CN1756817A - 用于涂层的热固性粉末组合物 - Google Patents
用于涂层的热固性粉末组合物 Download PDFInfo
- Publication number
- CN1756817A CN1756817A CN200480005727.3A CN200480005727A CN1756817A CN 1756817 A CN1756817 A CN 1756817A CN 200480005727 A CN200480005727 A CN 200480005727A CN 1756817 A CN1756817 A CN 1756817A
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- Prior art keywords
- acid
- glycol
- carboxy
- polyester
- amorphous polyester
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 238000000576 coating method Methods 0.000 title claims abstract description 43
- 229920001187 thermosetting polymer Polymers 0.000 title claims abstract description 20
- 239000000843 powder Substances 0.000 title abstract description 45
- 229920000728 polyester Polymers 0.000 claims abstract description 63
- 239000011248 coating agent Substances 0.000 claims abstract description 35
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 22
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 50
- 239000002253 acid Substances 0.000 claims description 36
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- 125000001931 aliphatic group Chemical group 0.000 claims description 22
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 18
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 12
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 12
- 239000000376 reactant Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- -1 alicyclic diol Chemical class 0.000 claims description 5
- 125000002723 alicyclic group Chemical group 0.000 claims description 5
- 229940051250 hexylene glycol Drugs 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- GHLKSLMMWAKNBM-UHFFFAOYSA-N dodecane-1,12-diol Chemical compound OCCCCCCCCCCCCO GHLKSLMMWAKNBM-UHFFFAOYSA-N 0.000 claims description 4
- 238000005227 gel permeation chromatography Methods 0.000 claims description 4
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 claims description 4
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims description 4
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 claims description 4
- 239000006096 absorbing agent Substances 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 claims description 2
- WMYINDVYGQKYMI-UHFFFAOYSA-N 2-[2,2-bis(hydroxymethyl)butoxymethyl]-2-ethylpropane-1,3-diol Chemical compound CCC(CO)(CO)COCC(CC)(CO)CO WMYINDVYGQKYMI-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims description 2
- 150000008065 acid anhydrides Chemical class 0.000 claims description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 claims description 2
- 229960005082 etohexadiol Drugs 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 230000009477 glass transition Effects 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 229940059574 pentaerithrityl Drugs 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 230000003068 static effect Effects 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- WTKWFNIIIXNTDO-UHFFFAOYSA-N 3-isocyanato-5-methyl-2-(trifluoromethyl)furan Chemical compound CC1=CC(N=C=O)=C(C(F)(F)F)O1 WTKWFNIIIXNTDO-UHFFFAOYSA-N 0.000 claims 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims 1
- TVIDDXQYHWJXFK-UHFFFAOYSA-N n-Dodecanedioic acid Natural products OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims 1
- HQHCYKULIHKCEB-UHFFFAOYSA-N tetradecanedioic acid Natural products OC(=O)CCCCCCCCCCCCC(O)=O HQHCYKULIHKCEB-UHFFFAOYSA-N 0.000 claims 1
- 239000003973 paint Substances 0.000 abstract description 18
- 239000002966 varnish Substances 0.000 abstract description 6
- 239000004922 lacquer Substances 0.000 abstract description 3
- 125000003368 amide group Chemical group 0.000 abstract description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 description 10
- 238000009472 formulation Methods 0.000 description 8
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000002950 deficient Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 3
- 241000723346 Cinnamomum camphora Species 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 229960000846 camphor Drugs 0.000 description 3
- 229930008380 camphor Natural products 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000032050 esterification Effects 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000001327 prunus amygdalus amara l. extract Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 239000003351 stiffener Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
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- 239000008199 coating composition Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
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- 238000004049 embossing Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- OKRNLSUTBJUVKA-UHFFFAOYSA-N n,n,n',n'-Tetrakis(2-hydroxyethyl)adipamide Chemical compound OCCN(CCO)C(=O)CCCCC(=O)N(CCO)CCO OKRNLSUTBJUVKA-UHFFFAOYSA-N 0.000 description 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 1
- 231100000148 Ames mutagenicity Toxicity 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 239000004593 Epoxy Chemical class 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229920006127 amorphous resin Polymers 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- FLPKSBDJMLUTEX-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) 2-butyl-2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]propanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)C(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)(CCCC)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 FLPKSBDJMLUTEX-UHFFFAOYSA-N 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
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- 239000004927 clay Substances 0.000 description 1
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- 230000002939 deleterious effect Effects 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005367 electrostatic precipitation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 150000001261 hydroxy acids Chemical group 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
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- 238000010309 melting process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- UJRDRFZCRQNLJM-UHFFFAOYSA-N methyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=CC=CC3=N2)=C1O UJRDRFZCRQNLJM-UHFFFAOYSA-N 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
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- YIMHRDBSVCPJOV-UHFFFAOYSA-N n'-(2-ethoxyphenyl)-n-(2-ethylphenyl)oxamide Chemical compound CCOC1=CC=CC=C1NC(=O)C(=O)NC1=CC=CC=C1CC YIMHRDBSVCPJOV-UHFFFAOYSA-N 0.000 description 1
- UUCAVBDCVCFNIN-UHFFFAOYSA-N n,n,n',n'-tetrakis(2-hydroxypropyl)hexanediamide Chemical compound CC(O)CN(CC(C)O)C(=O)CCCCC(=O)N(CC(C)O)CC(C)O UUCAVBDCVCFNIN-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
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- 238000012634 optical imaging Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
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- 231100000614 poison Toxicity 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
实施例2 | 实施例3 | 实施例4 | 实施例5 | |
iPA | 766.7 | 712.4 | 745.1 | 704.3 |
NPG | 193.3 | 343.2 | 262.2 | 307.0 |
EG | 112.1 | 66.2 | ||
HD | 81.2 | 85.8 | 75.0 | 131.6 |
AN | 30 | 31 | 30 | 21 |
ICI粘度mpa.s | 1500 | 1700 | 2200 | 4500 |
Tg,℃ | 56 | 57 | 57 | 57 |
配方A白色漆配制料 | 配方B褐色漆配制料 |
粘结剂 69.06 | 粘结剂 78.33 |
Kronos 2310 29.60 | Bayferrox 130 4.44 |
Resiflow PV5 0.99 | Bayferrox 3950 13.80 |
苯偶姻 0.35 | Carbon Black FW2 1.09 |
Resiflow PV5 0.99 | |
苯偶姻 0.35 |
实施例 | 配制料 | 聚酯 | 硬化剂 | 光泽 | 直接冲击 | 反向冲击 | Erichsen缓慢压花 | 视觉外观 |
7 | A | 1(95) | XL552(5) | 96 | 80 | 60 | 9.2 | g |
8 | A | 2(95) | XL552(5) | 92 | 100 | 80 | 9.3 | g |
9 | B | 2(95) | XL552(5) | 94 | 80 | 80 | 9.0 | g |
10 | A | 3(95) | XL552(5) | 95 | 60 | 60 | 8.7 | g |
11 | B | 3(95) | XL552(5) | 97 | 60 | 40 | 9.2 | g |
12 | A | 4(95) | XL552(5) | 91 | 80 | 80 | 8.7 | g |
13 | B | 4(95) | XL552(5) | 90 | 80 | 60 | 9.1 | g |
14 | A | 5(96.5) | XL552(3.5) | 90 | 80 | 60 | 8.6 | g |
15 | B | CC7617(95) | XL552(5) | 90 | 120 | 120 | 9.2 | m |
16 | B | CC7642(95) | XL552(5) | 91 | 0 | 0 | 3.2 | m |
UV-A(340nm,I=0.77W/m2/nm) | |||||
小时 | 实施例9 | 实施例11 | 实施例13 | 实施例15 | 实施例16 |
0 | 100 | 100 | 100 | 100 | 100 |
400 | 99 | 100 | 100 | 99 | 99 |
800 | 99 | 100 | 100 | 88 | 99 |
1200 | 98 | 99 | 100 | 74 | 97 |
1600 | 97 | 98 | 100 | 69 | 97 |
2000 | 95 | 97 | 99 | 63 | 95 |
2400 | 91 | 95 | 97 | 26 | 92 |
2800 | 82 | 92 | 96 | 86 | |
3200 | 81 | 88 | 94 | 80 | |
3600 | 73 | 82 | 90 | 80 | |
4000 | 66 | 83 | 88 | 73 | |
4400 | 61 | 86 | 87 | 76 | |
4800 | 50 | 86 | 85 | 69 | |
5200 | 48 | 86 | 84 | 75 | |
5600 | 47 | 86 | 88 | 66 | |
6000 | 46 | 85 | 88 | 60 | |
6400 | 43 | 89 | 88 | 54 | |
6800 | 41 | 91 | 88 | 57 | |
7200 | 33 | 91 | 89 | 71 | |
7600 | 91 | 91 | 66 | ||
8000 | 89 | 95 | 50 | ||
8400 | 87 | 95 | 50 | ||
8800 | 77 | 94 | 47 | ||
9200 | 50 | 87 | 45 | ||
9600 | 39 | 80 | 43 | ||
10000 | 27 | 66 | 41 | ||
10400 | 24 | 50 | 39 | ||
10800 | 47 | 35 | |||
11200 | 45 | 33 | |||
11600 | 43 | 30 | |||
12000 | 41 |
Claims (9)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03006357.2 | 2003-03-20 | ||
EP03006357 | 2003-03-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1756817A true CN1756817A (zh) | 2006-04-05 |
CN100381522C CN100381522C (zh) | 2008-04-16 |
Family
ID=33016837
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004800057273A Expired - Lifetime CN100381522C (zh) | 2003-03-20 | 2004-03-18 | 用于涂层的热固性粉末组合物 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20060217520A1 (zh) |
EP (1) | EP1608714B1 (zh) |
CN (1) | CN100381522C (zh) |
AT (1) | ATE489440T1 (zh) |
DE (1) | DE602004030226D1 (zh) |
ES (1) | ES2355563T3 (zh) |
WO (1) | WO2004083325A1 (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102365321A (zh) * | 2009-03-27 | 2012-02-29 | 帝斯曼知识产权资产管理有限公司 | 包含聚酯和作为交联剂的β-羟烷基酰胺的粉末涂料组合物 |
CN102399358A (zh) * | 2010-09-03 | 2012-04-04 | Sika技术股份公司 | 水作为发泡剂的热固性环氧树脂组合物 |
CN103613746A (zh) * | 2013-12-04 | 2014-03-05 | 衡阳山泰化工有限公司 | 一种高耐候户外型粉末涂料用纯聚酯树脂及其制备方法 |
CN101535420B (zh) * | 2006-10-30 | 2016-05-11 | 安德鲁·W·苏曼 | 可磨耗干膜润滑剂和其涂敷方法以及由此制成的物品 |
CN106133022A (zh) * | 2014-03-28 | 2016-11-16 | 东洋油墨Sc控股株式会社 | 聚酯树脂及罐用涂料 |
CN109734883A (zh) * | 2018-12-28 | 2019-05-10 | 安徽神剑新材料股份有限公司 | 一种快速固化型聚酯树脂及其制备方法 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2085441A1 (en) * | 2008-01-31 | 2009-08-05 | Cytec Surface Specialties, S.A. | Powder Composition |
EP2096140A1 (en) | 2008-02-29 | 2009-09-02 | Cytec S.r.l. | Powder compositions |
BRPI1013887A2 (pt) * | 2009-04-29 | 2016-07-19 | Dsm Ip Assets Bv | composição de revestimento em pó compreendendo um poliéster e um agente reticulante com grupos oxirano fornecendo resistência à corrosão melhorada a um substrato revestido com os mesmos |
CN102558519A (zh) * | 2010-12-28 | 2012-07-11 | 上海轻工业研究所有限公司 | 芳香族-脂肪族共聚酯及其合成方法 |
WO2020163424A1 (en) | 2019-02-05 | 2020-08-13 | Eastman Chemical Company | Reduced haze compositions for coatings |
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US4140729A (en) * | 1978-01-03 | 1979-02-20 | Mobil Oil Corporation | Linear polyester coil coating composition |
US4727111A (en) * | 1986-09-29 | 1988-02-23 | Ppg Industries, Inc. | Powder coating compositions based on mixtures of acid group-containing materials and beta-hydroxyalkylamides |
NL9201985A (nl) * | 1992-11-13 | 1994-06-01 | Dsm Nv | Poederverf op basis van een polymeer met vrije carbonzuurgroepen als bindmiddel en een beta-hydroxyalkylamidegroepen bevattende verbinding als crosslinker. |
BE1009779A4 (fr) * | 1995-12-06 | 1997-08-05 | Ucb Sa | Compositions thermodurcissables en poudre pour revetements. |
ES2212805T3 (es) * | 1996-07-12 | 2004-08-01 | Ems-Inventa Ag | Poliesteres que contienen grupos beta-hidroxialquilamida, procedimiento para su preparacion y su uso. |
US5637654A (en) * | 1996-08-12 | 1997-06-10 | Mcwhorter Technologies | Low temperature cure carboxyl terminated polyesters |
US6284845B1 (en) * | 1997-06-02 | 2001-09-04 | Mcwhorter Technologies | Low temperature cure carboxyl terminated polyesters |
US5880223A (en) * | 1997-12-19 | 1999-03-09 | Morton International, Inc. | Non-blooming polyester coating powder |
IT1311895B1 (it) * | 1999-03-12 | 2002-03-20 | Sir Ind Spa | Miscele di b-idrossialchilammidi e loro impiego come agentireticolanti per la preparazione di vernici in polvere. |
KR20020079880A (ko) * | 2000-12-21 | 2002-10-19 | 유씨비 소시에떼아노님 | 코팅용의 열경화성 분체 조성물 |
EP1608715B1 (en) * | 2003-03-20 | 2008-11-19 | Cytec Surface Specialties, S.A. | Thermosetting powder compositions for coatings |
-
2004
- 2004-03-18 WO PCT/EP2004/002799 patent/WO2004083325A1/en active Application Filing
- 2004-03-18 US US10/544,116 patent/US20060217520A1/en not_active Abandoned
- 2004-03-18 EP EP04721484A patent/EP1608714B1/en not_active Expired - Lifetime
- 2004-03-18 AT AT04721484T patent/ATE489440T1/de not_active IP Right Cessation
- 2004-03-18 CN CNB2004800057273A patent/CN100381522C/zh not_active Expired - Lifetime
- 2004-03-18 ES ES04721484T patent/ES2355563T3/es not_active Expired - Lifetime
- 2004-03-18 DE DE602004030226T patent/DE602004030226D1/de not_active Expired - Lifetime
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101535420B (zh) * | 2006-10-30 | 2016-05-11 | 安德鲁·W·苏曼 | 可磨耗干膜润滑剂和其涂敷方法以及由此制成的物品 |
CN102365321A (zh) * | 2009-03-27 | 2012-02-29 | 帝斯曼知识产权资产管理有限公司 | 包含聚酯和作为交联剂的β-羟烷基酰胺的粉末涂料组合物 |
CN102365321B (zh) * | 2009-03-27 | 2014-07-09 | 帝斯曼知识产权资产管理有限公司 | 包含聚酯和作为交联剂的β-羟烷基酰胺的粉末涂料组合物 |
CN102399358A (zh) * | 2010-09-03 | 2012-04-04 | Sika技术股份公司 | 水作为发泡剂的热固性环氧树脂组合物 |
CN102399358B (zh) * | 2010-09-03 | 2016-07-06 | Sika技术股份公司 | 水作为发泡剂的热固性环氧树脂组合物 |
US9475904B2 (en) | 2010-09-03 | 2016-10-25 | Sika Technology Ag | Heat curable epoxy resin composition with water as foaming agent |
CN103613746A (zh) * | 2013-12-04 | 2014-03-05 | 衡阳山泰化工有限公司 | 一种高耐候户外型粉末涂料用纯聚酯树脂及其制备方法 |
CN106133022A (zh) * | 2014-03-28 | 2016-11-16 | 东洋油墨Sc控股株式会社 | 聚酯树脂及罐用涂料 |
CN106133022B (zh) * | 2014-03-28 | 2018-03-30 | 东洋油墨Sc控股株式会社 | 聚酯树脂、罐用涂料及包覆罐 |
CN109734883A (zh) * | 2018-12-28 | 2019-05-10 | 安徽神剑新材料股份有限公司 | 一种快速固化型聚酯树脂及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN100381522C (zh) | 2008-04-16 |
US20060217520A1 (en) | 2006-09-28 |
ES2355563T3 (es) | 2011-03-29 |
ATE489440T1 (de) | 2010-12-15 |
DE602004030226D1 (de) | 2011-01-05 |
EP1608714A1 (en) | 2005-12-28 |
EP1608714B1 (en) | 2010-11-24 |
WO2004083325A1 (en) | 2004-09-30 |
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