CN1807333A - 一种混凝土引气剂 - Google Patents
一种混凝土引气剂 Download PDFInfo
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- CN1807333A CN1807333A CN 200610038322 CN200610038322A CN1807333A CN 1807333 A CN1807333 A CN 1807333A CN 200610038322 CN200610038322 CN 200610038322 CN 200610038322 A CN200610038322 A CN 200610038322A CN 1807333 A CN1807333 A CN 1807333A
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- 239000004567 concrete Substances 0.000 title claims abstract description 77
- 239000000047 product Substances 0.000 claims abstract description 35
- 239000011347 resin Substances 0.000 claims abstract description 30
- 229920005989 resin Polymers 0.000 claims abstract description 30
- 238000003756 stirring Methods 0.000 claims abstract description 24
- 238000005886 esterification reaction Methods 0.000 claims abstract description 19
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 15
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 11
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 8
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000008130 triterpenoid saponins Chemical class 0.000 claims abstract description 6
- -1 polyoxyethylene Polymers 0.000 claims description 31
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 28
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 16
- 230000032050 esterification Effects 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 16
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 8
- 230000004048 modification Effects 0.000 claims description 8
- 238000012986 modification Methods 0.000 claims description 8
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 7
- 235000021355 Stearic acid Nutrition 0.000 claims description 7
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 7
- 229940059574 pentaerithrityl Drugs 0.000 claims description 7
- 239000008117 stearic acid Substances 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 150000004054 benzoquinones Chemical class 0.000 claims description 5
- IFYDZTDBJZWEPK-UHFFFAOYSA-N alpha-hydroxyhexacosanoic acid Natural products CCCCCCCCCCCCCCCCCCCCCCCCC(O)C(O)=O IFYDZTDBJZWEPK-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 4
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 claims description 4
- 239000000376 reactant Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- VHOCUJPBKOZGJD-UHFFFAOYSA-N triacontanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O VHOCUJPBKOZGJD-UHFFFAOYSA-N 0.000 claims description 4
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 239000008399 tap water Substances 0.000 claims description 3
- 235000020679 tap water Nutrition 0.000 claims description 3
- NIONDZDPPYHYKY-SNAWJCMRSA-N (2E)-hexenoic acid Chemical compound CCC\C=C\C(O)=O NIONDZDPPYHYKY-SNAWJCMRSA-N 0.000 claims description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- OXEDXHIBHVMDST-UHFFFAOYSA-N 12Z-octadecenoic acid Natural products CCCCCC=CCCCCCCCCCCC(O)=O OXEDXHIBHVMDST-UHFFFAOYSA-N 0.000 claims description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- UOQHWNPVNXSDDO-UHFFFAOYSA-N 3-bromoimidazo[1,2-a]pyridine-6-carbonitrile Chemical compound C1=CC(C#N)=CN2C(Br)=CN=C21 UOQHWNPVNXSDDO-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 claims description 2
- 239000005639 Lauric acid Substances 0.000 claims description 2
- 235000021353 Lignoceric acid Nutrition 0.000 claims description 2
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000021314 Palmitic acid Nutrition 0.000 claims description 2
- 238000007259 addition reaction Methods 0.000 claims description 2
- YIYBQIKDCADOSF-UHFFFAOYSA-N alpha-Butylen-alpha-carbonsaeure Natural products CCC=CC(O)=O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 claims description 2
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 claims description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- KEDPQQQNTPFUME-UHFFFAOYSA-N dodecan-1-amine;2-(2-hydroxyethylamino)ethanol Chemical compound OCCNCCO.CCCCCCCCCCCCN KEDPQQQNTPFUME-UHFFFAOYSA-N 0.000 claims description 2
- FARYTWBWLZAXNK-WAYWQWQTSA-N ethyl (z)-3-(methylamino)but-2-enoate Chemical compound CCOC(=O)\C=C(\C)NC FARYTWBWLZAXNK-WAYWQWQTSA-N 0.000 claims description 2
- 230000004927 fusion Effects 0.000 claims description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 229940099563 lactobionic acid Drugs 0.000 claims description 2
- 229960004488 linolenic acid Drugs 0.000 claims description 2
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 claims description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 235000021313 oleic acid Nutrition 0.000 claims description 2
- 229940113162 oleylamide Drugs 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 claims description 2
- 229940066675 ricinoleate Drugs 0.000 claims description 2
- PCMORTLOPMLEFB-ONEGZZNKSA-N sinapic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC(OC)=C1O PCMORTLOPMLEFB-ONEGZZNKSA-N 0.000 claims description 2
- PCMORTLOPMLEFB-UHFFFAOYSA-N sinapinic acid Natural products COC1=CC(C=CC(O)=O)=CC(OC)=C1O PCMORTLOPMLEFB-UHFFFAOYSA-N 0.000 claims description 2
- YIYBQIKDCADOSF-ONEGZZNKSA-N trans-pent-2-enoic acid Chemical compound CC\C=C\C(O)=O YIYBQIKDCADOSF-ONEGZZNKSA-N 0.000 claims description 2
- 229940005605 valeric acid Drugs 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 17
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- 229920001223 polyethylene glycol Polymers 0.000 abstract description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 2
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- 239000003795 chemical substances by application Substances 0.000 description 44
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 239000013558 reference substance Substances 0.000 description 12
- 239000010881 fly ash Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
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- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 239000010883 coal ash Substances 0.000 description 6
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Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
混凝土配合比 | C(kg/m3) | Fa(kg/m3) | W(kg/m3) | S(kg/m3) | G1(kg/m3) | G2(kg/m3) | JMB(kg/m3) |
常态混凝土BC | 330 | 0 | 192 | 711 | 1166 | 0 | 1.65 |
常态混凝土BFC | 250 | 80 | 187 | 711 | 1166 | 0 | 1.60 |
碾压混凝土RCC | 56 | 105 | 79 | 759 | 598 | 898 | 1.30 |
配比BC | |||||
掺量(%) | SL(cm) | V0(%) | V60(%) | RV60(%) | |
对照品1 | 0.015 | 8.5 | 4.6 | 3.4 | 74 |
对照品2 | 0.015 | 7.8 | 4.9 | 3.7 | 76 |
对照品3 | 0.015 | 7.5 | 5.3 | 4.4 | 83 |
发明品1 | 0.015 | 8.0 | 4.6 | 3.5 | 76 |
发明品2 | 0.015 | 8.5 | 4.9 | 3.9 | 80 |
发明品3 | 0.015 | 8.0 | 5.3 | 4.3 | 82 |
发明品4 | 0.015 | 8.5 | 5.5 | 4.6 | 84 |
发明品5 | 0.015 | 7.8 | 5.4 | 4.6 | 85 |
发明品6 | 0.015 | 7.5 | 5.3 | 4.7 | 90 |
配比BFC | |||||
掺量(%) | SL(cm) | V0(%) | V60(%) | RV60(%) | |
对照品1 | 0.025 | 8.2 | 3.4 | 2.2 | 64 |
对照品2 | 0.025 | 8.3 | 3.6 | 2.4 | 68 |
对照品3 | 0.025 | 8.5 | 3.7 | 2.8 | 77 |
发明品1 | 0.025 | 7.8 | 3.4 | 2.4 | 70 |
发明品2 | 0.025 | 7.5 | 3.6 | 2.8 | 77 |
发明品3 | 0.025 | 8.0 | 3.7 | 3.0 | 80 |
发明品4 | 0.025 | 8.5 | 3.8 | 3.0 | 80 |
发明品5 | 0.025 | 8.0 | 4.5 | 3.7 | 82 |
发明品6 | 0.025 | 8.5 | 5.2 | 4.3 | 83 |
配比RCC | |||||
掺量(%) | VC(′) | V0(%) | V60(%) | RV60(%) | |
对照品1 | 0.035 | 3 | 3.55 | 2.2 | 62 |
对照品2 | 0.035 | 3 | 3.70 | 2.6 | 72 |
对照品3 | 0.035 | 3 | 4.2 | 3.2 | 75 |
发明品1 | 0.035 | 4 | 3.55 | 2.6 | 73 |
发明品2 | 0.035 | 3 | 3.65 | 2.9 | 79 |
发明品3 | 0.035 | 3 | 4.2 | 3.4 | 82 |
发明品4 | 0.035 | 4 | 5.7 | 4.7 | 82 |
发明品5 | 0.035 | 4 | 5.9 | 4.9 | 83 |
发明品6 | 0.035 | 5 | 6.0 | 5.2 | 86 |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2006100383220A CN100337964C (zh) | 2006-02-16 | 2006-02-16 | 一种混凝土引气剂 |
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Application Number | Priority Date | Filing Date | Title |
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CNB2006100383220A CN100337964C (zh) | 2006-02-16 | 2006-02-16 | 一种混凝土引气剂 |
Publications (2)
Publication Number | Publication Date |
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CN1807333A true CN1807333A (zh) | 2006-07-26 |
CN100337964C CN100337964C (zh) | 2007-09-19 |
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Application Number | Title | Priority Date | Filing Date |
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CNB2006100383220A Active CN100337964C (zh) | 2006-02-16 | 2006-02-16 | 一种混凝土引气剂 |
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Cited By (22)
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CN101805148A (zh) * | 2010-04-14 | 2010-08-18 | 深圳市五山建材实业有限公司 | 一种混凝土引气剂制备方法 |
CN101948267A (zh) * | 2010-09-01 | 2011-01-19 | 科之杰新材料(漳州)有限公司 | 一种混凝土引气剂及其制备方法 |
CN101549972B (zh) * | 2009-05-13 | 2012-02-01 | 中国水利水电第八工程局有限公司 | 混凝土复合引气剂及其制备方法 |
CN101704643B (zh) * | 2009-11-06 | 2012-06-27 | 中南林业科技大学 | 利用粗塔尔油分离精制残渣生产混凝土外加剂的方法 |
CN102712533A (zh) * | 2010-01-15 | 2012-10-03 | 拉法基公司 | 用于制备具有夹带空气的水硬性组合物的方法 |
CN101775255B (zh) * | 2009-01-12 | 2013-02-20 | 中冶建筑研究总院有限公司 | 一种松香缩聚物引气剂及其应用 |
CN103012541A (zh) * | 2009-09-25 | 2013-04-03 | 杭州中野天然植物科技有限公司 | 一种结构修饰型油茶皂甙的中间体及其制备方法和应用 |
CN104261745A (zh) * | 2014-09-30 | 2015-01-07 | 蒙城县义鼎建筑材料有限公司 | 一种机械化施工的专用聚合物干混砂浆 |
CN103012511B (zh) * | 2009-09-25 | 2015-01-28 | 青田中野天然植物科技有限公司 | 一种结构修饰型油茶皂甙的中间体及其应用 |
CN105217993A (zh) * | 2015-08-25 | 2016-01-06 | 建华建材(蚌埠)有限公司 | 一种混凝土高稳定性引气剂及其制备方法 |
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