CN100364401C - Synergistic compound pesticide contg. pyridaben and flucycloxuron, and its application - Google Patents
Synergistic compound pesticide contg. pyridaben and flucycloxuron, and its application Download PDFInfo
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- CN100364401C CN100364401C CNB2005100414385A CN200510041438A CN100364401C CN 100364401 C CN100364401 C CN 100364401C CN B2005100414385 A CNB2005100414385 A CN B2005100414385A CN 200510041438 A CN200510041438 A CN 200510041438A CN 100364401 C CN100364401 C CN 100364401C
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- pyridaben
- flucycloxuron
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- insecticidal compositions
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- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 239000005663 Pyridaben Substances 0.000 title claims abstract description 44
- PCKNFPQPGUWFHO-SXBRIOAWSA-N (Z)-flucycloxuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1)=CC=C1CO\N=C(C=1C=CC(Cl)=CC=1)\C1CC1 PCKNFPQPGUWFHO-SXBRIOAWSA-N 0.000 title claims abstract description 34
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 13
- 150000001875 compounds Chemical class 0.000 title claims description 3
- 239000000575 pesticide Substances 0.000 title description 3
- 239000000546 pharmaceutical excipient Substances 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims abstract description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 13
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 12
- 230000000749 insecticidal effect Effects 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- 230000000694 effects Effects 0.000 claims description 8
- 241001454293 Tetranychus urticae Species 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 230000000361 pesticidal effect Effects 0.000 claims description 5
- -1 polyoxyethylene Polymers 0.000 claims description 4
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 abstract description 3
- 241000488583 Panonychus ulmi Species 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 20
- 238000000034 method Methods 0.000 description 12
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 10
- 239000004495 emulsifiable concentrate Substances 0.000 description 10
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 description 10
- 239000002994 raw material Substances 0.000 description 10
- 238000005303 weighing Methods 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 241000607479 Yersinia pestis Species 0.000 description 7
- 239000003905 agrochemical Substances 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 241000238631 Hexapoda Species 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 2
- 235000016068 Berberis vulgaris Nutrition 0.000 description 2
- 241000335053 Beta vulgaris Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 206010018498 Goitre Diseases 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
- 241000819999 Nymphes Species 0.000 description 2
- 241000488581 Panonychus citri Species 0.000 description 2
- 238000004166 bioassay Methods 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 201000003872 goiter Diseases 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241001635274 Cydia pomonella Species 0.000 description 1
- 241001583841 Empoasca decipiens Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000255969 Pieris brassicae Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 241000510091 Quadrula quadrula Species 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 241001454295 Tetranychidae Species 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A synergistic composite insecticide for preventing and treating red spider contains pyridaben, flucycloxuron, assistant and excipient.
Description
Technical field
The present invention relates to a kind of Pesticidal combination and uses thereof, especially a kind of is the Pesticidal combination and the application thereof of main active with pyridaben and flucycloxuron.
Background technology
Pyridaben (adopted name: Pyridaben) chemical name: 2-tertiary butyl-5-(4-tertiary butyl benzylthio)-4-chloro-3 (2H)-pyridazinone
Chemical structural formula:
Key property: Insecticidal and acaricidal agent, wide spectrum, efficient, hold and imitate longly, have action of contace poison.
Controlling object: citrus: Panonychus citri, tetranychid, unguiculus mite, beginning tetranychid, rust mite, aleyrodid, aphid etc.; Cotton: cotton spider mites, cotton leafhopper etc.; Apple: tetranychid, rust mite, aphid etc.
Flucycloxuron (flucycloxuron) belongs to benzoyl area kind and kills mite, insecticide, is chitin synthesis inhibitor.Can prevent and treat goitre mite and tetranychid nymph (invalid) to adult, especially the apple on the apple stings goitre mite, elm (apple) Panonychus citri and Mai Keshi tetranychus telarius, and the ordinary maple leaf mite nymph on the various crops, also can prevent and treat the larva of some a little insect, soybean pretty young woman at night, codling moth are wherein arranged, Lay white butterfly and wild cabbage diamond-back moth.
The synergistic complex of agricultural chemicals is expanding prevention spectrum and the effective measures that improve desinsection quick-acting and lasting effect, but still finds no the Pesticidal combination that closes pyridaben and flucycloxuron up to now.
In addition, the resistance of present two spotted spider mite increases gradually, and the agent of agricultural chemicals list descends gradually to the effect of control of insect, gets ingredients and improves drug effect so also be badly in need of a kind of synergy, delays the generation of pest resistance.
Summary of the invention
The purpose of this invention is to provide and a kind ofly can produce higher cooperative synergism, both improved the performance of its quick-acting, again can there be certain lasting period, can overcome and delay pest resistance to insecticide, the expanding prevention spectrum, desinsection speed is fast, has reduced drug cost, Synergistic insecticidal compositions that contains pyridaben and flucycloxuron and application thereof that toxicity is light.
Technical scheme of the present invention is:
A kind of Synergistic insecticidal compositions that contains pyridaben and flucycloxuron, it is characterized in that the composite emulsion preparation that it is made up of primary activity composition pyridaben and flucycloxuron, auxiliary agent and excipients, wherein the weight portion of pyridaben is 0.1～30, the weight portion of flucycloxuron is 0.5～30, the weight portion of auxiliary agent is 3～15, and surplus is an excipients.
Described auxiliary agent is a kind of or its combination in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxypropylene block compound, the polyoxyethylene nonylphenol ether.
Described excipient is dimethylbenzene or solvent naphtha.
The effective ingredient that contains the Synergistic insecticidal compositions of pyridaben and flucycloxuron of the present invention is present in the composition with the synergy effective dose.
Optimum weight part of pyridaben and flucycloxuron is respectively 0.5～20 and 1～25.
Its application on the control mite pest, its effect is used apparently higher than its single agent.
Its effect the control two spotted spider mite uses apparently higher than its single agent.
Beneficial effect of the present invention:
Measure through indoor synergism test and to show: is 156～238 by pyridaben and flucycloxuron to the co-toxicity coefficient of two spotted spider mite, and test determination shows that all composite dose all has significant synergistic insecticidal action to two kinds of insects; Field control effectiveness test equally also shows the composite dose of effect that the insecticidal effect of beet tops moth larvae all is significantly higher than corresponding single agent agricultural chemicals that the present invention is all.
Pesticidal combination of the present invention is compared with prior art:
(1) compare with single agent, said composition has notable synergistic to lepidoptera pest, has obviously improved control efficiency.
(2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost.
(3) alternative high-toxic pesticide, and reduce the field dosage significantly, effectively reduce environmental pollution and residue of pesticide.
(4) have concurrently quick-acting and long-acting.
(5) compare with single agent product, produce and the use cost reduction.
(6) suppress the resistance enhancing of lepidoptera pest to agricultural chemicals.
(7) reduction is to the toxicity of warm blooded animal.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
The method that employing indoor bioassay of the present invention and field trial combine, earlier by indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage; On this basis, carry out field trial again.
Embodiment 1:
Take by weighing pyridaben 10 gram, flucycloxuron 2 grams, calcium dodecyl benzene sulfonate 4 grams, phenethyl phenol polyethenoxy ether 3 grams, surplus dimethylbenzene and add to 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms 12% pyridaben 5 percent of hexaflumuron emulsifiable concentrate preparation.
Carry out indoor synergy biologicall test, the selection beet exigua larvae is a target pest, and every processing repeats 3 times, and every concentration is handled 30, presses the abundant method of Sun Yun with the LC50 value and calculates co-toxicity coefficient:
The toxicity test effect of table 1 pyridaben flucycloxuron=10: 2 pairs of two spotted spider mite
| Concentration (μ g/mL) | I | II | III | |||
| Examination borer population (head) | Dead borer population (head) | Examination borer population (head) | Dead borer population (head) | Examination borer population (head) | Dead borer population (head) | |
| 100 | 10 | 9 | 10 | 7 | 10 | 8 |
| 20 | 10 | 8 | 10 | 7 | 10 | 8 |
| 4 | 10 | 6 | 10 | 6 | 10 | 8 |
| 0.8 | 10 | 6 | 10 | 5 | 10 | 5 |
| 0.16 | 10 | 5 | 10 | 3 | 10 | 4 |
| 0.032 | 10 | 1 | 10 | 2 | 10 | 3 |
| 0.0064 | 10 | 1 | 10 | 1 | 10 | 2 |
| 0.000128 | 10 | 2 | 10 | 0 | 10 | 2 |
| CK | 10 | 2 | 10 | 0 | 10 | 0 |
Regression equation: Y=4.94158+0.528111X
Lethal concentration: LC50=1.290102 μ g/mL (95% confidence limit: 0.533609-3.89801 μ g/mL)
Embodiment is prevented and treated the field control effectiveness test of beet armyworm, and the contrast medicine is that the result is as follows:
Result of the test:
| Handle (doubly) | Radix (head/20 leaves) | Preventive effect (%) | |||||
| 1 day | 3 days | 10 days | 15 days | 20 days | |||
| Embodiment 1 | 1000 | 432 | 100Aa | 96.7Aa | 95.9Aa | 88.1Aa | 81.2Aa |
| 1500 | 577 | 99.5Aa | 94.2Aa | 92.7Aa | 81.4AA | 70.2Aab | |
| 2000 | 535 | 99.4Aa | 92.5Aa | 87.6Aa | 75.0Aa | 63.8Ab | |
| 15% pyridaben EC1500 | 497 | 82.3Ba | 89.2Ba | 76.4Cc | 79.5Aa | 64.5Ab | |
| 5% flucycloxuron missible oil 1500 | 499 | 79.2Cc | 81.2Bb | 82,6Bb | 53.4Bb | 43.9Cc | |
| The CK rate that goes down | 491 | -4.7 | 6.4 | -38.2 | 29.2 | 31.1 | |
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable; A is illustrated on α=0.01 level remarkable, and B is illustrated on α=0.01 level variant, and C is illustrated on α=0.01 level not remarkable;
The above results shows, the complex composition of pyridaben and flucycloxuron is compared with two single agent and to be had following advantage: (1) has significantly improved the omnidistance control efficiency to two spotted spider mite; (2) have the quick-acting of enhancing and long hold effect concurrently, the insecticidal effect of 3 days, 10 days and 15 days all is significantly higher than each single agent after the dispenser.
Embodiment two.
Take by weighing pyridaben 0.1 gram, flucycloxuron 0.5 gram, calcium dodecyl benzene sulfonate 7, phenethyl phenol polyethenoxy ether 8, surplus dimethylbenzene and add to 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 0.6% pyridaben 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment three.
Take by weighing pyridaben 0.1 gram, flucycloxuron 30 grams, calcium dodecyl benzene sulfonate 5, phenethyl phenol polyethenoxy ether 5, surplus dimethylbenzene and add to 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 30.1% pyridaben 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment four.
Take by weighing pyridaben 30 grams, flucycloxuron 0.5 gram, calcium dodecyl benzene sulfonate 4, phenethyl phenol polyethenoxy ether 5, surplus dimethylbenzene and add to 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 30.5% pyridaben 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment five.
Take by weighing pyridaben 30 grams, flucycloxuron 30 grams, calcium dodecyl benzene sulfonate 1, phenethyl phenol polyethenoxy ether 2, surplus dimethylbenzene and add to 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 60% pyridaben 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment six.
Take by weighing pyridaben 30 grams, flucycloxuron 30 grams, calcium dodecyl benzene sulfonate 1, phenethyl phenol polyethenoxy ether 2, surplus dimethylbenzene and add to 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 60% pyridaben 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment seven.
Take by weighing pyridaben 0.5 gram, flucycloxuron 1 gram, calcium dodecyl benzene sulfonate 7, phenethyl phenol polyethenoxy ether 8, surplus dimethylbenzene and add to 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 1.5% pyridaben 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment eight.
Take by weighing pyridaben 0.5 gram, flucycloxuron 25 grams, calcium dodecyl benzene sulfonate 6, phenethyl phenol polyethenoxy ether 7, surplus dimethylbenzene and add to 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 25.5% pyridaben 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment nine.
Take by weighing pyridaben 20 grams, flucycloxuron 1 gram, calcium dodecyl benzene sulfonate 6, phenethyl phenol polyethenoxy ether 7, surplus dimethylbenzene and add to 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 21% pyridaben 5 percent of hexaflumuron emulsifiable concentrate.
Embodiment ten.
Take by weighing pyridaben 20 grams, flucycloxuron 25 grams, calcium dodecyl benzene sulfonate 3, phenethyl phenol polyethenoxy ether 2, surplus dimethylbenzene and add to 100 grams.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and forms preparation 45% pyridaben 5 percent of hexaflumuron emulsifiable concentrate.
Claims (5)
1. Synergistic insecticidal compositions that contains pyridaben and flucycloxuron, it is characterized in that the composite emulsion preparation that it is made up of primary activity composition pyridaben and flucycloxuron, auxiliary agent and excipients, wherein the weight portion of pyridaben is 0.1～30, the weight portion of flucycloxuron is 0.5～30, the weight portion of auxiliary agent is 3～15, and surplus is an excipients.
2. the Synergistic insecticidal compositions that contains pyridaben and flucycloxuron according to claim 1 is characterized in that described auxiliary agent is a kind of or its combination in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxypropylene block compound, the polyoxyethylene nonylphenol ether.
3. the Synergistic insecticidal compositions that contains pyridaben and flucycloxuron according to claim 1 is characterized in that described excipient is dimethylbenzene or solvent naphtha.
4. the Synergistic insecticidal compositions that contains pyridaben and flucycloxuron according to claim 1 is characterized in that the weight portion of pyridaben and flucycloxuron is respectively 0.5～20 and 1～25.
5. the described Pesticidal combination of claim 1 is used to prevent and treat two spotted spider mite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100414385A CN100364401C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. pyridaben and flucycloxuron, and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100414385A CN100364401C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. pyridaben and flucycloxuron, and its application |
Publications (2)
| Publication Number | Publication Date |
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| CN1911020A CN1911020A (en) | 2007-02-14 |
| CN100364401C true CN100364401C (en) | 2008-01-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2005100414385A Expired - Fee Related CN100364401C (en) | 2005-08-12 | 2005-08-12 | Synergistic compound pesticide contg. pyridaben and flucycloxuron, and its application |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101990893A (en) * | 2010-11-01 | 2011-03-30 | 吴明龙 | Pesticide composition containing etoxazole and pyridaben |
| CN106342850A (en) * | 2016-08-29 | 2017-01-25 | 广东中迅农科股份有限公司 | Insecticidal composition containing novaluron and pyridaben |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1402982A (en) * | 2002-09-30 | 2003-03-19 | 华南农业大学 | Pesticide prepared by mixing nimbin and benzoyl urea |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1402982A (en) * | 2002-09-30 | 2003-03-19 | 华南农业大学 | Pesticide prepared by mixing nimbin and benzoyl urea |
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