CN1664089A - Gramineae plant detergent and its preparing process - Google Patents
Gramineae plant detergent and its preparing process Download PDFInfo
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- CN1664089A CN1664089A CN 200510003019 CN200510003019A CN1664089A CN 1664089 A CN1664089 A CN 1664089A CN 200510003019 CN200510003019 CN 200510003019 CN 200510003019 A CN200510003019 A CN 200510003019A CN 1664089 A CN1664089 A CN 1664089A
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Abstract
An agrostological washing agent and the preparing method. The washing agent is produced by the following steps: employing straw or wheat straw as stock, geting the straw ash by controlling burning, taking the extract from the straw ash with water as main component and adding findings and getting the product. The findings comprises enzyme agent, surface activator, thickening agent and common salt. For hand-washing dinner set the enzyme agent added for washing agent is alkaline lipase; for cloth the enzyme agent comprises alkaline lipase, alkaline prolease, alkaline cellulase; the surface activator is alkyl heteroside in general, the thickening agent is carboxymethyl cellulose and common salt in general. The method for making is: preparing extract firstly, modifying the pH value of the extract to be 8~9, adding enzyme agent, surface activator, thickening agent according to the formula proportion and getting the washing agent. The product is characterized by the unique formula, non-contamination, good washing effect, simple production device, short process, low investment and energy consumption and adaptable for washing dinner set and cloth.
Description
Technical field
The invention belongs to washing composition, particularly belonging to a kind of is the washing composition of preparation of raw material with natural gramineae plant.
Background technology
Washing composition is indispensable daily necessities in the modern life.Yet the washing composition of at present commercially available various brands almost is formulated by the material of chemosynthesis entirely.Use these washing composition, it is residual to have some harmful chemical on the one hand, and the people is brought adverse influence; On the other hand, some chemical substances can pollute environment again, and for example the phosphoric acid salt in the chemosynthesis washing composition, benzene sulfonic acid sodium salt etc. can produce severe contamination, life threatening to water body and environment.Along with the development and the growth in the living standard of society, the heavy health of people, heavily environmental protection, scientific consciousness strengthen gradually, for various daily washing composition, have also proposed requirements such as " green ", " nuisanceless ".In recent years people also meet the environment protection state basic policy in research and require, strive for accomplishing the synchronous protective New-type detergent of human and environment, existing many new detergent formulation applications patent of invention.Sent out by, hair washing though the plant ash extracting solution has the people to be used for laundry in morning among the people, to adopt it be raw material does not appear in the newspapers as yet in conjunction with the washing composition of modern science and technology production.
Summary of the invention
It is the washing composition that main raw material is made that purpose of the present invention just is to provide a kind of gramineae plant that adopts, overcome existing washing composition to human health shortcoming unfavorable and that environment is polluted.
Another object of the present invention provides the compound method of this gramineae plant washing composition.
Gramineae plant washing composition of the present invention be with straw or straw be raw material, burn by control make plant ash, be the main body composition with the resulting extracting solution of water extraction plant ash, interpolation auxiliary material and the washing composition prepared.
The auxiliary material of this washing composition comprises zymin, tensio-active agent, thickening material, salt.
Wherein, manual dishwashing is an alkaline lipase with the zymin that washing composition added; Clothing comprises alkaline lipase, Sumizyme MP, alkali cellulose enzyme with the zymin that washing composition adds;
Used tensio-active agent is alkyl-glucoside (APG) normally, and used thickening material is carboxymethyl cellulose (CMC) and salt normally.
Washing composition of the present invention is as follows in the prescription of 500ml:
| Component | The manual dishwashing washing composition | The clothing washing composition |
| Alkaline lipase Sumizyme MP alkali cellulose enzyme alkyl-glucoside, (APG) carboxymethyl cellulose, (CMC) salt plant ash extracting solution, (pH value 8～9) | 8～10g 8g 6g 6g adds to 500ml | 10～12g 8g 6g 8g 6g 6g adds to 500ml |
Gramineae plant washing composition compound method of the present invention comprises:
(1) preparation extracting solution: select for use natural high-quality straw or straw to make raw material, control burning, stop working immediately when promptly burning, make the grey black of straw or straw to grey black; Get this grey black and add water boil, filter, remove lime-ash; 12～14 extracting solution is obtained as clear as crystal, pH value and is in clarification, and is standby;
(2) extracting solution is 8～9 with organic acid acetic acid or lemon acid for adjusting pH value after, press formula rate and add auxiliary material zymin, tensio-active agent, thickening material and salt, make washing composition;
The contriver points out: zymin is a kind of biological catalyst, its composition is a protein, its characteristic is that catalytic capability is bigger 1,000 ten thousand times to 10,000,000,000,000 times than typical catalyst, and it can producing reaction, as long as it contact with reactant one, and the enzyme dosage that participates in reaction is few, be a kind of effective catalyst, have good decontamination, wash clean effect.Alkaline lipase in the zymin can be removed edible animal-plant oil, human body sebum, makeup grease and all kinds of greasy dirt; Sumizyme MP can be removed protein(aceous)soil on the clothing etc. by catalytic hydrolysis; Alkali cellulose enzyme plays arrangement, renovation effect to the primitive fiber on the fabric, can make fabric sofetening and can protect its color.
The contriver also points out: the alkyl-glucoside (APG) that glucose that is made by corn, potato starch and lauric alcohol are made is the new generation of green tensio-active agent, because its biological degradation is complete, belongs to ep-type material.It has stronger broad spectrum antibiotic activity, obtains maybe will being used widely in the many fields that comprise washing composition.The carboxymethyl cellulose of being made by straw, straw, linen-cotton etc. (CMC) has nontoxic, tasteless, the incorrupt characteristics of prolonged preservation, be a kind of anti redeposition agent and thickening material, be widely used in industries such as food, medicine, weaving, household chemicals, can prevent that in washing process dirt is attached on the washes again.Salt can prevent that then carboxymethyl cellulose (CMC) from producing precipitation, and certain sterilization, preservative activity are arranged.
As everyone knows, the dirt of tableware mainly is fat, protein and starch residue; And the dirt of clothing has sebum, sweat stain, grease, protein, movement, bloodstain from human body, and from the dirt such as external items such as food, articles for use, toys.Therefore,, propose different detergent formulation, can remove different dirts effectively, reach clean purpose at different with the composition of clothing dirt and clean require different of tableware.
The contriver points out, use clothing of the present invention to must be noted that washing methods with washing composition, correct method is: earlier that clothing is moistening with a small amount of clear water, get this usefulness washing composition (the more clothing of spot can suitably increase) in the ratio of every clothes 5ml, add the about 25 ℃ warm water of 300ml temperature simultaneously, be applied in collar, cuff, the concentrated place of spot earlier, rubbing is better a little, then with remaining washing composition to going into clothing, knead with hand, soaked into about 30 minutes, and can machine-wash according to a conventional method or hand-wash.
Gramineae plant washing composition of the present invention, prescription is unique, the product quality excellence, washing effect is good.Compare with at present commercially available various washing composition, have the following advantages:
1. because the raw material and the auxiliary material that adopt are all nontoxic, therefore use this product to be perfectly safe;
2. it is good that this Betengent product is washed clean dirt-removing functions, can be used for washing clothes, tableware, kitchen range, smoke exhaust ventilator etc., and it is obvious to clean effect;
3. this Betengent product can complete biodegradable, and therefore the waste water of washing back discharging can not cause any pollution to water body and soil, belongs to Green Product;
4. this Betengent product character gentleness, non-stimulated during use, do not hurt sb.'s feelings, can not damage washes yet;
5. plant ash after with water extraction residual lime-ash, can be used as fertilizer material, realize making full use of;
6. straw, straw abundant raw material are cheap, so this Betengent product cost is lower;
7. this washing composition production unit is simple, and technical process is short, less investment, low, the instant effect of energy consumption.
8. this product meet that people-oriented, the requirement of the harmonious sustainable development of human and environment
China is rice and wheat big producing country, and a large amount of straw or straw are recycled, and produces washing composition of the present invention in conjunction with modern science and technology, and unique distinct Chinese characteristics meet the thinking of setting up recycling economy.
Embodiment
Embodiment prepares gramineae plant washing composition of the present invention by the following method:
The first step, the preparation extracting solution
(1) get 80kg high-quality dry rice straw or straw, flame-out immediately when control is burnt to grey black, note not burning till lime, make the about 10kg of grey black;
(2) get this grey black and add clear water 120kg and boil 10min, remove by filter lime-ash; With liming clarification, obtain as clear as crystal, pH value and be 12～14 the about 100kg of extracting solution, standby;
In second step, prepare by prescription
(1) get standby extracting solution 470ml and put into bottle, regulating the pH value with vinegar is 8～9;
(2) take by weighing carboxymethyl cellulose (CMC) 6g, it is an amount of to take pH value and be 8～9 extracting solution, and mix in the remaining extracting solution winter after 20 ℃, summer are at normal temperatures with the CMC stirring and dissolving, continues abundant stirring and evenly mixing, till no condensation product;
(3) in bottle, continue to add alkyl-glucoside (APG) 8g, shake up; Get liquid basified lipase 10g, salt 6g at last and pour in the bottle, abundant stirring shakes up miscible, makes the manual dishwashing washing composition; Here should notice that zymin and salt must add at last;
(4) press the clothing detergent formulation, in kind make the clothing washing composition;
Said process is all finished at normal temperatures.
During industrialized mass production, can on this little measurement basis, press multiple and amplify, reach required metering and get final product.
Send relevant department with the manual dishwashing made from washing composition, 9985-2000 detects according to standard GB, and the gained detected result is as follows:
| Test item and set quota | Detected result | Detect unit |
| Methyl alcohol mg/g＜1 formaldehyde mg/g＜0.1 arsenic (As)＜0.05 lead (Pb)＜1 | ??50mg/kg ??100mg/kg ??0.001mg/L ??0.433mg/L | Geochemical investigation institute of the laboratory Chinese Academy of Sciences of geochemical investigation institute of Center for Disease Control Guizhou Province, the Guizhou Province Chinese Academy of Sciences of Center for Disease Control laboratory |
Index such as total plate count and intestinal bacteria is not surveyed, but in industrial production, adopts conventional disinfection means, and other indexs reach the requirement of GB easily.
Claims (3)
1 one kinds is the washing composition of preparation of raw material with natural grass, it is characterized in that this washing composition is to be raw material, to burn by control that to make the extracting solution that plant ash, water obtain from plant ash be the washing composition that the main body composition adds auxiliary material zymin, tensio-active agent, thickening material, salt preparation with straw or straw;
This washing composition is as follows in the prescription of 500ml:
Component The manual dishwashing washing composition The clothing washing composition
Alkaline lipase alkali protease alkali cellulose enzyme alkyl-glucoside (APG) carboxymethyl cellulose (CMC) salt extract (pH value 8～9) 8～10g 8g 6g 6g adds to 500ml 10～12g 8g 6g 8g 6g 6g adds to 500ml
2 method for makings according to the described washing composition of claim 1, its feature comprises:
(1) preparation extracting solution: select for use natural high-quality straw or straw to make raw material, control burning, flame-out immediately when promptly burning to grey black, make grey black; Get this grey black and add water boil, filter, remove lime-ash; With liming clarification, it is standby to obtain as clear as crystal, pH value and be 12～14 extracting solution;
(2) extracting solution is 8～9 with organic acid such as acetic acid or lemon acid for adjusting pH value after, press formula rate and add auxiliary material zymin, tensio-active agent, thickening material and salt, make washing composition.
3 method for makings according to the described washing composition of claim 2 is characterized in that manual dishwashing is an alkaline lipase with the zymin that washing composition added; Clothing comprises alkaline lipase, Sumizyme MP, alkali cellulose enzyme with the zymin that washing composition adds; Used tensio-active agent is alkyl-glucoside (APG) normally, and used thickening material is carboxymethyl cellulose (CMC) and salt normally.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100030192A CN1318554C (en) | 2005-03-03 | 2005-03-03 | Gramineae plant detergent and its preparing process |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100030192A CN1318554C (en) | 2005-03-03 | 2005-03-03 | Gramineae plant detergent and its preparing process |
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| Publication Number | Publication Date |
|---|---|
| CN1664089A true CN1664089A (en) | 2005-09-07 |
| CN1318554C CN1318554C (en) | 2007-05-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100030192A Expired - Fee Related CN1318554C (en) | 2005-03-03 | 2005-03-03 | Gramineae plant detergent and its preparing process |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101220322B (en) * | 2007-12-12 | 2010-06-02 | 河南省科学院化学研究所有限公司 | Biological complex enzyme pipeline dredging agent and method for producing the same |
| CN102198059A (en) * | 2011-04-29 | 2011-09-28 | 安徽师范大学 | Novel cleaning material |
| CN102296315A (en) * | 2011-08-31 | 2011-12-28 | 蚌埠市钰诚五金工贸有限公司 | Degreasing agent and preparation method thereof |
| CN102296313A (en) * | 2011-08-31 | 2011-12-28 | 蚌埠市钰诚五金工贸有限公司 | High efficiency lipase phosphorus-free degreaser and its preparation method |
| CN102296317A (en) * | 2011-08-31 | 2011-12-28 | 蚌埠市钰诚五金工贸有限公司 | Lipase non-phosphorus degreasing agent and preparation method thereof |
| CN102465063A (en) * | 2010-11-17 | 2012-05-23 | 重庆市江北区雨良洁牌日用化工厂 | Thickening agent for washing article |
| CN105670841A (en) * | 2015-12-10 | 2016-06-15 | 柳州市京阳节能科技研发有限公司 | High-quality multi-grass cleanser |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1092100A (en) * | 1993-03-13 | 1994-09-14 | 缪波 | New-type detergent |
| CN1131184A (en) * | 1995-03-15 | 1996-09-18 | 梁钢 | Detergent |
| GB9913549D0 (en) * | 1999-06-10 | 1999-08-11 | Unilever Plc | Detergent compositions |
-
2005
- 2005-03-03 CN CNB2005100030192A patent/CN1318554C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101220322B (en) * | 2007-12-12 | 2010-06-02 | 河南省科学院化学研究所有限公司 | Biological complex enzyme pipeline dredging agent and method for producing the same |
| CN102465063A (en) * | 2010-11-17 | 2012-05-23 | 重庆市江北区雨良洁牌日用化工厂 | Thickening agent for washing article |
| CN102198059A (en) * | 2011-04-29 | 2011-09-28 | 安徽师范大学 | Novel cleaning material |
| CN102198059B (en) * | 2011-04-29 | 2013-04-03 | 安徽师范大学 | Novel cleaning material |
| CN102296315A (en) * | 2011-08-31 | 2011-12-28 | 蚌埠市钰诚五金工贸有限公司 | Degreasing agent and preparation method thereof |
| CN102296313A (en) * | 2011-08-31 | 2011-12-28 | 蚌埠市钰诚五金工贸有限公司 | High efficiency lipase phosphorus-free degreaser and its preparation method |
| CN102296317A (en) * | 2011-08-31 | 2011-12-28 | 蚌埠市钰诚五金工贸有限公司 | Lipase non-phosphorus degreasing agent and preparation method thereof |
| CN105670841A (en) * | 2015-12-10 | 2016-06-15 | 柳州市京阳节能科技研发有限公司 | High-quality multi-grass cleanser |
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| Publication number | Publication date |
|---|---|
| CN1318554C (en) | 2007-05-30 |
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Granted publication date: 20070530 Termination date: 20110303 |