CN100360030C - Synergistic compound pesticide contg. high efficiency cyfluthrin and flufenoxuron - Google Patents
Synergistic compound pesticide contg. high efficiency cyfluthrin and flufenoxuron Download PDFInfo
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- CN100360030C CN100360030C CNB2005100414370A CN200510041437A CN100360030C CN 100360030 C CN100360030 C CN 100360030C CN B2005100414370 A CNB2005100414370 A CN B2005100414370A CN 200510041437 A CN200510041437 A CN 200510041437A CN 100360030 C CN100360030 C CN 100360030C
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- flufenoxuron
- gamma cyhalothrin
- missible oil
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- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 title claims abstract description 71
- 230000002195 synergetic effect Effects 0.000 title abstract description 6
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 title abstract 2
- 229960001591 cyfluthrin Drugs 0.000 title abstract 2
- 239000000575 pesticide Substances 0.000 title description 4
- 150000001875 compounds Chemical class 0.000 title description 2
- 239000002917 insecticide Substances 0.000 claims abstract description 12
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 5
- 239000000546 pharmaceutical excipient Substances 0.000 claims abstract description 5
- 235000009566 rice Nutrition 0.000 claims abstract description 5
- 240000007594 Oryza sativa Species 0.000 claims abstract 2
- 239000005903 Gamma-cyhalothrin Substances 0.000 claims description 72
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 claims description 72
- 230000000361 pesticidal effect Effects 0.000 claims description 14
- 241000607479 Yersinia pestis Species 0.000 claims description 12
- 241000255777 Lepidoptera Species 0.000 claims description 8
- 241000256247 Spodoptera exigua Species 0.000 claims description 7
- 241000255969 Pieris brassicae Species 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 4
- 210000004894 snout Anatomy 0.000 claims description 4
- 239000002671 adjuvant Substances 0.000 claims description 2
- 235000016068 Berberis vulgaris Nutrition 0.000 abstract description 4
- 241000335053 Beta vulgaris Species 0.000 abstract description 4
- 239000002131 composite material Substances 0.000 abstract description 4
- 241000256259 Noctuidae Species 0.000 abstract 1
- 241000500437 Plutella xylostella Species 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 50
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 48
- 238000000034 method Methods 0.000 description 26
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 25
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 24
- 239000002994 raw material Substances 0.000 description 24
- 238000005303 weighing Methods 0.000 description 24
- 238000002360 preparation method Methods 0.000 description 23
- 241000238631 Hexapoda Species 0.000 description 12
- 239000003814 drug Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 210000003128 head Anatomy 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- -1 alpha-cyano-3-benzyloxy phenoxy Chemical group 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- 239000003905 agrochemical Substances 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- 241000209094 Oryza Species 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 2
- 241000255967 Helicoverpa zea Species 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004166 bioassay Methods 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- ZXQYGBMAQZUVMI-RDDWSQKMSA-N (1S)-cis-(alphaR)-cyhalothrin Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-RDDWSQKMSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 241000665051 Chilo sacchariphagus indicus Species 0.000 description 1
- 241000426497 Chilo suppressalis Species 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 1
- 241001465977 Coccoidea Species 0.000 description 1
- 241001364569 Cofana spectra Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000289763 Dasygaster padockina Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000738498 Epitrix pubescens Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000578422 Graphosoma lineatum Species 0.000 description 1
- 241001325860 Lacanobia oleracea Species 0.000 description 1
- 241000721703 Lymantria dispar Species 0.000 description 1
- 241000255685 Malacosoma neustria Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 241000346285 Ostrinia furnacalis Species 0.000 description 1
- 241000721451 Pectinophora gossypiella Species 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- FCZCIXQGZOUIDN-UHFFFAOYSA-N ethyl 2-diethoxyphosphinothioyloxyacetate Chemical compound CCOC(=O)COP(=S)(OCC)OCC FCZCIXQGZOUIDN-UHFFFAOYSA-N 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000005910 lambda-Cyhalothrin Substances 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000029052 metamorphosis Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A synergistic composite insecticide for preventing and treating rice borer, beet noctuid and high-resistance plutella xylostella larva contains high-effect cyfluthrin, flufenoxuron, assistant and excipient.
Description
One, technical field
The present invention relates to a kind of Pesticidal combination and uses thereof, especially a kind of is the Pesticidal combination and the application thereof of main active with gamma cyhalothrin and flufenoxuron.
Two, technical background
Gamma cyhalothrin claims cyhalothrin again.
ISO adopted name: lambda-cyhalothrin
Chemical name: alpha-cyano-3-benzyloxy phenoxy base-3-(2-chloro-3,3,3-trifluoro-propenyl)-2,2-dimethyl cyclopropane carboxylic acid ester
Structural formula:
Empirical formula: C23H19ClF3NO3
Gamma cyhalothrin is a kind of widely used pyrethroid insecticides, is high-efficient broad-spectrum insecticide, and tool is tagged and the insecticide of stomach poison function, and quick-acting is good, prevents and treats a lot of insects.Effective especially to coleoptera and Lepidoptera, the insect that is mainly used in control has rice leaf roller, paddy stem borer, striped rice borer, rice leafhopper, plant hopper, stinkbug, cutworm, aphid, corn borer, cotton bollworm, pink bollworm, looper, thrips, aleyrodid, flea beetle, tomato moth, dive fly, moth-eaten moth, gypsymoth, tent caterpillar and coccid etc.Gamma cyhalothrin has certain preventive effect to the insect and the evil mite of sucking mouth parts, can doublely control the mite class.Gamma cyhalothrin decomposes in plant corpus soon, and residual hazard is low, to the person poultry safety, environment is had no adverse effects.
Flufenoxuron (flufenoxuron) belongs to the benzoyl area kind insect growth regulator, IGR, and it is synthetic to suppress insect chitin, controls but the worm mite is double, and active high, the lasting period is long.Have and tag and stomach poison function, no systemic action.By suppressing chitinous formation, insect can not normally be casted off a skin and metamorphosis, especially to the control of normally casting off a skin and growing of larva, reach the purpose of desinsection.This medicament also has good blade face anelasticity.Can be used for preventing and treating the mite class and the insect of citrus, cotton, vegetables, soybean, fruit tree, seeding corn and other crops field mezzanine level, to predacious mite and insect safety.But relatively chrysanthemum ester insecticide is slow for the quick-acting of flufenoxuron insecticide, and influence is to the general control of insect, and is especially relatively poor to explosive pest controling effect.
The synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve desinsection quick-acting and lasting effect, still finds no the Pesticidal combination that closes gamma cyhalothrin and flufenoxuron up to now.
Lepidoptera pest as cabbage caterpillar, cotton bollworm, aphid, beet armyworm, the snout moth's larva of rice etc., increases gradually in present resistance, and the agent of agricultural chemicals list descends gradually to the effect of control of insect, and agriculture chemical compounding can obviously improve drug effect, and delays the generation of pest resistance.
Three, summary of the invention
1, goal of the invention
The purpose of this invention is to provide a kind of multifunctional insecticide composition and application thereof that prevents and treats lepidoptera pest.
2, technical scheme
For achieving the above object, gamma cyhalothrin and flufenoxuron assembly that the present invention will grow the lasting period obtain the new and effective multifunctional insecticide composition of a class.This insecticide has good preventive effect to the various pests that Lepidoptera is easy to generate resistance; And suppress insect the pesticide resistance of unitary agent (in gamma cyhalothrin or the flufenoxuron arbitrary) is produced.
A kind of Pesticidal combination is characterized in that it contains gamma cyhalothrin and flufenoxuron is an active ingredient, and wherein the weight ratio of gamma cyhalothrin and flufenoxuron is 0.1～30: 0.5～30.
Above-mentioned effective ingredient is present in the composition with the synergy effective dose.
The preferred weight ratio of gamma cyhalothrin and flufenoxuron is 0.5～20: 1～25.
The optimum weight ratio of gamma cyhalothrin and flufenoxuron is 1～10: 1～15.
Pesticidal combination of the present invention is that active ingredient and insecticides adjuvant and excipients are formulated with gamma cyhalothrin and flufenoxuron.
Pesticidal combination of the present invention is in the application that prevents and treats on the resistance lepidoptera pest, especially in the application that prevents and treats on the snout moth's larva of rice and cabbage caterpillar, the beet armyworm.
Above-described auxiliary agent is the one or more combinations in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy third rare block compound (as the newborn 33# of farming), the polyoxyethylene nonylphenol ether, and excipient comprises dimethylbenzene, solvent naphtha.Above auxiliary agent, excipient can be singly with or and also can add other auxiliary material with reaching.
Measure through indoor synergism test and to show: is 156-238 by gamma cyhalothrin and flufenoxuron to the co-toxicity coefficient of beet exigua larvae, and test determination shows that all composite dose all has significant synergistic insecticidal action to two kinds of insects; Field control effectiveness test equally also shows the composite dose of effect that the insecticidal effect of beet tops moth larvae all is significantly higher than corresponding single agent agricultural chemicals that the present invention is all.
3, beneficial effect
Purpose of the present invention just provides the Pesticidal combination of a kind of gamma cyhalothrin and flufenoxuron, it compared with prior art, can produce higher cooperative synergism, can both improve the performance of its quick-acting, again can be arranged certain lasting period, overcome and delayed pest resistance to insecticide, the expanding prevention spectrum, desinsection speed is fast, has reduced drug cost, has alleviated toxicity.
The present invention especially can be used for preventing and treating the snout moth's larva of rice and resistance cabbage caterpillar, beet armyworm, and its effect is used apparently higher than its single agent.
Pesticidal combination of the present invention compared with prior art produces following beneficial effect: (1) is compared with single agent, and said composition has notable synergistic to lepidoptera pest, has obviously improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; (3) alternative high-toxic pesticide, and reduce the field dosage significantly, effectively reduce environmental pollution and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with single agent product, produce and the use cost reduction; (6) suppress the resistance enhancing of lepidoptera pest to agricultural chemicals; (7) reduction is to the toxicity of warm blooded animal.
Four, embodiment
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.Pass through indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage earlier; On this basis, carry out field trial again.
Embodiment 1:
Take by weighing 2g gamma cyhalothrin, 2g flufenoxuron, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3 g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 4% gamma cyhalothrin 5 percent of hexaflumuron emulsifiable concentrate.
Carry out indoor synergy biologicall test, the selection beet exigua larvae is a target pest, and every processing repeats 3 times, and every concentration is handled 30, presses the abundant method of Sun Yun with the LC50 value and calculates co-toxicity coefficient:
The toxicity test effect of table 1 gamma cyhalothrin flufenoxuron=2: 2 pairs of beet armyworms
| Concentration (μ g/mL) | I | II | III | |||
| Examination borer population (head) | Dead borer population (head) | Examination borer population (head) | Dead borer population (head) | Examination borer population (head) | Dead borer population (head) | |
| 100 | 10 | 9 | 10 | 7 | 10 | 8 |
| 20 | 10 | 8 | 10 | 7 | 10 | 8 |
| 4 | 10 | 6 | 10 | 6 | 10 | 8 |
| 0.8 | 10 | 6 | 10 | 5 | 10 | 5 |
| 0.16 | 10 | 5 | 10 | 3 | 10 | 4 |
| 0.032 | 10 | 1 | 10 | 2 | 10 | 3 |
| 0.0064 | 10 | 1 | 10 | 1 | 10 | 2 |
| 0.000128 | 10 | 2 | 10 | 0 | 10 | 2 |
| CK | 10 | 2 | 10 | 0 | 10 | 0 |
Regression equation: Y=4.94158+0.528111X
Lethal concentration: LC50=1.290102 μ g/mL (95% confidence limit: 0.533609-3.89801 μ g/mL)
Embodiment is prevented and treated the field control effectiveness test of beet armyworm, and the contrast medicine is that the result is as follows:
Result of the test: unit: head/4
| Handle (ppm AI) | Extension rate | Radix before the medicine | Behind the medicine 3 days | Behind the medicine 10 days | Behind the medicine 15 days | |||
| Residual borer population | Preventive effect | Residual borer population | Preventive effect | Residual borer population | Preventive effect | |||
| Embodiment 1 | 3000 | 25.8 | 10.0 | 59.3a | 2.25 | 90.4a | 1.5 | 92.9a |
| 2500 | 30.8 | 11.0 | 62.4a | 4.75 | 83.0a | 1.5 | 94.0a | |
| 2000 | 29.8 | 10.5 | 63.1a | 2.75 | 89.9a | 1.0 | 95.8a | |
| 2.5% gamma cyhalothrin EC | 2000 | 25.25 | 13.75 | 54.4c | 8.25 | 63.9b | 7.75 | 62.2b |
| 5% stuck gram EC | 2000 | 27.25 | 15.65 | 57.4c | 7.45 | 72.6b | 6.35 | 76.7b |
| Contrast | 26.75 | 25.5 | 24.25 | 21.75 | ||||
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable; A is illustrated on α=0.01 level remarkable, and B is illustrated on α=0.01 level variant, and C is illustrated on α=0.01 level not remarkable:
The above results shows, the complex composition of gamma cyhalothrin and flufenoxuron is compared with two single agent and to be had following advantage: (1) has significantly improved the omnidistance control efficiency to beet armyworm; (2) have the quick-acting of enhancing and long hold effect concurrently, the insecticidal effect of 3 days, 10 days and 15 days all is significantly higher than each single agent after the dispenser.
Embodiment 2:
Take by weighing 1g gamma cyhalothrin, 3g flufenoxuron, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 4% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 3:
Take by weighing 5g gamma cyhalothrin, 7g flufenoxuron, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 12% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 4: take by weighing 0.1g gamma cyhalothrin, 3g flufenoxuron, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 3.1% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 5: take by weighing 5g gamma cyhalothrin, 7g flufenoxuron, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 12% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 6: take by weighing 0.5g gamma cyhalothrin, 3g flufenoxuron, calcium dodecyl benzene sulfonate 3g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 3.5% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 7: take by weighing 1g gamma cyhalothrin, 3g flufenoxuron, calcium dodecyl benzene sulfonate 3g, phenethyl phenol polyethenoxy ether 3g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 4% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 8: take by weighing 5g gamma cyhalothrin, 0.5g flufenoxuron, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 5.5% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 9: take by weighing 2.5g gamma cyhalothrin, 0.5g flufenoxuron, calcium dodecyl benzene sulfonate 2g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 3% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 10: take by weighing 1g gamma cyhalothrin, 2g flufenoxuron, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 3% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 11: take by weighing 2g gamma cyhalothrin, 4g flufenoxuron, calcium dodecyl benzene sulfonate 2g, phenethyl phenol polyethenoxy ether 1g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 12% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 12: take by weighing 1g gamma cyhalothrin, 6g flufenoxuron, calcium dodecyl benzene sulfonate 2g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 7% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 13: take by weighing 1g gamma cyhalothrin, 5g flufenoxuron, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 2g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 6% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 14: take by weighing 2g gamma cyhalothrin, 5g flufenoxuron, calcium dodecyl benzene sulfonate 3g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 7% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 15: take by weighing 1g gamma cyhalothrin, 3g flufenoxuron, calcium dodecyl benzene sulfonate 2g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 4% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 16: take by weighing 5g gamma cyhalothrin, 0.25g flufenoxuron, calcium dodecyl benzene sulfonate 2g, phenethyl phenol polyethenoxy ether 2g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 5.25% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 17: take by weighing 2g gamma cyhalothrin, 1.5g flufenoxuron, calcium dodecyl benzene sulfonate 2g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 3.5% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 18: take by weighing 2g gamma cyhalothrin, 3g flufenoxuron, calcium dodecyl benzene sulfonate 2g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 5% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 19: take by weighing 30g gamma cyhalothrin, 1g flufenoxuron, calcium dodecyl benzene sulfonate 14g, phenethyl phenol polyethenoxy ether 15g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 31% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 20: take by weighing 15g gamma cyhalothrin, 5g flufenoxuron, calcium dodecyl benzene sulfonate 15g, phenethyl phenol polyethenoxy ether 10g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 20% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 21: take by weighing 10g gamma cyhalothrin, 0.5g flufenoxuron, calcium dodecyl benzene sulfonate 10g, phenethyl phenol polyethenoxy ether 8g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 10.5% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 22: take by weighing 10g gamma cyhalothrin, 1g flufenoxuron, calcium dodecyl benzene sulfonate 10g, phenethyl phenol polyethenoxy ether 8g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 11% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 23: take by weighing 9g gamma cyhalothrin, 7.5g flufenoxuron, calcium dodecyl benzene sulfonate 10g, phenethyl phenol polyethenoxy ether 8g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 12% gamma cyhalothrin flufenoxuron missible oil.
Embodiment 24: take by weighing 6g gamma cyhalothrin, 6g flufenoxuron, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g, the method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 12% gamma cyhalothrin flufenoxuron missible oil.
Claims (6)
1, a kind of Pesticidal combination is characterized in that it contains gamma cyhalothrin and flufenoxuron is an active ingredient, and wherein the weight ratio of gamma cyhalothrin and flufenoxuron is 0.1～30: 0.5～30.
2, Pesticidal combination according to claim 1, the weight ratio that it is characterized in that gamma cyhalothrin and flufenoxuron is 0.5～20: 1～25.
3, Pesticidal combination according to claim 2, the weight ratio that it is characterized in that gamma cyhalothrin and flufenoxuron is 1～10: 1～15.
4,, it is characterized in that it is that active ingredient and insecticides adjuvant and excipients are formulated with gamma cyhalothrin and flufenoxuron according to the described Pesticidal combination of claim 1.
5, the described Pesticidal combination of claim 1 is in the application that prevents and treats on the resistance lepidoptera pest.
6, application according to claim 5, Pesticidal combination are used to prevent and treat the snout moth's larva of rice and cabbage caterpillar, beet armyworm.
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| CNB2005100414370A CN100360030C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. high efficiency cyfluthrin and flufenoxuron |
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| CNB2005100414370A CN100360030C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. high efficiency cyfluthrin and flufenoxuron |
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| CN1911031A CN1911031A (en) | 2007-02-14 |
| CN100360030C true CN100360030C (en) | 2008-01-09 |
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| CNB2005100414370A Expired - Fee Related CN100360030C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. high efficiency cyfluthrin and flufenoxuron |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1187296A (en) * | 1997-01-06 | 1998-07-15 | 美国家庭用品有限公司 | Method for control of resistant populations of lepidoptera |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1187296A (en) * | 1997-01-06 | 1998-07-15 | 美国家庭用品有限公司 | Method for control of resistant populations of lepidoptera |
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