颗粒分散体的制备方法 |
CN109553129A (zh) * | 2018-11-23 | 2019-04-02 | 中科合成油技术有限公司 | 纳米级高分散氧化锆及其制备方法与在合成气制备芳烃中的应用 |
CN111139525A (zh) * | 2020-01-06 | 2020-05-12 | 深圳市立洋光电子股份有限公司 | 二氧化锆晶体及其制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH0729771B2 (ja) * | 1986-01-14 | 1995-04-05 | 悦朗 加藤 | 単斜ジルコニア超微結晶の高分散ゾルまたはゲルおよび製造方法 |
DE3937640A1 (de) * | 1989-11-11 | 1991-05-16 | Huels Chemische Werke Ag | Zirkondioxidpulver, verfahren zu seiner herstellung, seine verwendung und aus ihm hergestellte sinterkoerper |
US5698483A (en) * | 1995-03-17 | 1997-12-16 | Institute Of Gas Technology | Process for preparing nanosized powder |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101717115B (zh) * | 2009-11-24 | 2012-04-18 | 福建省智胜矿业有限公司 | 有机酸法制备超细微部分稳定氧化锆 |
CN101704671B (zh) * | 2009-11-27 | 2012-02-08 | 清华大学 | 一种低温制备黑色氧化锆陶瓷的方法 |
CN106232526A (zh) * | 2014-04-24 | 2016-12-14 | 第稀元素化学工业株式会社 | 石榴石型化合物的制造方法和石榴石型化合物,以及含有该石榴石型化合物的全固态锂二次电池 |
CN106232526B (zh) * | 2014-04-24 | 2019-07-30 | 第一稀元素化学工业株式会社 | 石榴石型化合物的制造方法 |
CN105086515A (zh) * | 2014-05-22 | 2015-11-25 | 常州市卓群纳米新材料有限公司 | 一种纳米氧化锆有机分散液的制备方法 |
CN108689431A (zh) * | 2018-07-26 | 2018-10-23 | 北京化工大学 | 一种水相纳米氧化锆颗粒分散体的制备方法 |
CN108689431B (zh) * | 2018-07-26 | 2020-05-19 | 北京化工大学 | 一种水相纳米氧化锆颗粒分散体的制备方法 |
CN109553129A (zh) * | 2018-11-23 | 2019-04-02 | 中科合成油技术有限公司 | 纳米级高分散氧化锆及其制备方法与在合成气制备芳烃中的应用 |
CN109553129B (zh) * | 2018-11-23 | 2021-05-14 | 中科合成油技术有限公司 | 纳米级高分散氧化锆及其制备方法与在合成气制备芳烃中的应用 |
CN111139525A (zh) * | 2020-01-06 | 2020-05-12 | 深圳市立洋光电子股份有限公司 | 二氧化锆晶体及其制备方法 |
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Assignee: Shenzhen Ultra Technology Co., Ltd. Assignor: Tsinghua University Contract fulfillment period: 2008.10.15 to 2014.10.15 contract change Contract record no.: 2009440000002 Denomination of invention: Method for preparting Nano powder of zirconia Granted publication date: 20080820 License type: Exclusive license Record date: 20081231 |
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