CN1833055A - 在降低的反应温度下以高产率和高选择性制备纳米碳材料的改进的催化剂和方法 - Google Patents

在降低的反应温度下以高产率和高选择性制备纳米碳材料的改进的催化剂和方法 Download PDF

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Publication number
CN1833055A
CN1833055A CNA2004800219719A CN200480021971A CN1833055A CN 1833055 A CN1833055 A CN 1833055A CN A2004800219719 A CNA2004800219719 A CN A2004800219719A CN 200480021971 A CN200480021971 A CN 200480021971A CN 1833055 A CN1833055 A CN 1833055A
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carbon
catalyst
iron
morphology
nickel
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Chinese (zh)
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巴本德拉·帕拉丹
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Columbian Chemicals Co
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Columbian Chemicals Co
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
CNA2004800219719A 2003-07-28 2004-04-20 在降低的反应温度下以高产率和高选择性制备纳米碳材料的改进的催化剂和方法 Pending CN1833055A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/628,842 US20050025695A1 (en) 2003-07-28 2003-07-28 Catalyst and process to produce nanocarbon materials in high yield and at high selectivity at reduced reaction temperatures
US10/628,842 2003-07-28

Publications (1)

Publication Number Publication Date
CN1833055A true CN1833055A (zh) 2006-09-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2004800219719A Pending CN1833055A (zh) 2003-07-28 2004-04-20 在降低的反应温度下以高产率和高选择性制备纳米碳材料的改进的催化剂和方法

Country Status (9)

Country Link
US (1) US20050025695A1 (ja)
EP (1) EP1654406A4 (ja)
JP (1) JP2007500121A (ja)
KR (1) KR20060052923A (ja)
CN (1) CN1833055A (ja)
AR (1) AR044387A1 (ja)
BR (1) BRPI0413069A (ja)
TW (1) TW200505788A (ja)
WO (1) WO2005016853A2 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107124875A (zh) * 2014-11-06 2017-09-01 贝克休斯公司 制备抗摩擦涂层的方法

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7629553B2 (en) * 2005-06-08 2009-12-08 Unm.Stc Metal oxide nanoparticles and process for producing the same
KR101443222B1 (ko) 2007-09-18 2014-09-19 삼성전자주식회사 그라펜 패턴 및 그의 형성방법
CA2758694C (en) 2009-04-17 2017-05-23 Seerstone Llc Method for producing solid carbon by reducing carbon oxides
KR101900758B1 (ko) * 2011-11-29 2018-09-20 한화에어로스페이스 주식회사 그래핀 합성용 금속 박막 및 이를 이용한 그래핀 제조 방법
US9221685B2 (en) 2012-04-16 2015-12-29 Seerstone Llc Methods of capturing and sequestering carbon
WO2013158158A1 (en) 2012-04-16 2013-10-24 Seerstone Llc Methods for treating an offgas containing carbon oxides
MX354529B (es) 2012-04-16 2018-03-07 Seerstone Llc Métodos para producir carbono sólido mediante la reducción de dióxido de carbono.
NO2749379T3 (ja) 2012-04-16 2018-07-28
MX2014012548A (es) 2012-04-16 2015-04-10 Seerstone Llc Metodos y estructuras para reducir oxidos de carbono con catalizadores no ferrosos.
US9896341B2 (en) 2012-04-23 2018-02-20 Seerstone Llc Methods of forming carbon nanotubes having a bimodal size distribution
US10815124B2 (en) 2012-07-12 2020-10-27 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
CN107651667A (zh) 2012-07-12 2018-02-02 赛尔斯通股份有限公司 包含碳纳米管的固体碳产物以及其形成方法
MX2015000580A (es) 2012-07-13 2015-08-20 Seerstone Llc Metodos y sistemas para formar productos de carbono solido y amoniaco.
US9779845B2 (en) 2012-07-18 2017-10-03 Seerstone Llc Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same
WO2014039509A2 (en) 2012-09-04 2014-03-13 Ocv Intellectual Capital, Llc Dispersion of carbon enhanced reinforcement fibers in aqueous or non-aqueous media
MX2015006893A (es) 2012-11-29 2016-01-25 Seerstone Llc Reactores y metodos para producir materiales de carbono solido.
US10115844B2 (en) 2013-03-15 2018-10-30 Seerstone Llc Electrodes comprising nanostructured carbon
US9783416B2 (en) 2013-03-15 2017-10-10 Seerstone Llc Methods of producing hydrogen and solid carbon
WO2014151138A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Reactors, systems, and methods for forming solid products
EP3129133A4 (en) 2013-03-15 2018-01-10 Seerstone LLC Systems for producing solid carbon by reducing carbon oxides
WO2014151144A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Carbon oxide reduction with intermetallic and carbide catalysts
WO2018022999A1 (en) 2016-07-28 2018-02-01 Seerstone Llc. Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US54849A (en) * 1866-05-22 Improvement in trunk-locks
US4881994A (en) * 1987-04-30 1989-11-21 United Technologies Corporation Iron oxide catalyst propellant, and method for making same
US5618875A (en) * 1990-10-23 1997-04-08 Catalytic Materials Limited High performance carbon filament structures
US5458784A (en) * 1990-10-23 1995-10-17 Catalytic Materials Limited Removal of contaminants from aqueous and gaseous streams using graphic filaments
WO1997005994A1 (en) * 1995-08-04 1997-02-20 Microcoating Technologies Inc Chemical vapor deposition and powder formation using thermal spray with near supercritical and supercritical fluid solutions
US6221330B1 (en) * 1997-08-04 2001-04-24 Hyperion Catalysis International Inc. Process for producing single wall nanotubes using unsupported metal catalysts
CA2350099C (en) * 1998-11-03 2008-05-20 William Marsh Rice University Gas-phase nucleation and growth of single-wall carbon nanotubes from high pressure co
US6159538A (en) * 1999-06-15 2000-12-12 Rodriguez; Nelly M. Method for introducing hydrogen into layered nanostructures
US6485858B1 (en) * 1999-08-23 2002-11-26 Catalytic Materials Graphite nanofiber catalyst systems for use in fuel cell electrodes
US20020054849A1 (en) * 2000-09-08 2002-05-09 Baker R. Terry K. Crystalline graphite nanofibers and a process for producing same
US6537515B1 (en) * 2000-09-08 2003-03-25 Catalytic Materials Llc Crystalline graphite nanofibers and a process for producing same
WO2002026624A1 (en) * 2000-09-29 2002-04-04 President And Fellows Of Harvard College Direct growth of nanotubes, and their use in nanotweezers
US6503660B2 (en) * 2000-12-06 2003-01-07 R. Terry K. Baker Lithium ion battery containing an anode comprised of graphitic carbon nanofibers
US6752977B2 (en) * 2001-02-12 2004-06-22 William Marsh Rice University Process for purifying single-wall carbon nanotubes and compositions thereof
US7157068B2 (en) * 2001-05-21 2007-01-02 The Trustees Of Boston College Varied morphology carbon nanotubes and method for their manufacture
US6596187B2 (en) * 2001-08-29 2003-07-22 Motorola, Inc. Method of forming a nano-supported sponge catalyst on a substrate for nanotube growth
US6849245B2 (en) * 2001-12-11 2005-02-01 Catalytic Materials Llc Catalysts for producing narrow carbon nanostructures
US7378075B2 (en) * 2002-03-25 2008-05-27 Mitsubishi Gas Chemical Company, Inc. Aligned carbon nanotube films and a process for producing them
US20040005269A1 (en) * 2002-06-06 2004-01-08 Houjin Huang Method for selectively producing carbon nanostructures
US7846414B2 (en) * 2002-11-15 2010-12-07 Mcgill University Method for producing carbon nanotubes using a DC non-transferred thermal plasma torch

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107124875A (zh) * 2014-11-06 2017-09-01 贝克休斯公司 制备抗摩擦涂层的方法

Also Published As

Publication number Publication date
WO2005016853A3 (en) 2005-09-29
KR20060052923A (ko) 2006-05-19
EP1654406A2 (en) 2006-05-10
AR044387A1 (es) 2005-09-07
JP2007500121A (ja) 2007-01-11
EP1654406A4 (en) 2007-08-22
BRPI0413069A (pt) 2006-10-17
WO2005016853A2 (en) 2005-02-24
US20050025695A1 (en) 2005-02-03
TW200505788A (en) 2005-02-16

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