CN1840470B - 改进的含有硫化氢和二氧化硫的气体的处理方法 - Google Patents
改进的含有硫化氢和二氧化硫的气体的处理方法 Download PDFInfo
- Publication number
- CN1840470B CN1840470B CN2006100589539A CN200610058953A CN1840470B CN 1840470 B CN1840470 B CN 1840470B CN 2006100589539 A CN2006100589539 A CN 2006100589539A CN 200610058953 A CN200610058953 A CN 200610058953A CN 1840470 B CN1840470 B CN 1840470B
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- Prior art keywords
- acid
- functional group
- solvent
- gas
- catalytic system
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- 229910000037 hydrogen sulfide Inorganic materials 0.000 title claims description 8
- 238000000034 method Methods 0.000 claims abstract description 48
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- 125000000524 functional group Chemical group 0.000 claims description 52
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- NEGFNJRAUMCZMY-UHFFFAOYSA-N 3-(dimethylamino)benzoic acid Chemical compound CN(C)C1=CC=CC(C(O)=O)=C1 NEGFNJRAUMCZMY-UHFFFAOYSA-N 0.000 claims description 2
- MRBFWTDIRYEDBQ-UHFFFAOYSA-N 4-(2-aminoethyl)benzoic acid Chemical compound NCCC1=CC=C(C(O)=O)C=C1 MRBFWTDIRYEDBQ-UHFFFAOYSA-N 0.000 claims description 2
- FKOLPZLYCMWJNH-UHFFFAOYSA-N 4-carboxy-2-(morpholin-4-ium-4-ylmethyl)phenolate Chemical compound OC(=O)C1=CC=C(O)C(CN2CCOCC2)=C1 FKOLPZLYCMWJNH-UHFFFAOYSA-N 0.000 claims description 2
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- CSGQJHQYWJLPKY-UHFFFAOYSA-N CITRAZINIC ACID Chemical compound OC(=O)C=1C=C(O)NC(=O)C=1 CSGQJHQYWJLPKY-UHFFFAOYSA-N 0.000 claims description 2
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 claims description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 2
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 claims description 2
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- 125000004103 aminoalkyl group Chemical group 0.000 claims description 2
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- 235000003704 aspartic acid Nutrition 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
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- XJLSEXAGTJCILF-RXMQYKEDSA-N (R)-nipecotic acid zwitterion Chemical compound OC(=O)[C@@H]1CCCNC1 XJLSEXAGTJCILF-RXMQYKEDSA-N 0.000 description 1
- SYOANZBNGDEJFH-UHFFFAOYSA-N 2,5-dihydro-1h-triazole Chemical compound C1NNN=C1 SYOANZBNGDEJFH-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical class CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- NPKSPKHJBVJUKB-UHFFFAOYSA-N N-phenylglycine Chemical compound OC(=O)CNC1=CC=CC=C1 NPKSPKHJBVJUKB-UHFFFAOYSA-N 0.000 description 1
- SYNHCENRCUAUNM-UHFFFAOYSA-N Nitrogen mustard N-oxide hydrochloride Chemical compound Cl.ClCC[N+]([O-])(C)CCCl SYNHCENRCUAUNM-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229960002989 glutamic acid Drugs 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- CTAPFRYPJLPFDF-UHFFFAOYSA-N isoxazole Chemical compound C=1C=NOC=1 CTAPFRYPJLPFDF-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 150000003512 tertiary amines Chemical group 0.000 description 1
- 125000003831 tetrazolyl group Chemical group 0.000 description 1
- 150000004867 thiadiazoles Chemical class 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0218—Sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
- B01D53/8615—Mixtures of hydrogen sulfide and sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0222—Sulfur-containing compounds comprising sulfonyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/05—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR05/02367 | 2005-03-09 | ||
| FR0502367A FR2882942B1 (fr) | 2005-03-09 | 2005-03-09 | Procede perfectionne de traitement d'un gaz contenant de l'hydrogene sulfure et du dioxyde de soufre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1840470A CN1840470A (zh) | 2006-10-04 |
| CN1840470B true CN1840470B (zh) | 2012-05-30 |
Family
ID=35045130
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100589539A Expired - Fee Related CN1840470B (zh) | 2005-03-09 | 2006-03-09 | 改进的含有硫化氢和二氧化硫的气体的处理方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7597872B2 (https=) |
| EP (1) | EP1700631B1 (https=) |
| JP (1) | JP5048256B2 (https=) |
| CN (1) | CN1840470B (https=) |
| AT (1) | ATE472362T1 (https=) |
| CO (1) | CO5840260A1 (https=) |
| DE (1) | DE602006015114D1 (https=) |
| FR (1) | FR2882942B1 (https=) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2948578B1 (fr) * | 2009-07-31 | 2011-07-29 | Inst Francais Du Petrole | Solution absorbante contenant un inhibiteur de degradation derive d'un triazole ou d'un tetrazole et procede d'absorption de composes acides contenus dans un effluent gazeux |
| US8236276B2 (en) * | 2010-02-22 | 2012-08-07 | Fluor Enterprises, Inc. | System and method for sulfur recovery |
| US8871009B2 (en) * | 2012-06-22 | 2014-10-28 | Subramanian Iyer | System for removal of organic contaminants from bio-gas for renewable energy production |
| US9353026B2 (en) | 2013-07-19 | 2016-05-31 | Baker Hughes Incorporated | Oil soluble hydrogen sulfide scavenger |
| CN103611391B (zh) * | 2013-12-12 | 2016-01-20 | 北京博源恒升高科技有限公司 | 乙二醇类复合溶液脱除气体中SOx的方法 |
| CN103623689B (zh) * | 2013-12-12 | 2016-06-29 | 北京博源恒升高科技有限公司 | 多元醇复合溶液脱除气体中SOx的方法 |
| AU2015218491A1 (en) * | 2014-08-29 | 2016-03-17 | Commonwealth Scientific And Industrial Research Organisation | Absorbent solution for absorption of acid gas and process for absorption of acid gas |
| EA039814B1 (ru) * | 2016-04-18 | 2022-03-16 | Басф Се | Предварительно приготовленная смесь для получения абсорбента для удаления кислотных газов из потока текучей среды |
| CN106914103A (zh) * | 2017-04-11 | 2017-07-04 | 德阳劲达节能科技有限责任公司 | 一种克劳斯尾气低温脱硫系统及工艺 |
| CN108939801A (zh) * | 2018-08-13 | 2018-12-07 | 长有彬 | 一种脱硫剂制备方法 |
| CN109603472B (zh) * | 2018-11-29 | 2021-03-23 | 河北彩客化学股份有限公司 | 一种处理含二氧化硫废气的吸附剂及方法 |
| CN112023908B (zh) * | 2020-08-04 | 2023-03-17 | 华北电力大学 | 氮氧化物脱除催化剂及其制备方法 |
| CN114432841A (zh) * | 2020-10-20 | 2022-05-06 | 中国石油化工股份有限公司 | 吸收低浓度so2和催化克劳斯反应的双功能吸收剂及其制备 |
| CN116116170B (zh) * | 2021-11-15 | 2026-01-30 | 中石化南京化工研究院有限公司 | 含有醇胺的具有酸性气体吸收功能的组合物和应用 |
| CN119750501B (zh) * | 2024-11-22 | 2026-01-02 | 江西理工大学 | 一种利用乙酰胺改性胍基含水深共晶溶剂制备硫磺的方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1176288A (zh) * | 1996-09-09 | 1998-03-18 | 中国石油化工总公司 | 一种含锑化合物的催化裂化金属钝化剂的制备方法 |
| CN1180583A (zh) * | 1996-09-16 | 1998-05-06 | 法国石油公司 | 包括一个循环溶剂的贫硫步骤、对含有硫化氢和二氧化硫气体的处理方法和设备 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3160601A (en) * | 1959-07-13 | 1964-12-08 | Dow Corning | Amine salts of phosphoric acid and amine salts of carboxylic acid as silanol condensation catalysts |
| FR1492797A (fr) * | 1965-09-18 | 1967-08-25 | Inst Francais Du Petrole | Procédé d'épuration de gaz sulfuré et de production de soufre |
| FR1592092A (https=) | 1968-02-29 | 1970-05-11 | ||
| FR2115721A5 (https=) | 1970-11-30 | 1972-07-07 | Inst Francais Du Petrole | |
| FR2122674A5 (en) * | 1971-01-19 | 1972-09-01 | Inst Francais Du Petrole | Sulphur prodn - from hydrogen sulphide and sulphur dioxide |
| FR2138371B2 (https=) * | 1971-01-19 | 1973-05-25 | Inst Francais Du Petrole | |
| DE2253806C3 (de) * | 1972-11-03 | 1978-06-15 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Umsetzung des in Gasgemischen enthaltenen Schwefelwasserstoffs mit Schwefeldioxid nach dem Claus-Prozess |
| JPS5078592A (https=) * | 1973-11-16 | 1975-06-26 | ||
| JPS5218466A (en) * | 1975-07-25 | 1977-02-12 | Rhone Poulenc Ind | Removal of hydrogen sulfide from gas stream |
| US4456696A (en) * | 1981-04-09 | 1984-06-26 | Abbott Laboratories | Catalyst for making polyurethanes |
| DE68923793T2 (de) * | 1988-12-23 | 1996-04-04 | Petrolite Holdings Inc | Verfahren zum süssen von kohlenwasserstoffen. |
| FR2756197B1 (fr) | 1996-11-25 | 1999-01-08 | Inst Francais Du Petrole | Composition et son utilisation pour convertir un gaz contenant de l'hydrogene sulfure et de l'anhydride sulfureux en soufre |
| FR2757147B1 (fr) * | 1996-12-12 | 1999-01-29 | Inst Francais Du Petrole | Procede et dispositif d'epuration d'un gaz contenant de l'hydrogene sulfure et du dioxyde de soufre |
| US5928620A (en) * | 1997-09-10 | 1999-07-27 | The Regents Of The University Of California | Process employing single-stage reactor for recovering sulfur from H2 S- |
| FR2784370B1 (fr) | 1998-10-08 | 2001-03-09 | Inst Francais Du Petrole | Procede et dispositif de traitement d'un gaz contenant de l'hydrogene sulfure et du dioxyde de soufre, comportant une etape d'elimination de sous-produits solides |
| FR2786111B1 (fr) | 1998-11-20 | 2000-12-15 | Inst Francais Du Petrole | Procede et dispositif de traitement d'un gaz contenant de l'hydrogene sulfure et du dioxyde de soufre, comportant une etape d'elimination de sous-produits |
| JP2001288122A (ja) * | 2000-04-04 | 2001-10-16 | Daicel Chem Ind Ltd | 反応生成物と触媒との分離方法 |
| AR038161A1 (es) * | 2002-01-24 | 2004-12-29 | Basf Ag | Procedimiento para separar acidos de mezclas de reaccion quimicas con la ayuda de liquidos ionicos |
-
2005
- 2005-03-09 FR FR0502367A patent/FR2882942B1/fr not_active Expired - Fee Related
-
2006
- 2006-02-28 EP EP06290334A patent/EP1700631B1/fr not_active Expired - Lifetime
- 2006-02-28 AT AT06290334T patent/ATE472362T1/de not_active IP Right Cessation
- 2006-02-28 DE DE602006015114T patent/DE602006015114D1/de not_active Expired - Lifetime
- 2006-03-08 US US11/369,821 patent/US7597872B2/en not_active Expired - Fee Related
- 2006-03-09 CN CN2006100589539A patent/CN1840470B/zh not_active Expired - Fee Related
- 2006-03-09 JP JP2006063478A patent/JP5048256B2/ja not_active Expired - Fee Related
- 2006-03-09 CO CO06023951A patent/CO5840260A1/es active IP Right Grant
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1176288A (zh) * | 1996-09-09 | 1998-03-18 | 中国石油化工总公司 | 一种含锑化合物的催化裂化金属钝化剂的制备方法 |
| CN1180583A (zh) * | 1996-09-16 | 1998-05-06 | 法国石油公司 | 包括一个循环溶剂的贫硫步骤、对含有硫化氢和二氧化硫气体的处理方法和设备 |
Also Published As
| Publication number | Publication date |
|---|---|
| CO5840260A1 (es) | 2007-12-31 |
| FR2882942A1 (fr) | 2006-09-15 |
| EP1700631A1 (fr) | 2006-09-13 |
| JP2006247651A (ja) | 2006-09-21 |
| JP5048256B2 (ja) | 2012-10-17 |
| US20060204433A1 (en) | 2006-09-14 |
| DE602006015114D1 (de) | 2010-08-12 |
| FR2882942B1 (fr) | 2007-06-15 |
| ATE472362T1 (de) | 2010-07-15 |
| CN1840470A (zh) | 2006-10-04 |
| EP1700631B1 (fr) | 2010-06-30 |
| US7597872B2 (en) | 2009-10-06 |
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