CN1827174A - Disinfecting and sterilizing liquid with chelated silver iron, its production method and use - Google Patents
Disinfecting and sterilizing liquid with chelated silver iron, its production method and use Download PDFInfo
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- CN1827174A CN1827174A CN 200610034626 CN200610034626A CN1827174A CN 1827174 A CN1827174 A CN 1827174A CN 200610034626 CN200610034626 CN 200610034626 CN 200610034626 A CN200610034626 A CN 200610034626A CN 1827174 A CN1827174 A CN 1827174A
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Abstract
This invention is about a chelate silver ion sterilization liquid and method of manufacture and uses thereof, and its characteristics are:1) Proportionally composed of silver ion liquid, silicone fluid and assistants;2) The weight content of the silicone fluid and assistants in chelate nanosilver sterilization liquid is 0.5%.- 1.5%. each;and 3) The assistants are surface activator and sucrose ester; The chelate silver ion liquid is composed of chelate silver ion and distilled water or deionization water, and the silver ion density is 0.125%.-0.5%.. Compared with current technics, the biggest virtue of this invention is that it processes the nature fine silver to silver ion by mechanical chelate means, and the silver ion is pure natural and contains no elements or chemical leavings those are bad to fleshes or environment. The outstanding contribution of this invention is that it can depress cost and protect environment. This invention has the function of sterilizing quickly and it can be made to disinfection liquid solution or spray.
Description
Technical field
The present invention relates to a kind of chelated silver iron disinfection solution and manufacture method and purposes, have function of sterilizing, can make aqueous antiseptic solution or spray.Belong to antibiotic biocide technical field.
Background technology
At present, AT STATION, crowded public areas such as airport, school, hotel, hotel, large-scale meeting-place, public equipment such as ground, wall, railway carriage, cabin, platform, chair even air all are stained with pathogenic bacteria easily, need artificial sterilizing.Through anti-SAR one labour in 2003, people knew sanitarian importance.Just can avoid antibacterial to spread unchecked but how to clean and clean from which aspect, in general should set about from domestic hygiene and public health aspect, for example using disinfection solution is a kind of means preferably.
Silver is a kind of naturally occurring metal, and years'experiences proves that silver can play lethal effect to malignant bacteria, fungus, mycete, parasite and the virus of numerous kinds, but harmless to people's health.Because silver can sterilize and prevent accumulation of bacteria, can prevent that the antibacterial diffusion from reaching the purpose that stops disease carrying germ, therefore, silver is considered to a kind of effective antibacterial and parasiticide.In the prior art, silver generally is present in following form: the colloidal suspension liquid of silver nitrate, silver oxide or silver compound, but no matter be that a kind of form, all contain nitrate residue and other organic or inorganic chemical residues in the Ag-containing solution, these perform in public residue except human body is had the side effect, also can pollute environment.The Chinese patent communique discloses the many pieces of patent documentations about silver ion or nanometer silver antimicrobial disinfectant, for example: name is called " containing the antiseptic solution with the silver of poly-pectate and EDTA chelating ", application number is the application for a patent for invention of " 03824562.0 ", name is called " propolis and silver ion composite nanometer disinfectant and preparation method thereof ", application number is the application for a patent for invention of " 200510066437.6 ", name is called " liquid nanometer simple substance silver antibacterial agent and preparation method ", application number is the application for a patent for invention of " 200510036375.4 ", name is called " preparation method of nano silver-carrying antiseptic ", application number is the application for a patent for invention of " 00126579.2 ", name is called " a kind of disinfectant and purposes and manufacture method that contains silver ion ", application number is the application for a patent for invention of " 99113325.0 " etc., all contains chemical residues such as nitrate bar none.
Summary of the invention
First purpose of the present invention is for a kind of chelated silver iron disinfection solution is provided.Have the characteristics quick, environmental protection that sterilize.
Second purpose of the present invention is for a kind of manufacture method of chelated silver iron disinfection solution is provided.
The 3rd purpose of the present invention is for a kind of purposes of chelated silver iron disinfection solution is provided.
First purpose of the present invention can reach by taking following measure:
The chelated silver iron disinfection solution is characterized in that:
1) forms in proportion by chelated silver iron water, silicone oil and auxiliary agent;
2) described silicone oil, auxiliary agent shared weight percentage in the chelated silver iron disinfection solution respectively is 0.5 ‰～1.5 ‰;
3) described auxiliary agent is surfactant or sucrose ester.
First purpose of the present invention can also reach by taking following measure:
Aforementioned chelated silver iron water is made up of chelated silver iron and distilled water or deionized water, and its concentration of silver ions is 0.125 ‰～0.5 ‰.
Aforementioned chelated silver iron can be the powdery silver ion, easily is dissolved in water, constitutes the hydrolysis silver ion solution.
Aforementioned powdery silver ion is made through the mechanical type chelating by natural fine silver, does not contain other any chemical elements.
Second purpose of the present invention can reach by taking following measure:
The manufacture method of foregoing chelated silver iron disinfection solution is characterized in that:
1) be ready to powdery silver ion and the distilled water made through the mechanical type chelating by natural fine silver, described powdery silver ion is dissolved in the distilled water water, making concentration is 0.125 ‰～0.5 ‰ chelated silver iron water;
2) in proportion the 1st) add silicone oil and auxiliary agent respectively in the chelated silver iron aqueous solution that makes of step, and be stirred to abundant dissolving; The silicone oil that is added, auxiliary agent shared weight percentage in the chelated silver iron disinfection solution respectively is 0.5 ‰～1.5 ‰.
Second purpose of the present invention can also reach by taking following measure:
The 1st) used distilled water of step can adopt deionized water to replace.
The 2nd) go on foot used auxiliary agent and can be surfactant or sucrose ester.
The 3rd purpose of the present invention can also reach by taking following measure:
The purposes of foregoing chelated silver iron disinfection solution is characterized in that:
Make medical disinfection solution, be used for wound or affected part sterilizing.
Make general nail disinfection solution, be used for the public place sterilizing that staff can reach.
Make the sterilizing spray, be used for any indoor and outdoor sterilizing.
The present invention has following outstanding beneficial effect:
1, to be different from the most outstanding advantage of prior art be to adopt the method for mechanical chelating that natural fine silver is processed into silver ion in the present invention, these silver ions are pure natural character, do not contain any to human body, environmentally harmful element and chemical residue, do not contain residuals such as any nitrate nitrogen and nitrous acid in the disinfection solution, so there are not again problems such as treatment of nitric acid salt.The outstanding contributions that prior art is made are to reduce cost, protect the environment from pollution.
2, the chelated silver iron of the present invention's employing, it has abandoned the chelating equipment of existing costliness, adopts efficient cheap process for sequestration to make chelated silver iron, and method is simple, cheap.
2, the silver ion that the present invention relates to is the active atomic state, microgranule ratio nano silver is also little, with the silver of other carrier is antibiotic comparing, and has that transparency is high, silver carrying amount good, steady quality, silver ion rate of release long stable effect, adding proportion are low, safety non-toxic, nonhygroscopic advantage.
The specific embodiment:
Specific embodiment 1:
Present embodiment is made of in proportion chelated silver iron water, silicone oil and auxiliary agent; The concentration of described chelated silver iron water is 0.2 ‰; Described silicone oil, auxiliary agent shared weight percentage in the chelated silver iron disinfection solution respectively is 1 ‰; Described auxiliary agent is surfactant or sucrose ester.
The manufacture method of present embodiment comprises the steps:
1) be ready to be restrained by powdery silver ion 1 gram and distilled water 5000 that natural fine silver is made through the mechanical type chelating, described powdery silver ion fully is dissolved in the distilled water, making concentration is 0.2 ‰ chelated silver iron water;
2) in proportion the 1st) add silicone oil and auxiliary agent respectively in the chelated silver iron aqueous solution that makes of step, and be stirred to abundant dissolving; The silicone oil that is added, auxiliary agent shared weight percentage in the chelated silver iron disinfection solution respectively is 1.0 ‰.
In the manufacture method of present embodiment, the 1st) used distilled water of step can adopt deionized water to replace; The 2nd) go on foot used auxiliary agent and can be surfactant or sucrose ester.
The purposes of present embodiment is as follows: make medical disinfection solution, be used for wound or affected part sterilizing.Perhaps make general nail disinfection solution, be used for the public place sterilizing that staff can reach.Perhaps make the sterilizing spray, be used for any indoor and outdoor sterilizing.
The antibiotic rate of present embodiment can reach 100%.It firmly adsorbs and penetrates the cell wall of antibacterial, germ with stable speed slow release leukorrhagia electricity silver ion, thus destroy microorganisms electric transmission system, respiratory system, substance delivery system killing bacteria rapidly; After entering cyton, can also react, protein of bacteria is solidified, destroy the activity of bacterial cell synzyme, make cell forfeiture schizogamy ability and death with the foundation of antibacterial.Under the effect of light, the silver ion of oxidation state can become catalytic active center again, activates the oxygen in the water and air.Generation has the OH free radical and the active oxygen ion of very strong oxidability, destroys the fertility in the antibacterial at short notice, causes antibacterial death.After bacterial body lost activity, silver ion can dissociate out from thalline again, repeats fungicidal property.Its sterilizing ability is not subjected to light, heat damage, invariant color, and the lasting period is designed fatal consistent with goods.
With the silver of other carrier is antibiotic comparing, have that transparency is high, silver carrying amount good, steady quality, silver ion rate of release long stable effect (remain on 0.5mg/L, and the silver ion amount of other antibacterial was reduced to rapidly below the 0.5mg/L and constantly reduces from 2.5mg/L in 30 days), adding proportion low (common 0.3%), safety non-toxic (LD50＞2000mg/kg), the advantage of the moisture absorption (following 24 hours hydroscopicities 0.4% of 81% humidity) hardly.Test through CDC virus precaution control, to the SARS9 SARS) virus function has deactivation effect in various degree more than 4 hours the time, and deactivation rates 100% in 6 hours; To germ and cause that beriberic day lobe bacterium also has and quite significantly subtract effect extremely.
Specific embodiment 2:
The characteristics of present embodiment are: the concentration of chelated silver iron water is 0.125 ‰; Silicone oil, auxiliary agent shared weight percentage in the chelated silver iron disinfection solution respectively is 0.5 ‰; Described auxiliary agent can be surfactant or sucrose ester.
The manufacture process of present embodiment and purposes are with embodiment 1.
Specific embodiment 3:
The characteristics of present embodiment are: the concentration of chelated silver iron water is 0.15 ‰; Silicone oil, auxiliary agent shared weight percentage in the chelated silver iron disinfection solution respectively is 1.5 ‰; Described auxiliary agent can be surfactant or sucrose ester.
The manufacture process of present embodiment and purposes are with embodiment 1.
Specific embodiment 4:
The characteristics of present embodiment are: the concentration of chelated silver iron water is 0.25 ‰; Silicone oil, auxiliary agent shared weight percentage in the chelated silver iron disinfection solution respectively is 0.8 ‰; Described auxiliary agent can be surfactant or sucrose ester.
The manufacture process of present embodiment and purposes are with embodiment 1.
Specific embodiment 5:
The characteristics of present embodiment are: the concentration of chelated silver iron water is 0.35 ‰; Silicone oil, auxiliary agent shared weight percentage in the chelated silver iron disinfection solution respectively is 1.2 ‰; Described auxiliary agent can be surfactant or sucrose ester.
The manufacture process of present embodiment and purposes are with embodiment 1.
Specific embodiment 6:
The characteristics of present embodiment are: the concentration of chelated silver iron water is 0.5 ‰; Silicone oil, auxiliary agent shared weight percentage in the chelated silver iron disinfection solution respectively is 1.5 ‰; Described auxiliary agent can be surfactant or sucrose ester.
The manufacture process of present embodiment and purposes are with embodiment 1.
Scientific practice proves, as long as contain 50,000,000,000/can eliminate antibacterial in the water once the silver ionized water solution of gram.Because therefore no any toxicity of chelated silver iron itself and chemical residual material, meet environmental protection requirement, the product of manufacturing is a Green Product.Owing to be full water-soluble state, its liquid dispersed power is very good, is fit to make various ceramic products.The ceramic product of making has permanent automatic sterilizing sterilizing function.
The water-soluble material of the silver ion of chelating state can be widely used in various manufactured goods, cooperates on the actual life application products.And the silver ionized water of chelating state, more economical and have more low-cost benefit.Nanometer silver generally all between 60～20nm size, each silver ion of the silver ion of chelating state all independently, active high, also than the existing careful manyfold of producing of nanoparticle, even reach 100,000,100 times more than.Therefore utilization rate ten/height and economic can reduce cost on real utilization rate 10 times and not wait to 100 times.In goods, save other additive composition at some product, that is to say to reduce cost.
Claims (10)
1, chelated silver iron disinfection solution is characterized in that:
1) forms in proportion by chelated silver iron water, silicone oil and auxiliary agent;
2) described silicone oil, auxiliary agent shared weight percentage in the chelated silver iron disinfection solution respectively is 0.5 ‰～1.5 ‰;
3) described auxiliary agent is surfactant or sucrose ester.
2, chelated silver iron disinfection solution as claimed in claim 1 is characterized in that: aforementioned chelated silver iron water is made up of chelated silver iron and distilled water or deionized water, and its concentration of silver ions is 0.125 ‰～0.5 ‰.
3, chelated silver iron disinfection solution as claimed in claim 1, it is characterized in that: aforementioned chelated silver iron can be the powdery silver ion, easily is dissolved in water, constitutes the hydrolysis silver ion solution.
4, chelated silver iron disinfection solution as claimed in claim 1 is characterized in that: aforementioned powdery silver ion is made through the mechanical type chelating by natural fine silver, does not contain other any chemical elements.
5, the manufacture method of chelated silver iron disinfection solution as claimed in claim 1 is characterized in that:
1) be ready to powdery silver ion and the distilled water made through the mechanical type chelating by natural fine silver, described powdery silver ion is dissolved in the distilled water water, making concentration is 0.125 ‰～0.5 ‰ chelated silver iron water;
2) in proportion the 1st) add silicone oil and auxiliary agent respectively in the chelated silver iron aqueous solution that makes of step, and be stirred to abundant dissolving; The silicone oil that is added, auxiliary agent shared weight percentage in the chelated silver iron disinfection solution respectively is 0.5 ‰～1.5 ‰.
6, the manufacture method of chelated silver iron disinfection solution as claimed in claim 5 is characterized in that: the 1st) used distilled water of step can adopt deionized water to replace.
7, the manufacture method of chelated silver iron disinfection solution as claimed in claim 5 is characterized in that: the 2nd) go on foot used auxiliary agent and can be surfactant or sucrose ester.
8, the purposes of chelated silver iron disinfection solution as claimed in claim 1 is characterized in that: make medical disinfection solution, be used for wound or affected part sterilizing.
9, the purposes of chelated silver iron disinfection solution as claimed in claim 1 is characterized in that: make general nail disinfection solution, be used for the public place sterilizing that staff can reach.
10, the purposes of chelated silver iron disinfection solution as claimed in claim 1 is characterized in that: make the sterilizing spray, be used for any indoor and outdoor sterilizing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610034626 CN1827174A (en) | 2006-03-24 | 2006-03-24 | Disinfecting and sterilizing liquid with chelated silver iron, its production method and use |
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|---|---|---|---|
| CN 200610034626 CN1827174A (en) | 2006-03-24 | 2006-03-24 | Disinfecting and sterilizing liquid with chelated silver iron, its production method and use |
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| CN1827174A true CN1827174A (en) | 2006-09-06 |
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| CN 200610034626 Pending CN1827174A (en) | 2006-03-24 | 2006-03-24 | Disinfecting and sterilizing liquid with chelated silver iron, its production method and use |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113615716A (en) * | 2021-06-29 | 2021-11-09 | 佛山市风祁弘科生物科技有限公司 | Mite-removing and bacteriostatic spray composition and preparation process thereof |
-
2006
- 2006-03-24 CN CN 200610034626 patent/CN1827174A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113615716A (en) * | 2021-06-29 | 2021-11-09 | 佛山市风祁弘科生物科技有限公司 | Mite-removing and bacteriostatic spray composition and preparation process thereof |
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