CN1894175B - 催化反应的改进或与催化反应相关的改进 - Google Patents

催化反应的改进或与催化反应相关的改进 Download PDF

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Publication number
CN1894175B
CN1894175B CN2004800377426A CN200480037742A CN1894175B CN 1894175 B CN1894175 B CN 1894175B CN 2004800377426 A CN2004800377426 A CN 2004800377426A CN 200480037742 A CN200480037742 A CN 200480037742A CN 1894175 B CN1894175 B CN 1894175B
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China
Prior art keywords
catalyst
water
reactor
feed
olefin
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Expired - Fee Related
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CN2004800377426A
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English (en)
Chinese (zh)
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CN1894175A (zh
Inventor
S·W·比德尔
S·H·布朗
J·S·戈德斯马克
G·M·K·马泰斯
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/18—Acids of phosphorus; Salts thereof; Phosphorus oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C07C2/70—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
    • C07C2527/173—Phosphoric acid or other acids with the formula Hn+2PnO3n+1
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C10G2300/1092—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
CN2004800377426A 2003-12-18 2004-12-16 催化反应的改进或与催化反应相关的改进 Expired - Fee Related CN1894175B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US53077703P 2003-12-18 2003-12-18
US60/530,777 2003-12-18
PCT/EP2004/014475 WO2005058777A1 (en) 2003-12-18 2004-12-16 Improvements in or relating to catalysed reactions

Publications (2)

Publication Number Publication Date
CN1894175A CN1894175A (zh) 2007-01-10
CN1894175B true CN1894175B (zh) 2010-12-22

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Country Link
US (1) US20070255081A1 (enExample)
EP (1) EP1694617B1 (enExample)
JP (1) JP2007514702A (enExample)
KR (1) KR20070029127A (enExample)
CN (1) CN1894175B (enExample)
AT (1) ATE517074T1 (enExample)
CA (1) CA2548574C (enExample)
ES (1) ES2369777T3 (enExample)
WO (1) WO2005058777A1 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0507626D0 (en) 2005-04-15 2005-05-25 Exxonmobil Chem Patents Inc Branched olefin compositions
WO2006133908A2 (en) 2005-06-13 2006-12-21 Exxonmobil Chemical Patents Inc. Oligomerisation of olefins
FR2887538B1 (fr) * 2005-06-28 2008-01-04 Inst Francais Du Petrole Procede de traitement d'une zeolithe a petits et/ou moyens pores et son utilisation en oligomerisation des olefines legeres
US7588738B2 (en) 2005-08-23 2009-09-15 Exxonmobil Chemical Patents Inc. Series catalyst beds
FR2952646B1 (fr) * 2009-11-13 2012-09-28 Inst Francais Du Petrole Procede de production de carburants kerosene et diesel de haute qualite et de coproduction d'hydrogene a partir de coupes saturees legeres
US8921590B2 (en) 2009-12-15 2014-12-30 Exxonmobil Chemical Patents Inc. Oligomerisation process
WO2012033562A1 (en) 2010-09-07 2012-03-15 Exxonmobil Chemical Patents Inc. Extrudates including zeolite catalysts and their use in oligomerization processes
CN103237872B (zh) 2010-12-07 2015-12-09 埃克森美孚化学专利公司 利用溶剂萃取的方法
WO2013013886A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
WO2013013887A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
US9428427B2 (en) 2011-07-25 2016-08-30 Exxonmobil Chemical Patents Inc. Process for nitrile removal from hydrocarbon feeds
EP2736632B1 (en) 2011-07-25 2017-02-01 ExxonMobil Chemical Patents Inc. Integrated nitrile poison adsorption and desorption system
WO2013013888A2 (en) 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Olefin oligomerization process
US9505674B2 (en) 2012-11-29 2016-11-29 Exxonmobil Chemical Patents Inc. Processes for treating olefin feedstreams and related oligomerization processes
US9982201B2 (en) * 2013-12-02 2018-05-29 NexoSolutions LLC Removal of hydrocarbon contaminants
JP2018508557A (ja) 2015-03-20 2018-03-29 エクソンモービル ケミカル パテンツ インコーポレイテッド オレフィン含有炭化水素供給物をオリゴマー化生成物または水素化オリゴマー化生成物に変換する方法
EA038432B1 (ru) * 2017-12-01 2021-08-27 Публичное акционерное общество "СИБУР Холдинг" Способ олигомеризации олефинов с онлайн измерением концентрации хрома в каталитической системе
CN116459744B (zh) * 2023-05-31 2025-08-05 大庆中蓝石化有限公司 一种在线延长以硅胶为载体的固体磷酸催化剂寿命的装置及方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1277951A (zh) * 1995-02-07 2000-12-27 埃克森化学专利公司 烯烃低聚的方法和用途

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2681374A (en) * 1951-04-14 1954-06-15 Standard Oil Dev Co Control of catalyst hydration
FR1223381A (fr) * 1958-12-17 1960-06-16 Ets Kuhlmann Perfectionnements au procédé de fabrication de composés oxygénés par synthèse oxo
US3378590A (en) * 1964-05-27 1968-04-16 Toa Nenryo Kogyo Kk Production of aldehydes and/or alcohols from compound having olefinic double bonds
BE786859A (fr) * 1971-08-05 1973-01-29 Texaco Development Corp Appareil et procede de regulation de la concentration en acide dans uneinstallation d'alkylation
US3864346A (en) * 1971-08-05 1975-02-04 Texaco Inc Means and method for controlling the strength of acid in an alkylation unit
US3868422A (en) * 1971-12-23 1975-02-25 Eastman Kodak Co Multistage hydroformylation process
FR2269511B1 (enExample) * 1974-04-30 1978-01-27 Ugine Kuhlmann
DE2538037C3 (de) * 1975-08-27 1988-11-10 Hüls AG, 4370 Marl Verfahren zur Hydroformylierung von Olefinen
US4018846A (en) * 1975-12-29 1977-04-19 Exxon Research And Engineering Company Method for continuously controlling the water content of sulfuric acid alkylation catalyst
US4150062A (en) * 1976-12-20 1979-04-17 Mobil Oil Corporation Light olefin processing
US4334118A (en) * 1981-06-01 1982-06-08 Chevron Research Solid phosphoric acid catalyzed olefin polymerization process
US4544788A (en) * 1984-12-28 1985-10-01 Mobil Oil Corporation Control system for catalytic conversion of olefins to heavier hydrocarbons
US4740648A (en) * 1985-03-11 1988-04-26 Union Carbide Corporation Conversion of olefins to liquid motor fuels
DE3530839A1 (de) * 1985-08-29 1987-03-05 Ruhrchemie Ag Verfahren zur herstellung von 2-ethylhexanol
US4754096A (en) * 1987-07-13 1988-06-28 Mobil Oil Corporation Production of high viscosity index lubricating oils from lower olefins
US4973790A (en) * 1989-11-16 1990-11-27 Mobil Oil Corporation Process for upgrading light olefinic streams
KR100197450B1 (ko) * 1990-07-27 1999-06-15 에인혼 해롤드 올레핀-함유 하이드로포르밀화 공급원료를 탈황시키는 방법
US5672800A (en) * 1992-01-30 1997-09-30 Exxon Chemical Patents Inc. Alkene oligomerization
US5773679A (en) * 1995-12-26 1998-06-30 Mobil Oil Corporation Performance enhancement of zeolite catalysts with water cofeed
ES2187717T3 (es) * 1996-11-18 2003-06-16 Fina Technology Procedimiento de alquilacion con estabilidad catalitica mejorada.
US5744679A (en) * 1996-12-27 1998-04-28 Uop Llc Using water concentration to control ethylene oligomerization
US6111159A (en) * 1998-12-01 2000-08-29 Bp Amoco Corporation Hydrocarbon conversion process
JP4290301B2 (ja) * 2000-01-21 2009-07-01 ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド 炭化水素転化方法
GB0010433D0 (en) * 2000-04-28 2000-06-14 Exxon Chemical Patents Inc Alkene oligomerization process
DE10062448A1 (de) * 2000-12-14 2002-06-20 Oxeno Olefinchemie Gmbh Verfahren zur Hydrierung von Hydroformylierungsgemischen
JP4728577B2 (ja) * 2001-10-24 2011-07-20 エクソンモービル・ケミカル・パテンツ・インク オレフィンのオリゴマー化の方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1277951A (zh) * 1995-02-07 2000-12-27 埃克森化学专利公司 烯烃低聚的方法和用途

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
fabrizio Cavani et al.Effect of water in the performance of the "solid phosphoricacid"catalyst for alkylation of benzene to cumene and foroligomerization of propene.Applied Catalysis A97.1993,97177-196.
fabrizio Cavani et al.Effect of water in the performance of the "solid phosphoricacid"catalyst for alkylation of benzene to cumene and foroligomerization of propene.Applied Catalysis A97.1993,97177-196. *

Also Published As

Publication number Publication date
ATE517074T1 (de) 2011-08-15
EP1694617B1 (en) 2011-07-20
US20070255081A1 (en) 2007-11-01
CA2548574A1 (en) 2005-06-30
KR20070029127A (ko) 2007-03-13
CN1894175A (zh) 2007-01-10
EP1694617A1 (en) 2006-08-30
CA2548574C (en) 2012-08-14
JP2007514702A (ja) 2007-06-07
WO2005058777A1 (en) 2005-06-30
ES2369777T3 (es) 2011-12-05

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