CN105524557A - Application of water-based polymer material as antique finish adhesive material for restoration of porcelain antiques - Google Patents
Application of water-based polymer material as antique finish adhesive material for restoration of porcelain antiques Download PDFInfo
- Publication number
- CN105524557A CN105524557A CN201610091021.8A CN201610091021A CN105524557A CN 105524557 A CN105524557 A CN 105524557A CN 201610091021 A CN201610091021 A CN 201610091021A CN 105524557 A CN105524557 A CN 105524557A
- Authority
- CN
- China
- Prior art keywords
- water
- porcelain
- environment
- old
- adhesives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an application of a water-based polymer material as an antique finish adhesive material for restoration of porcelain antiques. The water-based polymer material is ET99SG environment-friendly water-based varnish for woodware, ET99N environment-friendly water-based clear primer for woodware or DF-01 water-based fluorocarbon emulsion. The water-based polymer material belongs to water-based materials and can be taken as the antique finish adhesive material for restoration of the porcelain antiques after the material is compounded with distilled water, use of banana oil is avoided, environmental protection is realized, and a color applied in a previous process is not affected. After a porcelain plate after antique finish processing with the antique finish adhesive material is subjected to dry-heat, ultraviolet and hydrothermal artificial accelerated aging, the color difference change of the porcelain plate is smaller than 5, the gloss change at 60 degrees is smaller, the porcelain plate has better yellowing resistance, and the restored porcelain antiques are more durable and can be stored for a long time.
Description
Technical field
The invention belongs to Techniques of Relics Protection field, be specifically related to the application that aqueous high molecular material is done in the reparation of porcelain historical relic in old adhesives.
Background technology
Porcelain historical relic belongs to common cultural relics in the collection of cultural institution, and be that the uniqueness of Chinese people is created, porcelain represents the long civilization of China with the national cultural feature of its uniqueness, and from moulding and the decoration of porcelain, it more ideally embodies Sinitic looks.Most of porcelain historical relics of collection are all Unearthed when Archaeological Studies product, come from ancient tomb or in storing sth. in a cellar, the hundreds of even several thousand at land disposal.The extruding of the stores caused due to the erosion of underground water and stratigraphic fluctuation, have many damaged or distortion time unearthed, what have is even incoherent.Therefore, repair the porcelain historical relic be unearthed, science and the artistic value of reproducing it just seem especially important.The general step of porcelain historical relic reparation comprises stickup, recruits and do old process.Wherein doing old process is committed step in Conservative restoration.Doing old process is exactly make old tackiness agent with zapon varnish as ceramic ware historical relic, is equipped with mineral dye and is made required effect; Above-mentioned materials is to recovery historical relic true qualities, and the object reaching restoring the old as the old has certain effect, but there is many defects, or even serious defect.Zapon varnish makes old tackiness agent as ceramic ware historical relic, need composite with thinner oil of bananas after could use as doing old matrix material, the main component of oil of bananas is benzene and benzene homologues, the health of life-time service to operator is harmful, also affect other people Working environment, have certain toxicity, and oil of bananas, benzene consumption are too much, also can affect the color done up in front road, lose gradation sense; Simultaneously its repair after through the time of about 5 years will deepen, peeling, aging, be unable to undergo the test of time, this is historical relic reparation avoiding greatly as usual; Under ultraviolet and red candle lamp, color is easily sent out light, is turned white, and makes other people can find out the place that historical relic is broken at a glance, loses principle and the effect of " restoring the old as the old ", the function of impact exhibition and effect.
The clear priming paint of the environment-friendly water-based woodenware of aqueous high molecular material ET99N and the environment-friendly water-based woodware varnish of ET99SG have the advantages such as low smell, low VOC, asepsis environment-protecting, yellowing resistance excellence, durable, are mainly used in the external coating of woodenware.Aqueous high molecular material DF-01 water-base fluorocarbon emulsion is for raw material with trifluorochloroethylene and other functional monomer, the two-pack using emulsion synthesize technology to prepare can cold cross-linking polymkeric substance, this polymkeric substance can form even, transparent coating, is mainly used in exterior wall protective system.Above-mentioned three kinds of aqueous high molecular materials are showed no the application of document announcement in porcelain is repaired.
Summary of the invention
Technical problem to be solved by this invention is to overcome the shortcoming that old adhesives is made in the reparation of above-mentioned porcelain historical relic, is aqueous high molecular material---and the clear priming paint of the environment-friendly water-based woodenware of DF-01 water-base fluorocarbon emulsion, ET99N, the environment-friendly water-based woodware varnish of ET99SG provide a kind of new purposes.
Solving the problems of the technologies described above adopted technical scheme is: the application in old adhesives done by aqueous high molecular material in the reparation of porcelain historical relic, and described aqueous high molecular material is the environment-friendly water-based woodware varnish of ET99SG, the clear priming paint of the environment-friendly water-based woodenware of ET99N or DF-01 water-base fluorocarbon emulsion.
When above-mentioned aqueous high molecular material is ET99SG environment-friendly water-based woodware varnish, described old adhesives of doing is that the environment-friendly water-based woodware varnish of ET99SG and distilled water mix for 1:3 ~ 1:8 in mass ratio, and the environment-friendly water-based woodware varnish of preferred ET99SG and distilled water mix for 1:4 ~ 1:7 in mass ratio.
When above-mentioned aqueous high molecular material is the environment-friendly water-based woodenware of ET99N clear priming paint, described old adhesives of doing is that the clear priming paint of the environment-friendly water-based woodenware of ET99N and distilled water mix for 1:2 ~ 1:8 in mass ratio, and the clear priming paint of the environment-friendly water-based woodenware of preferred ET99N and distilled water mix for 1:4 ~ 1:7 in mass ratio.
When above-mentioned aqueous high molecular material is DF-01 water-base fluorocarbon emulsion, described old adhesives of doing is that DF-01 water-base fluorocarbon emulsion and distilled water mix for 1:2 ~ 1:3 in mass ratio, and preferred DF-01 water-base fluorocarbon emulsion and distilled water are in mass ratio for 1:3 mixes.
The clear priming paint of the environment-friendly water-based woodenware of above-mentioned ET99N and the environment-friendly water-based woodware varnish of ET99SG are by Zijinghua Paint (Shanghai) Co., Ltd.) provide, DF-01 water-base fluorocarbon emulsion is provided by Dong Huan Chemical Co., Ltd. of Changshu City.
The present invention's DF-01 water-base fluorocarbon emulsion used, the clear priming paint of the environment-friendly water-based woodenware of ET99N, the environment-friendly water-based woodware varnish of ET99SG belong to water-based material, namely can be used as the reparation of porcelain historical relic and make old adhesives with distilled water is composite and use, avoid the use of lacquer thinner, environmental protection more, and do not affect the color done up in front road.Adopt and of the present inventionly make old adhesives and make the porcelain plate after old process through xeothermic, ultraviolet, damp and hot artificial accelerated aging, its chromatic aberration is all less than 5, the glossiness change of 60 ° of angles is also smaller, there is good yellowing resistance, make the porcelain historical relic after repairing more durable, can preserve for a long time.
Embodiment
Below in conjunction with embodiment, the present invention is further described, but protection scope of the present invention is not limited only to these embodiments.
Embodiment 1
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the environment-friendly water-based woodware varnish of ET99SG, its using method is as follows:
1, the preparation of old adhesives is done
Divide the another name environment-friendly water-based woodware varnish of 5.0gET99SG and 15.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the environment-friendly water-based woodware varnish of ET99SG is uniformly dispersed, obtains making old adhesives.
2, old process done by porcelain
What mineral color and step 1 are obtained makes old adhesives in mass ratio for 1:2 mixes, after stirring with glass stick, utilize writing brush or spray gun to be coated on porcelain historical relic equably to have filled a vacancy process place, after seasoning, repeatedly repeatedly apply again, until porcelain historical relic fill a vacancy the color of process place consistent with ambient color till.
Embodiment 2
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the environment-friendly water-based woodware varnish of ET99SG, its using method is as follows:
In the present embodiment, divide the another name environment-friendly water-based woodware varnish of 5.0gET99SG and 20.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the environment-friendly water-based woodware varnish of ET99SG is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 3
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the environment-friendly water-based woodware varnish of ET99SG, its using method is as follows:
In the present embodiment, divide the another name environment-friendly water-based woodware varnish of 5.0gET99SG and 25.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the environment-friendly water-based woodware varnish of ET99SG is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 4
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the environment-friendly water-based woodware varnish of ET99SG, its using method is as follows:
In the present embodiment, divide the another name environment-friendly water-based woodware varnish of 5.0gET99SG and 30.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the environment-friendly water-based woodware varnish of ET99SG is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 5
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the environment-friendly water-based woodware varnish of ET99SG, its using method is as follows:
In the present embodiment, divide the another name environment-friendly water-based woodware varnish of 5.0gET99SG and 35.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the environment-friendly water-based woodware varnish of ET99SG is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 6
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the environment-friendly water-based woodware varnish of ET99SG, its using method is as follows:
In the present embodiment, divide the another name environment-friendly water-based woodware varnish of 5.0gET99SG and 40.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the environment-friendly water-based woodware varnish of ET99SG is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 7
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the clear priming paint of the environment-friendly water-based woodenware of ET99N, its using method is as follows:
In the present embodiment, divide the another name clear priming paint of the environment-friendly water-based woodenware of 5.0gET99N and 10.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the clear priming paint of the environment-friendly water-based woodenware of ET99N is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 8
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the clear priming paint of the environment-friendly water-based woodenware of ET99N, its using method is as follows:
In the present embodiment, divide the another name clear priming paint of the environment-friendly water-based woodenware of 5.0gET99N and 15.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the clear priming paint of the environment-friendly water-based woodenware of ET99N is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 9
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the clear priming paint of the environment-friendly water-based woodenware of ET99N, its using method is as follows:
In the present embodiment, divide the another name clear priming paint of the environment-friendly water-based woodenware of 5.0gET99N and 20.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the clear priming paint of the environment-friendly water-based woodenware of ET99N is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 10
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the clear priming paint of the environment-friendly water-based woodenware of ET99N, its using method is as follows:
In the present embodiment, divide the another name clear priming paint of the environment-friendly water-based woodenware of 5.0gET99N and 25.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the clear priming paint of the environment-friendly water-based woodenware of ET99N is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 11
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the clear priming paint of the environment-friendly water-based woodenware of ET99N, its using method is as follows:
In the present embodiment, divide the another name clear priming paint of the environment-friendly water-based woodenware of 5.0gET99N and 30.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the clear priming paint of the environment-friendly water-based woodenware of ET99N is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 12
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the clear priming paint of the environment-friendly water-based woodenware of ET99N, its using method is as follows:
In the present embodiment, divide the another name clear priming paint of the environment-friendly water-based woodenware of 5.0gET99N and 35.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the clear priming paint of the environment-friendly water-based woodenware of ET99N is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 13
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with the clear priming paint of the environment-friendly water-based woodenware of ET99N, its using method is as follows:
In the present embodiment, divide the another name clear priming paint of the environment-friendly water-based woodenware of 5.0gET99N and 40.0g distilled water with balance, add in 50mL beaker, stir with glass stick, the clear priming paint of the environment-friendly water-based woodenware of ET99N is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 14
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with DF-01 water-base fluorocarbon emulsion, its using method is as follows:
In the present embodiment, divide another name 5.0gDF-01 water-base fluorocarbon emulsion and 10.0g distilled water with balance, add in 50mL beaker, stir with glass stick, DF-01 water-base fluorocarbon emulsion is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
Embodiment 15
Do to be applied as example in old adhesives in the reparation of porcelain historical relic with DF-01 water-base fluorocarbon emulsion, its using method is as follows:
In the present embodiment, divide another name 5.0gDF-01 water-base fluorocarbon emulsion and 15.0g distilled water with balance, add in 50mL beaker, stir with glass stick, DF-01 water-base fluorocarbon emulsion is uniformly dispersed, obtains making old adhesives.It is identical with embodiment 1 that old treatment process made by porcelain.
In order to determine beneficial effect of the present invention, what contriver adopted embodiment 1 ~ 15 to obtain do, and old adhesives carries out simulation to porcelain plate does old process, and carried out following sign to the sample after process, and particular case is as follows:
1, the process of filling a vacancy in porcelain reparation is simulated
Traditionally recruit step process white porcelain plate, the wherein used material that recruits is commercially available 3A glue and talcum powder, specific practice is as follows: by 3A glue and talcum powder in mass ratio for after 1:2 mixes, to coat on white porcelain plate and to be paved with white porcelain plate, laying depth is about 1cm, naturally dries.
2, simulate and do old process in porcelain reparation
Herein do old process, main finger for position of filling a vacancy do old, be that 1:2 mixes by the old matrix material of doing of mineral color and above-described embodiment 1 ~ 15 according to mass ratio, after stirring, utilize writing brush to be spread evenly across to fill a vacancy the white porcelain plate surface of process, after to be dried, then repeat above-mentioned steps, till the color of filling a vacancy covers in by the color of pigment.Do simultaneous test with zapon varnish traditionally simultaneously.This test is that clam is white at the mineral color doing to select in old process, and white pigment is easy to observe the problems such as variable color.
3, senile experiment
The above-mentioned analog sample doing old process is carried out respectively xeothermic aging, ultraviolet ageing and hydrothermal aging, wherein xeothermic aging be placed in xeothermic ageing oven, temperature is set as 100 ± 2 DEG C, continuous ageing 72 hours; Ultraviolet ageing is positioned in ultraviolet ageing case, and temperature is set as 63 DEG C, continuous ageing 1000 hours; Hydrothermal aging is positioned in hydrothermal aging case, and temperature is set as 50 DEG C, humid control 60%, continuous ageing 80 hours.
4, the change of old sample aging front and back optical property is done in simulation
(1) old sample aging front and back color difference analysis is made in simulation
Utilize HPG-2132 portable colorimeter to test the aberration that old sample aging front and back are done in simulation, the results are shown in Table 1.
The value of chromatism of the sample aging front and back of table 1
As shown in Table 1: for xeothermic aging all samples, except old sample made by zapon varnish, the value of chromatism of other sample aging front and back is all little by 5, show that old sample made by traditional material zapon varnish thermo-labile aging, be easy to xanthochromia, and the environment-friendly water-based woodware varnish of ET99SG, the clear priming paint of the environment-friendly water-based woodenware of ET99N and water-base fluorocarbon emulsion all compare resistant to thermal aging, color inhibition; For all samples of ultraviolet ageing and hydrothermal aging, its value of chromatism is all less than 5, show that all samples all has good anti-ultraviolet aging and the aging ability of heat resistance, but its value of chromatism of old sample made by traditional material zapon varnish is maximum in all samples, illustrate that the environment-friendly water-based woodware varnish of ET99SG, the clear priming paint of the environment-friendly water-based woodenware of ET99N and water-base fluorocarbon emulsion have stronger anti-ultraviolet ageing and the aging ability of heat resistance relative to zapon varnish.
(2) old sample aging front and back glossiness analysis is done in simulation
Utilize MG268PLUS Three-angle vancometer to test the glossiness that old sample aging front and back are done in simulation, glossiness depends primarily on the angle of light illumination and observation, this test and Selection 20 °, 60 ° and 85 ° of angle illumination, mainly 60 ° of angles.Each sample aging front and back glossiness changing value is in table 2.
Table 2 aging front and back sample glossiness changing value
As shown in Table 2, no matter be xeothermic aging, ultraviolet ageing or hydrothermal aging, for the surface of 60 ° of each samples of angle views, the change of its glossiness is all very little, namely see that the aging front and back of the glossiness of sample surfaces do not change substantially with eyes, illustrate that each sample glossiness is more stable.
Claims (7)
1. the application in old adhesives done by aqueous high molecular material in the reparation of porcelain historical relic, and described aqueous high molecular material is the environment-friendly water-based woodware varnish of ET99SG, the clear priming paint of the environment-friendly water-based woodenware of ET99N or DF-01 water-base fluorocarbon emulsion.
2. the application in old adhesives done by aqueous high molecular material according to claim 1 in the reparation of porcelain historical relic, it is characterized in that: described old adhesives of doing is that the environment-friendly water-based woodware varnish of ET99SG and distilled water mix for 1:3 ~ 1:8 in mass ratio.
3. the application in old adhesives done by aqueous high molecular material according to claim 2 in the reparation of porcelain historical relic, it is characterized in that: described old adhesives of doing is that the environment-friendly water-based woodware varnish of ET99SG and distilled water mix for 1:4 ~ 1:7 in mass ratio.
4. the application in old adhesives done by aqueous high molecular material according to claim 1 in the reparation of porcelain historical relic, it is characterized in that: described old adhesives of doing is that the clear priming paint of the environment-friendly water-based woodenware of ET99N and distilled water mix for 1:2 ~ 1:8 in mass ratio.
5. the application in old adhesives done by aqueous high molecular material according to claim 4 in the reparation of porcelain historical relic, it is characterized in that: described old adhesives of doing is that the clear priming paint of the environment-friendly water-based woodenware of ET99N and distilled water mix for 1:4 ~ 1:7 in mass ratio.
6. the application in old adhesives done by aqueous high molecular material according to claim 1 in the reparation of porcelain historical relic, it is characterized in that: described old adhesives of doing is that DF-01 water-base fluorocarbon emulsion and distilled water mix for 1:2 ~ 1:3 in mass ratio.
7. the application in old adhesives done by aqueous high molecular material according to claim 6 in the reparation of porcelain historical relic, it is characterized in that: described to make old adhesives be that DF-01 water-base fluorocarbon emulsion and distilled water are in mass ratio for 1:3 mixes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610091021.8A CN105524557B (en) | 2016-02-18 | 2016-02-18 | Application of the aqueous high molecular material in old adhesives is made in porcelain historical relic reparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610091021.8A CN105524557B (en) | 2016-02-18 | 2016-02-18 | Application of the aqueous high molecular material in old adhesives is made in porcelain historical relic reparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105524557A true CN105524557A (en) | 2016-04-27 |
| CN105524557B CN105524557B (en) | 2017-11-28 |
Family
ID=55767093
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610091021.8A Expired - Fee Related CN105524557B (en) | 2016-02-18 | 2016-02-18 | Application of the aqueous high molecular material in old adhesives is made in porcelain historical relic reparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105524557B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1660950A (en) * | 2005-01-26 | 2005-08-31 | 万俐 | Water paint in use for repairing ancient bronze, pottery and porcelain as before |
| CN101608083A (en) * | 2009-07-30 | 2009-12-23 | 陕西师范大学 | Sizing color painting reattachment restoration agent for ceramic relics |
-
2016
- 2016-02-18 CN CN201610091021.8A patent/CN105524557B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1660950A (en) * | 2005-01-26 | 2005-08-31 | 万俐 | Water paint in use for repairing ancient bronze, pottery and porcelain as before |
| CN101608083A (en) * | 2009-07-30 | 2009-12-23 | 陕西师范大学 | Sizing color painting reattachment restoration agent for ceramic relics |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105524557B (en) | 2017-11-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104209249B (en) | A kind of high light white UV coating construction process | |
| CN1660950A (en) | Water paint in use for repairing ancient bronze, pottery and porcelain as before | |
| CN101712846B (en) | Raw ancient building decorative paint | |
| CN101824263A (en) | Chameleon coating, use method thereof on colored coating steel plate and colored coating steel plate | |
| CN105527217A (en) | Externally-applied finish paint weatherability testing method | |
| Bomin et al. | A scientific investigation of five polymeric materials used in the conservation of murals in Dunhuang Mogao Grottoes | |
| CN107922758A (en) | High-performance coating | |
| CN104830208A (en) | Rib crack or bogging resistant environmentally-friendly photocurable high-filling GLAZE coloring agent | |
| TWI321145B (en) | Coating compositions suitable for use as a wood stain and/or toner | |
| CN104152010A (en) | Ultraviolet-curable pollution-resistant coating | |
| RU2716675C2 (en) | Method of producing construction material | |
| de la Rie et al. | An investigation of the photochemical stability of urea-aldehyde resin retouching paints: removability tests and colour spectroscopy | |
| CN101608082B (en) | Composite sealer for color paintings of ancient buildings | |
| CN101608083B (en) | Sizing color painting reattachment restoration agent for ceramic relics | |
| CN105524557A (en) | Application of water-based polymer material as antique finish adhesive material for restoration of porcelain antiques | |
| Sáez-Pérez et al. | Synthetic white pigments (white titanium and white zinc) in different binding media. Influence of environmental agents | |
| CN1660609A (en) | Technique method suitable for repairing cultural relics of stone inscription as before in field | |
| CN104672984B (en) | Ink adhesive, ink composite, printing composition, printing process and base material | |
| Llamas et al. | Colorimetric evaluation of three adhesives used in the consolidation of contemporary matte paint after artificial ageing | |
| Betz | The Influence Of Glass Transition Temperature On The Performance Of Acrylic Thermoplastic Adhesives | |
| van Basten et al. | Local Treatment for Monochrome Outdoor Painted Metal Sculptures: Assessing the Suitability of Conservation Paints for Retouching | |
| CN104608226A (en) | Paint woody printing blank and manufacturing method thereof | |
| Morris | A Performance Evaluation of Architectural Coatings to Preserve Aerosol Paint on Concrete | |
| ES2236923T3 (en) | ADHESIVE VARNISH FOR ABSORPTION OF POWDER PAINTS. | |
| CN110723987A (en) | Application of XW-HB water-based two-component self-drying paint as porcelain repairing glaze-imitating material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171128 Termination date: 20210218 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |