CN100360034C - Synergistic compound pesticide contg. flufenoxuron and Hostathion - Google Patents
Synergistic compound pesticide contg. flufenoxuron and Hostathion Download PDFInfo
- Publication number
- CN100360034C CN100360034C CNB2005100414366A CN200510041436A CN100360034C CN 100360034 C CN100360034 C CN 100360034C CN B2005100414366 A CNB2005100414366 A CN B2005100414366A CN 200510041436 A CN200510041436 A CN 200510041436A CN 100360034 C CN100360034 C CN 100360034C
- Authority
- CN
- China
- Prior art keywords
- hostathion
- flufenoxuron
- pesticidal combination
- weighing
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 title claims abstract description 64
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 230000002195 synergetic effect Effects 0.000 title abstract description 6
- 239000000575 pesticide Substances 0.000 title description 4
- 150000001875 compounds Chemical class 0.000 title description 2
- 239000002917 insecticide Substances 0.000 claims abstract description 9
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 8
- 235000009566 rice Nutrition 0.000 claims abstract description 8
- 239000000546 pharmaceutical excipient Substances 0.000 claims abstract description 5
- 240000007594 Oryza sativa Species 0.000 claims abstract 2
- 241000607479 Yersinia pestis Species 0.000 claims description 13
- 230000000361 pesticidal effect Effects 0.000 claims description 13
- 241000255777 Lepidoptera Species 0.000 claims description 8
- 241000255969 Pieris brassicae Species 0.000 claims description 5
- 241000256247 Spodoptera exigua Species 0.000 claims description 5
- 210000004894 snout Anatomy 0.000 claims description 5
- 239000004480 active ingredient Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000002671 adjuvant Substances 0.000 claims description 2
- 239000006071 cream Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 abstract description 4
- 235000016068 Berberis vulgaris Nutrition 0.000 abstract description 2
- 241000335053 Beta vulgaris Species 0.000 abstract description 2
- 241000256259 Noctuidae Species 0.000 abstract description 2
- 241000500437 Plutella xylostella Species 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 40
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 40
- 238000000034 method Methods 0.000 description 22
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 20
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 20
- 239000004495 emulsifiable concentrate Substances 0.000 description 20
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 description 20
- 239000002994 raw material Substances 0.000 description 20
- 238000005303 weighing Methods 0.000 description 20
- 241000238631 Hexapoda Species 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000003814 drug Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 241000209094 Oryza Species 0.000 description 6
- 210000003128 head Anatomy 0.000 description 6
- 230000000749 insecticidal effect Effects 0.000 description 6
- 230000002045 lasting effect Effects 0.000 description 5
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 240000008042 Zea mays Species 0.000 description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 3
- 235000005822 corn Nutrition 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 2
- 241000012249 Dendrolimus spectabilis Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 241000255967 Helicoverpa zea Species 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004166 bioassay Methods 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- -1 polyoxyethylene Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 241001465828 Cecidomyiidae Species 0.000 description 1
- 241000665051 Chilo sacchariphagus indicus Species 0.000 description 1
- 241000426497 Chilo suppressalis Species 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000289763 Dasygaster padockina Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
- 241000721451 Pectinophora gossypiella Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241001161749 Stenchaetothrips biformis Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 125000006332 fluoro benzoyl group Chemical group 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000029052 metamorphosis Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
Abstract
A synergistic composite insecticide for preventing and treating rice borer, beet noctuid and high-resistance plutella xylostella larva contains flufenoxuron, triazophos, assistant and excipient.
Description
One, technical field
The present invention relates to a kind of Pesticidal combination and uses thereof, especially a kind of is the Pesticidal combination and the application thereof of main active with flufenoxuron and Hostathion.
Two, background technology
Flufenoxuron (fluferoxuron), chemical name: 1-[4-(a-three fluoro-are to toloxyl for 2-chloro-a, a)-2-fluorophenyl]-3-(2,6-two fluorobenzoyl) urea belongs to the benzoyl area kind insect growth regulator, IGR, and it is synthetic to suppress insect chitin, control but the worm mite is double, active high, the lasting period is long.Have and tag and stomach poison function, no systemic action.By suppressing chitinous formation, insect can not normally be casted off a skin and metamorphosis, especially to the control of normally casting off a skin and growing of larva, reach the purpose of desinsection.This medicament also has good blade face anelasticity.Can be used for preventing and treating the mite class and the insect of citrus, cotton, vegetables, soybean, fruit tree, corn, seeding corn and other crops field mezzanine level, to predacious mite and insect safety.But relatively organophosphorus insecticides is slow for the quick-acting of flufenoxuron insecticide, and influence is to the general control of insect, and is especially relatively poor to explosive pest controling effect.
Hostathion (Triazophos), chemical name is: O, O-diethyl-O-(1-phenyl-1,2,4-triazole-3-yl) thiophosphate, be a kind of organic phosphor desinsection, miticide of high-efficiency broad spectrum, have strong stomach toxicity and action of contace poison, plant tissue there is stronger permeability, generally be used to prevent and treat the lepidoptera pest on fruit tree and the vegetables, before plantation, mix native processing and can prevent and treat cutworm and other noctuid, staple crops insects such as cotton, grain are all had good control efficiency, especially more remarkable to the effect of Plant nematode and pine caterpillars.Be applicable to the striped rice borer, paddy stem borer, rice borer bell, rice thrips, rice gall midge, leaf roll snout moth's larva, cotton bollworm, pink bollworm, aphid, pine caterpillars, cabbage caterpillar of control paddy rice, cotton, corn, fruit tree, vegetables etc. etc., but lasting effect is relatively poor.
The synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve desinsection quick-acting and lasting effect, still finds no the Pesticidal combination that closes flufenoxuron and Hostathion up to now.
Lepidoptera pest as cabbage caterpillar, cotton bollworm, aphid, beet armyworm, the snout moth's larva of rice etc., increases gradually in present resistance, and the agent of agricultural chemicals list descends gradually to the effect of control of insect, and agriculture chemical compounding can obviously improve drug effect, and delays the generation of pest resistance.
Three, summary of the invention
1, goal of the invention
The purpose of this invention is to provide a kind of multifunctional insecticide composition and application thereof that prevents and treats lepidoptera pest.
2, technical scheme
For achieving the above object, flufenoxuron and the good Hostathion assembly of quick-acting that the present invention will grow the lasting period obtain the new and effective multifunctional insecticide composition of a class.This insecticide has good preventive effect to the various pests that Lepidoptera is easy to generate resistance; And suppress insect the pesticide resistance of unitary agent (in Hostathion or the flufenoxuron arbitrary) is produced.
A kind of Pesticidal combination is characterized in that it contains flufenoxuron and Hostathion is an active ingredient, and wherein the weight ratio of flufenoxuron and Hostathion is 0.1～25: 0.5～30.
Effective ingredient is present in the composition with the synergy effective dose.
The preferred weight ratio of flufenoxuron and Hostathion is 0.5～20: 1～25.
The optimum weight ratio that is flufenoxuron and Hostathion is 1～10: 10～25.
Desinsection combination of the present invention is that active ingredient and insecticides adjuvant, excipient are mixed with cream preparation with flufenoxuron and Hostathion.
Pesticidal combination of the present invention is in the application that prevents and treats on the resistance lepidoptera pest.Especially in the application that prevents and treats on the snout moth's larva of rice and cabbage caterpillar, the beet armyworm.
Above-described auxiliary agent is the one or more combinations in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxypropylene block compound (as the newborn 33# of farming), the polyoxyethylene nonylphenol ether, and excipient comprises dimethylbenzene, solvent naphtha.Above auxiliary agent, excipient can be singly with or and also can add other auxiliary material with reaching.
Measure through indoor synergism test and to show: is 176-246 by flufenoxuron and Hostathion to the co-toxicity coefficient of rice leaf roller, and test determination shows that all composite dose all has significant synergistic insecticidal action to two kinds of insects; Field control effectiveness test equally also shows the composite dose of effect that the insecticidal effect of rice leaf roller all is significantly higher than corresponding single agent agricultural chemicals that the present invention is all.
3, beneficial effect
The Pesticidal combination that a kind of flufenoxuron and Hostathion are provided of the present invention, it compared with prior art, can produce higher cooperative synergism, can both improve the performance of its quick-acting, again can be arranged certain lasting period, overcome and delayed pest resistance to insecticide, the expanding prevention spectrum, desinsection speed is fast, has reduced drug cost, has alleviated toxicity.
The present invention especially can be used for preventing and treating the snout moth's larva of rice and resistance cabbage caterpillar, beet armyworm, and its effect is used apparently higher than its single agent.
Pesticidal combination of the present invention compared with prior art produces following beneficial effect: (1) is compared with single agent, and said composition has notable synergistic to lepidoptera pest, has obviously improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; (3) alternative high-toxic pesticide, and reduce the field dosage significantly, effectively reduce environmental pollution and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compare with single agent product, produce and the use cost reduction; (6) suppress the resistance enhancing of lepidoptera pest to agricultural chemicals; (7) reduction is to the toxicity of warm blooded animal.
Four, embodiment
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.Pass through indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage earlier; On this basis, carry out field trial again.
Implementation result:
Embodiment 1:
Take by weighing 2g flufenoxuron, 30g Hostathion, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 32% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Carry out indoor synergy biologicall test, the selection beet exigua larvae is a target pest, and every processing repeats 3 times, and every concentration is handled 30, uses LC
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
The toxicity test effect of table 1 Hostathion flufenoxuron=30: 2 pairs of rice leaf roller
| Concentration (μ g/mL) | I | II | III | |||
| Examination borer population (head) | Dead borer population (head) | Examination borer population (head) | Dead borer population (head) | Examination borer population (head) | Dead borer population (head) | |
| 100 | 10 | 9 | 10 | 7 | 10 | 8 |
| 20 | 10 | 8 | 10 | 7 | 10 | 8 |
| 4 | 10 | 6 | 10 | 6 | 10 | 8 |
| 0.8 | 10 | 6 | 10 | 5 | 10 | 5 |
| 0.16 | 10 | 5 | 10 | 3 | 10 | 4 |
| 0.032 | 10 | 1 | 10 | 2 | 10 | 3 |
| 0.0064 | 10 | 1 | 10 | 1 | 10 | 2 |
| 0.000128 | 10 | 2 | 10 | 0 | 10 | 2 |
| CK | 10 | 2 | 10 | 0 | 10 | 0 |
Regression equation: Y=4.94158+0.528111X
Lethal concentration: LC50=1.290102 μ g/mL (95% confidence limit: 0.533609-3.89801 μ g/mL)
Embodiment is prevented and treated the field control effectiveness test of rice leaf roller, and the contrast medicine is that the result is as follows:
Result of the test:
| Handle (ml/mu) | Behind the medicine 14 days | Behind the medicine 26 days |
| Average white leaf rate % | Protect leaf effect % | Insecticidal effect % | Average white leaf rate % | Protect leaf effect % | Insecticidal effect % | ||
| Embodiment 1 | 15 | 0.36 | 96.72aA | 100aA | 1.56 | 90.55bAB | 92.10aA |
| 20 | 0.20 | 98.18aA | 100aA | 0.82 | 94.61abAB | 98.08aA | |
| 25 | 0.09 | 99.02aA | 100aA | 0.29 | 98.46aA | 98.21aA | |
| 40% Hostathion EC20 | 2.18 | 80.60bB | 82.50bA | 2.15 | 84.25bB | 85.14aA | |
| 5% stuck gram EC20 | 2.58 | 76.53cC | 81.35bB | 3.05 | 81.27bB | 83.23aB | |
| CK | 12.18 | 19.70 | |||||
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable; A is illustrated on α=0.01 level remarkable, and B is illustrated on α=0.01 level variant, and C is illustrated on α=0.01 level not remarkable;
The above results shows, the complex composition of flufenoxuron and Hostathion is compared with two single agent and to be had following advantage: (1) has significantly improved the omnidistance control efficiency to beet armyworm; (2) have the quick-acting of enhancing and long hold effect concurrently, the insecticidal effect of 3 days, 10 days and 15 days all is significantly higher than each single agent after the dispenser.
Embodiment 2: take by weighing 5g flufenoxuron, 27g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 32% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 3: take by weighing 0.5g flufenoxuron, 30g Hostathion, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 9g, solubilizer oil to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 30.5% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 4: take by weighing 0.1g flufenoxuron, 30g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 30.1% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 5: take by weighing 1g flufenoxuron, 30g Hostathion, detergent alkylate calcium phosphate 7g, phenethyl phenol polyethenoxy ether 9g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 31% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 6: take by weighing 2g flufenoxuron, 25g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 8g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 27% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 7: take by weighing 5g flufenoxuron, 30g Hostathion, calcium dodecyl benzene sulfonate 9g, phenethyl phenol polyethenoxy ether 9g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 35% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 8: take by weighing 5g flufenoxuron, 25g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 30% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 9: take by weighing 10g flufenoxuron, 25g Hostathion, calcium dodecyl benzene sulfonate 10g, phenethyl phenol polyethenoxy ether 9g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 35% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 10: take by weighing 10g flufenoxuron, 15g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 7g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 25% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 11: take by weighing 10g flufenoxuron, 5g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 7g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 15% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 12: take by weighing 10g flufenoxuron, 10g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 5g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 20% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 13: take by weighing 20g flufenoxuron, 25g Hostathion, calcium dodecyl benzene sulfonate 15g, phenethyl phenol polyethenoxy ether 9g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 45% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 14: take by weighing 25g flufenoxuron, 0.5g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 25.5 Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 15: take by weighing 25g flufenoxuron, 2g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 27% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 16: take by weighing 25g flufenoxuron, 2.5g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 27.5% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 17: take by weighing 20g flufenoxuron, 20g Hostathion, calcium dodecyl benzene sulfonate 15g, phenethyl phenol polyethenoxy ether 12g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 40 Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 18: take by weighing 15g flufenoxuron, 10g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 9g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 25% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 19: take by weighing 2.5g flufenoxuron, 18g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 6g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 20.5% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment 20: take by weighing 2.5g flufenoxuron, 25g Hostathion, calcium dodecyl benzene sulfonate 7g, phenethyl phenol polyethenoxy ether 7g, add dimethylbenzene to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 27.5% Hostathion 5 percent of hexaflumuron emulsifiable concentrate.
Claims (6)
1, a kind of Pesticidal combination is characterized in that it contains flufenoxuron and Hostathion is an active ingredient, and wherein the weight ratio of flufenoxuron and Hostathion is 0.1～25: 0.5～30.
2, Pesticidal combination according to claim 1, the weight ratio that it is characterized in that flufenoxuron and Hostathion is 0.5～20: 1～25.
3, Pesticidal combination according to claim 2, the weight ratio that it is characterized in that flufenoxuron and Hostathion is 1～10: 10～25.
4,, it is characterized in that it is that active ingredient and insecticides adjuvant, excipient are mixed with cream preparation with flufenoxuron and Hostathion according to the described Pesticidal combination of claim 1.
5, the described Pesticidal combination of claim 1 is in the application that prevents and treats on the resistance lepidoptera pest.
6, application according to claim 5, Pesticidal combination are used to prevent and treat the snout moth's larva of rice and cabbage caterpillar, beet armyworm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100414366A CN100360034C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. flufenoxuron and Hostathion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100414366A CN100360034C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. flufenoxuron and Hostathion |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1911039A CN1911039A (en) | 2007-02-14 |
| CN100360034C true CN100360034C (en) | 2008-01-09 |
Family
ID=37720239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100414366A Expired - Fee Related CN100360034C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. flufenoxuron and Hostathion |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100360034C (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1348696A (en) * | 2001-11-02 | 2002-05-15 | 浙江新农化工有限公司 | Diazinone emulsion and its prepn. |
| CN1390458A (en) * | 2002-07-17 | 2003-01-15 | 倪正刚 | Composite insecticide |
| CN1440654A (en) * | 2003-01-21 | 2003-09-10 | 江苏粮满仓农化有限公司 | Organophosphorus pesticide with high triazophos emulsion content |
| CN1539285A (en) * | 2003-11-03 | 2004-10-27 | 浙江新农化工有限公司 | Composite insect disinfestation micellar emulsion contaning triazophos and 'Ruijinte', and its preparation method |
-
2005
- 2005-08-12 CN CNB2005100414366A patent/CN100360034C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1348696A (en) * | 2001-11-02 | 2002-05-15 | 浙江新农化工有限公司 | Diazinone emulsion and its prepn. |
| CN1390458A (en) * | 2002-07-17 | 2003-01-15 | 倪正刚 | Composite insecticide |
| CN1440654A (en) * | 2003-01-21 | 2003-09-10 | 江苏粮满仓农化有限公司 | Organophosphorus pesticide with high triazophos emulsion content |
| CN1539285A (en) * | 2003-11-03 | 2004-10-27 | 浙江新农化工有限公司 | Composite insect disinfestation micellar emulsion contaning triazophos and 'Ruijinte', and its preparation method |
Non-Patent Citations (1)
| Title |
|---|
| 新英汉农药辞典(上). 胡笑形(主编)，583，外文出版社. 1999 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1911039A (en) | 2007-02-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102113516B (en) | Insect killing compound containing chlorantraniliprole | |
| CN100353843C (en) | Synergistic compound pesticide contg. high efficiency cyfluthrin and lurfenuron, and its application | |
| CN101380008A (en) | Disinsection composition with synergistic action | |
| CN102342285B (en) | Sterilization disease-resistant composition and suspension seed coating agent thereof | |
| CN101473816B (en) | Avermectin microcapsule suspending agent | |
| CN100382698C (en) | Synergistic compound pesticide contg. flufenoxuron | |
| CN101485329B (en) | Agricultural chemical composition for disinsection and use thereof | |
| CN102342284B (en) | Sterilization disease-resistant composition and suspension seed coating agent thereof | |
| CN101380004B (en) | Synergistic insecticidal compositions containing spinosad and lufenuron | |
| CN100353842C (en) | Synergistic compound pesticide contg. high efficiency cypermethrin and lurfenuron, and its application | |
| CN1911038A (en) | Synergistic compound pesticide contg. trans-cypermethrin and chlopyrifos | |
| CN101305727B (en) | Efficient pesticides composition containing avermectin and profenofos | |
| CN100360034C (en) | Synergistic compound pesticide contg. flufenoxuron and Hostathion | |
| CN100360032C (en) | Synergistic compound pesticide contg. high efficiency cypermethrin and pyrimidifen and its application | |
| CN100353845C (en) | Synergistic compound pesticide contg. lurfenuron and chlopyrifos, and its application | |
| CN103053594A (en) | Synergistic insecticidal composition containing tolfenpyrad and theta-cypermethrin and its application | |
| CN101461369A (en) | Synergistic insecticidal composition containing novaluron and chlopyrifos, and use thereof | |
| CN102415396A (en) | Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof | |
| CN100360030C (en) | Synergistic compound pesticide contg. high efficiency cyfluthrin and flufenoxuron | |
| CN106804597A (en) | A kind of Pesticidal combination of the nitrile of worm containing acetyl and fipronil bisamide | |
| CN101380009A (en) | Disinsection composition with synergistic action | |
| CN1911030A (en) | Synergistic compound pesticide contg. trans-cypermethrin and fipronil | |
| CN100353844C (en) | Synergistic compound pesticide contg. high efficiency cypemethrin and flufenoxuron | |
| CN113826640B (en) | Sanitary insecticidal composition containing flonicamid and application thereof | |
| CN107372522A (en) | A kind of composition pesticide containing fenazaquin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: NANJING RED SUN CO., LTD. Free format text: FORMER OWNER: NANJING FIRST PESTICIDE GROUP CO., LTD. Effective date: 20111021 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C56 | Change in the name or address of the patentee |
Owner name: NANJING FIRST PESTICIDE GROUP CO., LTD. Free format text: FORMER NAME: NANJING NO.1 PESTICIDE CO., LTD. |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 211300 NANJING, JIANGSU PROVINCE TO: 211318 NANJING, JIANGSU PROVINCE |
|
| CP01 | Change in the name or title of a patent holder |
Address after: 211300 Pagoda Road 269, Gaochun County, Jiangsu, Nanjing Patentee after: Nanjing No.1 Pesticide Group Co.,Ltd. Address before: 211300 Pagoda Road 269, Gaochun County, Jiangsu, Nanjing Patentee before: NANJING NO 1 PESTICIDE Co.,Ltd. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20111021 Address after: Dongfeng Road, Xi Zhen Gaochun County of Nanjing City, Jiangsu province 211318, No. 8 Patentee after: NANJING RED SUN Co.,Ltd. Address before: 211300 Pagoda Road 269, Gaochun County, Jiangsu, Nanjing Patentee before: Nanjing No.1 Pesticide Group Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080109 Termination date: 20200812 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |