CN102660398A - Isomaltose hypgather enzyme-containing detergent - Google Patents
Isomaltose hypgather enzyme-containing detergent Download PDFInfo
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- CN102660398A CN102660398A CN2012101510591A CN201210151059A CN102660398A CN 102660398 A CN102660398 A CN 102660398A CN 2012101510591 A CN2012101510591 A CN 2012101510591A CN 201210151059 A CN201210151059 A CN 201210151059A CN 102660398 A CN102660398 A CN 102660398A
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Abstract
The invention discloses an isomaltose hypgather enzyme-containing detergent which comprises at least one conventional enzyme-containing detergent component and is added with isomaltose hypgather, wherein the mass ratio of the isomaltose hypgather to the conventional enzyme-containing detergent is less than 300:1000. The isomaltose hypgather enzyme-containing detergent is added with decontamination capability, and has the advantages of skin health care, environmental friendliness and the like.
Description
Technical field
The invention belongs to the washing composition technical field, be specifically related to a kind of oligomeric isomaltose enzyme-containing detergent.
Background technology
The conventional ingredient of washing composition generally comprises chemical ingredientss such as tensio-active agent, washing assistant, SYNTHETIC OPTICAL WHITNER and polymkeric substance.Tensio-active agent can infiltrate blood through skin, makes calcium ion concn decline in the blood, and acidification of blood makes the people tired easily, also can cause the decline of liver toxin expelling ability, reduces immunizing power, induces an illness.Phosphate compounds in the washing assistant can cause phytoplankton bloom after getting into water body, causes body eutrophication.SYNTHETIC OPTICAL WHITNER and hydrolysate thereof, suspension polymer can not be fully by biological degradations.Washing composition such as washing powder have become people's daily life indispensable requisites, therefore, improve washing composition, use not to be detrimental to health, and do not destroy ecotope, and energy-efficient washing composition becomes problem demanding prompt solution.Enzyme is widely used in the washing composition as the fill-in of detergent component at present, compares with compositions such as tensio-active agent, washing assistant, SYNTHETIC OPTICAL WHITNER, and its soil-removing action is stronger, and harmless, is prone to be degraded environmentally safe.Using washing composition in our life is inevitably, therefore, improves washing composition, and the washing composition that develop harmful to human not, does not destroy environment becomes problem demanding prompt solution.
Oligomeric isomaltose is a kind of of functional oligose, and the main function composition is the above oligose of α-1,6 glycosidic link bonded isomaltose, panose, Isomaltotriose and tetrose.Oligomeric isomaltose is widely used in food and the healthcare products because of its good properties, and is safe, environmentally safe.Oligomeric isomaltose does not also appear in the newspapers as the composition of washing composition.
Summary of the invention
The technical problem that the present invention mainly solves provides and a kind ofly is not detrimental to health, and does not destroy the enzyme-containing detergent of environment, and further improves the soil removability of enzyme-containing detergent.
For this reason, the present invention provides a kind of oligomeric isomaltose enzyme-containing detergent, contains at least a conventional enzyme-containing detergent constituent, also contains oligomeric isomaltose, in proportion uniform mixing.
Preferably, said oligomeric isomaltose: the weight ratio of conventional enzyme-containing detergent constituent is less than 300:1000.
Preferably, said oligomeric isomaltose: the scope of the weight ratio of conventional enzyme-containing detergent constituent is 0.5:1000-300:1000.
Preferably, said oligomeric isomaltose: the scope of the weight ratio of conventional enzyme-containing detergent constituent is 0.5:1000-50:1000.
Preferably, said oligomeric isomaltose: the scope of the weight ratio of conventional enzyme-containing detergent constituent is 0.5:1000-25:1000.
The present invention is as a kind of oligomeric isomaltose enzyme-containing detergent; Also contain conventional enzyme-containing detergent constituent, comprise enzyme, tensio-active agent, SYNTHETIC OPTICAL WHITNER, white dyes, enzyme stabilizers, dispersion agent, spot suspension agent, water-softening agent, sanitas, sequestrant, spices etc.Enzyme is mainly one or more in cellulase, hemicellulase, px, proteolytic enzyme, glycase, zytase, alkaline lipase, Phospholipid hydrolase, polygalacturonase, oxydase, reductase enzyme, the LSD.
The formulation of oligomeric isomaltose enzyme-containing detergent of the present invention can be block, Powdered, particulate state, paste or liquid form.
Oligomeric isomaltose enzyme-containing detergent of the present invention can be fabric detergent, dish washing detergent, shampoo, Liquid soap, fruits and vegetables washing composition, medical clean-out system etc.
With respect to prior art, beneficial effect of the present invention is, one of which, and the adding of oligomeric isomaltose has improved the soil removability of enzyme-containing detergent.Its two, the present invention proportionally carries out uniform mixing with common conventional enzyme-containing detergent constituent and oligomeric isomaltose, need not special ME, when improving soil removability, does not increase cost.Its three, it is all harmless to HUMAN HEALTH newly to add the composition oligomeric isomaltose, also pollution-free to environment, has advantages such as safety, environmental protection.
Description of drawings
Fig. 1 is the weight ratio and the cotton decontamination proportionlity figure of different amount oligomeric isomaltoses and conventional enzymatic detergent compositions.
Embodiment
Below in conjunction with accompanying drawing and specific embodiment the present invention is done further explain.
When in conventional enzyme-containing detergent, adding the oligomeric isomaltose composition, the soil removability of enzyme-containing detergent increases.
Conventional enzyme-containing detergent constituent among the present invention can be selected from enzyme, tensio-active agent, SYNTHETIC OPTICAL WHITNER, white dyes, enzyme stabilizers, dispersion agent, spot suspension agent, water-softening agent, sanitas, sequestrant, spices etc.
The precise nature of these components and mix physical form that content will depend on component with and the precise nature of the washing composition operation of using.
A kind of preferred ingredients is an enzyme, and enzyme can be selected from cellulase, hemicellulase, px, proteolytic enzyme, glycase, zytase, alkaline lipase, Phospholipid hydrolase, polygalacturonase, oxydase, reductase enzyme, LSD or their mixture.
A kind of preferred ingredients is a tensio-active agent; Can be aniorfic surfactant, cats product, zwitterionics, non-ionics and their combination, can be selected from a kind of or more kinds of of metal carboxylate tensio-active agent, LABS (LAS), aliphatic alcohol sulfate (AS or FAS), secondary paraffin sulfonate (SAS), sulfonated (AOS), fatty alcohol polyoxyethylene ether sulfate (AES), AEO (AE), methyl ester sulfonate or alpha-sulfo fatty acid methyl ester (MES), APG (APG), N-alkyl glucose amide (AGA), TX10 (APE), fatty alkylolamide (FAA), betanin derivative, imidazolidine derivatives etc. like tensio-active agent.
A kind of preferred ingredients is a sanitas, can be parabens (nipagin esters), is mainly its methyl esters, propyl ester, butyl ester etc.; And quaternary ammonium salt surface active agent, O-SyL, Imidurea; Organic acid, as take off acetic acid, TRIMETHOXY BENZOIC ACID (FOR MANUFACTURING OF T.M. and its esters, Sorbic Acid and its esters, phenylformic acid and its esters, Whitfield's ointment, phenylic acid; Some fragrance component etc.
A kind of preferred ingredients is a sequestrant; Heavy metal ion chelating agent is at qualitative tart; As have phosphoric acid or a carboxylic acid functional; Can contend with its tart form and positively charged ion, exist like the complex compound of alkalimetal ion, ammonium salt or substituted ammonium salt ion or its mixture, the form of salt.Be preferably organophosphate, like alkylidene group SULPHOSUCCINIC ACID ESTER, basic metal ethane, 1-hydroxyl bisphosphate and time amino trimethylene methyl phosphorodithioate etc.
A kind of preferred ingredients is the spot suspension agent, can be selected from a kind of or more kinds of of Walocel MT 20.000PV (sodium), Volpo S 10, Vinylpyrrolidone polymer, macromolecule polyacrylic acid, Vltra tears, Type 3U, carboxyl methyl starch, natural gum etc.
A kind of preferred ingredients is a water-softening agent, can be selected from a kind of or more kinds of of phosphoric acid salt, nitrogenous organic sequestering agent and acrylic polymers, Starso, zeolite, yellow soda ash, water glass etc.
A kind of preferred ingredients is a spices, mainly comprises the spices that incapsulates, fragrance precursor, pure fragrance material and composition thereof.Materials such as various chemical substances such as aldehyde, ketone, ester are used to the manufacturing of spices.The crude vegetal of the complex mixture of various chemical ingredientss and animal oil and exudate also are used as spice oil.It can be better simply that the used spices of the present invention is formed, and also can be complicated, can be natural, or the chemical composition of synthetic.
Those skilled in the art can be according to the applied specific field of washing composition, and actual needs is selected and adjusted.These selections and adjustment all can not produce substantial effect to the present invention.
As when being used for washing clothes, also can comprise clothing whitening agent, fabric softening, dyestuff etc. in the washing composition of the present invention.
For the ease of rinsing, can in washing composition, add Yi Pao ﹑ skimmer.
When washing hand liquid ﹑ hand, then also can add and steep the ﹑ suds-stabilizing agent with dish washing detergent etc.
When being used to wash, can add friction agent, like Shi Ying Sha ﹑ Gui Zao Tu ﹑ Hua Shi Fen ﹑ lime carbonate etc. to the crust that has firm stain such as Lu Zao ﹑ Chui Ju ﹑ wall.
In order to clean coloured dirt such as Se Su ﹑ Cha Gou ﹑ Ka Fei Zi ﹑ dish stain etc.; Can add SYNTHETIC OPTICAL WHITNER and acvator; The former is like chloramines T ﹑ DICHLOROISOCYANURIC ACID and ﹑ Lv Suan of Yan Na ﹑ Piao Bai Fen ﹑ Guo Peng Suan Na ﹑ SPC-D thereof etc., the latter such as tetraacetyl ethylene diamine (TAED) etc.
In order to increase clean bacterium effect, need to add antiseptic-germicide.Antiseptic-germicide commonly used has the adjacent phenylester of: Ben Fen ﹑ Jia Fen ﹑ etc.
In order to increase the solubleness of tensio-active agent and auxiliary agent in the liquid washing agent, and promote the consistency of each compatibility component to reduce cloud point, can add solubilizing agent, make surface active agent solubilization, then can make solution become transparence, prevent that deposition from separating out and be separated.Solubilizing agent commonly used has the Na Yan ﹑ Jia Yan ﹑ ammonium salt and the Yi Chun ﹑ Yi Bing Chun ﹑ Yi glycol Dan Ding Mi ﹑ alkyl phosphate of Jia Ben Huang Suan ﹑ xylene monosulfonic acid and isopropyl sulfonic acid, urea etc.
Being used for class higher liquid or the detergent paste relevant with human body, during like Liquid soap, shampoo etc., can adding pearling agent, mainly is to give washing composition pearlescent gloss, also can add the washing composition stickiness simultaneously, makes the washing composition outward appearance more beautiful.Like ethylene glycol monostearate, EGDS etc.
In addition, enzyme-containing detergent of the present invention can like the liquid of Powdered or particulate solid, bar, tablet or non-water, comprise gel and paste form for any form easily.When being the enzyme-containing detergent of liquid form, can comprise the enzyme stabilizers composition in the washing composition of the present invention, like boric acid etc.The enzyme stabilizers and the consumption thereof that are used for liquid washing agent are known to those skilled in the art, and those skilled in the art can select suitable enzyme stabilizers according to actual needs for use, and the effect of oligomeric isomaltose among the present invention is not produced materially affect.
In order washing composition to be made liquid or paste; Also can add in the washing composition: thickening material; Cheng Shu Zhi ﹑ macrogol ester class, longer chain fatty acid with He like natural resin, and derivatived cellulose such as CMC 99.5 (CMC), Natvosol, Type 3U, methylhydroxypropylcellulose, sodium-chlor, Repone K, magnesium chloride, ammonium chloride, saltcake etc.; Buffer reagent: what be used to regulate the pH value has sulfonic acid, Hydrocerol A, phosphoric acid, Sodium Tetraborate, a SODIUM PHOSPHATE, MONOBASIC etc.
Embodiment
In order to verify the enhancement of oligomeric isomaltose to the enzyme-containing detergent soil removability, the inventor is employed in the oligomeric isomaltose that adds different ratios in the conventional enzyme-containing detergent constituent, and the test enzyme-containing detergent is to the washing effect of cotton spot.
Test materials
The cotton calico is cut into 8 cm * 8 cm cloths in the test;
Conventional enzyme-containing detergent constituent: X 2073 20 wt/%, polyoxyethylenated alcohol sodium sulfate 10wt/%, trolamine 1 wt/%, white dyes 0.3 wt/%; Spices 0.2 wt/%, Xylo-Mucine 1 wt/%, water glass 8 wt/%, yellow soda ash 12wt/%; Sodium sulfate 10%, 4A zeolite 29.5 wt/%, Sumizyme MP 2 wt/%; Alkaline lipase 2 wt/%, cellulase 2 wt/%, glycase 2 wt/%;
Mixing oil spot Ye – presses mass ratio mixing soy sauce and the edible oil preparation of 1:1;
Testing sequence
One, stains the making of stain cloth
Spot is poured in the pallet, get cloth compregnate one time after, with the reverse compregnate of staining cloth one time, dry naturally again.
Two, washing process
Take by weighing the conventional enzyme-containing detergent constituent of 1 g in large beaker, add the tap water of 200 mL, promptly concentration is 0.5%, and glass stick stirs the enzyme-containing detergent composition is dissolved fully;
The control group that does not add oligomeric isomaltose is set, and the sample sets that adds 0.0005g, 0.005g, 0.01g, 0.025g, 0.05g, 0.3 g oligomeric isomaltose, stir, fully dissolving;
Put into the cloth that has spot that step 1 prepares, soaking at room temperature 30 minutes, during every stirred once with glass stick at a distance from 5 minutes, churning time is about 20 seconds at every turn;
Take out cloth, dewater, dry naturally under the room temperature with after the RB50-3012G of the Rongshida type automatic washing machine tap water rinsing 2 times.
Three, detergency test
Instrument: DATACOLORSF600X blancometer.The D65 light source, 10Deg.
Method: through the whiteness value of test white cloth before and after washing, estimate washing effect, whiteness value is high more, explains that then washing effect is good more.Get 5 tests at every soiled cotton pros and cons and average and be whiteness value, and be calculated as follows decontamination value R (%):
R (%)=(A2-A1)/(A0-A1) * 100%, wherein A0 is that cloth specimen stains preceding whiteness value; Al is that cloth specimen stains the back whiteness value; A2 is for staining cloth specimen washing back whiteness value.
Calculate decontamination ratio F according to formula F=R1/R0, wherein R1 is the decontamination value of the enzyme-containing detergent of adding oligomeric isomaltose; R0 is the decontamination value that does not add the enzyme-containing detergent of oligomeric isomaltose.
That is, F＞1 o'clock, detersive power is stronger than former enzyme-containing detergent; During F=1, detersive power is suitable with former enzyme-containing detergent; F＜1 o'clock, detersive power than former enzyme-containing detergent a little less than.
Those skilled in the art are known: washing composition is not to be that to add many more detersive poweies strong more.When washing composition reach a certain amount of after, detersive power has just no longer increased along with the adding of washing composition, and the trend of minimizing is arranged on the contrary; Early existing a large amount of experimental data documents prove that the concentration that adds the aqueous solution of washing composition is optimum with 0.2%-0.5%, and at this moment the surfactivity of the aqueous solution is the highest, and the washing soil removability reaches the strongest, and increasing the washing composition detersive power can not increase more yet again.General knowledge according to these those skilled in the art; And the maximum recommended consumption of this conventional enzymatic detergent constituent; So it is 0.5% that the control Example of this experiment is provided with the concentration of aqueous solution of conventional enzymatic detergent constituent; Therefore the maximum soil removability that can represent the conventional enzymatic detergent constituent of this kind to reach can be used as the contrast (R0) of all embodiment.
Test result
Table 1 different ratios oligomeric isomaltose and conventional enzyme-containing detergent constituent decontamination value and and conventional enzyme-containing detergent constituent decontamination ratio
Fig. 1 is the oligomeric isomaltose of different ratios and the weight ratio and the cloth decontamination value variation diagram of conventional enzymatic detergent compositions; The data of associative list 1; It is thus clear that; After having added oligomeric isomaltose, the weight ratio scope of oligomeric isomaltose and conventional enzymatic detergent compositions all can make the soil removability of enzyme-containing detergent increase when 0.5:1000-300:1000.When the weight ratio of oligomeric isomaltose and conventional enzymatic detergent compositions scope at 0.5:1000-5:1000; Soil removability increases gradually; When the weight ratio of oligomeric isomaltose and conventional enzymatic detergent compositions is that 5:1000 (embodiment 2) reaches peak R=87.55; F=1.23, when scope at 5:1000-300:1000 of the weight ratio of oligomeric isomaltose and conventional enzymatic detergent compositions, soil removability descends to some extent.
Can draw thus, the interpolation of a small amount of oligomeric isomaltose can significantly increase the soil removability of enzyme-containing detergent, and its clean effect is improved.
Yet, it will be understood by those skilled in the art that in practical application; Owing to need to consider other factors such as cost; The relative content of oligomeric isomaltose can suitably be chosen in this scope in the enzyme-containing detergent of the present invention, like the amount of the corresponding oligomeric isomaltose of the conventional enzyme-containing detergent composition of per 1000 g less than 300 g, as being 0.5-300 g; Or the scope of 0.5-50 g, or 0.5-25 g.Concrete selection foundation and scope can be definite according to practical situation by those skilled in the art, and can therefore not limit scope of the present invention.
Simultaneously; Owing to added oligomeric isomaltose composition in the enzyme-containing detergent with multi-biological functional; Therefore enzyme-containing detergent provided by the present invention is except that having the high-effective cleansing ability, and the multi-biological that also has oligomeric isomaltose and had is active, has expanded its effect.
Can significantly strengthen the detersive power of enzyme-containing detergent about the interpolation of more a spot of oligomeric isomaltose, the contriver thinks that possible reason comprises, oligomeric isomaltose can strengthen the activity of zymin in the enzyme-containing detergent.So, in common conventional enzyme-containing detergent composition, add a spot of oligomeric isomaltose, just can reach the effect that strengthens decontamination, have wide range of applications.
In addition, the present invention proportionally carries out uniform mixing with common conventional enzyme-containing detergent constituent and oligomeric isomaltose, need not special ME, when obviously improving soil removability, does not significantly increase cost.
The above embodiment of the present invention does not constitute the qualification to protection domain of the present invention.Any various other corresponding changes and distortion of making according to technical conceive of the present invention all should be included in the protection domain of claim of the present invention.
Claims (8)
1. the oligomeric isomaltose enzyme-containing detergent contains at least a conventional enzyme-containing detergent constituent, it is characterized in that also contain oligomeric isomaltose, said oligomeric isomaltose: the weight ratio of conventional enzyme-containing detergent constituent is less than 300:1000.
2. oligomeric isomaltose enzyme-containing detergent according to claim 1 is characterized in that, said oligomeric isomaltose: the scope of the weight ratio of conventional enzyme-containing detergent constituent is 0.5:1000-300:1000.
3. oligomeric isomaltose enzyme-containing detergent according to claim 1 is characterized in that, said oligomeric isomaltose: the scope of the weight ratio of conventional enzyme-containing detergent constituent is 0.5:1000-50:1000.
4. oligomeric isomaltose enzyme-containing detergent according to claim 2 is characterized in that, said oligomeric isomaltose: the scope of the weight ratio of conventional enzyme-containing detergent constituent is 0.5:1000-25:1000.
5. according to the arbitrary described oligomeric isomaltose enzyme-containing detergent of claim 1-4; It is characterized in that said conventional enzyme-containing detergent constituent is selected from enzyme, tensio-active agent, sanitas, sequestrant, SYNTHETIC OPTICAL WHITNER, white dyes, enzyme stabilizers, dispersion agent, spot suspension agent, water-softening agent, spices.
6. oligomeric isomaltose enzyme-containing detergent according to claim 5; It is characterized in that described enzyme is selected from one or more in cellulase, hemicellulase, px, proteolytic enzyme, glycase, zytase, alkaline lipase, Phospholipid hydrolase, polygalacturonase, oxydase, reductase enzyme, the LSD.
7. oligomeric isomaltose enzyme-containing detergent according to claim 1 is characterized in that, its formulation is block, Powdered, particulate state, paste or liquid form.
8. oligomeric isomaltose enzyme-containing detergent according to claim 1 is characterized in that, said enzyme-containing detergent is fabric detergent, dish washing detergent, shampoo, Liquid soap, fruits and vegetables washing composition, medical clean-out system.
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| CN2012101510591A CN102660398A (en) | 2012-05-16 | 2012-05-16 | Isomaltose hypgather enzyme-containing detergent |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666826A (en) * | 2013-11-27 | 2014-03-26 | 南通晶鑫光学玻璃有限公司 | Automobile windshield wipe cleaner and preparation method thereof |
| CN103666873A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Pre-washing spotting agent for clothing |
| CN107982135A (en) * | 2017-12-25 | 2018-05-04 | 深圳市芭格美生物科技有限公司 | A kind of shampoo and preparation method thereof |
| CN109971562A (en) * | 2019-04-23 | 2019-07-05 | 南京巨鲨显示科技有限公司 | Medical manual multienzyme cleaning sheet of a kind of slow-release and preparation method thereof |
| CN110003991A (en) * | 2019-04-23 | 2019-07-12 | 南京巨鲨显示科技有限公司 | A kind of medical multienzyme cleaning cream and preparation method thereof removing the heavy scale |
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| CN1332787A (en) * | 1998-10-23 | 2002-01-23 | 宝洁公司 | Fabrid care composition and method |
| CN102260607A (en) * | 2011-07-13 | 2011-11-30 | 广州市正阳工业科技有限公司 | Food detergent |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1332787A (en) * | 1998-10-23 | 2002-01-23 | 宝洁公司 | Fabrid care composition and method |
| CN102260607A (en) * | 2011-07-13 | 2011-11-30 | 广州市正阳工业科技有限公司 | Food detergent |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666873A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Pre-washing spotting agent for clothing |
| CN103666873B (en) * | 2013-11-22 | 2015-08-19 | 陈卡丹 | A kind of clothing prewashing spotting agent |
| CN103666826A (en) * | 2013-11-27 | 2014-03-26 | 南通晶鑫光学玻璃有限公司 | Automobile windshield wipe cleaner and preparation method thereof |
| CN107982135A (en) * | 2017-12-25 | 2018-05-04 | 深圳市芭格美生物科技有限公司 | A kind of shampoo and preparation method thereof |
| CN109971562A (en) * | 2019-04-23 | 2019-07-05 | 南京巨鲨显示科技有限公司 | Medical manual multienzyme cleaning sheet of a kind of slow-release and preparation method thereof |
| CN110003991A (en) * | 2019-04-23 | 2019-07-12 | 南京巨鲨显示科技有限公司 | A kind of medical multienzyme cleaning cream and preparation method thereof removing the heavy scale |
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