CN1847147B - 从胺类化合物的混合物合成zbm-30沸石的方法 - Google Patents
从胺类化合物的混合物合成zbm-30沸石的方法 Download PDFInfo
- Publication number
- CN1847147B CN1847147B CN2006100089398A CN200610008939A CN1847147B CN 1847147 B CN1847147 B CN 1847147B CN 2006100089398 A CN2006100089398 A CN 2006100089398A CN 200610008939 A CN200610008939 A CN 200610008939A CN 1847147 B CN1847147 B CN 1847147B
- Authority
- CN
- China
- Prior art keywords
- gel
- mixture
- metal source
- zbm
- amine compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- -1 amine compounds Chemical class 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 27
- 239000010457 zeolite Substances 0.000 title claims abstract description 25
- 229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 24
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 230000002194 synthesizing effect Effects 0.000 title description 2
- 239000007787 solid Substances 0.000 claims abstract description 37
- 229910052751 metal Inorganic materials 0.000 claims abstract description 25
- 239000002184 metal Substances 0.000 claims abstract description 25
- 238000002360 preparation method Methods 0.000 claims abstract description 21
- 238000002425 crystallisation Methods 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000008025 crystallization Effects 0.000 claims abstract description 5
- 239000000499 gel Substances 0.000 claims description 59
- 239000002243 precursor Substances 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000004411 aluminium Substances 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 8
- 239000011541 reaction mixture Substances 0.000 claims description 8
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 7
- 238000013019 agitation Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 238000010189 synthetic method Methods 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 150000003973 alkyl amines Chemical class 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 2
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- IYPZRUYMFDWKSS-UHFFFAOYSA-N piperazin-1-amine Chemical compound NN1CCNCC1 IYPZRUYMFDWKSS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 60
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 27
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 20
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 12
- 238000009415 formwork Methods 0.000 description 11
- 239000000377 silicon dioxide Substances 0.000 description 8
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 7
- 229910002012 Aerosil® Inorganic materials 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 229960001866 silicon dioxide Drugs 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000008119 colloidal silica Substances 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical group [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 125000006308 propyl amino group Chemical group 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0500712 | 2005-01-24 | ||
| FR0500712A FR2881128B1 (fr) | 2005-01-24 | 2005-01-24 | Nouvelle methode de synthese de la zeolithe zbm-30 a partir d'un melange de composes amines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1847147A CN1847147A (zh) | 2006-10-18 |
| CN1847147B true CN1847147B (zh) | 2011-01-26 |
Family
ID=34953997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100089398A Expired - Fee Related CN1847147B (zh) | 2005-01-24 | 2006-01-24 | 从胺类化合物的混合物合成zbm-30沸石的方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7544347B2 (enExample) |
| EP (1) | EP1683761B1 (enExample) |
| JP (1) | JP2006206433A (enExample) |
| CN (1) | CN1847147B (enExample) |
| FR (1) | FR2881128B1 (enExample) |
| ZA (1) | ZA200600566B (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2852863B1 (fr) * | 2003-03-24 | 2005-05-06 | Inst Francais Du Petrole | Catalyseur et son utilisation pour l'amelioration du point d'ecoulement de charges hydrocarbonnees |
| FR2893019B1 (fr) * | 2005-11-04 | 2008-01-04 | Inst Francais Du Petrole | Procede de preparation de zeolithes de type zbm-30 utilisant un compose de type etherdiammonium comme structurant organique |
| FR2926028B1 (fr) * | 2008-01-04 | 2010-02-12 | Inst Francais Du Petrole | Catalyseur comprenant au moins une zeolithe particuliere et au moins une silice-alumine et procede d'hydrocraquage de charges hydrocarbonees utilisant un tel catalyseur |
| FR2932811B1 (fr) * | 2008-06-24 | 2010-09-03 | Inst Francais Du Petrole | Procede de conversion de charges issues de sources renouvelables en bases carburants gazoles de bonne qualite mettant en oeuvre un catalyseur de type zeolithique |
| CN106315611A (zh) * | 2016-08-24 | 2017-01-11 | 山东齐鲁华信高科有限公司 | 一种ssz‑13分子筛的制备方法 |
| EP3762335B1 (en) | 2018-03-09 | 2022-02-23 | Chevron U.S.A. Inc. | Synthesis of *mre framework type molecular sieves |
| US11964875B2 (en) * | 2022-03-24 | 2024-04-23 | Chevron U.S.A. Inc. | Synthesis of *MRE framework type molecular sieves |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0046504A1 (de) * | 1980-08-21 | 1982-03-03 | BASF Aktiengesellschaft | Kristalliner Metallsilikatzeolith ZBM-30 und Verfahren zu seiner Herstellung |
| US20020018747A1 (en) * | 2000-05-25 | 2002-02-14 | Board Of Trustees Operating Michigan State University | Ultrastable porous aluminosilicate structures |
| US20040232048A1 (en) * | 2003-03-24 | 2004-11-25 | Eric Benazzi | Catalyst and its use for improving the pour point of hydrocarbon charges |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3068017D1 (en) * | 1979-07-12 | 1984-07-05 | Mobil Oil Corp | Method of preparing zeolite zsm-48, the zeolite so prepared and its use as catalyst for organic compound conversion |
| DE3006471A1 (de) * | 1980-02-21 | 1981-08-27 | Basf Ag, 6700 Ludwigshafen | Kristalline isotaktische zeolithe, verfahren zur herstellung derselben sowie deren verwendung als katalysatoren |
| DE3021580A1 (de) * | 1980-06-07 | 1981-12-24 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von zeolithen und verwendung derselben als katalysatoren |
| US6713041B1 (en) * | 2002-02-12 | 2004-03-30 | Uop Llc | Crystalline aluminosilicate zeolitic composition: UZM-9 |
| FR2893019B1 (fr) * | 2005-11-04 | 2008-01-04 | Inst Francais Du Petrole | Procede de preparation de zeolithes de type zbm-30 utilisant un compose de type etherdiammonium comme structurant organique |
-
2005
- 2005-01-24 FR FR0500712A patent/FR2881128B1/fr not_active Expired - Fee Related
-
2006
- 2006-01-10 EP EP06290068A patent/EP1683761B1/fr not_active Not-in-force
- 2006-01-19 ZA ZA2006/00566A patent/ZA200600566B/en unknown
- 2006-01-23 US US11/337,080 patent/US7544347B2/en not_active Expired - Fee Related
- 2006-01-24 CN CN2006100089398A patent/CN1847147B/zh not_active Expired - Fee Related
- 2006-01-24 JP JP2006014606A patent/JP2006206433A/ja active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0046504A1 (de) * | 1980-08-21 | 1982-03-03 | BASF Aktiengesellschaft | Kristalliner Metallsilikatzeolith ZBM-30 und Verfahren zu seiner Herstellung |
| US20020018747A1 (en) * | 2000-05-25 | 2002-02-14 | Board Of Trustees Operating Michigan State University | Ultrastable porous aluminosilicate structures |
| US20040232048A1 (en) * | 2003-03-24 | 2004-11-25 | Eric Benazzi | Catalyst and its use for improving the pour point of hydrocarbon charges |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1847147A (zh) | 2006-10-18 |
| EP1683761B1 (fr) | 2013-03-13 |
| US7544347B2 (en) | 2009-06-09 |
| ZA200600566B (en) | 2006-12-27 |
| US20060292070A1 (en) | 2006-12-28 |
| FR2881128B1 (fr) | 2007-03-23 |
| EP1683761A1 (fr) | 2006-07-26 |
| JP2006206433A (ja) | 2006-08-10 |
| FR2881128A1 (fr) | 2006-07-28 |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110126 Termination date: 20140124 |