CN1878805A - 用于制备多相丙烯共聚物的多步法 - Google Patents

用于制备多相丙烯共聚物的多步法 Download PDF

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Publication number
CN1878805A
CN1878805A CNA200480032867XA CN200480032867A CN1878805A CN 1878805 A CN1878805 A CN 1878805A CN A200480032867X A CNA200480032867X A CN A200480032867XA CN 200480032867 A CN200480032867 A CN 200480032867A CN 1878805 A CN1878805 A CN 1878805A
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China
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formula
alkyl
group
compound
saturated
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Pending
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CNA200480032867XA
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English (en)
Chinese (zh)
Inventor
L·雷斯科尼
P·费拉里
G·切钦
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Basell Polyolefine GmbH
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Basell Polyolefine GmbH
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Publication of CN1878805A publication Critical patent/CN1878805A/zh
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/02Carriers therefor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/02Heterophasic composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00Chemical blending or stepwise polymerisation process with the same catalyst

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
CNA200480032867XA 2003-09-11 2004-08-04 用于制备多相丙烯共聚物的多步法 Pending CN1878805A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP03102736 2003-09-11
EP03102736.0 2003-09-11
US60/503,234 2003-09-16

Publications (1)

Publication Number Publication Date
CN1878805A true CN1878805A (zh) 2006-12-13

Family

ID=37510733

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA200480032867XA Pending CN1878805A (zh) 2003-09-11 2004-08-04 用于制备多相丙烯共聚物的多步法

Country Status (7)

Country Link
US (1) US20070276095A1 (cg-RX-API-DMAC7.html)
EP (1) EP1664137A1 (cg-RX-API-DMAC7.html)
JP (1) JP2007505173A (cg-RX-API-DMAC7.html)
KR (1) KR20060133960A (cg-RX-API-DMAC7.html)
CN (1) CN1878805A (cg-RX-API-DMAC7.html)
BR (1) BRPI0413961A (cg-RX-API-DMAC7.html)
WO (1) WO2005023889A1 (cg-RX-API-DMAC7.html)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005538198A (ja) * 2002-09-06 2005-12-15 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
KR101113341B1 (ko) 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
EP1664139A1 (en) * 2003-09-11 2006-06-07 Basell Polyolefine GmbH Multistep process for preparing heterophasic propylene copolymers
EP1518866A1 (en) * 2003-09-29 2005-03-30 Basell Poliolefine Italia S.P.A. Process for the preparation of porous ethylene polymers
JP4897670B2 (ja) 2004-05-04 2012-03-14 バーゼル・ポリオレフィン・ゲーエムベーハー アタクチック1−ブテンポリマー類の製造方法
RU2410388C2 (ru) 2005-03-18 2011-01-27 Базелль Полиолефине Гмбх Металлоценовые соединения
WO2006097500A1 (en) 2005-03-18 2006-09-21 Basell Polyolefine Gmbh Metallocene compounds
WO2006100258A1 (en) * 2005-03-23 2006-09-28 Basell Polyolefine Gmbh Process for the polymerization of olefins
KR101289946B1 (ko) 2005-03-23 2013-07-26 바젤 폴리올레핀 게엠베하 올레핀의 중합 방법
EP1871832B1 (en) * 2005-04-21 2012-06-13 Basell Poliolefine Italia S.r.l. Biaxially oriented propylene polymer films
US7964679B2 (en) * 2005-05-03 2011-06-21 Basell Poliolefine Italia S.R.L. Process for the polymerization of alpha olefins
US7985799B2 (en) 2005-05-11 2011-07-26 Basell Poliolefine Italia S.R.L. Polymerization process for preparing polyolefin blends
WO2006134046A1 (en) * 2005-06-13 2006-12-21 Basell Polyolefine Gmbh Process for the copolymerization of propylene
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
US8742042B2 (en) 2006-04-21 2014-06-03 Basell Polyolefine Gmbh Process for the preparation of ethylene copolymers
EP2010579A1 (en) * 2006-04-21 2009-01-07 Basell Polyolefine GmbH Process for the preparation of ethylene propylene copolymers
CN100516093C (zh) * 2006-04-21 2009-07-22 中国科学院上海有机化学研究所 烯烃聚合催化剂
JP5201943B2 (ja) * 2007-10-24 2013-06-05 日本ポリプロ株式会社 熱可塑性樹脂重合粒子
JP5201944B2 (ja) * 2007-10-24 2013-06-05 日本ポリプロ株式会社 熱可塑性樹脂重合粒子
ES2674576T3 (es) 2012-12-21 2018-07-02 Borealis Ag Catalizador
JP6193398B2 (ja) 2012-12-21 2017-09-06 ボレアリス エージー 触媒
ES2645256T3 (es) 2012-12-21 2017-12-04 Borealis Ag Catalizadores
EP2813517B2 (en) 2013-06-10 2019-06-26 Borealis AG Process for the preparation of a propylene polymer
WO2016089174A1 (ko) * 2014-12-04 2016-06-09 주식회사 엘지화학 무연신 폴리프로필렌계 필름
JP6848059B2 (ja) * 2017-06-30 2021-03-24 三井化学株式会社 プロピレン系重合体、その製造方法、プロピレン系樹脂組成物および成形体
WO2019213345A1 (en) 2018-05-03 2019-11-07 Dow Global Technologies Llc Propylene-based polymer compositions with excellent flexibility and hot air weldability

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3202370B2 (ja) * 1992-12-09 2001-08-27 三菱化学株式会社 プロピレンブロック共重合体の製造法
BE1007040A3 (fr) * 1993-05-25 1995-02-28 Solvay Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur.
DE4317655A1 (de) * 1993-05-27 1994-12-01 Basf Ag Mehrphasige Blockcopolymerisate des Propylens
EP0816395B1 (en) * 1994-04-11 2000-07-19 Mitsui Chemicals, Inc. Process for preparing propylene polymer composition and propylene polymer composition
JP4024295B2 (ja) * 1994-04-11 2007-12-19 三井化学株式会社 プロピレン系重合体組成物の製造方法およびプロピレン系重合体組成物
DE19621022B4 (de) * 1996-05-24 2014-12-31 Basell Polyolefine Gmbh Hochmolekulares Ethylen/Propylen-Reaktorblend mit breiter Molmassenverteilung
FR2765225B1 (fr) * 1997-06-30 2000-01-14 Atochem Elf Sa Composante catalytique solide pour la polymerisation des olefines
BE1012364A3 (fr) * 1998-12-22 2000-10-03 Solvay Procede pour la preparation d'une composition catalytique pour la polymerisation des alpha-olefines, composition catalytique obtenue et procede de polymerisation utilisant une telle composition catalytique
US6399535B1 (en) * 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
DE19962910A1 (de) * 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE19962814A1 (de) * 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
EP1250365A2 (de) * 1999-12-23 2002-10-23 Basell Polypropylen GmbH Übergangsmetallverbindung, ligandensystem, katalysatorsystem und seine verwendung zur polymerisation und copolymerisation von olefinen
US20020107344A1 (en) * 2000-12-07 2002-08-08 Peterson Thomas Henry Supprt materials for use with polymerization catalysts
JP3990929B2 (ja) * 2001-03-29 2007-10-17 日本ポリプロ株式会社 プロピレン系ブロック共重合体の製造方法
WO2003046022A1 (en) * 2001-11-27 2003-06-05 Basell Polyolefine Gmbh Process for the treatment of polymer compositions
DE60213452T2 (de) * 2001-11-30 2007-08-23 Basell Polyolefine Gmbh Metallocene und verfahren zur herstellung von propylenpolymeren

Also Published As

Publication number Publication date
EP1664137A1 (en) 2006-06-07
US20070276095A1 (en) 2007-11-29
WO2005023889A1 (en) 2005-03-17
JP2007505173A (ja) 2007-03-08
KR20060133960A (ko) 2006-12-27
BRPI0413961A (pt) 2006-10-31

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