CN1684771A - 用于烃自热水蒸气转化的多层催化剂和使用所述催化剂的方法 - Google Patents
用于烃自热水蒸气转化的多层催化剂和使用所述催化剂的方法 Download PDFInfo
- Publication number
- CN1684771A CN1684771A CNA03823257XA CN03823257A CN1684771A CN 1684771 A CN1684771 A CN 1684771A CN A03823257X A CNA03823257X A CN A03823257XA CN 03823257 A CN03823257 A CN 03823257A CN 1684771 A CN1684771 A CN 1684771A
- Authority
- CN
- China
- Prior art keywords
- catalyst
- catalyst layer
- layer
- hydrocarbons
- oxides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0244—Coatings comprising several layers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Sustainable Energy (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Manufacturing & Machinery (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02019014.6 | 2002-08-26 | ||
| EP02019014A EP1393804A1 (de) | 2002-08-26 | 2002-08-26 | Mehrschichtiger Katalysator zur autothermen Dampfreformierung von Kohlenwasserstoffen und Verfahren zu seiner Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1684771A true CN1684771A (zh) | 2005-10-19 |
Family
ID=31197822
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA03823257XA Pending CN1684771A (zh) | 2002-08-26 | 2003-08-26 | 用于烃自热水蒸气转化的多层催化剂和使用所述催化剂的方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7150866B2 (enExample) |
| EP (2) | EP1393804A1 (enExample) |
| JP (1) | JP4950420B2 (enExample) |
| CN (1) | CN1684771A (enExample) |
| AU (1) | AU2003264107A1 (enExample) |
| WO (1) | WO2004024324A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106268307A (zh) * | 2016-10-20 | 2017-01-04 | 中国船舶重工集团公司第七八研究所 | 一种盒式催化单元 |
| CN106660033A (zh) * | 2014-06-27 | 2017-05-10 | 尤雷卡特股份公司 | 用于限制催化剂颗粒散发粉尘的方法 |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040037757A1 (en) * | 2001-05-07 | 2004-02-26 | Kiyoshi Taguchi | Hydrogen purification apparatus |
| GB0119327D0 (en) * | 2001-08-08 | 2001-10-03 | Johnson Matthey Plc | Catalyst |
| US7160533B2 (en) * | 2002-12-20 | 2007-01-09 | Honda Giken Kogyo Kabushiki Kaisha | Platinum-ruthenium containing catalyst formulations for hydrogen generation |
| EP1578529A2 (en) * | 2002-12-20 | 2005-09-28 | Honda Giken Kogyo Kabushiki Kaisha | Platinum and rhodium and/or iron containing catalyst formulations for hydrogen generation |
| CN100368280C (zh) * | 2002-12-20 | 2008-02-13 | 本田技研工业株式会社 | 用于中低温度氢产生的含有碱金属的催化剂配方 |
| JP2006511424A (ja) * | 2002-12-20 | 2006-04-06 | 本田技研工業株式会社 | 水素生成用白金―アルカリ/アルカリ土類触媒配合物 |
| CA2511018A1 (en) * | 2002-12-20 | 2004-07-15 | Honda Giken Kogyo Kabushiki Kaisha | Catalyst formulations for hydrogen generation |
| US7214331B2 (en) | 2004-02-26 | 2007-05-08 | The Boc Group, Inc. | Catalyst configuration and methods for syngas production |
| US8617265B2 (en) * | 2004-04-12 | 2013-12-31 | Intelligent Energy, Inc. | Hydrogen generation apparatus incorporating a staged catalyst and method for using same |
| JP2005305338A (ja) * | 2004-04-22 | 2005-11-04 | Toyota Motor Corp | 排ガス浄化触媒及びその製造方法 |
| KR100647700B1 (ko) * | 2005-09-14 | 2006-11-23 | 삼성에스디아이 주식회사 | 담지 촉매 및 이를 이용한 연료전지 |
| US7442364B1 (en) * | 2005-11-16 | 2008-10-28 | Wang Chi S | Plasma-induced hydrogen production from water |
| US20070130831A1 (en) * | 2005-12-08 | 2007-06-14 | General Electric Company | System and method for co-production of hydrogen and electrical energy |
| KR101255237B1 (ko) * | 2006-02-07 | 2013-04-16 | 삼성에스디아이 주식회사 | 연료전지용 담지 촉매, 그 제조방법, 이를 포함하는연료전지용 전극 및 상기 전극을 포함하는 연료전지 |
| JP5173180B2 (ja) * | 2006-10-30 | 2013-03-27 | 株式会社キャタラー | 排ガス浄化用触媒 |
| KR100837396B1 (ko) * | 2007-01-15 | 2008-06-12 | 삼성에스디아이 주식회사 | 담지 촉매, 그 제조방법, 이를 포함하는 캐소드 전극 및상기 캐소드 전극을 포함하는 연료전지 |
| CN101842157A (zh) * | 2007-10-29 | 2010-09-22 | 株式会社Ict | 氮氧化物去除用催化剂和使用该催化剂的氮氧化物去除方法 |
| US9132416B1 (en) | 2007-11-29 | 2015-09-15 | U.S. Department Of Energy | Nano-structured noble metal catalysts based on hexametallate architecture for the reforming of hydrocarbon fuels |
| US8431043B2 (en) * | 2008-02-15 | 2013-04-30 | Cummins Inc. | System and method for on-board waste heat recovery |
| US20100068130A1 (en) * | 2008-09-17 | 2010-03-18 | Frederick Carl Wilhelm | Process for the Production of Hydrogen Gas Employing a Thermally Stable Catalyst |
| US8207084B2 (en) * | 2009-06-23 | 2012-06-26 | Ford Global Technologies, Llc | Urea-resistant catalytic units and methods of using the same |
| US20110159400A1 (en) * | 2010-03-02 | 2011-06-30 | Ford Global Technologies, Llc | Hybrid Catalyst System and Electrode Assembly Employing the Same |
| US20110159403A1 (en) * | 2010-03-02 | 2011-06-30 | Ford Global Technologies, Llc | Layered Catalyst Assembly and Electrode Assembly Employing the Same |
| US9745191B2 (en) | 2011-04-11 | 2017-08-29 | Saudi Arabian Oil Company | Auto thermal reforming (ATR) catalytic structures |
| GB201303396D0 (en) * | 2013-02-26 | 2013-04-10 | Johnson Matthey Plc | Oxidation catalyst for a combustion engine |
| KR102356149B1 (ko) | 2014-02-07 | 2022-01-28 | 바스프 코포레이션 | 공급원료의 열분해용 촉매 |
| DE102014218726A1 (de) | 2014-09-18 | 2016-04-07 | Robert Bosch Gmbh | Brennstoffzellenvorrichtung mit verbessertem Anodengasprozessor |
| WO2017026037A1 (ja) | 2015-08-10 | 2017-02-16 | 日産自動車株式会社 | 固体酸化物形燃料電池システム |
| CN108550861B (zh) * | 2018-05-03 | 2020-06-19 | 深圳市鑫三奇科技有限公司 | 一种燃料电池用触媒层 |
| US11958047B2 (en) | 2018-06-29 | 2024-04-16 | Shell Usa, Inc. | Electrically heated reactor and a process for gas conversions using said reactor |
| US12382670B2 (en) * | 2020-11-04 | 2025-08-05 | Samsung Electronics Co., Ltd. | Thin film structure and semiconductor device comprising the same |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4415484A (en) * | 1982-04-26 | 1983-11-15 | United Technologies Corporation | Autothermal reforming catalyst |
| DE3382193D1 (de) | 1982-09-30 | 1991-04-11 | Engelhard Corp | Verfahren zur herstellung von wasserstoffreichem gas aus kohlenwasserstoffen. |
| JP3061399B2 (ja) * | 1990-06-20 | 2000-07-10 | 株式会社日本触媒 | ディーゼルエンジン排ガス浄化用触媒および浄化方法 |
| US6470152B2 (en) | 1992-03-17 | 2002-10-22 | Sony Corporation | Photographic and video image system |
| JP3281087B2 (ja) * | 1993-02-10 | 2002-05-13 | 日本碍子株式会社 | 排ガス浄化用触媒 |
| US6110861A (en) | 1997-06-02 | 2000-08-29 | The University Of Chicago | Partial oxidation catalyst |
| DE19727841A1 (de) | 1997-06-24 | 1999-01-07 | Fraunhofer Ges Forschung | Verfahren und Vorrichtung zur autothermen Reformierung von Kohlenwasserstoffen |
| US20020007595A1 (en) * | 1997-06-24 | 2002-01-24 | Uli Maier-Roeltgen | Method for reforming hydrocarbons autothermally |
| WO1999033567A1 (en) | 1997-12-24 | 1999-07-08 | Shell Internationale Research Maatschappij B.V. | Multiple layer monolithic structure and use thereof |
| GB9806199D0 (en) | 1998-03-24 | 1998-05-20 | Johnson Matthey Plc | Catalytic generation of hydrogen |
| JP3743995B2 (ja) | 1999-12-15 | 2006-02-08 | 日産自動車株式会社 | メタノール改質触媒 |
| DE10025032A1 (de) * | 2000-05-20 | 2001-11-29 | Dmc2 Degussa Metals Catalysts | Verfahren zur autothermen, katalytischen Dampfreformierung von Kohlenwasserstoffen |
| US6436363B1 (en) * | 2000-08-31 | 2002-08-20 | Engelhard Corporation | Process for generating hydrogen-rich gas |
| JP2002104808A (ja) * | 2000-09-27 | 2002-04-10 | Hitachi Ltd | 燃料改質方法 |
| US6713040B2 (en) * | 2001-03-23 | 2004-03-30 | Argonne National Laboratory | Method for generating hydrogen for fuel cells |
-
2002
- 2002-08-26 EP EP02019014A patent/EP1393804A1/de not_active Withdrawn
-
2003
- 2003-08-20 US US10/644,377 patent/US7150866B2/en not_active Expired - Fee Related
- 2003-08-26 AU AU2003264107A patent/AU2003264107A1/en not_active Abandoned
- 2003-08-26 JP JP2004535170A patent/JP4950420B2/ja not_active Expired - Fee Related
- 2003-08-26 CN CNA03823257XA patent/CN1684771A/zh active Pending
- 2003-08-26 WO PCT/EP2003/009449 patent/WO2004024324A1/de not_active Ceased
- 2003-08-26 EP EP03794941A patent/EP1542800B1/de not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106660033A (zh) * | 2014-06-27 | 2017-05-10 | 尤雷卡特股份公司 | 用于限制催化剂颗粒散发粉尘的方法 |
| CN106660033B (zh) * | 2014-06-27 | 2019-11-05 | 尤雷卡特股份公司 | 用于限制催化剂颗粒散发粉尘的方法 |
| CN106268307A (zh) * | 2016-10-20 | 2017-01-04 | 中国船舶重工集团公司第七八研究所 | 一种盒式催化单元 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004024324A1 (de) | 2004-03-25 |
| EP1542800A1 (de) | 2005-06-22 |
| EP1542800B1 (de) | 2012-07-18 |
| US20040063577A1 (en) | 2004-04-01 |
| JP4950420B2 (ja) | 2012-06-13 |
| EP1393804A1 (de) | 2004-03-03 |
| AU2003264107A1 (en) | 2004-04-30 |
| JP2005537132A (ja) | 2005-12-08 |
| US7150866B2 (en) | 2006-12-19 |
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