CN101824263A - Chameleon coating, use method thereof on colored coating steel plate and colored coating steel plate - Google Patents
Chameleon coating, use method thereof on colored coating steel plate and colored coating steel plate Download PDFInfo
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- CN101824263A CN101824263A CN201010142353A CN201010142353A CN101824263A CN 101824263 A CN101824263 A CN 101824263A CN 201010142353 A CN201010142353 A CN 201010142353A CN 201010142353 A CN201010142353 A CN 201010142353A CN 101824263 A CN101824263 A CN 101824263A
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Abstract
The invention discloses a chameleon coating comprising the following raw materials in parts by weight: 10-40 parts of matrix material, 1-20 parts of filling material, 1-25 parts of solvent, 3-20 parts of curing agent, 1-10 parts of pigment, 1-10 parts of assistant and 1-10 parts of angular heterochromous powder or comprising the following raw materials in parts by weight: 10-50 parts of matrix material, 1-20 parts of filling material, 1-25 parts of solvent, 2-10 parts of curing agent, 1-5 parts of pigment, 1-10 parts of assistant and 1-10 parts of optical interference powder. The invention also relates to the use method of the chameleon coating on a colored coating steel plate and a novel colored coating steel plate.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of chameleon coating, and relate to the using method of this coating on color coating layer steel plate, the present invention has also disclosed a kind of color coating layer steel plate.
Background technology
Along with the raising of expanding economy and living standards of the people, people are more and more higher to the pursuit of aesthetic conceptions.So having products such as the furniture of chameleon effect and household electrical appliances more and more is subjected to people and thinks highly of.
Though the formation method of changeable colors along with angle effect is not that people are strange, by the distribution level difference of pigment changeable colors along with angle, the effect that the color that is caused by optical physics phenomenons such as reflection, refraction and interference changes with viewing angle.In false proof field, because the function of its changeable colors along with angle of pigment changeable colors along with angle can not or be taken a picture and simply duplicate out by traditional duplicating machine, this just makes pseudo-technology for making become complicated more, and the cost height.So this pigment is applied to the false proof markings such as currency, certificate, trade mark and Valued Securities.But the false proof markings such as the currency with changeable colors along with angle, certificate, trade mark and the Valued Securities of its production, be generally papery or plastic or other material, with respect to the color coated steel plates processing parameter, traditional changeable colors along with angle production method has not anti-High Temperature And Velocity more than 300 ℃, is not suitable for the defective that big area is produced in enormous quantities.
In the known technology, after applying coating, do not make the surface have the technology enlightenment of chameleon effect by the quick continuous production of high bake relevant for steel plate, and in the practical application, have the demand market of similar production technique and coating and color coating layer steel plate really.
Summary of the invention
But the object of the present invention is to provide a kind of high-temperature baking resistant, can be adapted to the chameleon coating that common color coated steel plates tinuous production is produced in batches, this coating can make color coating layer steel plate possess the changeable colors along with angle effect, and then expanded the security purposes and the performance attractive in appearance of color coating layer steel plate, and this chameleon coating is easy to use.
Technical scheme of the present invention is: a kind of chameleon coating comprises the raw material of following parts by weight: matrix material 10-40 part, filler 1-20 part, solvent 1-25 part, solidifying agent 3-20 part, pigment 1-10 part, auxiliary agent 1-10 part and changeable colors along with angle powder 1-10 part.
A kind of chameleon coating comprises the raw material of following parts by weight: matrix material 10-50 part, filler 1-20 part, solvent 1-20 part, solidifying agent 2-10 part, pigment 1-5 part, auxiliary agent 1-10 part and interference of light powder 1-10 part.
In a preferred embodiment of the present invention, described chameleon coating comprises that also parts by weight are not more than 1 part pH value conditioning agent.
In a preferred embodiment of the present invention, described matrix material package is drawn together any one or more than one the combination in Resins, epoxy, saturated polyester resin, polyvinyl chloride (PVC) RESINS, acrylic resin, silicon modified polyesters resin, polyvinylidene fluoride resin and the urethane.
In a preferred embodiment of the present invention, described filler comprises any one or more than one the combination in Rutile type Titanium Dioxide, talcum powder, lime carbonate, Magnesium Silicate q-agent, calcium sulfate, mica powder and the barium sulfate.
In a preferred embodiment of the present invention, described solvent is included as any one or more than one the combination in toluene, dimethylbenzene, aniline, N-BUTYL ACETATE, butyl glycol ether and the Diethylene Glycol butyl ether, and described solidifying agent is methyl-etherified melamine resin or butyl ether melamine resin.
In a preferred embodiment of the present invention, described pigment comprises that carbon black, iron oxide black, chromic acid are black, any one or more than one the combination in ultramarine, medium chrome yellow medium yellow, phthalocyanine blue and phthalein viridescent, pearl white, the toluidine red.
In a preferred embodiment of the present invention, described auxiliary agent comprises any one or more than one the combination in wetting dispersing agent, flow agent, adhesion promoter, anti-settling agent, defoamer and the wear-resisting scratch-resisting agent.
In a preferred embodiment of the present invention, described changeable colors along with angle powder comprises any one or more than one the combination in aluminum oxide, magnesium fluoride and the chromic oxide metal oxide of multilayer chip; Described interference of light powder comprises any one or its combination in glass flake, pearlescence, the quartzy thin slice.
In a preferred embodiment of the present invention, the particle diameter of described changeable colors along with angle powder is 10-200 μ m, and the particle diameter of described interference of light powder is 10-100 μ m.
In a preferred embodiment of the present invention, described pH value conditioning agent is an organic alcohol amine class pH value conditioning agent, and described organic alcohol amine class pH value conditioning agent comprises any one or its combination in GX-3 organic alcohol amine compounds, WD-150 organic alcohol amine compounds, M70 organic alcohol amine compounds or the M75 organic alcohol amine compounds.
Another object of the present invention is to provide the using method of chameleon coating on color coating layer steel plate, by chameleon coating being used in combination at color coating layer steel plate, steel plate class and extended use can be promoted, and the work-ing life of color coating layer steel plate can be prolonged.
A kind of chameleon coating is in the using method of color coating layer steel plate:
To comprise meter by weight: the chameleon coating of matrix material 10-40 part, filler 1-20 part, solvent 1-25 part, solidifying agent 3-20 part, pigment 1-10 part, auxiliary agent 1-10 part and changeable colors along with angle powder 1-10 part is coated in the color coating layer surface formation changeable colors along with angle layer of color coating layer steel plate with the thickness of 10-200 μ m;
The changeable colors along with angle layer is dried;
To comprise meter by weight: the chameleon coating of matrix material 10-50 part, filler 1-20 part, solvent 1-20 part, solidifying agent 2-10 part, pigment 1-5 part, auxiliary agent 1-10 part and interference of light powder 1-10 part is coated in the surface formation interference of light layer of changeable colors along with angle layer with the thickness of 10-100 μ m;
Interference of light layer is dried.
The present invention has also disclosed a kind of new type colorful coating layer steel plate, possesses the performance of changeable colors along with angle, thereby has expanded the function and the use range of steel plate.
A kind of color coating layer steel plate, comprise: the color coating layer steel plate substrate that is provided with color coating layer, described color coating layer is provided with the changeable colors along with angle layer, be provided with interference of light layer on the surface of changeable colors along with angle layer, described changeable colors along with angle layer is by comprising meter by weight: the chameleon coating of matrix material 10-40 part, filler 1-20 part, solvent 1-25 part, solidifying agent 3-20 part, pigment 1-10 part, auxiliary agent 1-10 part and changeable colors along with angle powder 1-10 part forms through applying oven dry; Described interference of light layer is by comprising meter by weight: the chameleon coating of matrix material 10-50 part, filler 1-20 part, solvent 1-20 part, solidifying agent 2-10 part, pigment 1-5 part, auxiliary agent 1-10 part and interference of light powder 1-10 part forms through applying oven dry.
The present invention is directed to the changeable colors along with angle layer and the interference of light layer of color coating layer steel plate, chameleon coating has targetedly been proposed respectively, make both in use can play complementary action, can not interfere and conflict each other, can directly be coated on bright and clean surface; And by two kinds of novel chameleon coating uses on color coating layer steel plate, make color coating layer steel plate possess chameleon effect with different angles or different light rays change different colours, thereby can improve false proof, the sight and the ornamental and corrosion resistance nature of product such as furniture and household electrical appliances, easy to use; The color coating layer steel plate that the present invention discloses can promote the class of color coating layer steel plate and expand purposes, and can prolong the work-ing life of color coating layer steel plate.
Description of drawings
Embodiment
Below in conjunction with accompanying drawing preferred embodiment of the present invention is described in detail, thereby protection scope of the present invention is made more explicit defining so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that.
Embodiment
Embodiment 1:
Following table is the prescription of the chameleon coating of formation embodiments of the invention 1:
Embodiment 2:
Following table is the prescription of embodiments of the invention 2:
Embodiment 3:
Following table is the prescription of embodiments of the invention 3:
Embodiment 4:
Following table is the prescription of embodiments of the invention 4:
Embodiment 5:
Following table is the prescription of embodiments of the invention 5:
In the foregoing description mentioned pH value conditioning agent be organic alcohol amine class pH value conditioning agent also promptly: GX-3 organic alcohol amine compounds, WD-150 organic alcohol amine compounds, M70 organic alcohol amine compounds and the M75 organic alcohol amine compounds that is provided by sky, Beijing, BeiJing, China city letter commerce and trade limited liability company all preferably is provided for GX-3, WD-150, M70 and M75 organic alcohol amine compounds.
Mentioned wetting dispersing agent, flow agent, adhesion promoter, anti-settling agent, defoamer and wear-resisting scratch-resisting agent all preferably uses the model by the production and sales of U.S. Mei Liken chemical industry Group Co.,Ltd to be NSF163 type wetting dispersing agent, LK418 type flow agent, NSF304 type adhesion promoter, 180P type anti-settling agent, NSF063A type defoamer and the agent of NSF790 type wear-resisting scratch-resisting in the foregoing description.
First component of arbitrary embodiment of the foregoing description 1-5 is mixed,, obtain chameleon coating as the changeable colors along with angle layer through high speed dispersion with after grinding; Second component of arbitrary embodiment of the foregoing description 1-5 is mixed,, obtain chameleon coating as interference of light layer through high speed dispersion with after grinding.
By the technique effect of resulting first, second component of the foregoing description 1-5 by shown in the following table:
| Project | Embodiments of the invention 1-5 |
| Condition in container | No lump is uniform state after the stirring |
| The curved value of T | ??≤3T |
| Reverse impact (joule) | ??≥9J |
| Project | Embodiments of the invention 1-5 |
| Salt spray resistance | 480h is non-foaming, and nothing comes off |
| The artificial weathering ageing resistance | 500h is non-foaming, and nothing comes off, flawless |
| Organic solvent-resistant test (butanone) | 100 times no abnormal |
| Coatingsurface chameleon variable color kind | ??≥5 |
To being coated in uniformly on the smooth steel plate by the resulting chameleon coating of the foregoing description 1-5, the mensuration of the chameleon effect of the coating that forms is as follows:
Determining instrument uses the albedo measurement instrument, and the experimental record during test is by shown in the following table:
| Thickness/μ m (coat-thickness) | ??25 | ??40 | ??100 | ??220 | ??300 |
| The coatingsurface of chameleon coating of the present invention is with angle variable color color category | ??5 | ??5 | ??7 | ??6 | ??5 |
| The coatingsurface of common coating model is with angle variable color color category | ??1 | ??1 | ??1 | ??1 | ??1 |
Application examples 1:
Referring to accompanying drawing 1, the resulting chameleon coating of arbitrary embodiment of the foregoing description 1-5 is applied on the color coating layer steel plate, specifically: first component is coated on coating roller on the surface-treated layer 2 of a side of color coating layer steel plate substrate 3, form changeable colors along with angle layer 5, after the drying, second component is coated the surface of changeable colors along with angle layer 5 with coating roll, surface at changeable colors along with angle layer 5 forms interference of light layer 6, drying again, obtain by Chameleonic colored coating steel plate shown in the drawings, in the present embodiment, the thickness of changeable colors along with angle layer 5 and interference of light layer 6 respectively is 40 μ m.Opposite side at color coating layer steel plate substrate 3 is respectively arranged with surface-treated layer 2 and back layer 1, and back layer 1 forms by common baking vanish.
Application examples 2:
Only the thickness with changeable colors along with angle layer 5 and interference of light layer 6 changes 200 μ m and 100 μ m respectively into, and all the other are all with the description to embodiment 1.
Application examples 3:
Increase operation before will applying changeable colors along with angle layer 5, on the surface-treated layer 2 of a side surface of color coating layer steel plate substrate 3, apply common primer base, form and hide chromatograph 4, after the drying, first component is coated the surface that hides chromatograph 4 with coating roll, form changeable colors along with angle layer 5 on the surface that hides chromatograph 4, after the drying, second component is coated the surface of changeable colors along with angle layer 5 with coating roll, surface at changeable colors along with angle layer 5 forms interference of light layer 6, drying will hide chromatograph 4 again, the thickness of changeable colors along with angle layer 5 and interference of light layer 6 respectively changes 10 μ m into, all the other all with the description of application examples 1.
The resulting Chameleonic colored coating steel plate of above-mentioned application examples has the technique effect shown in the following table after tested:
From above-mentioned example as can be seen, the present invention is by two kinds of novel chameleon coating uses on color coating layer steel plate, make color coating layer steel plate possess chameleon effect with different angles or different light rays change different colours, thereby can improve false proof, the sight and the ornamental and corrosion resistance nature of product such as furniture and household electrical appliances, easy to use; The color coating layer steel plate that the present invention discloses can promote the class of color coating layer steel plate and expand purposes, and can prolong the work-ing life of color coating layer steel plate
The above; it only is the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (10)
1. a chameleon coating is characterized in that, comprises the raw material of following parts by weight: matrix material 10-40 part, filler 1-20 part, solvent 1-25 part, solidifying agent 3-20 part, pigment 1-10 part, auxiliary agent 1-10 part and changeable colors along with angle powder 1-10 part.
2. a chameleon coating is characterized in that, comprises the raw material of following parts by weight: matrix material 10-50 part, filler 1-20 part, solvent 1-20 part, solidifying agent 2-10 part, pigment 1-5 part, auxiliary agent 1-10 part and interference of light powder 1-10 part.
3. chameleon coating according to claim 1 and 2 is characterized in that, described chameleon coating comprises that also parts by weight are not more than 1 part pH value conditioning agent.
4. chameleon coating according to claim 1 and 2, it is characterized in that described matrix material package is drawn together any one or more than one the combination in Resins, epoxy, saturated polyester resin, polyvinyl chloride (PVC) RESINS, acrylic resin, silicon modified polyesters resin, polyvinylidene fluoride resin and the urethane.
5. chameleon coating according to claim 1 and 2, it is characterized in that described pigment comprises that carbon black, iron oxide black, chromic acid are black, any one or more than one the combination in ultramarine, medium chrome yellow medium yellow, phthalocyanine blue and phthalein viridescent, pearl white, the toluidine red.
6. according to claim 1 and 2 described chameleon coating, it is characterized in that described changeable colors along with angle powder comprises any one or more than one the combination in aluminum oxide, magnesium fluoride and the chromic oxide metal oxide of multilayer chip; Described interference of light powder comprises any one or its combination in glass flake, pearlescence, the quartzy thin slice.
7. chameleon coating according to claim 6 is characterized in that, the particle diameter of described changeable colors along with angle powder is 10-200 μ m, and the particle diameter of described interference of light powder is 10-100 μ m.
8. chameleon coating according to claim 3, it is characterized in that, described pH value conditioning agent is an organic alcohol amine class pH value conditioning agent, and described organic alcohol amine class pH value conditioning agent comprises any one or its composition in GX-3 organic alcohol amine compounds, WD-150 organic alcohol amine compounds, M70 organic alcohol amine compounds or the M75 organic alcohol amine compounds.
9. a chameleon coating is in the using method of color coating layer steel plate:
To comprise meter by weight: the chameleon coating of matrix material 10-40 part, filler 1-20 part, solvent 1-25 part, solidifying agent 3-20 part, pigment 1-10 part, auxiliary agent 1-10 part and changeable colors along with angle powder 1-10 part is coated in the color coating layer surface formation changeable colors along with angle layer of color coating layer steel plate with the thickness of 10-200 μ m;
The changeable colors along with angle layer is dried;
To comprise meter by weight: the chameleon coating of matrix material 10-50 part, filler 1-20 part, solvent 1-20 part, solidifying agent 2-10 part, pigment 1-5 part, auxiliary agent 1-10 part and interference of light powder 1-10 part is coated in the surface formation interference of light layer of changeable colors along with angle layer with the thickness of 10-100 μ m;
Interference of light layer is dried.
10. color coating layer steel plate, comprise: the color coating layer steel plate substrate that is provided with color coating layer, described color coating layer is provided with the changeable colors along with angle layer, be provided with interference of light layer on the surface of changeable colors along with angle layer, it is characterized in that: described changeable colors along with angle layer is by comprising meter by weight: the chameleon coating of matrix material 10-40 part, filler 1-20 part, solvent 1-25 part, solidifying agent 3-20 part, pigment 1-10 part, auxiliary agent 1-10 part and changeable colors along with angle powder 1-10 part forms through applying oven dry; Described interference of light layer is by comprising meter by weight: the chameleon coating of matrix material 10-50 part, filler 1-20 part, solvent 1-20 part, solidifying agent 2-10 part, pigment 1-5 part, auxiliary agent 1-10 part and interference of light powder 1-10 part forms through applying oven dry.
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| CN201010142353.7A CN101824263B (en) | 2010-04-09 | 2010-04-09 | Chameleon coating, use method thereof on colored coating steel plate and colored coating steel plate |
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| CN109608965A (en) * | 2018-11-26 | 2019-04-12 | 浙江万丰摩轮有限公司 | A kind of preparation method of light-operated discoloration colorful aluminium alloy wheel hub |
| CN109608965B (en) * | 2018-11-26 | 2020-09-18 | 浙江万丰摩轮有限公司 | Preparation method of light-operated color-changing colorful aluminum alloy hub |
| CN112724804A (en) * | 2020-12-29 | 2021-04-30 | 老虎表面技术新材料（清远）有限公司 | Powder coating composition with color changing effect and coating thereof |
| CN116162374A (en) * | 2023-02-23 | 2023-05-26 | 首钢集团有限公司 | Antibacterial chameleon composite coating, color steel plate and preparation method and application thereof |
| CN116162374B (en) * | 2023-02-23 | 2024-05-10 | 首钢集团有限公司 | Antibacterial chameleon composite coating, color steel plate and preparation method and application thereof |
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