CN102763681A - Granula containing clothianidin - Google Patents
Granula containing clothianidin Download PDFInfo
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- CN102763681A CN102763681A CN2012102867375A CN201210286737A CN102763681A CN 102763681 A CN102763681 A CN 102763681A CN 2012102867375 A CN2012102867375 A CN 2012102867375A CN 201210286737 A CN201210286737 A CN 201210286737A CN 102763681 A CN102763681 A CN 102763681A
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- humic acid
- thiophene worm
- worm amine
- granule
- tefluthrin
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Abstract
Granula containing clothianidin comprises, by weight, 0.01%-10% of one of bifenthrin, cyfluthrin or tefluthrin, 0.01%-15% of clothianidin, 0.1%-40% of humic acid, 1%-15% of auxiliaries, 1%-10% of binder and the balance carriers. The granula containing the clothianidin is used for preventing and controlling soil insects, nematode and pests on the ground of crops such as sugarcanes, peanuts, corns and bananas, and is obvious in synergistic effect, good in prevention and control effect and long in a validity period. The granula can obviously improve a preventing and control effect of the crops on root knot nematode and pathogenic bacteria, simultaneously promotes development of crop root stocks and growth of plants, and improves yield and quality of the crops.
Description
Technical field
The present invention relates to the pesticidal preparations field, specifically is the granule of clothianidin-containing.
Background technology
At present, domestic cultural control soil insect is generally adopted granule, and active component is mainly high malicious carbofuran, terbufos, thimet, Isofenphos methyl, phonamiphos etc., the use of these medicaments, and three aspect problems below existing:
1, very big to the producer and user's harm, because these composition toxicity height, annual all the generation used the dead accident of these high toxicants poisonings, the serious threat producer and user's life and health because of producing in a large number.
2, residual life long, cause residual the exceeding standard of agricultural product farmings, have a strong impact on the quality and the price of agricultural product, become the major obstacles that China's non-polluted farm product is produced, have influence on the people's health; And the use of a large amount of high-toxic pesticides causes serious destruction to environment and ecology.
3, the long-term single use of these high toxicants causes the resistance of insect serious, thereby makes peasant household have to strengthen dosage, has further increased the weight of the agricultural residual risk that exceeds standard and poison, and has increased the drug cost of peasant household.
In recent years; With middle low toxicity active composition such as AVM, chlopyrifos, orthene etc. is that master's granule also is applied in the agricultural gradually; Though solved high, the residual problem such as exceed standard of toxicity; But the action spectrum of these active components is narrower, satisfied not the demand of peasant household, and use cost is higher.Chinese patent 201110281635.X discloses a kind of complex insecticidal composition and application thereof that contains thiophene worm amine; Form by the active component of the 5%-80% that accounts for insecticidal total weight and the auxiliary agent of surplus; Active component is by thiophene worm amine and pyrethroid coumpound is composite forms, and the weight ratio of thiophene worm amine and pyrethroid coumpound is 1:99-99:1; And disclose by gamma cyhalothrin 1%-20%, thiophene worm amine 1%-60%, binding agent 0.5%-8%, wetting agent 1%-4%, sustained release agent 1%-8% and filler and supplied 100% granule processed; Supply 100% granule processed and supply 100% granule processed by thiophene worm amine 1%-60%, tefluthrin 1%-30%, binding agent 0.5%-8%, wetting agent 1%-4%, sustained release agent 1%-8% and filler by thiophene worm amine 1%-60%, decis 1%-40%, binding agent 0.5-8%, wetting agent 1%-4%, sustained release agent 1%-8% and filler.This invention is compared with single agent, and drug effect is high, the lasting period is long, has enlarged the control spectrum of insect, low toxicity, low-residual, safety.But should invent less to the regulating action of crop, heavier for pest damage, that growing way is more weak crop belts, though can effectively control the generation of insect pest, it is slower that crop growing state recovers, a little less than the resistance against diseases.
Summary of the invention
The granule that the purpose of this invention is to provide a kind of clothianidin-containing solves problems such as the granule be used for pest control at present is little to the regulating action of crop, insect prevention and control ensuing crop growing way recovers slower, and resistance against diseases is weak.
The present invention solves the problems of the technologies described above the technical scheme of being taked: the granule of clothianidin-containing; Form by following components in weight percentage: pyrethroid insecticidal constituent 0.01%～10%; Thiophene worm amine 0.01%～15%, humic acid 0.1%～40%, auxiliary agent 1%～15%; Binding agent 1%～10%, carrier supplies 100%.
Described pyrethroid insecticidal constituent is any in Biphenthrin, cyfloxylate or the tefluthrin.
Described auxiliary agent is one or more combinations in lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate, naphthalenesulfonate formaldehyde condensation compound, sodium butylnaphthalenesulfonate, AEO, the dioctyl sodium sulfosuccinate.
Described binding agent is one or more combinations in starch, sucrose, polyvinyl alcohol, the carboxymethyl cellulose.
Described carrier is one or more combinations in white carbon black, diatomite, active carbon, kaolin, bentonite, calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulphate, sodium sulphate, calcium sulphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate, talcum powder, river sand, the flyash.
The preparation method of the granule of described clothianidin-containing is: by formula rate thiophene worm amine, pyrethroid insecticidal constituent, humic acid, auxiliary agent, binding agent and carrier are mixed; Pulverize; Stir after adding water-wet; Use the screw extruder pelletizer granulation again, sieve after the drying, promptly get the granule of clothianidin-containing of the present invention.
The granule of clothianidin-containing of the present invention is used to prevent and treat soil insect, nematode of crops such as sugarcane, peanut, corn, banana and insect on the ground, comprises grub, root-knot nematode, thrips, aphid, snout moth's larva etc.
The present invention has following beneficial effect:
(1) active ingredient of the present invention is made up of thiophene worm amine, pyrethroid insecticidal constituent and humic acid, and three kinds of component synergistic functions are obvious, and prevention effect is good, and the lasting period is long, reduces spraying times and formulation rate, reduces drug cost.
(2) the present invention not only can realize the generation of prevention and control insect pest effectively, and can significantly improve the prevention effect of crop to root-knot nematode and pathogen, promotes crop root development and plant strain growth simultaneously, improves the yield and quality of crop.
(3) with calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulphate, sodium sulphate, calcium sulphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate during as carrier; Can supply nutrient components such as the required N of crop, P, K, S, Ca, further improve output.
Embodiment
Except that specified otherwise was arranged, the content of granule of the present invention was weight percent content.
Embodiment 1
0.12% thiophene worm amine biphenyl humic acid granule
Prescription: thiophene worm amine 0.01kg, Biphenthrin 0.01kg, humic acid 0.1kg, calcium lignosulfonate 0.4kg, lauryl sodium sulfate 0.6kg, polyvinyl alcohol 1kg, ammonium chloride 10kg, ammonium dihydrogen phosphate (ADP) 25kg, kaolin 20kg, sodium sulphate complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 0.12% thiophene worm amine biphenyl humic acid granule.
Embodiment 2
2% thiophene worm amine biphenyl humic acid granule
Prescription: thiophene worm amine 0.3kg, Biphenthrin 0.2kg, humic acid 1.5kg, AEO 1kg, lauryl sodium sulfate 0.5kg, starch 1kg, potassium sulphate 25kg, ammonium dihydrogen phosphate (ADP) 20kg, kaolin 20kg, diatomite complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 2% thiophene worm amine biphenyl humic acid granule.
Embodiment 3
6% thiophene worm amine biphenyl humic acid granule
Prescription: thiophene worm amine 4kg, Biphenthrin 1kg, humic acid 1kg, dioctyl sodium sulfosuccinate 1kg, naphthalenesulfonate formaldehyde condensation compound 3kg, sucrose 2kg, carboxymethyl cellulose 3kg, ammonium sulfate 15kg, calcium carbonate 20kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 6% thiophene worm amine biphenyl humic acid granule.
Embodiment 4
10% thiophene worm amine biphenyl humic acid granule
Prescription: thiophene worm amine 4kg, Biphenthrin 2kg, humic acid 4kg, sodium butylnaphthalenesulfonate 4kg, AEO 2kg, sucrose 2kg, carboxymethyl cellulose 3kg, potassium dihydrogen phosphate 18kg, active carbon 5kg, flyash complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 10% thiophene worm amine biphenyl humic acid granule.
Embodiment 5
15% thiophene worm amine biphenyl humic acid granule
Prescription: thiophene worm amine 3kg, Biphenthrin 2kg, humic acid 10kg, calcium lignosulfonate 4kg, naphthalenesulfonate formaldehyde condensation compound 2kg, sucrose 3kg, starch 5kg, talcum powder 20kg, calcium dihydrogen phosphate complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 15% thiophene worm amine biphenyl humic acid granule.
Embodiment 6
15.11% thiophene worm amine biphenyl humic acid granule
Prescription: thiophene worm amine 15kg, Biphenthrin 0.01kg, humic acid 0.1kg, calcium lignosulfonate 2kg, AEO 4kg, polyvinyl alcohol 5kg, starch 5kg, kaolin 15kg, calcium carbonate complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 15.11% thiophene worm amine biphenyl humic acid granule.
Embodiment 7
10.11% thiophene worm amine biphenyl humic acid granule
Prescription: thiophene worm amine 0.01kg, Biphenthrin 10kg, humic acid 0.1kg, sodium lignin sulfonate 3kg, AEO 4kg, polyvinyl alcohol 4kg, sucrose 5kg, river sand 15kg, calcium carbonate complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 10.11% thiophene worm amine biphenyl humic acid granule.
Embodiment 8
25.1% thiophene worm amine biphenyl humic acid granule
Prescription: thiophene worm amine 15kg, Biphenthrin 10kg, humic acid 0.1kg, calcium lignosulfonate 5kg, AEO 2kg, polyvinyl alcohol 3kg, starch 4kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 25.1% thiophene worm amine biphenyl humic acid granule.
Embodiment 9
30.01% thiophene worm amine biphenyl humic acid granule
Prescription: thiophene worm amine 15kg, Biphenthrin 0.01kg, humic acid 15kg, calcium lignosulfonate 3kg, sodium butylnaphthalenesulfonate 12kg, polyvinyl alcohol 5kg, sucrose 5kg, ammonium sulfate 10kg, calcium dihydrogen phosphate 10kg, bentonite complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 30.01% thiophene worm amine biphenyl humic acid granule.
Embodiment 10
40.02% thiophene worm amine biphenyl humic acid granule
Prescription: thiophene worm amine 0.01kg, Biphenthrin 0.01kg, humic acid 40kg, sodium lignin sulfonate 3kg, naphthalenesulfonate formaldehyde condensation compound 5kg, polyvinyl alcohol 5kg, starch 5kg, talcum powder 15kg, white carbon black 3kg, calcium dihydrogen phosphate complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 40.02% thiophene worm amine biphenyl humic acid granule.
Embodiment 11
65% thiophene worm amine biphenyl humic acid granule
Prescription: thiophene worm amine 15kg, Biphenthrin 10kg, humic acid 40kg, sodium butylnaphthalenesulfonate 4kg, dioctyl sodium sulfosuccinate 2kg, carboxymethyl cellulose 5kg, sucrose 4kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 65% thiophene worm amine biphenyl humic acid granule.
Embodiment 12
0.12% thiophene worm amine cyfluthrin humic acid granule
Prescription: thiophene worm amine 0.01kg, cyfloxylate 0.01kg, humic acid 0.1kg, calcium lignosulfonate 0.5kg, lauryl sodium sulfate 0.5kg, polyvinyl alcohol 1kg, ammonium chloride 20kg, ammonium dihydrogen phosphate (ADP) 25kg, kaolin 30kg, sodium sulphate complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 0.12% thiophene worm amine cyfluthrin humic acid granule.
Embodiment 13
3% thiophene worm amine cyfluthrin humic acid granule
Prescription: thiophene worm amine 0.7kg, cyfloxylate 0.3kg, humic acid 2kg, naphthalenesulfonate formaldehyde condensation compound 2kg, lauryl sodium sulfate 2kg, starch 3kg, ammonium sulfate 30kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 3% thiophene worm amine cyfluthrin humic acid granule.
Embodiment 14
8% thiophene worm amine cyfluthrin humic acid granule
Prescription: thiophene worm amine 2kg, cyfloxylate 3kg, humic acid 3kg, AEO 2kg, naphthalenesulfonate formaldehyde condensation compound 4kg, sucrose 1kg, carboxymethyl cellulose 3kg, bentonite 25kg, urea complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 8% thiophene worm amine cyfluthrin humic acid granule.
Embodiment 15
12% thiophene worm amine cyfluthrin humic acid granule
Prescription: thiophene worm amine 4kg, cyfloxylate 2kg, humic acid 6kg, sodium butylnaphthalenesulfonate 4kg, naphthalenesulfonate formaldehyde condensation compound 2kg, sucrose 7kg, carboxymethyl cellulose 3kg, urea 15kg, bentonite complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 12% thiophene worm amine cyfluthrin humic acid granule.
Embodiment 16
15.11% thiophene worm amine cyfluthrin humic acid granule
Prescription: thiophene worm amine 15kg, cyfloxylate 0.01kg, humic acid 0.1kg, calcium lignosulfonate 2kg, AEO 3kg, polyvinyl alcohol 3kg, starch 7kg, ammonium dihydrogen phosphate (ADP) 25kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 15.11% thiophene worm amine cyfluthrin humic acid granule.
Embodiment 17
10.11% thiophene worm amine cyfluthrin humic acid granule
Prescription: thiophene worm amine 0.01kg, cyfloxylate 10kg, humic acid 0.1kg, sodium lignin sulfonate 5kg, lauryl sodium sulfate 2kg, polyvinyl alcohol 4kg, sucrose 5kg, calcium carbonate 15kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 10.11% thiophene worm amine cyfluthrin humic acid granule.
Embodiment 18
25.1% thiophene worm amine cyfluthrin humic acid granule
Prescription: thiophene worm amine 15kg, cyfloxylate 10kg, humic acid 0.1kg, calcium lignosulfonate 6kg, lauryl sodium sulfate 5kg, AEO 4kg, polyvinyl alcohol 3kg, starch 4kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 25.1% thiophene worm amine cyfluthrin humic acid granule.
Embodiment 19
35.01% thiophene worm amine cyfluthrin humic acid granule
Prescription: thiophene worm amine 15kg, cyfloxylate 0.01kg, humic acid 20kg, calcium lignosulfonate 3kg, sodium butylnaphthalenesulfonate 6kg, polyvinyl alcohol 3kg, sucrose 6kg, kaolin 10kg, bentonite complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 35.01% thiophene worm amine cyfluthrin humic acid granule.
Embodiment 20
40.02% thiophene worm amine cyfluthrin humic acid granule
Prescription: thiophene worm amine 0.01kg, cyfloxylate 0.01kg, humic acid 40kg, calcium lignosulfonate 4kg, naphthalenesulfonate formaldehyde condensation compound 5kg, polyvinyl alcohol 5kg, starch 5kg, white carbon black 6kg, calcium dihydrogen phosphate complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 40.02% thiophene worm amine cyfluthrin humic acid granule.
Embodiment 21
65% thiophene worm amine cyfluthrin humic acid granule
Prescription: thiophene worm amine 15kg, cyfloxylate 10kg, humic acid 40kg, sodium butylnaphthalenesulfonate 5kg, dioctyl sodium sulfosuccinate 2kg, carboxymethyl cellulose 3kg, sucrose 5kg, calcium carbonate 10kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 65% thiophene worm amine cyfluthrin humic acid granule.
Embodiment 22
0.12% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 0.01kg, tefluthrin 0.01kg, humic acid 0.1kg, calcium lignosulfonate 0.3kg, lauryl sodium sulfate 0.7kg, polyvinyl alcohol 1kg, ammonium sulfate 20kg, kaolin 30kg, sodium sulphate complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 0.12% thiophene worm amine tefluthrin humic acid granule.
Embodiment 23
5% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 1kg, tefluthrin 2kg, humic acid 2kg, calcium lignosulfonate 1kg, AEO 3kg, polyvinyl alcohol 3kg, starch 5kg, ammonium chloride 20kg, kaolin 20kg, calcium sulphate complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 5% thiophene worm amine tefluthrin humic acid granule.
Embodiment 24
10% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 2kg, tefluthrin 3kg, humic acid 5kg, sodium lignin sulfonate 2kg, lauryl sodium sulfate 3kg, polyvinyl alcohol 3kg, sucrose 5kg, ammonium sulfate 20kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 10% thiophene worm amine tefluthrin humic acid granule.
Embodiment 25
15% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 4kg, tefluthrin 2kg, humic acid 9kg, sodium lignin sulfonate 3kg, AEO 4kg, polyvinyl alcohol 5kg, starch 5kg, ammonium sulfate 25kg, bentonite complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 15% thiophene worm amine tefluthrin humic acid granule.
Embodiment 26
30% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 2kg, tefluthrin 8kg, humic acid 20kg, calcium lignosulfonate 5kg, lauryl sodium sulfate 2kg, polyvinyl alcohol 5kg, ammonium chloride 20kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 30% thiophene worm amine tefluthrin humic acid granule.
Embodiment 27
15.11% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 15kg, tefluthrin 0.01kg, humic acid 0.1kg, sodium lignin sulfonate 3kg, AEO 2kg, sucrose 5kg, urea 20kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 15.11% thiophene worm amine tefluthrin humic acid granule.
Embodiment 28
10.11% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 0.01kg, tefluthrin 10kg, humic acid 0.1kg, sodium lignin sulfonate 5kg, AEO 3kg, polyvinyl alcohol 3kg, sucrose 5kg, urea 25kg, calcium carbonate complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 10.11% thiophene worm amine tefluthrin humic acid granule.
Embodiment 29
40.02% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 0.01kg, tefluthrin 0.01kg, humic acid 40kg, calcium lignosulfonate 5kg, AEO 3kg, polyvinyl alcohol 5kg, sucrose 3kg, kaolin 20kg, ammonium chloride complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 40.02% thiophene worm amine tefluthrin humic acid granule.
Embodiment 30
25.1% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 15kg, tefluthrin 10kg, humic acid 0.1kg, calcium lignosulfonate 5kg, AEO 2kg, polyvinyl alcohol 3kg, starch 4kg, ammonium dihydrogen phosphate (ADP) 20kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 25.1% thiophene worm amine tefluthrin humic acid granule.
Embodiment 31
55.01% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 15kg, tefluthrin 0.01kg, humic acid 40kg, calcium lignosulfonate 4kg, AEO 5kg, polyvinyl alcohol 4kg, starch 6kg, ammonium chloride 10kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 55.01% thiophene worm amine tefluthrin humic acid granule.
Embodiment 32
50.01% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 0.01kg, tefluthrin 10kg, humic acid 40kg, calcium lignosulfonate 3kg, sodium butylnaphthalenesulfonate 5kg, polyvinyl alcohol 4kg, sucrose 5kg, potassium chloride 10kg, bentonite complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 50.01% thiophene worm amine tefluthrin humic acid granule.
Embodiment 33
65% thiophene worm amine tefluthrin humic acid granule
Prescription: thiophene worm amine 15kg, tefluthrin 10kg, humic acid 40kg, sodium butylnaphthalenesulfonate 4kg, dioctyl sodium sulfosuccinate 2kg, carboxymethyl cellulose 3kg, sucrose 4kg, kaolin complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 65% thiophene worm amine tefluthrin humic acid granule.
Invention application example 1
Carry out the control of banana root-knot nematode with embodiment 1-11 products obtained therefrom,, will test to handle being provided with as follows according to the product estimated cost:
Handle 1:0.12% thiophene worm amine biphenyl humic acid granule 300kg/ mu.
Handle 2:2% thiophene worm amine biphenyl humic acid granule 12.5kg/ mu.
Handle 3:6% thiophene worm amine biphenyl humic acid granule 1.1kg/ mu.
Handle 4:10% thiophene worm amine biphenyl humic acid granule 1kg/ mu.
Handle 5:15% thiophene worm amine biphenyl humic acid granule 1.25kg/ mu.
Handle 6:15.11% thiophene worm amine biphenyl humic acid granule 0.3kg/ mu.
Handle 7:10.11% thiophene worm amine biphenyl humic acid granule 1kg/ mu.
Handle 8:25.1% thiophene worm amine biphenyl humic acid granule 0.3kg/ mu.
Handle 9:30.01% thiophene worm amine biphenyl humic acid granule 0.3kg/ mu.
Handle 10:40.02% thiophene worm amine biphenyl humic acid granule 300kg/ mu.
Handle 11:65% thiophene worm amine biphenyl humic acid granule 0.3kg/ mu.
Handle 12:2% Biphenthrin granule 5kg/ mu.
Handle 13:1% thiophene worm amine granule 5kg/ mu.
Handle 14: blank.
Above-mentioned processing is used when the banana field planting, carries out the root-knot nematode investigation of causing harm behind the medicine in 45 days, 90 days respectively, carries out determination of yield during results, and final statistics is as shown in the table:
It is thus clear that under the approaching prerequisite of use cost, embodiment 1-11 products obtained therefrom is obviously high than Biphenthrin, the preventive effect of thiophene worm amine list time spent to the preventive effect of banana root-knot nematode, the lasting period is long, and can make the banana production growth more than 20%.
Invention application example 2
Carry out the control of peanut grub and peanut aphid with embodiment 12-21 products obtained therefrom,, will test to handle being provided with as follows according to the product estimated cost:
Handle 1:0.12% thiophene worm amine cyfluthrin humic acid granule 300kg/ mu.
Handle 2:3% thiophene worm amine cyfluthrin humic acid granule 6kg/ mu.
Handle 3:8% thiophene worm amine cyfluthrin humic acid granule 1.5kg/ mu.
Handle 4:12% thiophene worm amine cyfluthrin humic acid granule 1kg/ mu.
Handle 5:15.11% thiophene worm amine cyfluthrin humic acid granule 0.3kg/ mu.
Handle 6:10.11% thiophene worm amine cyfluthrin humic acid granule 1kg/ mu.
Handle 7:25.1% thiophene worm amine cyfluthrin humic acid granule 0.3kg/ mu.
Handle 8:35.01% thiophene worm amine cyfluthrin humic acid granule 0.3kg/ mu.
Handle 9:40.02% thiophene worm amine cyfluthrin humic acid granule 300kg/ mu.
Handle 10:65% thiophene worm amine cyfluthrin humic acid granule 0.3kg/ mu.
Handle 11:2% cyfloxylate granule 5kg/ mu.
Handle 12:1% thiophene worm amine granule 5kg/ mu.
Handle 13: blank.
Above-mentioned processing is used when peanut seeding, and 30 days " Invest, Then Investigate " peanut aphids situation that causes harm is gathered in the crops after 100 days and carried out the investigation of peanut grub insect population number and peanut yield is measured, and final statistics is as shown in the table:
It is thus clear that under the approaching prerequisite of use cost, embodiment 12-21 products obtained therefrom is aspect control peanut aphid and peanut grub, all obviously than cyfloxylate, the preventive effect of thiophene worm amine list time spent height, the lasting period is long, and can make peanut yield increase more than 20% for preventive effect.
Invention application example 3
Carry out the control of sugarcane moth borer with embodiment 22-33 products obtained therefrom,, will test to handle being provided with as follows according to the product estimated cost:
Handle 1:0.12% thiophene worm amine tefluthrin humic acid granule 300kg/ mu.
Handle 2:5% thiophene worm amine tefluthrin humic acid granule 12.5kg/ mu.
Handle 3:10% thiophene worm amine tefluthrin humic acid granule 1.1kg/ mu.
Handle 4:15% thiophene worm amine tefluthrin humic acid granule 1kg/ mu.
Handle 5:30% thiophene worm amine tefluthrin humic acid granule 1.25kg/ mu.
Handle 6:15.11% thiophene worm amine tefluthrin humic acid granule 0.3kg/ mu.
Handle 7:10.11% thiophene worm amine tefluthrin humic acid granule 1kg/ mu.
Handle 8:40.02% thiophene worm amine tefluthrin humic acid granule 0.3kg/ mu.
Handle 9:25.1% thiophene worm amine tefluthrin humic acid granule 0.3kg/ mu.
Handle 10:55.01% thiophene worm amine tefluthrin humic acid granule 300kg/ mu.
Handle 11:50.01% thiophene worm amine tefluthrin humic acid granule 0.3kg/ mu.
Handle 12:65% thiophene worm amine tefluthrin humic acid granule
Handle 13:2% tefluthrin granule 5kg/ mu.
Handle 14:1% thiophene worm amine granule 5kg/ mu.
Handle 15: blank.
Above-mentioned processing is used when sugarcane is sowed, and carries out the sugarcane moth borer condition survey of causing harm behind the medicine in 60 days, 90 days respectively, carries out determination of yield during the sugarcane harvesting, and final statistics is as shown in the table:
It is thus clear that under the approaching prerequisite of use cost, embodiment 22-33 products obtained therefrom is obviously high than tefluthrin, the preventive effect of thiophene worm amine list time spent to the preventive effect of sugarcane moth borer, the lasting period is long, and can make the sugarcane yield growth more than 20%.
Indoor joint toxicity measuring test 1
Thiophene worm amine, Biphenthrin and be mixed, test to the indoor joint toxicity measuring of corn borer with thiophene worm amine, two kinds of single agent of Biphenthrin as the contrast medicament, and according to No. 6, No. 1-mixture of following ratio preparation mixture:
No. 1 thiophene worm of mixture amine: Biphenthrin=1:1000
No. 2 thiophene worms of mixture amine: Biphenthrin=1:1
No. 3 thiophene worms of mixture amine: Biphenthrin=2:1
No. 4 thiophene worms of mixture amine: Biphenthrin=3:2
No. 5 thiophene worms of mixture amine: Biphenthrin=4:1
No. 6 thiophene worms of mixture amine: Biphenthrin=1500:1
Test is the examination worm with the corn borer, and blank is set, and adopts dip method to carry out toxicity test and do statistical analysis thiophene worm amine, Biphenthrin and above-mentioned 6 mixtures, and final statistics is as shown in the table:
Toxicity Determination result shows, thiophene worm amine, Biphenthrin are mixed co-toxicity coefficient to corn borer all greater than 120 according to above-mentioned 6 different ratios, explains that these two kinds of active ingredients are mixed and have synergistic function.
Indoor joint toxicity measuring test 2
Thiophene worm amine, cyfloxylate, humic acid and be mixed, test to the indoor joint toxicity measuring of Meloidogyne incognita with thiophene worm amine, cyfloxylate, three kinds of single agent of humic acid as the contrast medicament, and according to No. 11, No. 7-mixture of following ratio preparation mixture:
No. 7 thiophene worms of mixture amine: cyfloxylate: humic acid=1:1:1
No. 8 thiophene worms of mixture amine: cyfloxylate: humic acid=3:1:3
No. 9 thiophene worms of mixture amine: cyfloxylate: humic acid=7:3:2
No. 10 thiophene worms of mixture amine: cyfloxylate: humic acid=1500:1:10
No. 11 thiophene worms of mixture amine: cyfloxylate: humic acid=1:1000:10
Test is the examination worm with the Meloidogyne incognita, and blank is set, and adopts dip method to carry out toxicity test and do statistical analysis thiophene worm amine, cyfloxylate, humic acid and above-mentioned 5 mixtures, and final statistics is as shown in the table:
Toxicity Determination result shows, thiophene worm amine, cyfloxylate are mixed co-toxicity coefficient to Meloidogyne incognita all greater than 120 according to above-mentioned 5 different ratios, explains that these two kinds of active ingredients are mixed and have synergistic function.
Indoor joint toxicity measuring test 3
Thiophene worm amine, tefluthrin and be mixed, test to the indoor joint toxicity measuring of Frankliniella occidentalis with thiophene worm amine, two kinds of single agent of tefluthrin as the contrast medicament, and according to No. 16, No. 12-mixture of following ratio preparation mixture:
No. 12 thiophene worms of mixture amine: tefluthrin=1500:1
No. 13 thiophene worms of mixture amine: tefluthrin=1:1
No. 14 thiophene worms of mixture amine: tefluthrin=1:2
No. 15 thiophene worms of mixture amine: tefluthrin=1:4
No. 16 thiophene worms of mixture amine: tefluthrin=1:1000
Test is the examination worm with the Frankliniella occidentalis, and blank is set, and the cowpea method is soaked in thiophene worm amine, tefluthrin and above-mentioned 5 mixtures employing carry out toxicity test and do statistical analysis, and final statistics is as shown in the table:
Toxicity Determination result shows, thiophene worm amine, tefluthrin are mixed co-toxicity coefficient to Frankliniella occidentalis all greater than 120 according to above-mentioned 5 different ratios, explains that these two kinds of active ingredients are mixed and have synergistic function.
Claims (4)
1. the granule of clothianidin-containing is made up of pyrethroid insecticidal constituent, thiophene worm amine, auxiliary agent, binding agent and carrier, it is characterized in that; Prescription is made up of following components in weight percentage: pyrethroid insecticidal constituent 0.01%～10%, thiophene worm amine 0.01%～15%, humic acid 0.1%～40%; Auxiliary agent 1%～15%; Binding agent 1%～10%, carrier supplies 100%
Described pyrethroid insecticidal constituent is any in Biphenthrin, cyfloxylate or the tefluthrin.
2. the granule of clothianidin-containing according to claim 1; It is characterized in that described auxiliary agent is one or more combinations in lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate, naphthalenesulfonate formaldehyde condensation compound, sodium butylnaphthalenesulfonate, AEO, the dioctyl sodium sulfosuccinate.
3. the granule of clothianidin-containing according to claim 1 is characterized in that, described binding agent is one or more combinations in starch, sucrose, polyvinyl alcohol, the carboxymethyl cellulose.
4. the granule of clothianidin-containing according to claim 1; It is characterized in that described carrier is one or more combinations in white carbon black, diatomite, active carbon, kaolin, bentonite, calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulphate, sodium sulphate, calcium sulphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate, talcum powder, river sand, the flyash.
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| CN104151085A (en) * | 2014-08-29 | 2014-11-19 | 联保作物科技有限公司 | Slow release preparation of nutritional pesticide fertilizer for killing pests in sugarcane field and preparation method of slow release preparation |
| CN104186547A (en) * | 2014-09-05 | 2014-12-10 | 杨新兰 | Pesticide granule containing humic acid and clothianidin |
| CN104255803A (en) * | 2014-09-23 | 2015-01-07 | 谢绪叶 | Pesticide granules containing clothianidin and diazinon |
| CN104686564A (en) * | 2015-03-16 | 2015-06-10 | 广东中迅农科股份有限公司 | Tefluthrin, clothianidin and pyraclostrobin containing pesticide composition |
| CN105399565A (en) * | 2015-11-19 | 2016-03-16 | 金正大诺泰尔化学有限公司 | Multifunctional suspending seed coating agent for corn and preparation method of multifunctional suspending seed coating agent |
| CN112573964A (en) * | 2021-01-08 | 2021-03-30 | 中诚国联（河南）生物科技有限公司 | High-tower pesticide-fertilizer containing clothianidin and cyfluthrin and preparation method thereof |
| CN112956480A (en) * | 2021-02-04 | 2021-06-15 | 四川眉山凯尔化工有限公司 | Pesticide raw material formula |
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| CN101179938A (en) * | 2005-05-19 | 2008-05-14 | Fmc有限公司 | Insecticidal compositions suitable for use in preparation of insecticidal liquid fertilizers |
| CN102365972A (en) * | 2011-09-30 | 2012-03-07 | 山东京蓬生物药业股份有限公司 | Synergistic insecticidal compound containing clothianidin and bifenthrin and application thereof |
| CN102379308A (en) * | 2011-09-21 | 2012-03-21 | 江苏扬农化工股份有限公司 | Mixed insecticidal composition containing clothianidin and application of mixed insecticidal composition |
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| CN101179938A (en) * | 2005-05-19 | 2008-05-14 | Fmc有限公司 | Insecticidal compositions suitable for use in preparation of insecticidal liquid fertilizers |
| WO2007042152A1 (en) * | 2005-10-11 | 2007-04-19 | Bayer Cropscience Ag | Oil based suspension concentrates |
| CN102379308A (en) * | 2011-09-21 | 2012-03-21 | 江苏扬农化工股份有限公司 | Mixed insecticidal composition containing clothianidin and application of mixed insecticidal composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104151085A (en) * | 2014-08-29 | 2014-11-19 | 联保作物科技有限公司 | Slow release preparation of nutritional pesticide fertilizer for killing pests in sugarcane field and preparation method of slow release preparation |
| CN104186547A (en) * | 2014-09-05 | 2014-12-10 | 杨新兰 | Pesticide granule containing humic acid and clothianidin |
| CN104255803A (en) * | 2014-09-23 | 2015-01-07 | 谢绪叶 | Pesticide granules containing clothianidin and diazinon |
| CN104686564A (en) * | 2015-03-16 | 2015-06-10 | 广东中迅农科股份有限公司 | Tefluthrin, clothianidin and pyraclostrobin containing pesticide composition |
| CN105399565A (en) * | 2015-11-19 | 2016-03-16 | 金正大诺泰尔化学有限公司 | Multifunctional suspending seed coating agent for corn and preparation method of multifunctional suspending seed coating agent |
| CN112573964A (en) * | 2021-01-08 | 2021-03-30 | 中诚国联（河南）生物科技有限公司 | High-tower pesticide-fertilizer containing clothianidin and cyfluthrin and preparation method thereof |
| CN112956480A (en) * | 2021-02-04 | 2021-06-15 | 四川眉山凯尔化工有限公司 | Pesticide raw material formula |
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| CN102763681B (en) | 2014-08-20 |
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