CN1911034A - Synergistic compound pesticide contg. high efficiency cypermethrin and lurfenuron, and its application - Google Patents

Synergistic compound pesticide contg. high efficiency cypermethrin and lurfenuron, and its application Download PDF

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CN1911034A
CN1911034A CN 200510041446 CN200510041446A CN1911034A CN 1911034 A CN1911034 A CN 1911034A CN 200510041446 CN200510041446 CN 200510041446 CN 200510041446 A CN200510041446 A CN 200510041446A CN 1911034 A CN1911034 A CN 1911034A
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cypermethrin
beta
acarus tritici
tritici urea
grams
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CN100353842C (en
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杨寿海
邢平
黄爱新
周典海
赵维祯
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Nanjing No1 Pesticide Group Co ltd
NANJING RED SUN CO Ltd
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Nanjing No1 Pesticide Co Ltd
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Abstract

A synergistic composite insecticide for preventing and treating rice borer, beet noctuid and high-resistance plutella xylostella larva contains high-effect cypermethrin, iurfenuron, assistant and excipient.

Description

A kind of Synergistic insecticidal compositions and application thereof that contains beta-cypermethrin and Acarus tritici urea
Technical field
The present invention relates to a kind of Pesticidal combination and uses thereof, especially a kind of is the Synergistic insecticidal compositions and the application thereof of main active with beta-cypermethrin and Acarus tritici urea.
Background technology
Beta-cypermethrin (efficient alphamethrin) chemical name is: (1R, S)-suitable, trans-2,2-dimethyl-3-(2, the 2-dichloroethylene)-cyclopropane-carboxylic acid-(R, S)-alpha-cyano-3-phenoxy benzyl ester.
Chemical structural formula is:
Figure A20051004144600031
Beta-cypermethrin has very high stomach toxicity and action of contace poison to insect, knock down rapidly, the tool ovicidal activity, good stability is arranged on plant, the anti-rain drop erosion of energy, effect length is stablized, held to photo-thermal, mammalian toxicity is lower than cypermethrin, drug effect is 2 times of cypermethrins, this product insecticidal spectrum is wide, and sanitary insect pests such as agriculture and forestry injurious insects such as Lepidoptera, Semiptera, diptera, Homoptera, coleoptera on the crops such as cotton, vegetables, fruit tree and mosquitos and flies, cockroach, flea, bedbug, louse, ant are all had high killing effect.
Acarus tritici urea (Lufenuron), chemical name: N-[[[2,5-two chloro-4-(1,1,2,3,3,3-hexafluoro third oxygen) phenyl] amino] carboxyl]-2, the 6-difluorobenzamide.Be by the exploitation of Switzerland Syngenta Co.,Ltd, CAS:103055-07-8, its 5% missible oil commodity U.S.A by name removes.The Acarus tritici urea belongs to benzoyl area kind and kills mite, insecticide, and a kind of insect growth regulator, IGR is a chitin synthesis inhibitor.Be mainly used in control beet armyworm, prodenia litura, tomato moth, diamond-back moth, cotton bollworm, lima bean pod borer, melon thin,tough silk snout moth's larva, oriental tobacco budworm, thrips, rust mite, citrus leaf-miner, plant hopper etc.Tool stomach toxicity and action of contace poison, the unique insecticidal mechanism of tool: suppress insect decortication, desinsection, to kill ovum effective, insect has eaten and has sprayed the crop that U.S.A removes and stopped to get food in 2 hours, enters dead worm peak in 2-3 days.Be characterized in 1. low toxicity, suitable non-polluted farm product production.2. desinsection kills ovum, kills large and small larva, 14 days lasting periods.3. permeability is strong, positive spray medicine, the dead worm in the back side, dead ovum.4. anti-rain washes away, and spraying rains after back 15 minutes does not influence drug effect.
In China, because Acarus tritici urea import price height, usable floor area is confined on the high part fruit and vegetables of economic value added, the application area is less, can not in the crop pests control, use widely, and the Acarus tritici urea is not seen the control of insect that field crops such as being used in paddy rice, wheat is arranged in the document at home and abroad.
Lepidoptera pest as cabbage caterpillar, cotton bollworm, aphid, beet armyworm, the snout moth's larva of rice etc., increases gradually in present resistance, and the agent of agricultural chemicals list descends gradually to the effect of control of insect, and agriculture chemical compounding can obviously improve drug effect, and delays the generation of pest resistance.Still find no the Pesticidal combination that closes beta-cypermethrin and Acarus tritici urea up to now.
Summary of the invention
The purpose of this invention is to provide a kind of Synergistic insecticidal compositions and application thereof of containing beta-cypermethrin and Acarus tritici urea that prevents and treats lepidoptera pest.
Technical scheme of the present invention is:
A kind of Synergistic insecticidal compositions that contains beta-cypermethrin and Acarus tritici urea, it is characterized in that it is by primary activity composition beta-cypermethrin and Acarus tritici urea, and auxiliary agent and excipients is composite forms, wherein the weight portion of each component is: 0.1~30 part of beta-cypermethrin, 0.5~30 part of Acarus tritici urea, auxiliary agent is 3~15 parts, and surplus is an excipients, and exists with the cream preparation form.
Described auxiliary agent is the one or more combinations in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound or the polyoxyethylene nonylphenol ether, and excipient is dimethylbenzene or solvent naphtha or its combination.
The Synergistic insecticidal compositions effective ingredient that contains beta-cypermethrin and Acarus tritici urea of the present invention is present in the composition with the synergy effective dose.
Optimum weight part of beta-cypermethrin and Acarus tritici urea is 0.5~20 and 1~25.
Pesticidal combination of the present invention is in the application and the application on the control snout moth's larva of rice and cabbage caterpillar, beet armyworm that prevent and treat on the resistance lepidoptera pest.
Beneficial effect of the present invention:
Pesticidal combination of the present invention compared with prior art produces following beneficial effect: (1) is compared with single agent, and said composition has notable synergistic to lepidoptera pest, has obviously improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; (3) alternative high-toxic pesticide, and reduce the field dosage significantly, effectively reduce environmental pollution and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with single agent product, produce and the use cost reduction; (6) suppress the resistance enhancing of lepidoptera pest to agricultural chemicals; (7) reduction is to the toxicity of warm blooded animal.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
Embodiment 1:
Take by weighing beta-cypermethrin 3 gram, Acarus tritici urea 2 grams, calcium dodecyl benzene sulfonate 4 grams, phenethyl phenol polyethenoxy ether 3 grams, surplus dimethylbenzene and add to gross weight 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 5% beta-cypermethrin Acarus tritici urea missible oil.
Carry out indoor synergy biologicall test, the selection beet exigua larvae is a target pest, and every processing repeats 3 times, and every concentration is handled 30, uses LC 50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
The toxicity test effect of table 1 beta-cypermethrin Acarus tritici urea=3: 2 pairs of beet armyworms
Concentration (μ g/mL) I II III
Examination borer population (head) Dead borer population (head) Examination borer population (head) Dead borer population (head) Examination borer population (head) Dead borer population (head)
100 10 9 10 7 10 8
20 10 8 10 7 10 8
4 10 6 10 6 10 8
0.8 10 6 10 5 10 5
0.16 10 5 10 3 10 4
0.032 10 1 10 2 10 3
0.0064 10 1 10 1 10 2
0.000128 10 2 10 0 10 2
CK 10 2 10 0 10 0
Regression equation: Y=4.94158+0.528111X
Lethal concentration: LC50=1.290102 μ g/mL (95% confidence limit: 0.533609-3.89801 μ g/mL)
Embodiment is prevented and treated the field control effectiveness test of beet armyworm, and the contrast medicine is that the result is as follows:
Unit: head/4
Handle (ppm AI) Extension rate Radix before the medicine Behind the medicine 3 days Behind the medicine 10 days Behind the medicine 15 days
Residual borer population Preventive effect Residual borer population Preventive effect Residual borer population Preventive effect
Embodiment 1 3000 25.8 10.0 59.3a 2.25 90.4a 1.5 92.9a
2500 30.8 11.0 62.4a 4.75 83.0a 1.5 94.0a
2000 29.8 10.5 63.1a 2.75 89.9a 1.0 95.8a
4.5% beta-cypermethrin EC 2000 25.25 13.75 54.4c 8.25 63.9b 7.75 62.2b
5% stuck gram EC 2000 27.25 15.65 57.4c 7.45 72.6b 6.35 76.7b
Contrast 26.75 25.5 24.25 21.75
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable
Embodiment 2:
Take by weighing beta-cypermethrin 0.1 gram, Acarus tritici urea 0.5 gram, calcium dodecyl benzene sulfonate 10 grams, phenethyl phenol polyethenoxy ether 5 grams, surplus dimethylbenzene and add ad pond om 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 0.6% beta-cypermethrin Acarus tritici urea missible oil.
Embodiment 3:
Take by weighing beta-cypermethrin 0.1 gram, Acarus tritici urea 30 grams, calcium dodecyl benzene sulfonate 5 grams, phenethyl phenol polyethenoxy ether 3 grams, surplus dimethylbenzene and add ad pond om 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 30.1% beta-cypermethrin Acarus tritici urea missible oil.
Embodiment 4:
Take by weighing beta-cypermethrin 30 gram, Acarus tritici urea 0.5 gram, calcium dodecyl benzene sulfonate 4 grams, phenethyl phenol polyethenoxy ether 6 grams, surplus dimethylbenzene and add ad pond om 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 30.5% beta-cypermethrin Acarus tritici urea missible oil.
Embodiment 5:
Take by weighing beta-cypermethrin 30 gram, Acarus tritici urea 30 grams, calcium dodecyl benzene sulfonate 1 gram, phenethyl phenol polyethenoxy ether 2 grams, surplus dimethylbenzene and add ad pond om 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 60% beta-cypermethrin Acarus tritici urea missible oil.
Embodiment 6:
Take by weighing beta-cypermethrin 0.5 gram, Acarus tritici urea 1 gram, calcium dodecyl benzene sulfonate 8 grams, phenethyl phenol polyethenoxy ether 7 grams, surplus dimethylbenzene and add ad pond om 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 1.5% beta-cypermethrin Acarus tritici urea missible oil.
Embodiment 7:
Take by weighing beta-cypermethrin 0.5 gram, Acarus tritici urea 25 grams, calcium dodecyl benzene sulfonate 5 grams, phenethyl phenol polyethenoxy ether 6 grams, surplus dimethylbenzene and add ad pond om 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 25.5% beta-cypermethrin Acarus tritici urea missible oil.
Embodiment 8:
Take by weighing beta-cypermethrin 20 gram, Acarus tritici urea 1 gram, calcium dodecyl benzene sulfonate 8 grams, phenethyl phenol polyethenoxy ether 7 grams, surplus dimethylbenzene and add ad pond om 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 21% beta-cypermethrin Acarus tritici urea missible oil.
Embodiment 9:
Take by weighing beta-cypermethrin 20 gram, Acarus tritici urea 25 grams, calcium dodecyl benzene sulfonate 3 grams, phenethyl phenol polyethenoxy ether 4 grams, surplus dimethylbenzene and add ad pond om 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 45% beta-cypermethrin Acarus tritici urea missible oil.
Above-mentioned result shows, the complex composition of effective cypermethrin and lufenuron is compared with two single doses and to be had following advantages: (1) has significantly improved the omnidistance prevention effect to beet armyworm; (2) have quick-acting and the long holding effect of enhancing concurrently, the desinsection effect of 3 days, 10 days and 15 days all is significantly higher than each single dose after the dispenser.

Claims (6)

1, a kind of Synergistic insecticidal compositions that contains beta-cypermethrin and Acarus tritici urea, it is characterized in that it is by primary activity composition beta-cypermethrin and Acarus tritici urea, and auxiliary agent and excipients is composite forms, wherein the weight portion of each component is: 0.1~30 part of beta-cypermethrin, 0.5~30 part of Acarus tritici urea, auxiliary agent is 3~15 parts, and surplus is an excipients, and exists with the cream preparation form.
2, the Synergistic insecticidal compositions that contains beta-cypermethrin and Acarus tritici urea according to claim 1, it is characterized in that described auxiliary agent is the one or more combinations in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound or the polyoxyethylene nonylphenol ether, excipient is dimethylbenzene or solvent naphtha or its combination.
3, the Synergistic insecticidal compositions that contains beta-cypermethrin and Acarus tritici urea according to claim 1 is characterized in that effective ingredient is present in the composition with the synergy effective dose.
4, the Synergistic insecticidal compositions that contains beta-cypermethrin and Acarus tritici urea according to claim 1, the weight portion that it is characterized in that beta-cypermethrin and Acarus tritici urea is 0.5~20 and 1~25.
5, the described Pesticidal combination of claim 1 is in the application that prevents and treats on the resistance lepidoptera pest.
6, preventing and treating the snout moth's larva of rice and cabbage caterpillar, beet armyworm according to the described Pesticidal combination of claim 5.
CNB200510041446XA 2005-08-12 2005-08-12 Synergistic compound pesticide contg. high efficiency cypermethrin and lurfenuron, and its application Expired - Fee Related CN100353842C (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103053571A (en) * 2011-10-18 2013-04-24 南京华洲药业有限公司 Synergistic insecticidal composition containing pymetrozine and lufenuron and application
CN103053591A (en) * 2011-10-18 2013-04-24 南京华洲药业有限公司 Synergistic insecticidal composition containing lufenuron and pyrethroid insecticide and its application

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CN102626073A (en) * 2012-04-01 2012-08-08 广西田园生化股份有限公司 Ultra-low volume liquid containing lufenuron and pyrethroid insecticides

Family Cites Families (1)

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Publication number Priority date Publication date Assignee Title
PT1119256E (en) * 1998-10-09 2003-10-31 Novartis Ag ORAL COMBINATION OF LUFENURAO AND NITENPIRAM AGAINST FLIES

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103053571A (en) * 2011-10-18 2013-04-24 南京华洲药业有限公司 Synergistic insecticidal composition containing pymetrozine and lufenuron and application
CN103053591A (en) * 2011-10-18 2013-04-24 南京华洲药业有限公司 Synergistic insecticidal composition containing lufenuron and pyrethroid insecticide and its application

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