CN1911038A - Synergistic compound pesticide contg. trans-cypermethrin and chlopyrifos - Google Patents
Synergistic compound pesticide contg. trans-cypermethrin and chlopyrifos Download PDFInfo
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- CN1911038A CN1911038A CN 200510041428 CN200510041428A CN1911038A CN 1911038 A CN1911038 A CN 1911038A CN 200510041428 CN200510041428 CN 200510041428 CN 200510041428 A CN200510041428 A CN 200510041428A CN 1911038 A CN1911038 A CN 1911038A
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- cypermethrin
- theta
- chlopyrifos
- pesticidal combination
- chlorpyrifos
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Abstract
A synergistic composite insecticide for preventing and treating rice borer and high-resistance plutella xylostella contains trans-cypermethrin, chlorpyrifos, assistant and excipient.
Description
One, technical field
The present invention relates to a kind of Pesticidal combination and uses thereof, especially a kind of is the Pesticidal combination and the application thereof of main active with theta-cypermethrin and chlopyrifos.
Two, background technology
Theta-cypermethrin (theta-cypermethrin), chemical name: (IR is trans) S and (IS is trans) R-alpha-cyano-(3-benzyloxy phenoxy base)-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester.
Theta-cypermethrin is a kind of widely used pyrethroid insecticides, is high-efficient broad-spectrum insecticide, and tool is tagged and the insecticide of stomach poison function, prevents and treats a lot of insects.Effective especially to coleoptera and Lepidoptera, be mainly used in the control seedling arrange, cereal.The insect of control has meadow pretty young woman at night, rice leaf roller, striped rice borer, rice leafhopper, plant hopper, stinkbug, cutworm, aphid, corn borer, cotton bollworm, pink bollworm, looper, thrips, aleyrodid, flea beetle, tomato moth, dive fly, moth-eaten moth, gypsymoth, tent caterpillar and cured coccid etc.Also can prevent and treat animal body epizoa, sheep lice and ked, directly be sprayed onto animal on one's body or on the building, can knock down rapidly and lasting control around fly.
Theta-cypermethrin decomposes in plant corpus soon, and residual hazard is low, to the person poultry safety, environment is had no adverse effects.Be theta-cypermethrin missible oil but register the product that uses at present at home, do not have and other agriculture chemical compounding compositions.
Chlopyrifos (chlorpyrifos) chemical name is: O, O-diethyl-O-(3,5, the 6-trichloro-2-pyridyl) thiophosphate.Chlopyrifos is the broad spectrum type insecticide, have tag, stomach toxicity and fumigation action.Can prevent and treat tea geometrid, smaller green leaf hopper, cotten aphid, two-spotted spider mite, rice fulgorid, rice leaf roller, wheat mythimna separata and ox, sheep vermin and soil insect.
The synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve preventive effect, still finds no the Pesticidal combination that closes theta-cypermethrin and chlopyrifos up to now.
Lepidoptera pest as cabbage caterpillar, cotton bollworm, aphid, beet armyworm, the snout moth's larva of rice etc., increases gradually in present resistance, and the agent of agricultural chemicals list descends gradually to the effect of control of insect, and agriculture chemical compounding can obviously improve drug effect, and delays the generation of pest resistance.
Three, summary of the invention
1, goal of the invention
But the purpose of this invention is to provide multifunctional insecticide composition and its application of said composition that a kind of synergy prevents and treats the resistance lepidoptera pest, make full use of both mutual supplement with each other's advantages, obtain a kind of new and effective multifunctional insecticide composition, the various pests that this insecticide antagonism diamond-back moth, the snout moth's larva of rice, beet armyworm etc. are easy to generate resistance has good preventive effect.
2, technical scheme
A kind of Pesticidal combination, it is an active ingredient with theta-cypermethrin and chlopyrifos, wherein the weight ratio of theta-cypermethrin and chlopyrifos is 0.1～30: 0.5～60.
Effective ingredient is present in the composition with the synergy effective dose in this Pesticidal combination.
The weight ratio of theta-cypermethrin and chlopyrifos preferred 0.5～20 in this Pesticidal combination: 15～50.
The optimum weight ratio of theta-cypermethrin and chlopyrifos is 1～5: 15～20 in this Pesticidal combination.This Pesticidal combination is that active ingredient and insecticides adjuvant and excipient are mixed with missible oil, aqueous emulsion or microemulsion with theta-cypermethrin and chlopyrifos.
Above-mentioned Pesticidal combination is in the application that prevents and treats on the resistance lepidoptera pest, especially in the application that prevents and treats on the diamond-back moth and the snout moth's larva of rice.
The Pesticidal combination of theta-cypermethrin provided by the invention and chlopyrifos compared with prior art can produce higher cooperative synergism, and overcome and delayed pest resistance to insecticide, the expanding prevention spectrum, desinsection speed is fast, has reduced drug cost, has alleviated toxicity.The present invention especially can be used for preventing and treating the diamond-back moth and the snout moth's larva of rice of high resistance, and its effect is used apparently higher than its single agent.
For achieving the above object, the present invention is by the network analysis to theta-cypermethrin and dursban insecticidal characteristic, make full use of both mutual supplement with each other's advantages, theta-cypermethrin and chlopyrifos is composite according to certain ratio, obtain a kind of new and effective multifunctional insecticide composition.The various pests that this insecticide antagonism diamond-back moth, the snout moth's larva of rice, beet armyworm etc. are easy to generate resistance has good preventive effect; And the inhibition insect is to the pesticide resistance generation of unitary agent (theta-cypermethrin or chlopyrifos).
The compound pesticide compositions of high-efficiency prevention and control lepidoptera pest of the present invention is made up of theta-cypermethrin and two kinds of active components of chlopyrifos and insecticides adjuvant, excipient, also can go into other auxiliary material simultaneously if desired.Auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound (as farming breast 33
#), the one or more combinations in the polyoxyethylene nonylphenol ether, excipient comprises cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can singly be used or and use.
Beneficial effect of the present invention
Pesticidal combination of the present invention compared with prior art produces following beneficial effect: (1) is compared with single agent, and the said composition antagonism lepidoptera pest such as the snout moth's larva of rice, resistance diamond-back moth etc. has notable synergistic, obviously improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; (3) alternative high-toxic pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with chlopyrifos or the agent of theta-cypermethrin list, produce and the use cost reduction; (6) suppress the resistance enhancing of lepidoptera pest to agricultural chemicals; (7) reduction is to the toxicity of warm blooded animal.
Four, embodiment
The invention will be further described below in conjunction with embodiment:
Embodiment 1:
Take by weighing 2g theta-cypermethrin, 30g chlopyrifos, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 32% theta-cypermethrin-chlorpyrifos ec.
Carry out indoor synergy biologicall test, selecting the resistance diamond-back moth is target pest, and every processing repeats 3 times, and every concentration is handled 60, presses the abundant method of Sun Yun with the LC50 value and calculates co-toxicity coefficient:
The indoor measurement result of table 1.32% theta-cypermethrin-chlorpyrifos ec and single agent antagonism diamond-back moth thereof:
| Medicament | The mensuration project | Drug concentration (mg/l) | ||||||
| 0 | 2.5 | 5 | 10 | 20 | 40 | 80 | ||
| 40% chlorpyrifos ec | Death toll | 3 | 27 | 36 | 41 | 47 | 55 | 60 |
| Corrected mortality % | 42.1 | 57.9 | 66.7 | 77.2 | 91.2 | 99.9 | ||
| 4.5% theta-cypermethrin missible oil | Death toll | 3 | 12 | 31 | 43 | 50 | 55 | 57 |
| Corrected mortality % | 15.8 | 49.1 | 70.2 | 82.5 | 91.2 | 94.7 | ||
| 32% theta-cypermethrin chlorpyrifos ec | Death toll | 3 | 29 | 35 | 43 | 52 | 58 | 60 |
| Corrected mortality % | 45.6 | 56.1 | 70.2 | 86.0 | 96.5 | 99.9 | ||
Annotate: the resistance diamond-back moth that every drug concentration is handled adds up to 60.
Calculate toxicity regression equation and the lethal concentration of 50 LC50 of each medicament antagonism diamond-back moth with probability value method, the results are shown in Table 2:
Toxicity regression equation and the lethal concentration of 50 LC of table 2 32% theta-cypermethrin chlorpyrifos ec and single agent antagonism diamond-back moth
50
| Medicament | Virulence regression equation | LC 50(mg/l) | LC 95(mg/l) | Co-toxicity coefficient |
| Chlorpyrifos ec | Y＝3.63040+1.728332X | 6.20065 | 55.4801 | |
| Theta-cypermethrin missible oil | Y＝4.17070+1.373014X | 4.01788 | 63.3848 | |
| The theta-cypermethrin chlopyrifos | Y＝4.09841+1.594831X | 3.67554 | 39.5081 | 132.6645 |
Embodiment 2:
Take by weighing 6g theta-cypermethrin, 26g chlopyrifos, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33
#2g, alkylphenol polyoxyethylene 1g, dimethylbenzene 13g adds water to 100g.The method of above raw material being prepared routinely aqueous emulsion drops into the mixing of mixing kettle high speed, forms aqueous emulsion preparation 32% theta-cypermethrin-chlorpyrifos aqueous emulsion.
Embodiment 3:
Take by weighing 2g theta-cypermethrin, 30g chlopyrifos, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33
#2g, alkylphenol polyoxyethylene 1g, cyclohexanone 10g adds water to 100g.The method that above raw material is prepared microemulsion routinely drops in the mixing kettle mixes, and forms microemulsion formulation 32% theta-cypermethrin-chlorpyrifos micro emulsion.
It is as follows that embodiment is carried out test of pesticide effectiveness result:
| Handle (extension rate) | Radix before the medicine | Behind the medicine 2 days | Behind the medicine 5 days | Behind the medicine 10 days | ||||
| Residual borer population | Preventive effect | Residual borer population | Preventive effect | Residual borer population | Preventive effect | |||
| Embodiment 1 | 500 | 360 | 40 | 88.44a | 32 | 90.20a | 22 | 91.22a |
| 1000 | 372 | 52 | 85.45ab | 60 | 82.12b | 42 | 83.78b | |
| 1500 | 572 | 164 | 70.16c | 132 | 74.41c | 88 | 77.91c | |
| Embodiment 2 | 500 | 330 | 85 | 85.16 | 88 | 88.87A | 79 | 83.22a |
| 1000 | 328 | 81 | 80.6 | 80 | 82.04B | 74 | 78.61b | |
| 1500 | 467 | 72 | 71.95 | 73 | 75.65C | 64 | 70.92c | |
| Embodiment 3 | 500 | 352 | 63 | 82.2a | 41 | 88.32a | 31 | 91.25a |
| 1000 | 435 | 87 | 80.1ab | 64 | 85.2b | 46 | 89.38b | |
| 1500 | 467 | 111 | 76.2c | 101 | 78.3c | 119 | 74.56c | |
| 40% chlopyrifos 1000 | 512 | 100 | 79.24b | 78 | 83.12b | 52 | 85.40b | |
| 4.5% theta-cypermethrin-1000 | 390 | 110 | 70.64c | 108 | 69.05c | 98 | 63.90d | |
| Contrast | 408 | 392 | 368 | 284 | ||||
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable; A is illustrated on α=0.01 level remarkable, and B is illustrated on α=0.01 level variant, and C is illustrated on α=0.01 level not remarkable;
Field efficacy is the result show, theta-cypermethrin chlopyrifos composition antagonism diamond-back moth has good control efficiency, and control efficiency all is better than the effect that single agent kind is better than direct each Dan Pin of while.
Embodiment 4:
Take by weighing 0.5g theta-cypermethrin, 15g chlopyrifos, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 15.5% theta-cypermethrin-chlorpyrifos ec.
Embodiment 5: take by weighing 5g theta-cypermethrin, 5g chlopyrifos, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 10% theta-cypermethrin-chlorpyrifos ec.
Embodiment 6: take by weighing 2g theta-cypermethrin, 40g chlopyrifos, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 42% theta-cypermethrin-chlorpyrifos ec.
Embodiment 7: take by weighing 0.2g theta-cypermethrin, 50g chlopyrifos, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 8g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 50.2 theta-cypermethrins-chlorpyrifos ec.
Embodiment 8: take by weighing 5g theta-cypermethrin, 40g chlopyrifos, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 45% theta-cypermethrin-chlorpyrifos ec.
Embodiment 9: take by weighing 5g theta-cypermethrin, 30g chlopyrifos, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 35% theta-cypermethrin-chlorpyrifos ec.
Embodiment 10: take by weighing 20g theta-cypermethrin, 5g chlopyrifos, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 25% theta-cypermethrin-chlorpyrifos ec.
Embodiment 11: take by weighing 30g theta-cypermethrin, 2g chlopyrifos, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 7g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 32% theta-cypermethrin-chlorpyrifos ec.
Embodiment 12: take by weighing 2g theta-cypermethrin, 5g chlopyrifos, calcium dodecyl benzene sulfonate 3g, phenethyl phenol polyethenoxy ether 2g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 7% theta-cypermethrin-chlorpyrifos ec.
Embodiment 13: take by weighing 4g theta-cypermethrin, 3g chlopyrifos, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 7% theta-cypermethrin-chlorpyrifos ec.
Embodiment 14: take by weighing 2g theta-cypermethrin, 8g chlopyrifos, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 10% theta-cypermethrin-chlorpyrifos ec.
Embodiment 15: take by weighing 3g theta-cypermethrin, 5g chlopyrifos, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene are to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 8% theta-cypermethrin-chlorpyrifos ec.
Claims (7)
1, a kind of Pesticidal combination is characterized in that it contains theta-cypermethrin and chlopyrifos is an active ingredient, and wherein the weight ratio of theta-cypermethrin and chlopyrifos is 0.1～30: 0.5～60.
2, Pesticidal combination according to claim 1 is characterized in that effective ingredient is present in the composition with the synergy effective dose.
3, Pesticidal combination according to claim 1, the weight ratio that it is characterized in that theta-cypermethrin and chlopyrifos is 0.5～20: 15～50.
4, Pesticidal combination according to claim 3, the weight ratio that it is characterized in that theta-cypermethrin and chlopyrifos is 1～5: 15～20.
5,, it is characterized in that it is that active ingredient and insecticides adjuvant and excipient are mixed with missible oil, aqueous emulsion or microemulsion with theta-cypermethrin and chlopyrifos according to the described Pesticidal combination of claim 1.
6, the described Pesticidal combination of claim 1 is in the application that prevents and treats on the resistance lepidoptera pest.
7, according to the application of the described Pesticidal combination of claim 6 on the control diamond-back moth and the snout moth's larva of rice.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510041428 CN1911038A (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. trans-cypermethrin and chlopyrifos |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510041428 CN1911038A (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. trans-cypermethrin and chlopyrifos |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102232352A (en) * | 2010-04-23 | 2011-11-09 | 陈明忠 | Method for preventing and controlling non-visual pest rice blast of paddy rice |
| CN101606531B (en) * | 2009-07-24 | 2012-05-23 | 江苏省绿盾植保农药实验有限公司 | Compound insecticide containing silafluofen and chlorpyrifos |
| CN102657216A (en) * | 2012-03-31 | 2012-09-12 | 河北省农林科学院植物保护研究所 | Use of pesticide mixed preparation containing chlorpyrifos and high-efficiency cypermethrin in control of Athetis lepigone Moschler |
| CN110999901A (en) * | 2019-11-12 | 2020-04-14 | 南京华洲药业有限公司 | Composite insecticidal and acaricidal nano water agent containing fenpropathrin and chlorpyrifos, and preparation method and application thereof |
-
2005
- 2005-08-12 CN CN 200510041428 patent/CN1911038A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101606531B (en) * | 2009-07-24 | 2012-05-23 | 江苏省绿盾植保农药实验有限公司 | Compound insecticide containing silafluofen and chlorpyrifos |
| CN102232352A (en) * | 2010-04-23 | 2011-11-09 | 陈明忠 | Method for preventing and controlling non-visual pest rice blast of paddy rice |
| CN102657216A (en) * | 2012-03-31 | 2012-09-12 | 河北省农林科学院植物保护研究所 | Use of pesticide mixed preparation containing chlorpyrifos and high-efficiency cypermethrin in control of Athetis lepigone Moschler |
| CN110999901A (en) * | 2019-11-12 | 2020-04-14 | 南京华洲药业有限公司 | Composite insecticidal and acaricidal nano water agent containing fenpropathrin and chlorpyrifos, and preparation method and application thereof |
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