CN1660950A - Water paint in use for repairing ancient bronze, pottery and porcelain as before - Google Patents
Water paint in use for repairing ancient bronze, pottery and porcelain as before Download PDFInfo
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- CN1660950A CN1660950A CN 200510038256 CN200510038256A CN1660950A CN 1660950 A CN1660950 A CN 1660950A CN 200510038256 CN200510038256 CN 200510038256 CN 200510038256 A CN200510038256 A CN 200510038256A CN 1660950 A CN1660950 A CN 1660950A
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Abstract
A water paint for repairing ancient bronze and ceramic vessels to keep its cold color is prepared through proportionally mixing wtaer-soluble paint, water color slurry, pigment and water, adding talc powder or gypsum powder, levelling agent and other assistant, and stirring.
Description
Technical field
The present invention relates to a kind of coating, particularly a kind of water-borne coatings that is used to repair bronze work in ancient times, ceramic component.
Background technology
In state-owned 5,000 years magnificent history, stayed many ancient records and relics, its medium bronze, ceramic ware are to have the common again historical relic of suitable history.During bronze work, ceramic ware historical relic are kept at the ancient tomb mostly or store sth. in a cellar, at land disposal hundreds of even several thousand.The extruding of the stores that causes owing to phreatic erosion and stratigraphic fluctuation has much damaged or distortion when unearthed, that have even incoherent.Therefore, repair unearthed bronze work, ceramic ware as usual, science and the artistic value of reproducing it just seem especially important.
Before the present invention, to the reparation of bronze work, ceramic ware historical relic, the one, the historical relic of welding or bonding fragmentation, the 2nd, recruit broken partial section; Then the cultural artifact surface of repair place is made old accent color treatments.Make the tackiness agent of old material with shellac water (coating agent which has to be dissolved in alcohol before use), zapon varnish as bronze work, be equipped with the effect that mineral dye makes cupric oxide (black), Red copper oxide (redness), copper carbonate (blueness), alkali formula greening copper (green), mud (yellow) etc.; Adopt pyroxylin(e)finish, shellac water that pottery, woodenware, tile carving historical relic are done old processing; Adopt zapon varnish, shellac water, acrylic paint, enamel paint, polyamine fat crystal paint that porcelain glaze colours historical relics such as (ceramic whiteware, celadons) is done old processing; Adopt lacquer, shellac water, zapon varnish etc. that the lacquer wood historical relic is done old processing; Adopt zapon varnish, shellac water, acrylic paint etc. that the colored drawing mural painting is done old processing, its raw material of going into lacquer is that inorganic raw material such as titanium dioxide, red iron oxide, chrome yellow, chrome green, the phthalein mountain valley with clumps of trees and bamboo are green, phthalein mountain valley with clumps of trees and bamboo orchid etc. is for making old pigment, and thinner is an organic solvent.
These methods and material belong to solvent reducible coatings, and to recovering the historical relic true qualities, the purpose that reaches restoring the old as the old has certain effect, but exists many defectives, or even serious defective.The thinner of shellac water is an alcohol, and the thinner of zapon varnish is an oil of bananas, and the thinner of acrylic paint is N-BUTYL ACETATE, vinyl acetic monomer, and the thinner of polyurethane rock crystal paint is toluene, dimethylbenzene, and the thinner of enamel paint and alkyd varnish is a gasoline.Life-time service benzene is deleterious to operator's health, also influences other people Working environment, and certain toxicity is arranged; Alcohol in the working method, oil of bananas, benzene consumption are too much, also can influence the color that preceding road is done up, lose gradation sense; Though the color of having done closely with former historical relic was in several years: as will deepen after 5 years, peeling, aging, be unable to undergo the test of time, this is historical relic reparation avoiding greatly as usual; Under ultraviolet and red candle lamp, color is easily sent out light, is turned white, and makes other people just can find out the place that historical relic is broken in a glance, has lost the principle and the effect of " restoring the old as the old ", the function and the effect of influence exhibition; In addition, can molten pigment in zapon varnish, the shellac water all be mineral dyes, particle is thicker, be not suitable for doing the bag slurry on bronze, brass or copper ware surface and porcelain glaze do old.
Summary of the invention
Purpose of the present invention just is to overcome above-mentioned defective, designs a kind of bronze, ceramic ware historical relic new water-borne coatings as usual of repairing.
Technical scheme of the present invention is: be applicable to bronze in ancient times, ceramic ware reparation water-borne coatings as usual, comprise water soluble paint, aqueous color paste, pigment, be in harmonious proportion with water and make.
Advantage of the present invention and effect are the do old material of modern water-borne coatings replacement solvent based coating in the past as bronze, ceramics in repairing, nontoxic, the no burn into of its advantage does not burn, security is good, repairing environment is not needed too much requirement, reparation personnel life-time service does not influence healthy, belongs to environment-friendly materials; After coating drying and the curing, can not cause the phenomenon of upper strata dissolving lower floor color and luster; After the coating film forming, as requested, as densification, luminous coatingsurface does not have bubble, levelling is even, UV resistant; As rugged patina layer and unearthed mud spot, the incrustation scale of pottery, all can reach color and luster and effect---" restoring the old as the old " of former historical relic.
The invention enables renovation technique to oversimplify, easy handling and convenient, cost is low, is that old good material is made in bronze, the reparation of ceramic ware historical relic.
Embodiment
Embodiment 1:
Materials:
1, coating: pure acrylic acid ester copolymer emulsion, vinylbenzene---acrylate copolymer emulsion, organosilicon-modified acrylic emulsion, aqueous polyvinyl acetate emulsion are and water soluble alkyd resin, water-soluble epoxy resin, Polyester Resin Water Soluble, acrylic resin, water soluble polyurethane resin.
2, filler: terra alba, talcum powder, silicon-dioxide, silica powder, zinc sulfide white.
3, pigment: titanium dioxide, iron oxide yellow, carbon black, ultramarine, lead chrome green etc.
4, aqueous color paste: titanium white, iron oxide red, iron oxide yellow, carbon black, phthalocyanine blue, phthalein viridescent, light green, organic yellow, bright red, fuchsin agent
5, auxiliary agent: defoamer, flow agent, UV light absorber, thickening agents.
6, water: tap water, cationic water.
Earlier the bonding of historical relics such as bronze work, ceramic ware or the outer slit of welding are filled and led up, promptly played putty.Get phenylpropyl alcohol (or pure third, silicon third, white glues water, water soluble alkyd resin, water-soluble epoxy resin, Polyester Resin Water Soluble, acrylic resin, water soluble polyurethane resin is a kind of) 100 grams then, terra alba (or talcum powder, silica powder, zinc sulfide white, silicon-dioxide one or two or more kinds) 300 grams; Titanium dioxide (or iron oxide red, phthalein green grass or young crops, indigo plant, lemon yellow, ultramarine, iron black one or two or more kinds) is an amount of, and water is an amount of, and four kinds of materials are in harmonious proportion evenly, is applied to bronze, brass or copper ware, ceramic ware, tile carving, lacquer wood, place, the bonding slit of colored drawing mural painting historical relic then.
Pure acrylic acid ester copolymer emulsion (being called for short pure third), vinylbenzene is acrylate copolymer emulsion (abbreviation phenylpropyl alcohol), organosilicon-modified acrylic emulsion (being called for short silicon third) one by one
Embodiment 2:
The incompleteness of historical relic such as bronze, brass or copper ware, pottery is repaired the coating at position.
Material is the same.Get pure third (or phenylpropyl alcohol, white glues water, silicon third, water-soluble alcohol acid, Resins, epoxy, vibrin, acrylic resin, waterborne polyurethane resin is a kind of) 100 grams; Titanium dioxide 30 grams, talcum powder 200 grams, flow agent is an amount of; Aqueous color paste titanium white (or iron oxide red, iron oxide yellow, carbon black, phthalocyanine blue, phthalein viridescent, light green, organic yellow, bright red, fuchsin one or two or more kinds) is an amount of, water, in right amount, be in harmonious proportion and evenly be coated on the putty place that bronze, brass or copper ware, pottery, tile carving, lacquer wood, colored drawing mural painting historical relic are tied.
Embodiment 3:
Doing of the shinny high light position of the glaze light of the bag of bronze, brass or copper ware slurry (mercury oozes, colors such as watermelon is green, pitch-dark Gu), porcelain, tile carving, lacquer wood, lacquerware is old.
Get high gloss silicon third (or pure third, phenylpropyl alcohol, water-soluble epoxy resin, vibrin, waterborne polyurethane resin is a kind of) 100 grams, aqueous color paste titanium white (or iron oxide red, iron oxide yellow, carbon black, phthalocyanine blue, phthalein viridescent, light green, organic yellow, bright red, fuchsin one or two or more kinds) is an amount of, flow agent, defoamer, UV light absorber are all an amount of, be in harmonious proportion evenly the repair place of brushing or spraying and bronze, brass or copper ware, pottery, tile carving, lacquerware.
Embodiment 4:
The rugged rusty scale of bronze, brass or copper ware, doing of the white lime calcium that the mud layer of pottery and grave stay when being unearthed is old.
Get pure-acrylic emulsion (or phenylpropyl alcohol, organosilicon crylic acid latex, water-soluble epoxy resin, vibrin, acrylic resin, waterborne polyurethane resin is a kind of) 100 grams, terra alba (or talcum powder, silica powder, zinc sulfide white, silicon-dioxide one or two or more kinds) 200 grams, thickening agents is an amount of, titanium white powder pigment (or iron oxide red, phthalocyanine blue, lemon yellow, ultramarine, iron black one or two or more kinds) 5～10 grams, be in harmonious proportion evenly, roll with the instrument of pointed cone type then and scrape up, or touch up with the toothbrush bullet, with painting brush and all can.
Obtaining polyacrylic acid emulsion, poly-vinegar vinyl acetate emulsion and water-base resin content in the above example is 30～100 grams, is lower than 30 grams as the content of coating, and the sticking power of old material is made in influence, drops easily.
After every coating parches in the above example, do not influence the old material of doing of the second layer, it is careless slightly the solvent-thinned paint class promptly not occur, and two layers of color will have the phenomenon that mixes mutually up and down.
Water-borne coatings of the present invention also can be used as historical relic reparation materials as usual such as being used for colored drawing mural painting, tile carving, lacquer wood.
Claims (6)
1. be applicable to bronze in ancient times, ceramic ware reparation water-borne coatings as usual, comprise the mediation of water soluble paint and aqueous color paste and make.
2. bronze in ancient times, the ceramic ware reparation water-borne coatings as usual of being applicable to according to claim 1, it is characterized in that adding filler, filler comprises talcum powder, terra alba, zinc sulfide white, silicon-dioxide, silica powder, yellow mud powder, mica powder, kaolin, can select wherein any or more than two kinds.
3. according to claim 1,2 described bronze in ancient times, the ceramic ware reparation water-borne coatingss as usual of being applicable to, it is characterized in that adding auxiliary agent, auxiliary agent comprises flow agent, thickening agents, UV light absorber, defoamer, can select wherein any or more than two kinds.
4. bronze in ancient times, the ceramic ware reparation water-borne coatings as usual of being applicable to according to claim 1, it is characterized in that water soluble paint comprises pure acrylic acid ester copolymer emulsion, styrene-propene acid copolymer emulsion, organosilicon-modified acrylic emulsion, water-soluble epoxy resin, water-based polyurethane, water-based fluororesin, can select wherein any or combination more than two kinds.
5. bronze in ancient times, the ceramic ware reparation water-borne coatings as usual of being applicable to according to claim 1, it is characterized in that the water-based colorant comprises titanium white, iron oxide red, iron oxide yellow, carbon black, phthalocyanine blue, phthalein viridescent, light green, organic yellow, bright red, fuchsin, can select wherein any or more than two kinds.
6. bronze in ancient times, the ceramic ware reparation water-borne coatings as usual of being applicable to according to claim 1 is characterized in that auxiliary agent comprises flow agent, thickening agents, UV light absorber, defoamer, can select wherein any or more than two kinds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510038256 CN1660950A (en) | 2005-01-26 | 2005-01-26 | Water paint in use for repairing ancient bronze, pottery and porcelain as before |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510038256 CN1660950A (en) | 2005-01-26 | 2005-01-26 | Water paint in use for repairing ancient bronze, pottery and porcelain as before |
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| CN1660950A true CN1660950A (en) | 2005-08-31 |
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| CN 200510038256 Pending CN1660950A (en) | 2005-01-26 | 2005-01-26 | Water paint in use for repairing ancient bronze, pottery and porcelain as before |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101608083B (en) * | 2009-07-30 | 2010-07-07 | 陕西师范大学 | Sizing color painting reattachment restoration agent for ceramic relics |
| CN101875042A (en) * | 2010-03-30 | 2010-11-03 | 冷贝生 | Surface treatment method for antiquing zodiac heads of Old Summer Palace |
| CN102268665A (en) * | 2011-07-21 | 2011-12-07 | 洛阳粤钰青铜器有限公司 | Rust making liquid and bronze-colored rust-making method on bronze ware surface by utilizing same |
| CN102268666A (en) * | 2011-07-21 | 2011-12-07 | 洛阳粤钰青铜器有限公司 | Rusting solution and method for forming green rust on surface of bronze ware |
| CN102344728A (en) * | 2011-05-31 | 2012-02-08 | 吴江新慈木业有限公司 | Coating adopting modified acrylic acid resin as main material |
| CN102344730A (en) * | 2011-05-31 | 2012-02-08 | 吴江新慈木业有限公司 | Coating adopting aqueous acrylic acid resin as main material |
| CN103204703A (en) * | 2013-02-04 | 2013-07-17 | 陕西师范大学 | Application of ZB-F600 two-component FEVE aqueous fluororesin in pretreatment of damage-prone pottery decorated with colored drawing before restoration |
| CN104478480A (en) * | 2014-12-24 | 2015-04-01 | 中南大学 | Color-adjustabledesalination/deacidificationand reinforcement nano-material for cultural relic repair and protection as well as preparation method of nano-material |
| CN105524557A (en) * | 2016-02-18 | 2016-04-27 | 南京博物院 | Application of water-based polymer material as antique finish adhesive material for restoration of porcelain antiques |
| CN105921694A (en) * | 2016-07-15 | 2016-09-07 | 李万祥 | Making technology for copying bronze ware |
| CN105967760A (en) * | 2016-05-05 | 2016-09-28 | 华若延 | Archaized brick manufacturing method |
| CN106497178A (en) * | 2016-10-19 | 2017-03-15 | 苏州工业园区园林绿化工程有限公司 | Coating repaired by ancient gardens colored drawing |
| CN106497436A (en) * | 2016-10-25 | 2017-03-15 | 陕西师范大学 | A kind of relics adhesive of Color tunable |
| CN106699213A (en) * | 2017-03-30 | 2017-05-24 | 宁波莳绘金缮文化创意有限公司 | Metal repairing technological method |
| CN107499044A (en) * | 2017-08-25 | 2017-12-22 | 胡文贤 | Technology for making brick sculpture |
| CN109913018A (en) * | 2019-02-13 | 2019-06-21 | 临沂大学 | A kind of fine arts environmental protection coating material and preparation method thereof and ager |
| CN110723987A (en) * | 2019-10-17 | 2020-01-24 | 南京博物院 | Application of XW-HB water-based two-component self-drying paint as porcelain repairing glaze-imitating material |
| CN112500033A (en) * | 2020-08-05 | 2021-03-16 | 湖州锦程岗石制品有限公司 | Wukang ancient stone imitation formula and preparation process thereof |
-
2005
- 2005-01-26 CN CN 200510038256 patent/CN1660950A/en active Pending
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101608083B (en) * | 2009-07-30 | 2010-07-07 | 陕西师范大学 | Sizing color painting reattachment restoration agent for ceramic relics |
| CN101875042A (en) * | 2010-03-30 | 2010-11-03 | 冷贝生 | Surface treatment method for antiquing zodiac heads of Old Summer Palace |
| CN102344728A (en) * | 2011-05-31 | 2012-02-08 | 吴江新慈木业有限公司 | Coating adopting modified acrylic acid resin as main material |
| CN102344730A (en) * | 2011-05-31 | 2012-02-08 | 吴江新慈木业有限公司 | Coating adopting aqueous acrylic acid resin as main material |
| CN102268665A (en) * | 2011-07-21 | 2011-12-07 | 洛阳粤钰青铜器有限公司 | Rust making liquid and bronze-colored rust-making method on bronze ware surface by utilizing same |
| CN102268666A (en) * | 2011-07-21 | 2011-12-07 | 洛阳粤钰青铜器有限公司 | Rusting solution and method for forming green rust on surface of bronze ware |
| CN103204703A (en) * | 2013-02-04 | 2013-07-17 | 陕西师范大学 | Application of ZB-F600 two-component FEVE aqueous fluororesin in pretreatment of damage-prone pottery decorated with colored drawing before restoration |
| CN103204703B (en) * | 2013-02-04 | 2014-05-14 | 陕西师范大学 | Application of ZB-F600 two-component FEVE aqueous fluororesin in pretreatment of damage-prone pottery decorated with colored drawing before restoration |
| CN104478480A (en) * | 2014-12-24 | 2015-04-01 | 中南大学 | Color-adjustabledesalination/deacidificationand reinforcement nano-material for cultural relic repair and protection as well as preparation method of nano-material |
| CN105524557A (en) * | 2016-02-18 | 2016-04-27 | 南京博物院 | Application of water-based polymer material as antique finish adhesive material for restoration of porcelain antiques |
| CN105967760B (en) * | 2016-05-05 | 2018-08-10 | 江门市华陶陶瓷有限公司 | A kind of production method of Antique Imitation Tiles |
| CN105967760A (en) * | 2016-05-05 | 2016-09-28 | 华若延 | Archaized brick manufacturing method |
| CN105921694A (en) * | 2016-07-15 | 2016-09-07 | 李万祥 | Making technology for copying bronze ware |
| CN106497178A (en) * | 2016-10-19 | 2017-03-15 | 苏州工业园区园林绿化工程有限公司 | Coating repaired by ancient gardens colored drawing |
| CN106497436A (en) * | 2016-10-25 | 2017-03-15 | 陕西师范大学 | A kind of relics adhesive of Color tunable |
| CN106497436B (en) * | 2016-10-25 | 2018-03-06 | 陕西师范大学 | A kind of ceramic relics adhesive of Color tunable |
| CN106699213A (en) * | 2017-03-30 | 2017-05-24 | 宁波莳绘金缮文化创意有限公司 | Metal repairing technological method |
| CN107499044A (en) * | 2017-08-25 | 2017-12-22 | 胡文贤 | Technology for making brick sculpture |
| CN109913018A (en) * | 2019-02-13 | 2019-06-21 | 临沂大学 | A kind of fine arts environmental protection coating material and preparation method thereof and ager |
| CN110723987A (en) * | 2019-10-17 | 2020-01-24 | 南京博物院 | Application of XW-HB water-based two-component self-drying paint as porcelain repairing glaze-imitating material |
| CN112500033A (en) * | 2020-08-05 | 2021-03-16 | 湖州锦程岗石制品有限公司 | Wukang ancient stone imitation formula and preparation process thereof |
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