CN102379308A - Mixed insecticidal composition containing clothianidin and application of mixed insecticidal composition - Google Patents

Mixed insecticidal composition containing clothianidin and application of mixed insecticidal composition Download PDF

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CN102379308A
CN102379308A CN201110281635XA CN201110281635A CN102379308A CN 102379308 A CN102379308 A CN 102379308A CN 201110281635X A CN201110281635X A CN 201110281635XA CN 201110281635 A CN201110281635 A CN 201110281635A CN 102379308 A CN102379308 A CN 102379308A
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clothianidin
polyoxyethylene
ether
selected
agent
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CN201110281635XA
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Chinese (zh)
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戚明珠
章超
贾炜
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江苏优士化学有限公司
江苏扬农化工股份有限公司
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Publication of CN102379308A publication Critical patent/CN102379308A/en

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Abstract

The invention provides a mixed insecticide containing clothianidin, which comprises an activated ingredient and adjuvant. The activated ingredient accounts for 5% to 8% of total weight of the insecticide, the adjuvant accounts for the remaining percentage of the total weight of the insecticide, the activated ingredient is composed of clothianidin and pyrethroid compound, and the weight ratio of the clothianidin to the pyrethroid compound is 1:99 to 99:1. Quick acting of the mixed insecticidal composition can be improved while the mixed insecticidal composition has better persistence, the mixed insecticidal composition is evident in synergy of farmland pest control, drug application amount can be reduced, cost is saved, and drug resistance of pests is delayed. The invention further provides application of the mixed insecticidal composition to field pest control.

Description

含有噻虫胺的复配杀虫组合物及其应用 Clothianidin containing compound pesticidal compositions and use thereof

技术领域 FIELD

[0001] 本发明涉及一种农药杀虫组合物,具体涉及一种含有噻虫胺的复配农药杀虫组合物。 [0001] The present invention relates to a pesticide pesticidal composition, comprising in particular to a compound of clothianidin pesticide pesticidal composition.

背景技术 Background technique

[0002] 噻虫胺,英文名称(clothianidin),分子式:C6H8C1N#2S,化学名称: (E)-1-(2-氯-1,3-噻唑-5-基甲基)-3-甲基-2-2-硝基胍。 [0002] clothianidin, English name (, clothianidin), the formula: C6H8C1N # 2S, Chemical Name: (E) -1- (2- chloro-1,3-thiazol-5-yl) -3-methyl -2-2- nitroguanidine.

[0003] 噻虫胺是一种用于水稻、蔬菜、果树及其它作物上防治蚜虫、叶蝉、蓟马、飞虱等半翅目、鞘翅目、双翅目和某些鳞翅目类害虫的新烟碱类杀虫剂,具有高效、广谱、用量少、毒性低、药效持效期长、对作物无药害、使用安全、与常规农药无交互抗性等优点,有卓越的内吸和渗透作用,是替代高毒有机磷农药的又一品种。 [0003] Clothianidin is an apparatus for control of aphids, leafhoppers, thrips, etc. Hemiptera planthoppers on rice, vegetables, fruit trees and other crops, Coleoptera, Diptera and Lepidoptera pests certain neonicotinoid insecticide, an efficient, broad spectrum, with less low toxicity, long duration efficacy, no injury to crops, safe, and no advantages of cross-resistance to conventional pesticides and the like, have excellent the systemic and infiltration, an alternative is highly toxic organophosphorus pesticide another species.

[0004] 高效氯氟氰菊酯又称功夫菊酯。 [0004] Cyhalothrin known as cyhalothrin. ISO通用名称:lambda-cyhalothrin,分子式: C23H19ClF3NO3,化学名称:α -氰基-3-苯氧苄基_3_ (2-氯-3,3,3-三氟丙烯基)-2,2- 二甲基环丙烷羧酸酯。 ISO common name: lambda-cyhalothrin, molecular formula: C23H19ClF3NO3, chemical name: α - cyano-3-phenoxybenzyl _3_ (2-chloro-3,3,3-trifluoropropene-yl) -2,2- cyclopropanecarboxylic acid methyl ester.

[0005] 高效氯氟氰菊酯是一种应用较为广泛的拟除虫菊酯类杀虫剂,为高效广谱杀虫剂,具触杀和胃毒作用的杀虫剂,速效性好,防治多种害虫。 [0005] Lambda-cyhalothrin is a pyrethroid is widely used insecticide for efficient broad-spectrum insecticides, insecticide with contact and stomach action, good quick result, control a variety of pests. 对鞘翅目和鳞翅目特别有效,主要用于防治的害虫有稻纵卷叶螟、三化螟、二化螟、黑尾叶蝉、飞虱、蝽象、地老虎、蚜虫、玉米螟、棉铃虫、棉铃红虫、蓟马、粉虱、跳甲、甘蓝叶蛾、潜蝇、蠹蛾、舞毒蛾、天幕毛虫和蚧壳虫等。 Particularly Coleoptera and Lepidoptera effective, mainly for the control of pests leafroller, yellow stem borer, Chilo suppressalis, Nephotettix cincticeps, planthoppers, stink bugs, cutworms, aphids, corn borer, bollworm, boll red worms, thrips, whiteflies, flea beetles, cabbage leaf moth, maggot, codling moth, gypsy moth, tent caterpillars and scale insects and so on. 高效氯氟氰对刺吸式口器害虫及害螨有一定防效,可兼治螨类。 Cyhalothrin of sucking insects and harmful mites necessarily effective, be rid of mites. 高效氯氟氰菊酯在植物体内分解快,残毒低,对人畜安全,对环境无不良影响。 Cyhalothrin in plants decompose fast, low residues, safety to humans and animals, no adverse effects on the environment.

[0006] 七氟菊酯(Tefluthrin),属拟除虫菊酯类杀虫剂,是土壤杀虫剂,能很好地防治鞘翅目和栖息在土壤中德鳞翅目和某些双翅目害虫,可广谱地防治土壤节肢动物,包括南瓜十二星甲、金针虫、跳甲、金龟子、甜菜隐食甲、地老虎、玉米螟、瑞典麦秆蝇等。 [0006] tefluthrin (Tefluthrin), is a pyrethroid insecticide, a soil insecticide, can be a good control of Coleoptera and Lepidoptera habitat and certain Diptera pests in the soil and Germany, be broad-spectrum control of soil arthropods, including pumpkin A twelve stars, wireworms, flea beetles, beetle, beet A hidden food, cutworms, corn borer, Sweden straw flies.

[0007] 溴氰菊酯(deltamethrin)化学名称:右旋-顺式_2,2_ 二甲基_3_ (2,2_ 二溴乙烯基)环丙烷羧酸-(¾ - α -氰基-3-苯氧基苄酯,是一种生物活性较高的拟除虫菊酯类杀虫药物。作用方式以触杀胃毒为主,对害虫有一定的趋避和拒食作用,无内吸和熏蒸作用, 杀虫谱广,击倒速度快,尤其对鳞翅目幼虫及蚜虫杀伤力大,但对螨类无效,作用部位在神经系统,为神经毒剂,使昆虫过度兴奋,麻痹而死。 [0007] deltamethrin (deltamethrin) Chemical Name: dextrose - cis-dimethyl _3_ _2,2_ (2,2_ dibromovinyl) cyclopropanecarboxylate - (¾ - α - cyano-3 - phenoxybenzyl ester, a higher biological activity pyrethroid insecticidal drugs manner stomach based tag, a certain degree of aversion to pests and antifeedant action, and no systemic fumigation, kill. broad-spectrum insect, down speed, especially for Lepidoptera larvae and aphids lethality large, but the mites invalid, the site of action in the nervous system, nerve agents, insect over-excited, paralysis and died.

[0008] 目前,由于鳞翅目害虫,如菜青虫、棉铃虫、蚜虫、甜菜叶蛾等抗性逐渐增加,农药单剂对害虫的防治效果逐渐下降,农药复配可以明显提高药效,并延缓害虫抗性的产生。 [0008] At present, due to the lepidopteran pests such as cabbage worm, cotton bollworm, aphids, beet leaf moth resistance gradually increased, a single dose of pesticides for pest control effect gradually decreased pesticide compound can significantly improve the efficacy and delay the pest resistance.

发明内容 SUMMARY

[0009] 本发明的目的之一在于提供一种杀虫效果好,用药成本低,不易产生抗药性的含有噻虫胺的复配杀虫组合物。 [0009] One object of the present invention to provide an insecticidal effective and low cost treatment, not easy to produce drug resistance compound pesticidal composition comprising clothianidin.

[0010] 本发明的另一目的在于提供上述杀虫组合物的用途。 [0010] Another object of the present invention is to provide use of the above-described pesticidal compositions.

[0011] 为了实现上述目的,本发明的技术方案是这样的:[0012] 提供一种含有噻虫胺的复配杀虫剂,它由占杀虫剂总重量5%〜80%的活性成分和余量的助剂组成,且所述的活性成分由噻虫胺(组分A)和拟除虫菊酯类化合物(组分B) 复配组成,噻虫胺和拟除虫菊酯类化合物的重量比为1 : 99〜99 : 1。 [0011] To achieve the above object, the technical solution of the present invention is such that: [0012] to provide a compound containing clothianidin insecticide that 5% ~ 80% of the total weight of the pesticide active ingredient accounted for by and the balance consisting of additives, and the active ingredient by the clothianidin (component a) and a pyrethroid compound (component B) compounded composition, by weight of pyrethroid and clothianidin ratio of compound 1: 99~99: 1.

[0013] 所述的拟除虫菊酯类化合物优选高效氯氟氰菊酯、七氟菊酯或溴氰菊酯中的一种或两种以上的混合物。 [0013] The pyrethroid compound is preferably lambda-cyhalothrin, deltamethrin, or tefluthrin mixture of one or two or more types.

[0014] 所述的助剂可以是润湿齐IJ、分散齐ϋ、缓释剂、崩解齐ϋ、乳化剂、防冻齐ϋ、增稠剂、消泡剂、粘结剂或填料中的一种或两种以上的混合物。 Additives [0014] The IJ together may be a wetting, dispersing Qi ϋ, release agents, disintegrants Qi ϋ, emulsifiers, antifreeze Qi ϋ, thickeners, defoamers, binders or fillers or a mixture of two or more kinds.

[0015] 本发明所述的杀虫组合物可以使用常规助剂按照常规方法制成水分散粒剂、悬浮剂或颗粒剂,按重量百分比计,可以包括如下具体配方: [0015] The pesticidal composition of the present invention may be used in accordance with a conventional method customary auxiliaries water dispersible granules, suspensions or granules, in percent by weight, may include the following specific formulations:

[0016] 本发明组合物制成高效氯氟氰·噻虫胺水分散粒剂时包括如下组分:高效氯氟氰1 %〜20%、噻虫胺〜80%、润湿剂〜4%、分散剂〜10%、缓释剂1%〜8%、崩解剂丨“^〜彳^^填料余量。 [0016] The compositions of the present invention comprises the following components dispersed granules made cyhalothrin clothianidin · Water: cyhalothrin 1% ~20%, Clothianidin ~ 80% ~ 4% wetting agent , ~ 10% dispersing agent, release agent 1% ~ 8%, disintegrant | 'or ^ - ^^ filler margin left foot.

[0017] 本发明组合物制成噻虫胺·七氟菊酯水分散粒剂时包括如下组分:噻虫胺〜 80%、七氟菊酯〜30%、润湿剂〜4%、分散剂〜10%、缓释剂〜8%、崩解剂1%〜4%、填料余量。 [0017] The present invention includes compositions made clothianidin · tefluthrin water dispersible granules of the following components: 80% of clothianidin, tefluthrin ~ 30% ~ 4% wetting agent, dispersing agent ~ 10%, ~ 8% release agent, 1% ~ 4% disintegrant, filler margin.

[0018] 本发明组合物制成噻虫胺·溴氰菊酯水分散粒剂时包括如下组分:噻虫胺〜 80%、溴氰菊酯〜40%、润湿剂1%〜4(%、分散剂1(%〜10%、缓释剂〜8%、崩解剂1%〜4%、填料余量。 [0018] The present invention includes compositions made clothianidin · deltamethrin water dispersible granules of the following components: 80% of clothianidin, deltamethrin ~ 40% ~ 4% wetting agent 1 ( %, dispersant 1 (% ~ 10% ~ 8% release agent, 1% ~ 4% disintegrant, filler margin.

[0019] 将本发明所述的杀虫剂制备成水分散粒剂的方法是:将配方料混合均勻,用超微气流粉碎机粉碎,经捏合,然后加入流化床造粒干燥机中进行造粒、干燥、筛分后取样分析。 Method [0019] The insecticide prepared according to the present invention are water dispersible granules: the formulation evenly mixed, pulverized by a jet mill ultrafine, kneaded, and then a fluid bed granulation dryer join granulation, drying, sampling and analysis after the screening.

[0020] 本发明组合物制成高效氯氟氰·噻虫胺悬浮剂时包括如下组分:高效氯氟氰〜20%、噻虫胺〜60%、乳化剂〜4%、分散剂2%〜6%、缓释剂0. 〜3%、 [0020] The compositions of the present invention comprises the following components is made cyhalothrin · clothianidin suspension: ~ 20% cyhalothrin, clothianidin ~ 60% ~ 4% emulsifier, 2% dispersant ~ 6%, 0.05 ~ 3% release agent,

防冻剂1%〜8%、增稠剂0. 〜1%、消泡剂0. 〜0.5%、水余量。 1% ~ 8% antifreeze, 0.5 ~ 1% thickener, antifoaming agent 0.5 ~ 0.5%, the balance water.

[0021] 本发明组合物制成噻虫胺•七氟菊酯悬浮剂时包括如下组分:噻虫胺〜60%、 七氟菊酯〜30%、乳化剂〜4%、分散剂2%〜6%、缓释剂0. 〜3%、防冻剂 [0021] The compositions of the present invention is prepared comprising the components of clothianidin tefluthrin • suspending agent: ~ 60% of clothianidin, tefluthrin ~ 30% ~ 4% emulsifier, 2% dispersant ~ 6%, 0.05 ~ 3% release agent, antifreeze

〜8%、增稠剂0. 〜1%、消泡剂0. 〜0. 5%、水余量。 ~ 8%, 0.5 ~ 1% thickener, antifoaming agent 0.5 ~ 0. 5%, balance water.

[0022] 本发明组合物制成噻虫胺•溴氰菊酯悬浮剂时包括如下组分:噻虫胺1 %〜60%、 溴氰菊酯〜40%、乳化剂〜4%、分散剂2%〜6%、缓释剂0. 〜3%、防冻剂 [0022] The present invention includes compositions made • clothianidin deltamethrin suspension of the following components: clothianidin 1% ~ 60%, ~ 40% deltamethrin, ~ 4% emulsifier, dispersant 2% ~ 6%, 0.05 ~ 3% release agent, antifreeze

〜8%、增稠剂0. 〜1%、消泡剂0. 〜0. 5%、水余量。 ~ 8%, 0.5 ~ 1% thickener, antifoaming agent 0.5 ~ 0. 5%, balance water.

[0023] 将本发明所述的杀虫剂制备成悬浮剂的方法是:将上述配方料中除有效成分外的其余组分经高速剪切混合均勻,加入有效成分,在球磨机中球磨2〜3小时,使粒径在5um 以下。 [0023] The insecticide prepared according to the method of the present invention suspending agents are: compound of the above formulation remaining components except the active ingredient by high shear mixing, is added the active ingredient, milling in a ball mill 2 ~ 3 hours to 5um in diameter or less.

[0024] 本发明组合物制成高效氯氟氰·噻虫胺颗粒剂时包括如下组分:高效氯氟氰〜20%、噻虫胺〜60%、粘结剂0. 5%〜8%、润湿剂1%〜4%、缓释剂1%〜8%、 [0024] The compositions of the present invention comprises the following components is made cyhalothrin · clothianidin Granules: cyhalothrin ~ 20%, ~ 60% of clothianidin, 0.5% ~ 8% binder , 1% ~ 4% wetting agent, release agent 1% ~ 8%,

填料余量。 Filler margin.

[0025] 本发明组合物制成噻虫胺•七氟菊酯颗粒剂时包括如下组分:噻虫胺〜60%、 七氟菊酯1 %〜30 %、粘结剂0. 5 %〜8 %、润湿剂1 %〜4%、缓释剂1 %〜8 %、填料余量。 [0025] When the compositions of the invention made of clothianidin • tefluthrin granule comprises the following components: ~ 60% of clothianidin, tefluthrin 1% ~ 30%, ~ 0.5% binder 8% wetting agent 1% ~ 4%, 1% ~ 8% release agent, fillers balance.

[0026] 本发明组合物制成噻虫胺•溴氰菊酯颗粒剂时包括如下组分:噻虫胺1 %〜60%、 溴氰菊酯1 %〜40 %、粘结剂0. 5 %〜8 %、润湿剂1 %〜4 %、缓释剂1 %〜8 %、填料余量。 [0026] The compositions of the present invention comprises the following components is made • clothianidin deltamethrin Granules: clothianidin 1% ~ 60%, ~ 40% 1% deltamethrin, binder 0.5 % ~ 8% ~ 4% 1% wetting agent, release agent 1% ~ 8%, the balance filler. [0027] 将本发明所述的杀虫剂制备成颗粒剂的方法是:将配方料混合均勻,用超微气流粉碎机粉碎,经捏合,然后加入流化床造粒干燥机中进行造粒、干燥、筛分后取样分析。 [0027] The insecticide of the present invention is prepared as granules method is: Formulation evenly mixed, pulverized by a jet mill ultrafine, kneaded, fluidized bed granulation drier followed by addition of granulating , drying, sampling and analysis after the screening.

[0028] 上述的乳化剂选自:烷基苯磺酸钙(如南京太化有限公司的农乳500#)、OP系列磷酸酯(壬基酚聚氧乙烯醚磷酸酯)、苯基酚聚氧乙基醚磷酸酯(如南京太化有限公司的600#磷酸酯)、苯乙烯聚氧乙烯醚硫酸铵盐、烷基联苯醚二磺酸镁盐、三乙醇胺盐、苄基二甲基酚聚氧乙基醚(如邢台蓝星助剂厂的农乳400#)、宁乳36#(苯乙基酚甲醛树脂聚氧乙基醚)、苯乙基酚聚氧乙基聚丙烯基醚(如邯郸市新迪亚化工有限责任公司的农乳1600#)、 环氧乙烷-环氧丙烷嵌段共聚物、壬基酚聚氧乙烯醚(如海安石化的OP系列)、蓖麻油聚氧乙烯醚(如天津宏美的EL系列)、烷基芳基聚氧丙烯聚氧乙烯醚(如南京太化的农乳33#)、烷基芳基聚氧乙烯聚氧丙烯醚(如南京太化的农乳34#)、司盘系列(山梨醇酐单硬脂酸酯)、吐温系列(失水山梨醇脂肪酸酯聚氧乙烯醚)、肪醇醇聚 [0028] The emulsifier is selected from: calcium alkylbenzenesulfonate (e.g., too Nanjing Chemical Co., Ltd. Agricultural Emulsifier 500 #), OP phosphate series (polyoxyethylene nonyl phenyl ether phosphate), poly-phenylphenol oxygen ether phosphates (e.g., too Nanjing Chemical Co., Ltd. # 600 phosphate), styrene polyoxyethylene ether sulfate salts, alkyl biphenyl ether disulfonic acid magnesium salt, triethanolamine salt, benzyldimethylamine phenol polyoxyethylene ether (e.g., additive plant agricultural Xingtai Lansing milk # 400), rather milk # 36 (phenethyl phenol formaldehyde resin polyoxyethylene ether), polyoxyethylated phenols phenethyl group polypropylene ethers (e.g. Handan Xindiya Chemical Co., Ltd. agricultural Emulsifier # 1600), an ethylene oxide - propylene oxide block copolymers, polyoxyethylene nonyl phenyl ether (e.g., MSC petrochemical OP series), castor oil polyoxyethylene ethers (such as an EL Tianjin Hiromi series), polyoxypropylene alkyl aryl polyoxyethylene ethers (e.g., too much of Nanjing agricultural Emulsifier # 33), alkylaryl polyoxyethylene polyoxypropylene ethers (e.g., Nanjing too much of the agricultural milk # 34), Span series (sorbitan monostearate), Tween series (sorbitan fatty acid esters, polyoxyethylene ethers), fatty alcohol polyglycol alcohol 乙烯醚(如邢台蓝星助剂厂的AEO系列)中的一种或多种。 One or more vinyl ether (e.g., Blue Star Xingtai additives plant AEO series) was added.

[0029] 上述分散剂选自:聚羧酸盐(例如,TERSPERSE 2500,美国亨斯迈公司出品)、木质素磺酸盐、烷基酚聚氧乙烯醚甲醛缩合物硫酸盐、烷基苯磺酸钙盐、萘磺酸甲醛缩合物钠盐、烷基酚聚氧乙烯醚、脂肪胺聚氧乙烯醚、脂肪酸聚氧乙烯酯、甘油脂肪酸酯聚氧乙烯醚中的一种或多种。 [0029] The dispersant is selected from: polycarboxylates (e.g., TERSPERSE 2500, Huntsman Corp.), lignin sulfonates, polyoxyethylene alkyl phenol formaldehyde condensate sulfates, alkylbenzenesulfonate calcium salt, sodium salt of naphthalenesulfonic acid formaldehyde condensates, polyoxyethylene alkyl phenol ethers, polyoxyethylene fatty amines, polyoxyethylene fatty acid esters, polyoxyethylene glycerol fatty acid esters, one or more vinyl ether.

[0030] 上述润湿剂选自:烷基酚聚氧乙烯基醚甲醛缩合物硫酸盐、烷基苯聚氧乙烯醚磷酸酯、苯乙基酚聚氧乙烯基醚磷酸酯、烷基硫酸盐、烷基磺酸盐(例如TERSPERSE 2425,美国亨斯迈公司出品)、萘磺酸盐(例如ΝΝ0)、十二烷基硫酸钠、拉开粉BX、润湿渗透剂F、 十二烷基苯磺酸中的一种或多种。 [0030] The wetting agent is selected from: polyoxyethylene alkylphenol ether sulfates formaldehyde condensate, polyoxyethylene alkyl ether phosphate, polyoxyethylene phenethyl phenol ether phosphates, alkyl sulfates , alkyl sulfonates (e.g. TERSPERSE 2425, Huntsman Corp.), naphthalenesulfonates (e.g. ΝΝ0), sodium lauryl sulfate, opened powder BX, wetting penetrant F., dodecyl one or more of sulfonic acid.

[0031] 所述崩解剂选自:硫酸铵、膨润土、尿素、丁二酸、碳酸氢钠、氯化铝、柠檬酸中的一种或多种。 [0031] The disintegrant is selected from: ammonium sulfate, bentonite, urea, succinic acid, sodium bicarbonate, aluminum chloride, one or more of citric acid.

[0032] 上述防冻剂选自:乙二醇、丙二醇、丙三醇、甘油、尿素中的一种或多种。 [0032] The antifreezing agent is selected from: one or more of ethylene glycol, propylene glycol, glycerol, glycerine, urea is.

[0033] 上述增稠剂选自:黄原胶、羟甲基纤维素、羟乙基纤维素、甲基纤维素、硅酸铝美、 聚乙烯醇中的一种或多种。 [0033] The thickening agent is selected from: xanthan gum, hydroxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose, aluminum silicate United States, one or more of polyvinyl alcohol.

[0034] 上述消泡剂选自:硅酮类化合物、硅油、C8-10脂肪醇类化合物、C10-20饱和脂肪酸类化合物中的一种或多种。 [0034] The defoaming agent is selected from: one or more silicone-based compounds, silicone oils, compounds C8-10 fatty alcohols, C10-20 saturated fatty acids in the compound.

[0035] 上述粘结剂选自:聚乙烯醇、糊精、羟甲基纤维素、聚乙烯吡咯烷酮、褐藻酸钠、木质磺酸钙等。 [0035] The binder is selected from: polyvinyl alcohol, dextrin, hydroxymethyl cellulose, polyvinylpyrrolidone, sodium alginate, calcium lignosulfonate.

[0036] 上述缓释剂选自:甲基纤维素、羟甲基纤维素,改性淀粉、阿拉伯胶、聚乙烯醇等。 [0036] The release agent is selected from: methyl cellulose, hydroxymethyl cellulose, modified starch, gum arabic, polyvinyl alcohol and the like.

[0037] 上述的填料选自:高岭土、陶土、硅藻土、膨润土、白炭黑、凹凸棒土、淀粉、轻质碳酸钙中的一种或多种。 [0037] The filler is selected from: one or more of kaolin, china clay, diatomaceous earth, bentonite, white carbon, attapulgite, starch, light calcium.

[0038] 本发明还提供所述的杀虫组合物在防治农田害虫方面的应用。 [0038] The present invention further application of the pesticidal composition in combating agricultural pests provided.

[0039] 所述的农田害虫包括飞虱科、蚜虫科、粉虱科或叶蝉科的害虫。 [0039] said agricultural pests include planthoppers, aphids Branch, or Aleyrodidae insects of the Cicadellidae. 所述的农田害虫优选包括甘蓝蚜、棉蚜、麦蚜、桃蚜、小绿斑叶蝉、棉铃虫、蓟马、甘薯粉虱或温室粉虱。 Preferably said agricultural pest comprising cabbage aphid, cotton aphid, wheat aphid, Myzus persicae, small green leafhopper, cotton bollworm, thrips, sweetpotato whitefly or glasshouse whitefly.

[0040] 本发明的优点在于:(1)与单剂相比,药效高、持效期长、延缓了害虫抗药性的产生;(2)扩大了害虫防治谱,一药多治,减少了用药量及用药次数,降低了成本;(3)对抗性蚜虫、粉虱具有很好的防治效果;(4)具有低毒、低残留、安全等特点。 [0040] The advantage of the present invention is that: (1) Compared with the single dose, high efficacy, long duration, delaying the development of resistance of pests; (2) expanding the spectrum of pest control, a multi-drug treatment, to reduce the the dosage and frequency of administration, reducing the cost; (3) antagonistic aphids, whiteflies has good control effect; (4) having a low toxicity and residue, and security features. 具体实施方式 Detailed ways

[0041] 下面结合实例对本发明内容作进一步说明,噻虫胺> 95%,高效氯氟氰原药^92% (江苏扬农化工股份有限公司),七氟菊酯原药> 95% (江苏扬农化工股份有限公司)、溴氰菊酯原药彡98.5% (江苏扬农化工股份有限公司)。 [0041] The following examples of the present invention in conjunction with further illustrated, clothianidin> 95%, cyhalothrin ^ 92% of the original drug (Aminoantipyrine Chemical Co., Ltd.), tefluthrin TC> 95% (Jiangsu Young farmers Chemical Co., Ltd.), the original drug San deltamethrin 98.5% (Yangzhou agricultural Chemical Co., Ltd.).

[0042] 制剂实例1 高效氯氟氰·噻虫胺水分散粒剂 [0042] Formulation Example 1-cyhalothrin clothianidin water dispersible granules

[0043] IOg高效氯氟氰、60g噻虫胺、6g十二烷基苯磺酸钠、4g烷基萘磺酸盐甲醛缩合物、 Ig改性淀粉、硅藻土补至100g。 [0043] IOg cyhalothrin, clothianidin 60g, 6g of sodium dodecylbenzenesulfonate, 4g alkylnaphthalene sulfonate formaldehyde condensate, an Ig modified starches, diatomaceous earth made up to 100g. 混合粉碎制粒成为70%高效氯氟氰·噻虫胺水分散粒剂。 Mixing and pulverizing 70% of granulating become cyhalothrin clothianidin water-dispersible granules. 制剂实例2 :45%高效氯氟氰·噻虫胺悬浮剂 Formulation Example 2: 45% · cyhalothrin clothianidin SC

[0044] 5g高效氯氟氰、40g噻虫胺、5g农乳34#、5g聚羧酸盐、5g乙二醇、0. Ig黄原胶、Ig 改性淀粉、0. 5g硅酮类化合物、水补至100g。 [0044] 5g cyhalothrin, 40g clothianidin, 5g Nongru 34 #, 5g polycarboxylates, 5g of ethylene glycol, 0. Ig xanthan gum, Ig modified starch, 0. 5g silicone-based compound water up to 100g. 混合研磨制成45%高效氯氟氰·噻虫胺悬浮剂。 Mix mulled-cyhalothrin 45% clothianidin suspending agents.

[0045] 制剂实例3 高效氯氟氰·噻虫胺颗粒剂 [0045] Formulation Example 3-cyhalothrin clothianidin granules

[0046] 15g高效氯氟氰、35g噻虫胺、4g萘磺酸盐、4g聚乙烯醇、淀粉补至100g。 [0046] 15g cyhalothrin, clothianidin 35g, 4g naphthalene sulfonate, 4g of polyvinyl alcohol, starch up to 100g. 混合粉碎制粒成为50%高效氯氟氰·噻虫胺颗粒剂。 Mixing and pulverizing 50% of granulating become cyhalothrin · clothianidin granules.

[0047] 制剂实例4 : 15%噻虫胺·七氟菊酯水分散粒剂 [0047] Formulation Example 4: 15% of clothianidin · tefluthrin water dispersible granules

[0048] IOg七氟菊酯、5g噻虫胺、6g聚羧酸盐、3g烷基磺酸盐、Ig改性淀粉、硅藻土补至100g。 [0048] IOg tefluthrin, 5g clothianidin, polycarboxylates 6g, 3g alkyl sulfonate, an Ig modified starches, diatomaceous earth made up to 100g. 混合粉碎造粒制成15%噻虫胺·七氟菊酯水分散粒剂。 Mixing and pulverizing 15% of clothianidin pelletization amine tefluthrin water dispersible granules.

[0049] 制剂实例5 :25%噻虫胺·七氟菊酯悬浮剂 [0049] Formulation Example 5: 25% of clothianidin suspension · tefluthrin

[0050] 20g噻虫胺、5g七氟菊酯、5g聚氧乙烯醚、5g聚羧酸盐、5g乙二醇、0. Ig黄原胶、Ig 改性淀粉、0. 5g硅酮类化合物、水补至100g。 [0050] 20g of clothianidin, 5g tefluthrin, 5g polyoxyethylene ethers, 5g polycarboxylates, 5g of ethylene glycol, 0. Ig xanthan gum, Ig modified starch, 0. 5g silicone-based compound water up to 100g. 混合研磨制成25%噻虫胺•七氟菊酯悬浮剂。 Mix mulled • 25% of clothianidin tefluthrin suspending agents.

[0051] 制剂实例6 噻虫胺·七氟菊酯颗粒剂 [0051] Formulation Example 6 clothianidin · tefluthrin granule

[0052] 15g七氟菊酯、25g噻虫胺、6g烷基磺酸盐、5g改性淀粉、硅藻土补至100g,混合粉碎造粒制成40%噻虫胺·七氟菊酯颗粒剂。 [0052] 15g tefluthrin, clothianidin 25g, 6g alkyl sulfonates, 5g modified starches, diatomaceous earth up to 100g, 40% mixed and ground pelletization clothianidin particles tefluthrin · agents.

[0053] 制剂实例7 :35%噻虫胺·溴氰菊酯水分散粒剂 [0053] Formulation Example 7: 35% of clothianidin · deltamethrin water dispersible granules

[0054] 15g噻虫胺、20g溴氰菊酯、6g木质素磺酸盐、3g烷基磺酸盐、4g甲基纤维素、5g硫酸铵、硅藻土补至100g。 [0054] 15g of clothianidin, 20g deltamethrin, lignosulfonates 6g, 3g alkylsulfonates, 4g methylcellulose, 5g of ammonium sulfate, diatomaceous earth made up to 100g. 混合粉碎造粒制成35%噻虫胺·溴氰菊酯水分散粒剂。 Mixing and pulverizing 35% of clothianidin pelletization amine deltamethrin water dispersible granules.

[0055] 制剂实例8 : 15%噻虫胺·溴氰菊酯悬浮剂 [0055] Formulation Example 8: 15% of clothianidin deltamethrin suspension ·

[0056] Sg噻虫胺、7g溴氰菊酯、6g烷基苯磺酸钙盐、4g萘磺酸盐、5g乙二醇、0. Ig黄原胶、Ig阿拉伯胶、0. 5g硅酮类化合物、水补至100g。 [0056] Sg clothianidin, 7g deltamethrin, 6g calcium alkylbenzenesulfonate, 4g naphthalenesulfonate, 5g of ethylene glycol, 0. Ig xanthan gum, Ig acacia, 0. 5g Silicone compounds, water up to 100g. 混合研磨制成15%噻虫胺·溴氰菊酯悬浮剂。 Mix mulled · 15% of clothianidin deltamethrin suspension.

[0057] 制剂实例9 噻虫胺·溴氰菊酯颗粒剂 [0057] Formulation Example 9 clothianidin · deltamethrin granules

[0058] 25g噻虫胺、5g溴氰菊酯、6g烷基磺酸盐、5g聚乙烯醇、淀粉补至100g,混合粉碎造粒制成30%噻虫胺·溴氰菊酯颗粒剂。 [0058] 25g of clothianidin, 5g deltamethrin, alkylsulfonates 6g, 5g polyvinyl alcohol, starch up to 100g, 30% mixed and ground pelletization Clothianidin · deltamethrin granules.

[0059] 实施应用例一:防治十字花科蔬菜(甘蓝)蚜虫田间药效试验 [0059] Example embodiments of an application: prevention of cruciferous vegetables (cabbage) field efficacy trials aphids

[0060] 作物:十字花科蔬菜(甘蓝);防治对象:蚜虫 [0060] Crop: cruciferous vegetables (cabbage); control object: Aphids

[0061] 处理药剂防治十字花科蔬菜(甘蓝)蚜虫药效如表1 : [0061] Control processing agent cruciferous vegetables (cabbage) aphids efficacy as shown in Table 1:

[0062] 表1. [0062] Table 1.

[0063]处理名称 稀释倍数 虫口基数 药后3天 药后7天 残虫数 防效(%) 残虫数 防效(%)制剂实例1 8000 876 90 89.72 88 90.00制剂实例4 2000 923 92 90.03 85 90.79制剂实例7 4000 899 88 90.21 85 90.5550%噻虫胺WDG 6500 899 114 87.32 142 84.202.5%高效氯氟氰EC 2000 825 255 69.09 289 64.97 [0063] 3 days after the drug seven days residues insects Number control effect (%) after treatment Name dilution insect population base drug residues insects Number of control efficacy (%) Formulation Example 1,800,087,690 89.72 88 90.00 Formulation Example 4,200,092,392 90.03 85 90.79 formulation example 85 7400089988 90.21 90.5550% clothianidin WDG 6500 899 114 87.32 142 84.202.5% cyhalothrin EC 2000 825 255 69.09 289 64.97

[0064] 由表1可知,本发明制剂对十字花科蔬菜(甘蓝)蚜虫有较好的速效性,3天后防效在89%以上,7天后防效在90%以上,对十字花科蔬菜(甘蓝)蚜虫的防治效果优于对照药剂,并且在本试验用药范围内对靶标作物及有益生物安全。 [0064] As apparent from Table 1, the formulations of the present invention has good fast-acting aphids of cruciferous vegetables (cabbage), 3 days at 89% efficiency defense, the defense 7 days over 90% efficiency, Crucifer (cabbage) aphids control effects than the control drug, and the drug within the scope of the present experiment the target crop safety and beneficial organisms.

[0065] 实施应用例二:防治柑桔黑刺粉虱田间药效试验 [0065] Application Example Two: Prevention citrus spiny whitefly Field Trial

[0066] 作物:柑桔;防治对象:黑刺粉虱 [0066] Crop: Citrus; Control Object: spiny whitefly

[0067] 处理药剂防治柑桔黑刺粉虱药效如表2。 [0067] Processing agents to control citrus spiny whitefly efficacy in Table 2.

[0068] 表2. [0068] Table 2.

[0069] [0069]

Figure CN102379308AD00071

[0070] 由表2可知,本发明制剂对防治柑桔黑刺粉虱有较好的速效性及持效性,并且其药效均优于对照,防效均达到80%以上。 [0070] As apparent from Table 2, the formulations of the present invention to control citrus spiny whitefly has good fast-acting and holding effect, and its efficacy than the control, control efficacy over 80%. 在本试验范围内,本发明药剂对靶标作物及有益生物安全。 In the range of the experiment, the agent of the present invention, the target crop safety and beneficial organisms.

[0071] 实施应用例三:防治甘蓝蚜虫室内毒力测定 [0071] Application Example III: Toxicity assay Cabbage aphids

[0072] 将两种单剂分别按噻虫胺与高效氯氟氰菊酯比例(有效成分)1 : 2、1 : 4、1 : 8、 2 : 1、4 : UlO : 1混合配成二元复配剂作为五个处理,进行室内生物测定增效作用。 [0072] Both single dose and clothianidin respectively cyhalothrin ratio (active ingredient) 1: 2,1: 4,1: 8, 2: 1,4: UlO: 1 mixing two dubbed as the five-membered complex treatment agent, synergism for bioassay. 供试药剂为噻虫胺、高效氯氟氰菊酯;供试昆虫为甘蓝蚜虫。 Test agent is clothianidin, cyhalothrin; cabbage aphid test insects. 称取一定量噻虫胺和高效氯氟氰菊酯原药,用丙酮和乳化剂吐温-80(0. )配成IOOOppm母液,将两种单剂分别按上述方法配制成5个处理的二元复配剂、IOOOppm噻虫胺母液、IOOOppm高效氯氟氰菊酯母液,分别用水稀释5个浓度,以清水处理作空白对照;采用浸虫、浸叶法测定,将蚜虫连同甘蓝叶片浸入药液中5秒后取出,用吸水纸吸去多余的药液或风干后,剔除有翅成蚜、若蚜,只保留无翅成蚜,将其放入培养皿中保湿饲养,然后放入25°C光照培养箱中,48小时后分别调查存活虫数,计算死亡率、毒力和共毒系数。 Weigh a certain amount of clothianidin and Cyhalothrin original drug, acetone and emulsifier Tween 80 (0.) The mother liquor IOOOppm dubbed, the two single agents are as described above formulated into five treatment Determination leaf dipping method, together with cabbage leaves dipped aphids insects using dipping,; binary composite formulation, IOOOppm clothianidin liquor, IOOOppm cyhalothrin mother liquor was diluted with water five concentrations, as control treated with water liquid removed after 5 seconds, absorb excess liquid with absorbent paper, or air-dried, excluding alate aphid nymphs, leaving only wingless adult aphids, the moisture feeding it into a petri dish and then placed 25 ° C incubator light, after 48 hours the number of surviving insects were survey, mortality was calculated, and the co-toxicity coefficient virulence. 测定计算结果如下: Measurement results is calculated as follows:

[0073] 表3不同药剂对甘蓝蚜虫的毒力与共毒系数测定结果G8小时) [0073] TABLE 3 different germicide cabbage aphid co-toxicity coefficient of the measurement results G8 h)

[0074] [0074]

Figure CN102379308AD00081

[0075] 测定结果表明(表3):噻虫胺与高效氯氟氰菊酯复配后对蚜虫有显著的增效作用。 [0075] Results showed (Table 3): the clothianidin and Cyhalothrin complex has a significant synergistic effect on aphids.

[0076] 综上所述,本发明的杀虫组合物是活性成分A与活性成分B复配而成,活性成分A 为噻虫胺,活性成分B为高效氯氟氰菊酯、七氟菊酯、溴氰菊酯中的一种,此复配方案具有对蚜虫、粉虱、甜菜叶蛾、蓟马等害虫的防治具有速效性高、持效性长,一药多治的优点,与现有的单一制剂相比,除具有显著的杀虫效果外,更能有效的降低施药成本,减缓抗性的产生,减少制剂残留量,对作物无污染、安全性好,符合农药制剂的安全性要求。 [0076] In summary, the pesticidal composition is the active ingredient of the present invention, the active ingredients A and B mixed together, as active ingredients clothianidin A, B cyhalothrin as the active ingredient Spodoptera, chrysanthemum heptafluoro ester a deltamethrin in this embodiment has a complex prevention aphids, whiteflies, beet leaf miner, thrips pest quick result with a high, long holding effect, the advantages of a multi-drug treatment, and as compared to conventional single preparation, in addition to having a remarkable insecticidal effect, the more effectively reduce administration costs, slow the development of resistance, to reduce the residual amount of the formulation, the crop pollution, safety, compliance with pesticide formulations security requirements.

Claims (10)

1. 一种含有噻虫胺的复配杀虫剂,其特征在于:它由占杀虫剂总重量5%〜80%的活性成分和余量的助剂组成,且所述的活性成分由噻虫胺和拟除虫菊酯类化合物复配组成, 噻虫胺和拟除虫菊酯类化合物的重量比为1 : 99〜99 : 1。 An amine-containing compound clothianidin pesticide, characterized in that: it consists of 5% ~ 80% of the total weight of the pesticide active ingredient and the remainder consisting of additives, and the active ingredient from the pyrethroid and clothianidin compound combination composed, by weight of pyrethroid and clothianidin compound ratio is 1: 99~99: 1.
2.权利要求1所述的复配杀虫剂,其特征在于:所述的拟除虫菊酯类化合物选自高效氯氟氰菊酯、七氟菊酯或溴氰菊酯中的一种或两种以上的混合物。 2. The compound according to claim 1 pesticides, characterized in that: the pyrethroid compound is selected from cyhalothrin, deltamethrin, or tefluthrin one kind or two mixtures of the above.
3.权利要求1所述的复配杀虫剂,其特征在于:所述的助剂是润湿剂、分散剂、缓释齐U、 崩解剂、乳化剂、防冻剂、增稠剂、消泡剂、粘结剂或填料中的一种或两种以上的混合物。 Insecticide compound according to claim 1, wherein: said auxiliaries are wetting agents, dispersants, release homogeneous U, disintegrants, emulsifiers, antifreeze agents, thickening agents, antifoaming agent, binder, or filler over one or a mixture of two.
4.权利要求3所述的复配杀虫剂,其特征在于:所述的乳化剂选自烷基苯磺酸钙、OP 系列磷酸酯、苯基酚聚氧乙基醚磷酸酯、苯乙烯聚氧乙烯醚硫酸铵盐、烷基联苯醚二磺酸镁盐、三乙醇胺盐、苄基二甲基酚聚氧乙基醚、宁乳36#、苯乙基酚聚氧乙基聚丙烯基醚、环氧乙烷-环氧丙烷嵌段共聚物、壬基酚聚氧乙烯醚、蓖麻油聚氧乙烯醚、烷基芳基聚氧丙烯聚氧乙烯醚、烷基芳基聚氧乙烯聚氧丙烯醚、司盘系列、吐温系列或肪醇醇聚氧乙烯醚中的一种或多种;所述分散剂选自聚羧酸盐、木质素磺酸盐、烷基酚聚氧乙烯醚甲醛缩合物硫酸盐、烷基苯磺酸钙盐、萘磺酸甲醛缩合物钠盐、烷基酚聚氧乙烯醚、脂肪胺聚氧乙烯醚、脂肪酸聚氧乙烯酯或甘油脂肪酸酯聚氧乙烯醚中的一种或多种;所述润湿剂选自烷基酚聚氧乙烯基醚甲醛缩合物硫酸盐、烷基苯聚氧乙烯 Insecticide compound according to claim 3, wherein: said emulsifier is selected from calcium alkylbenzenesulfonate, OP series phosphate, polyoxyethylene phenylphenol ether phosphate ester, a styrene polyoxyethylene ether sulfate salts, alkyl biphenyl ether disulfonic acid magnesium salt, triethanolamine salt, benzyl dimethyl phenol polyoxyethylene ether, # 36 rather milk, phenethyl polyoxyethylated polypropylene ether, ethylene oxide - propylene oxide block copolymers, polyoxyethylene nonyl phenyl ether, polyoxyethylene castor oil ethers, polyoxypropylene alkyl aryl polyoxyethylene ethers, alkyl aryl polyoxyethylene polyoxypropylene ethers, Span series, Tween series or fatty alcohol polyethylene oxide alcohols, one or more vinyl ether; the dispersant is selected from polycarboxylates, lignin sulfonates, alkylphenol vinyl ether sulfates formaldehyde condensate, calcium alkylbenzene sulfonate, sodium salt of naphthalenesulfonic acid formaldehyde condensates, polyoxyethylene alkyl phenol ethers, polyoxyethylene fatty amines, polyoxyethylene fatty acid ester or glycerin fatty acid ester one or more polyoxyethylene ether; the wetting agent is selected from polyoxyethylene alkylphenol ether sulfates formaldehyde condensate, polyoxyethylene alkyl 醚磷酸酯、苯乙基酚聚氧乙烯基醚磷酸酯、烷基硫酸盐、烷基磺酸盐、萘磺酸盐、十二烷基硫酸钠、拉开粉BX、润湿渗透剂F或十二烷基苯磺酸中的一种或多种;所述崩解剂选自硫酸铵、膨润土、尿素、丁二酸、碳酸氢钠、氯化铝或柠檬酸中的一种或多种;所述防冻剂选自乙二醇、丙二醇、丙三醇、甘油或尿素中的一种或多种;所述增稠剂选自黄原胶、羟甲基纤维素、羟乙基纤维素、甲基纤维素、硅酸铝美或聚乙烯醇中的一种或多种;所述消泡剂选自硅酮类化合物、硅油、C8-10脂肪醇类化合物或C10-20 饱和脂肪酸类化合物中的一种或多种;所述粘结剂选自聚乙烯醇、糊精、羟甲基纤维素、聚乙烯吡咯烷酮、褐藻酸钠或木质磺酸钙中的一种或多种;所述缓释剂选自甲基纤维素、羟甲基纤维素,改性淀粉、阿拉伯胶或聚乙烯醇中的一种或多种;所述的填料 Ether phosphates, polyoxyethylene phenethyl phenol ether phosphates, alkyl sulfates, alkyl sulfonates, naphthalene sulfonates, sodium lauryl sulfate, opened powder BX, F or wetting penetrant One or more of dodecylbenzenesulfonic acid; the disintegrant is selected from one kind of ammonium sulfate, bentonite, urea, succinic acid, sodium bicarbonate, citric acid or aluminum chloride or more ; the cryoprotectant is selected from one or more of ethylene glycol, propylene glycol, glycerol, glycerine or urea; said thickener is selected from xanthan gum, hydroxymethyl cellulose, hydroxyethyl cellulose , methyl cellulose, polyvinyl alcohol or US aluminum silicate, one or more; the defoaming agent is selected from silicone-based compounds, silicone oils, fatty alcohols C8-10 or C10-20 unsaturated fatty acids compounds one or more compounds; the binder is selected from polyvinyl alcohols, dextrins, hydroxymethyl cellulose, polyvinyl pyrrolidone, sodium alginate or calcium lignosulfonates of one or more; the said release agent is selected from methyl cellulose, hydroxymethyl cellulose, modified starch, acacia or one or more polyvinyl alcohol; said filler 自高岭土、陶土、 硅藻土、膨润土、白炭黑、凹凸棒土、淀粉或轻质碳酸钙中的一种或多种。 Since kaolin, china clay, diatomaceous earth, bentonite, white carbon, attapulgite, starch, precipitated calcium carbonate, or of one or more.
5.权利要求1所述的复配杀虫剂,其特征在于,由如下组分组成:高效氯氟氰〜 20%、噻虫胺〜80%、润湿剂〜4%、分散剂〜10%、缓释剂〜8%、崩解剂1%〜4%、填料余量。 Insecticide compound according to claim 1, characterized by the following constituents: ~ 20% cyhalothrin, clothianidin ~ 80% ~ 4% wetting agent, dispersing agent ~ 10 % ~ 8% release agent, 1% ~ 4% disintegrant, filler margin.
6.权利要求1所述的复配杀虫剂,其特征在于,由如下组分组成:高效氯氟氰〜 20%、噻虫胺〜60%、乳化剂〜4%、分散剂2%〜6%、缓释剂0. 〜3%、防冻剂〜8%、增稠剂0. 〜1%、消泡剂0. 〜0. 5%、水余量。 Insecticide compound according to claim 1, characterized by the following constituents: ~ 20% cyhalothrin, clothianidin ~ 60% ~ 4% emulsifier, 2% - dispersing agent 6%, slow-release agent 0.5 ~ 3% ~ 8% antifreeze, 0.5 ~ 1% thickener, antifoaming agent 0.5 ~ 0. 5%, balance water.
7.权利要求1所述的复配杀虫剂,其特征在于,由如下组分组成:高效氯氟氰〜 20%、噻虫胺〜60%、粘结剂0. 5%〜8%、润湿剂〜4%、缓释剂〜8%、填料余量。 Insecticide compound according to claim 1, characterized by the following constituents: ~ 20% cyhalothrin, clothianidin ~ 60%, 0.5% ~ 8% binder, ~ 4% wetting agent, release agent ~ 8%, the balance filler.
8.权利要求1所述的杀虫组合物在防治农田害虫方面的应用。 The insecticidal composition of claim 1 in the prevention and treatment of agricultural pest application of claim.
9.权利要求8所述的应用,其特征在于:所述的农田害虫包括飞虱科、蚜虫科、粉虱科或叶蝉科的害虫。 9. The use according to claim 8, wherein: said agricultural pests include planthoppers, aphids Branch, or Aleyrodidae insects of the Cicadellidae.
10.权利要求8所述的应用,其特征在于:所述的农田害虫包括甘蓝蚜、棉蚜、麦蚜、桃蚜、小绿斑叶蝉、棉铃虫、蓟马、甘薯粉虱或温室粉虱。 10. The use according to claim 8, wherein: said agricultural pests include cabbage aphid, cotton aphid, wheat aphid, Myzus persicae, small green leafhopper, cotton bollworm, thrips, sweetpotato whitefly or glasshouse powder louse.
CN201110281635XA 2011-09-21 2011-09-21 Mixed insecticidal composition containing clothianidin and application of mixed insecticidal composition CN102379308A (en)

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CN102696659A (en) * 2012-05-03 2012-10-03 陕西韦尔奇作物保护有限公司 Insecticidal composition containing tefluthrin and neonicotinoids
CN102763681A (en) * 2012-08-13 2012-11-07 广西汇丰生物科技有限公司 Granula containing clothianidin
CN104686564A (en) * 2015-03-16 2015-06-10 广东中迅农科股份有限公司 Tefluthrin, clothianidin and pyraclostrobin containing pesticide composition
CN106386842A (en) * 2016-08-17 2017-02-15 陕西西大华特科技实业有限公司 An insecticidal composition containing clothianidin and lambda-cyhalothrin
CN106470549A (en) * 2014-06-24 2017-03-01 拜耳作物科学股份公司 The purposes of active compound combinations
CN106614698A (en) * 2016-10-20 2017-05-10 安徽省农业科学院植物保护与农产品质量安全研究所 Composition with clothianidin and deltamethrin and method for preparing composition

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CN1646017A (en) * 2002-01-31 2005-07-27 拜尔农作物科学股份公司 Synergistic insecticidal mixtures

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CN1477930A (en) * 2000-10-06 2004-02-25 孟山都技术有限公司 Method for seed treatment with combinatons of pyrethrins/pyrethroids and clothianidin
CN1646017A (en) * 2002-01-31 2005-07-27 拜尔农作物科学股份公司 Synergistic insecticidal mixtures

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102696659A (en) * 2012-05-03 2012-10-03 陕西韦尔奇作物保护有限公司 Insecticidal composition containing tefluthrin and neonicotinoids
CN102696659B (en) * 2012-05-03 2016-12-28 陕西韦尔奇作物保护有限公司 A kind of Pesticidal combination containing Tefluthrin Yu anabasine
CN102763681A (en) * 2012-08-13 2012-11-07 广西汇丰生物科技有限公司 Granula containing clothianidin
CN102763681B (en) 2012-08-13 2014-08-20 广西汇丰生物科技有限公司 Granula containing clothianidin
CN106470549A (en) * 2014-06-24 2017-03-01 拜耳作物科学股份公司 The purposes of active compound combinations
CN104686564A (en) * 2015-03-16 2015-06-10 广东中迅农科股份有限公司 Tefluthrin, clothianidin and pyraclostrobin containing pesticide composition
CN106386842A (en) * 2016-08-17 2017-02-15 陕西西大华特科技实业有限公司 An insecticidal composition containing clothianidin and lambda-cyhalothrin
CN106614698A (en) * 2016-10-20 2017-05-10 安徽省农业科学院植物保护与农产品质量安全研究所 Composition with clothianidin and deltamethrin and method for preparing composition

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