CN107129715A - Special airless spraying interior wall sealing wax of engineering and preparation method thereof - Google Patents
Special airless spraying interior wall sealing wax of engineering and preparation method thereof Download PDFInfo
- Publication number
- CN107129715A CN107129715A CN201710323800.0A CN201710323800A CN107129715A CN 107129715 A CN107129715 A CN 107129715A CN 201710323800 A CN201710323800 A CN 201710323800A CN 107129715 A CN107129715 A CN 107129715A
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- CN
- China
- Prior art keywords
- parts
- special
- interior wall
- airless spraying
- wall sealing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005507 spraying Methods 0.000 title claims abstract description 48
- 239000012173 sealing wax Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims description 11
- 238000012407 engineering method Methods 0.000 title description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000000839 emulsion Substances 0.000 claims abstract description 60
- 239000003973 paint Substances 0.000 claims abstract description 52
- 229920000642 polymer Polymers 0.000 claims abstract description 49
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 45
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 45
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 45
- 235000010215 titanium dioxide Nutrition 0.000 claims abstract description 31
- 229920002678 cellulose Polymers 0.000 claims abstract description 21
- 235000010980 cellulose Nutrition 0.000 claims abstract description 21
- 241001417490 Sillaginidae Species 0.000 claims abstract description 12
- 238000005703 Whiting synthesis reaction Methods 0.000 claims abstract description 12
- 230000009477 glass transition Effects 0.000 claims abstract description 11
- GANNOFFDYMSBSZ-UHFFFAOYSA-N [AlH3].[Mg] Chemical compound [AlH3].[Mg] GANNOFFDYMSBSZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000391 magnesium silicate Substances 0.000 claims abstract description 4
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 33
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical class O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 33
- 238000002156 mixing Methods 0.000 claims description 32
- 239000004642 Polyimide Substances 0.000 claims description 31
- 229920001721 polyimide Polymers 0.000 claims description 31
- 239000002270 dispersing agent Substances 0.000 claims description 30
- 239000003755 preservative agent Substances 0.000 claims description 30
- 239000002904 solvent Substances 0.000 claims description 30
- 239000000080 wetting agent Substances 0.000 claims description 30
- 230000002335 preservative effect Effects 0.000 claims description 29
- 125000000217 alkyl group Chemical group 0.000 claims description 28
- 239000004408 titanium dioxide Substances 0.000 claims description 28
- 239000013530 defoamer Substances 0.000 claims description 27
- 241000276489 Merlangius merlangus Species 0.000 claims description 25
- 239000002562 thickening agent Substances 0.000 claims description 23
- -1 carbon ester Chemical class 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 22
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000003112 inhibitor Substances 0.000 claims description 18
- 239000001913 cellulose Substances 0.000 claims description 17
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 16
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 11
- 229920002125 Sokalan® Polymers 0.000 claims description 11
- 239000003513 alkali Substances 0.000 claims description 11
- 150000002460 imidazoles Chemical group 0.000 claims description 11
- 239000004584 polyacrylic acid Substances 0.000 claims description 11
- 229920000570 polyether Polymers 0.000 claims description 11
- 239000004800 polyvinyl chloride Substances 0.000 claims description 11
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 11
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical group CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 11
- 159000000000 sodium salts Chemical class 0.000 claims description 11
- 230000008719 thickening Effects 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 239000004593 Epoxy Substances 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical class [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 7
- 230000007547 defect Effects 0.000 abstract description 2
- 239000004816 latex Substances 0.000 abstract 1
- 229920000126 latex Polymers 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 24
- 238000000576 coating method Methods 0.000 description 24
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 16
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 229910052901 montmorillonite Inorganic materials 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 239000000440 bentonite Substances 0.000 description 9
- 229910000278 bentonite Inorganic materials 0.000 description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 description 8
- 239000010410 layer Substances 0.000 description 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- FEXXLIKDYGCVGJ-UHFFFAOYSA-N butyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCC1OC1CCCCCCCC(=O)OCCCC FEXXLIKDYGCVGJ-UHFFFAOYSA-N 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 150000003949 imides Chemical group 0.000 description 5
- 239000011229 interlayer Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002966 varnish Substances 0.000 description 5
- UOFGSWVZMUXXIY-UHFFFAOYSA-N 1,5-Diphenyl-3-thiocarbazone Chemical compound C=1C=CC=CC=1N=NC(=S)NNC1=CC=CC=C1 UOFGSWVZMUXXIY-UHFFFAOYSA-N 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 4
- 238000005034 decoration Methods 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 238000002798 spectrophotometry method Methods 0.000 description 4
- 239000004927 clay Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000000889 atomisation Methods 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 244000309464 bull Species 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical class 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
- 239000004811 fluoropolymer Substances 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 229910052615 phyllosilicate Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 230000009974 thixotropic effect Effects 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- VPJOGDPLXNTKAZ-UHFFFAOYSA-N 2-methylpropanoic acid;2,2,4-trimethylpentane-1,3-diol Chemical class CC(C)C(O)=O.CC(C)C(O)C(C)(C)CO VPJOGDPLXNTKAZ-UHFFFAOYSA-N 0.000 description 1
- NNOHXABAQAGKRZ-UHFFFAOYSA-N 3,5-dinitrobenzoyl chloride Chemical compound [O-][N+](=O)C1=CC(C(Cl)=O)=CC([N+]([O-])=O)=C1 NNOHXABAQAGKRZ-UHFFFAOYSA-N 0.000 description 1
- SJZRECIVHVDYJC-UHFFFAOYSA-N 4-hydroxybutyric acid Chemical compound OCCCC(O)=O SJZRECIVHVDYJC-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229910001579 aluminosilicate mineral Inorganic materials 0.000 description 1
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GCAIEATUVJFSMC-UHFFFAOYSA-N benzenetetracarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1C(O)=O GCAIEATUVJFSMC-UHFFFAOYSA-N 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000003694 hair properties Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The special airless spraying interior wall sealing wax of engineering is provided, it is included according to mass fraction meter, 8.5 11 parts of polymer emulsions, 36 parts of Nanometer Titanium Dioxides, 10 15 parts of kaolin, 20 40 parts of coarse whitings, 0.3 0.5 parts of celluloses and 0.1 0.2 parts of aluminium-magnesium silicates；Wherein, the mass percent of styrene is 35 45% in polymer emulsion, and OH mass percent is 4 10%, MFT<0 DEG C, glass transition temperature is 30 50 DEG C.Compared with generic latex paint, cost performance of the present invention is high, and combination property is strong, strong adaptability, and airless spraying is without orange peel, shrinkage cavity, the film defect such as pinprick.
Description
Technical field
The present invention relates generally to paint field, more particularly to the special airless spraying interior wall sealing wax of engineering and its preparation side
Method.
Background technology
As the improvement of people's living standards, requirement to house also more and more higher, public domain environmental requirement is increasingly
Height, aligned environment is become better and better, service quality more and more higher, how to meet the demand of people, and as program of real estate enterprise, building is applied
Work enterprise, decoration enterprise, property management etc. is common the problem of consider.Program of real estate enterprise is construction blank many years ago
Room, or only to public domain, such as corridor, underground garage etc. carries out simply scraping ash, and in recent years, more program of real estate enterprise
In view of the demand of owner, decorations are carried out to public domain, building quality is lifted, client satisfaction is allowed, are decorated style
Emerge in an endless stream, patch block is plastered, Puttying, swabbing, brush emulsion paint pastes a variety of styles such as marble and deposited, and simply smears
Ash, Puttying can not reach ideal effect, or even when corridor is walked about, easily fall ash, influence owner, or paste Dali
Stone, the lifting grade such as ceramic tile, so that Building Checks Price is influenceed, therefore a kind of economical and practical emulsion paint turns into current real estate enterprise
Industry, the optimal selection of decoration enterprise and property management can not only reach good decorative effect, and cost also will not
Significantly improve, and physical life is longer, just there is good scouring performance and fungicidal properties.
When presently relevant enterprise uses or promotes emulsion paint, still constructed using roller applications, not only construction cost is high, effect
Rate is low, and easily causes that coating surface slivering is serious, and rough surface influences attractive in appearance, during spraying, easily occurs shrinkage cavity, the disadvantage such as pinprick.
The content of the invention
In order to solve above-mentioned partial technical problems, the present inventor has found after extensive studies it, the invention provides
A kind of special airless spraying interior wall sealing wax of engineering, the product has good levelability, and prominent covering power, paint film is fine and smooth, and symbol
National bull's eye product requirement is closed, belongs to environmental type product.Specifically, the present invention includes herein below：
An aspect of of the present present invention is there is provided the special airless spraying interior wall sealing wax of engineering, and it is included according to mass fraction meter,
8.5-11 parts of polymer emulsions, 3-6 parts of Nanometer Titanium Dioxides, 10-15 parts of kaolin, 20-40 parts of coarse whitings, 0.3-0.5 parts of celluloses and
0.1-0.2 parts of aluminium-magnesium silicates；
Wherein, the mass percent of styrene is 35-45% ,-OH mass percent 4- in the polymer emulsion
10%, MFT<0 DEG C, glass transition temperature is 30-50 DEG C.
In some embodiments, in the special airless spraying interior wall sealing wax of described engineering, the polymer emulsion has 25-
35 parts of styrene, 5-10 parts of polyvinyl chloride, 1-5 parts of butyl epoxy stearates, 10-15 parts of polyimides and the carbon of 20-25 parts 12
Ester is constituted.
In some embodiments, in the special airless spraying interior wall sealing wax of described engineering, the polyimides be containing
The polyimides of alkyl side chain and phenyl ring；
Wherein, the alkyl side chain number is 12-15, and the phenyl ring number is 12-15.
In some embodiments, in the special airless spraying interior wall sealing wax of described engineering, in addition to modified organic swelling
Soil；And
The mass ratio of the Nanometer Titanium Dioxide, the kaolin and the coarse whiting sum and the organic modified bentonite is 1:
0.5-1.2。
In some embodiments, in the special airless spraying interior wall sealing wax of described engineering, the kaolin is particle diameter
The calcined kaolin of 4000 mesh, the coarse whiting is the powdered whiting of the mesh of particle diameter 800.
In some embodiments, in the special airless spraying interior wall sealing wax of described engineering, in addition to according to mass fraction
Following components of meter：
0.8-1 parts of environmentally friendly solvents, 0.5-0.8 parts of dispersants, 0.1-0.2 parts of wetting agents, 0.1-0.3 parts of defoamers, 0.1-
0.3 portion of preservative, 0.5-0.8 parts of mould inhibitors and 0.2-0.3 parts of thickeners.
In some embodiments, in the special airless spraying interior wall sealing wax of described engineering,
The environmentally friendly solvent is propane diols or/and ethylene glycol；
The dispersant is polyacrylic acid sodium salt, and its solid content is 40%；
The wetting agent is fatty alcohol alkoxy compound；
The defoamer is polysiloxane-polyether copolymer emulsion；
The preservative is imidazoles；With
The thickener is that hydrophobically-modified alkali is swelled class thickening.
An aspect of of the present present invention is there is provided the preparation method of the special airless spraying interior wall sealing wax of engineering, and it includes,
Cellulose, aluminium-magnesium silicate and deionized water are added in paint mixing tank, 15- is stirred under 400-600r/min rotating speeds
25min；
Environmentally friendly solvent, dispersant, wetting agent, defoamer, preservative and mould inhibitor are sequentially added into the paint mixing tank,
1-5min is stirred under 400-600r/min rotating speeds；
Under 700-900r/min rotating speeds, Nanometer Titanium Dioxide is added into the paint mixing tank successively, and in 1000-1200r/
Under min rotating speeds, 25-35min is stirred, to fineness≤55um；
Polymer emulsion, coalescents are added under 400-600r/min rotating speeds into the paint mixing tank, 2-5min are stirred, directly
Viscosity is 100-105KU to 21-25 DEG C.
Beneficial effect：
The special airless spraying interior wall sealing wax of engineering of the present invention, with the thixotropic emulsion of the polymer rich in styrene
The special airless spraying interior wall sealing wax of engineering prepared for base-material, addition functional aid, the product has good levelability, dashes forward
Go out covering power (contrast ratio ＞ 0.93) paint film fine and smooth, II grades of mildew resistance, and meet national bull's eye product requirement, belong to environmental protection
Type product.It is convenient for production, also using independent raw material choosing method, it can be used for indoor different zones decorations demand,
And with good mildew resistance, scrub performance improves paint film service life.
In the special airless spraying interior wall sealing wax of engineering of the present invention, with the thixotropic breast of the polymer rich in styrene
Liquid is base-material, coordinates low-shear viscosity, and high yield polyurethanes thickener adjusts product thixotropy, improves spraying atomization
Efficiency and the parcel ability to color stuffing, improve coating surface hardness, and feel improves scrub performance ＞ 3000 times.
In the special airless spraying interior wall sealing wax of engineering of the present invention, with organic modified bentonite, nano-TiO2With it is poly-
Polymer resin is constituted, and organic modified bentonite mutually forms equally distributed three-dimensional network structure with polymer, meanwhile, in net
Nano-TiO is uniformly distributed in network structure2, mixed according to filler with organic modified bentonite according to predetermined ratio, enhancement engineering is special
With the albedo of airless spraying interior wall sealing wax, and then improve the covering power of the special airless spraying interior wall sealing wax of engineering.
Embodiment
Now describe the various exemplary embodiment of the present invention in detail, the detailed description is not considered as the limit to the present invention
System, and it is understood as the more detailed description to certain aspects of the invention, characteristic and embodiment.
It should be understood that heretofore described term is only to be to describe special embodiment, this hair is not intended to limit
It is bright.In addition, for the number range in the present invention, it is thus understood that it is also specifically disclosed that every between the upper and lower bound of the scope
Individual median.Median and any other statement value in any statement value or stated ranges or in the scope in
Between each less scope between value be also included in the present invention.These small range of upper and lower bounds can independently include
Or exclude in the range of.
Unless otherwise stated, all technologies used herein and scientific terminology have the routine in field of the present invention
The identical meanings that technical staff is generally understood that.Although the present invention only describes preferred method and material, the present invention's
Implement or can also be used and similar or equivalent any method described herein and material in testing.The institute mentioned in this specification
There is document to be incorporated by reference into, the method related to the document to disclosure and description and/or material.It is incorporated to any
When document conflicts, it is defined by the content of this specification.
In the present invention, vocabulary of terms both includes singulative, also including plural form, unless context separately clearly refers to
Go out.Heretofore described " at least one " refers not only to the situation comprising " one " or " one kind ", prior also comprising " many
It is individual " or " a variety of " situation.
In the present invention, airless spraying technology is also known as airless spraying, is that need not spray to make coating by compressed air
Atomization, but applying high pressure to coating makes the technique that expectation is atomized when spraying.Airless spraying is to reduce the loss of coating, subtract
Few pollution to air, improves the efficiency of coating operation.Airless spraying is that coating is applied into high pressure (being usually 11-25MPa), is made
It sprays from paint spray nozzle, when coating shoots out out the moment of nozzle, just occurs fierceness with air with the speed for being up to 100m/s
Collide at a high speed, coating is broken into particulate, before the speed of coating ion does not decay, coating data continues continuous with air forward
Repeatedly collide, it is pulverized that coating ion is not put, and is atomized coating, and stick to coated article surface.
The special airless spraying interior wall sealing wax of engineering is provided in the present invention, it includes, 8.5-11 parts of polymer emulsions, 3-6 parts
Nanometer Titanium Dioxide, 10-15 part kaolin, 20-40 parts of coarse whitings, 0.3-0.5 parts of celluloses and 0.1-0.2 parts of aluminium-magnesium silicates；
Wherein, in the polymer emulsion mass percent 35-45% ,-OH of styrene mass percent 4-10%,
MFT<0 DEG C, glass transition temperature is 30-50 DEG C.
Further, the cellulose is hydroxyethyl cellulose, and 2% solution is 1500- in 25 DEG C of viscosity
2500mPa.s.。
The micro- block of styrene can increase molecule chain rigidity in polymer emulsion, cause the modulus of elasticity of rubber to increase,
Reduction paint film strength, elasticity, cold resistance and wearability.
In the present invention, the polymer emulsion is by 25-35 parts of styrene, 5-10 parts of polyvinyl chloride, 1-5 parts of epoxystearic acids
Butyl ester, 10-15 part polyimides and the carbon ester of 20-25 parts 12 composition.
Butyl epoxy stearate is mutually dissolved in polyvinyl chloride, using the luminous reflectanc of butyl epoxy stearate, meanwhile,
Butyl epoxy stearate is to nano-TiO2Surface oleophylic modification is carried out, makes the carboxyl in stearic acid to nano-TiO2The hydroxyl on surface
Generation esterification, forms monomolecular film on paint surface, improves the albedo of fluoropolymer resin.
Polyimides is a kind of aromatic heterocyclic polymer containing imide ring in main chain, with excellent resistance to elevated temperatures,
Dielectric properties and mechanical property.
12 carbon esters are alcohol ester-12, and molecular formula is 2,2,4- trimethyl -1,3 pentanediol mono isobutyrates, also known as 12 carbon
Ester, alcohol ester-12 strong adaptability, consumption is few to have good stability under different PH environment, and film forming is closely knit.
In the present invention, the polyimides is the polyimides containing alkyl side chain and phenyl ring；
Wherein, the alkyl side chain number is 12-15, and the phenyl ring number is 12-15.
It is raw material using benzenediol, bromo n-alkane and 3,5- dinitrobenzoyl chloride, through etherified, esterification and catalysis
Hydrogenation etc. step synthesis the diamine monomer 3 containing alkyloxy side chain, 5- diaminobenzoic acid -4 '-alkoxy phenyl esters, and respectively with
Double [the 4- hydroxy acid phenoxyls phenyl] propane dianhydrides of benzene tetracarboxylic acid acid anhydride, BP-3,3 ', 4,4 '-tetracarboxylic acid dianhydride and 2,2-
The Kapton containing alkyl side chain is prepared in reaction.Polyimides containing alkyl side chain is in visible-near ultraviolet region
Light transmittance reduced with the increase of alkyl side chain, increase polyimides luminous reflectanc, and polyimides light reflection
Ability strengthens with the increase of the quantity of phenyl ring, and alkyl side chain number is 14, phenyl ring number in the polyimides containing alkyl side chain
It is 15 for 14, or alkyl side chain number, phenyl ring number is 15, or alkyl side chain number is 16, phenyl ring number is 16.
Meanwhile, the polyimides containing alkyl side chain and the continuous phase with dimensional network structure improve and contain alkyl side
The surface tension and heat endurance of the polyimides of chain, lift the light reflective properties and stability of water-in-water multicolor coating.
In the continuous phase with dimensional network structure, nano-TiO is filled2, fluoropolymer resin and filler, improve reflection every
The spatial configuration of hot water-in-water multicolor coating, on the basis of the luminous reflectanc of lifting water-in-water multicolor coating, improves water bag
The insulating power of water multicolor finish.
Covering power is a kind of optical properties, and the degree of reflection of light directly affects the height of covering power.The engineering of the present invention
In the special polymer emulsion without gas coating interior wall sealing wax, polyvinyl chloride, butyl epoxy stearate and polyimides development are utilized
Into the high polymer emulsion of albedo, the polymer emulsion of high reflection power improves the special airless spraying interior wall sealing wax of engineering
Covering power.
In the present invention, in addition to organic modified bentonite；
The mass ratio of Nanometer Titanium Dioxide, kaolin and coarse whiting sum and the organic modified bentonite is 1:0.5-1.2.Enter one
Step ground, the kaolin is the calcined kaolin of the mesh of particle diameter 4000, and the coarse whiting is the powdered whiting of the mesh of particle diameter 800.
Bentonite is also named montmorillonite, have the title of " omnipotent " clay.General white, grey, pink and rate loess etc.
Multiple color.Sodium base bentonite is divided into according to the species of bentonite interlayer cation, it is calcium-base bentonite, hydrogen-based bentonite, organic
Bentonite.Bentonite is the clay that a kind of montmorillonite is main component, and montmorillonite is layer aluminosilicate mineral, there is two (Si-
Al) one [Al (Mg, Fe)-(O, OH)] octahedral layer composition of folder in the middle of-O tetrahedral layers.Belong to 3 layers of clay mineral of TOT types,
Rich in the crystallization water, interlayer carries negative electrical charge, can adsorb Mg2+、Ca2+、Na+、k+Deng cation.Bentonitic performance is depended primarily on
Montmorillonite species and content contained by it, it has very strong hygroscopicity, and water swelling easily forms the gel of thixotroping class, in water
Dispersion layer soliquid in medium, its dense dispersion has the characteristic of typical shear shinning, after shear action is stopped,
Because system has positive thixotropy, the extension over time of its structure and be gradually restored, and then the viscosity of system is had
Gone up.In addition, also there is huge surface area, thus ion-exchange capacity and adsorption capacity are very strong.
Montmorillonite mineral crystal structure is a kind of phyllosilicate, and the aliovalent class matter of cation is there is in its construction unit layer
Isomorphous replacement, such as Al3+It may replace the Si in silicon-oxy tetrahedron4+, Fe2+Or Mg2+Replace the Al in alumina octahedral3+, just produce
Interlayer negative electrical charge.The negative electrical charge of montmorillonite is mainly due to Mg2+Replace a part of Al in alumina octahedral3+Produced, and
Interlayer is distributed in, so that " macroanion " of the montmorillonite structure cell just as a Liquidity limit.But most of this kind of negative electrical charge point
Between the cation adsorbed on the negative electrical charge and Clay Minerals And Clay Oxides plate face being distributed in the plate face of phyllosilicate, aluminum oxide octahedral sheet
It is distant, so, weaker cation binding force promotes cation exchange.Cation exchange capacity (CEC) is that montmorillonite is most important
Feature.Therefore, when bentonite is scattered in coating, polyvinyl alcohol, acrylic acid, polyvinyl acetate, hydroxy ethyl fiber in coating
Polar group-OH ,-the COOH ,-CH of the organic molecules such as element, carboxymethyl cellulose2CH2OH etc., by the montmorillonite layer in bentonite
Between negative electrical charge attracted, and then insert interlayer, formed " montmorillonite-organic molecule " compound.This compound has in coating
There is anti-settling effect, because montmorillonite is cross-linked with each other to form equally distributed three-dimensional network structure with organic molecule, this stands
The suspension effect that body net can have been realized.Again because organic molecule can enter between montmorillonite layer, so as to increase the denseness of coating.This
Montmorillonite organic double compound after kind of generation has irreversible characteristic, after dehydration lyophobic dust, therefore add painting
The water resistance of film.
Further, engineering is special without gas coating interior wall sealing wax in the present invention, in addition to, 0.8-1 parts of environmentally friendly solvents, 0.5-
0.8 part of dispersant, 0.1-0.2 parts of wetting agents, 0.1-0.3 parts of defoamers, 0.1-0.3 portions of preservatives, 0.5-0.8 parts of mould inhibitors and
0.2-0.3 parts of thickeners.
Further, environmentally friendly solvent is propane diols or/and ethylene glycol；The dispersant is polyacrylic acid sodium salt, and it contains admittedly
Measure as 40%；The wetting agent is fatty alcohol alkoxy compound；The defoamer is polysiloxane-polyether copolymer emulsion；Institute
Preservative is stated for imidazoles；It is that hydrophobically-modified alkali is swelled class thickening with the thickener.
Covering power of the present invention is by referring to national national standard《GB/T 1726-1979 coating covers amylograph》Come
Test.
Surface drying time of the present invention is by referring to national standard《GB/T 6753.2-1986 coating surface drying experiments
Ballotini method》To test.
Contrast ratio of the present invention is by referring to national standard《GB/T23981-2009 whites and light colour paint contrast ratio
Determine》To test.
Water resistance of the present invention is by referring to national standard《GB/T 1733-1993 paint film water resistance determination methods》Come
Test.
VOC of the present invention passes through national standard《GB/T 23986-2009 paint and varnish is waved
The measure gas chromatography of hair property organic compound (VOC) content》To test.
Formaldehyde of the present invention passes through national standard《The measure of content of formaldehyde in GB/T 23993-2009 water paints
Acetylacetone,2,4-pentanedione AAS》To test.
Lead content of the present invention passes through national standard《GB/T 9758.1-1988 paint and varnish " soluble metals
The measure of content " part 1：The measure NITRATE BY FLAME ATOMIC of lead content draws spectroscopic methodology and dithizone spectrophotometry》To test.
Cadmium content of the present invention passes through national standard《GB/T 9758.4-1988 paint and varnish " soluble metals
The part of the measure of content " the 4th：The measure NITRATE BY FLAME ATOMIC of cadmium content draws spectroscopic methodology and dithizone spectrophotometry》To test.
Content of 6-valence Cr ions of the present invention passes through national standard《GB/T 9758.5-1988 paint and varnish is " soluble
The part of the measure of tenor " the 5th：The measure NITRATE BY FLAME ATOMIC of content of 6-valence Cr ions draws spectroscopic methodology and dithizone spectrophotometry》
To test.
Tribute content of the present invention passes through national standard《GB/T 9758.7-1988 paint and varnish " soluble metals
The part of the measure of content " the 7th：The measure NITRATE BY FLAME ATOMIC of tribute content draws spectroscopic methodology and dithizone spectrophotometry》To test.
Embodiment
Embodiment 1
A kind of special airless spraying interior wall sealing wax of engineering, it is included according to mass fraction meter, 8.5 parts of polymer emulsions, 3
Part Nanometer Titanium Dioxide, 10 parts of kaolin, 20 parts of coarse whitings, 0.3 part of cellulose and 0.1 part of aluminium-magnesium silicate；
Wherein, the mass percent of styrene is 35% in the polymer emulsion, and-OH mass percent is 4%, most
Low film formation temperature<0 DEG C, glass transition temperature is 30 DEG C.
Wherein, the polymer emulsion is gathered by 25 parts of styrene, 5 parts of polyvinyl chloride, 1 part of butyl epoxy stearate, 10 parts
Acid imide and 20 part of 12 carbon ester composition, wherein, the polyimides is the polyimides containing alkyl side chain and alkyl；
Wherein, the alkyl side chain number is 12, and the phenyl ring number is 12.
In such scheme, in addition to organic modified bentonite；
The mass ratio of the Nanometer Titanium Dioxide, the kaolin and the coarse whiting sum and the organic modified bentonite is 1：
0.5。
In such scheme, the kaolin is the calcined kaolin of the mesh of particle diameter 4000, and the coarse whiting is the weight of the mesh of particle diameter 800
Matter calcium carbonate.
In such scheme, in addition to according to following components of mass fraction meter：0.8 part of environmentally friendly solvent, 0.5 part of dispersant,
0.1 part of wetting agent, 0.1 part of defoamer, 0.1 portion of preservative, 0.5 part of mould inhibitor and 0.2 part of thickener.
Further, the environmentally friendly solvent is propane diols or/and ethylene glycol；The dispersant is polyacrylic acid sodium salt, its
Solid content is 40%；
The wetting agent is fatty alcohol alkoxy compound；The defoamer is polysiloxane-polyether copolymer emulsion；It is described
Preservative is imidazoles；The thickener is that hydrophobically-modified alkali is swelled class thickening.
Preparation process：
Cellulose, aluminium-magnesium silicate and deionized water are added in paint mixing tank, 15- is stirred under 400-600r/min rotating speeds
25min；
Environmentally friendly solvent, dispersant, wetting agent, defoamer, preservative and mould inhibitor are sequentially added into the paint mixing tank,
1-5min is stirred under 400-600r/min rotating speeds；
Under 700-900r/min rotating speeds, Nanometer Titanium Dioxide is added into the paint mixing tank successively, and in 1000-1200r/
Under min rotating speeds, 25-35min is stirred, to fineness≤55um；
Polymer emulsion, coalescents are added under 400-600r/min rotating speeds into the paint mixing tank, 2-5min are stirred, directly
Viscosity is 100-105KU to 21-25 DEG C.
Embodiment 2
A kind of special airless spraying interior wall sealing wax of engineering, it is included according to mass fraction meter, 11 parts of polymer emulsions, 6
Part Nanometer Titanium Dioxide, 15 parts of kaolin, 40 parts of coarse whitings, 0.5 part of cellulose and 0.2 part of aluminium-magnesium silicate；
Wherein, the mass percent of styrene is 45% in the polymer emulsion, and-OH mass percent is 10%,
MFT<0 DEG C, glass transition temperature is 50 DEG C.
Wherein, the polymer emulsion is gathered by 35 parts of styrene, 10 parts of polyvinyl chloride, 5 parts of butyl epoxy stearates, 15 parts
Acid imide and 25 part of 12 carbon ester composition, wherein, the polyimides is the polyimides containing alkyl side chain and phenyl ring；
Wherein, the alkyl side chain number is 15, and the phenyl ring number is 15.
In such scheme, in addition to organic modified bentonite；
The mass ratio of the Nanometer Titanium Dioxide, the kaolin and the coarse whiting sum and the organic modified bentonite is 1：
1.2。
In such scheme, the kaolin is the calcined kaolin of the mesh of particle diameter 4000, and the coarse whiting is the weight of the mesh of particle diameter 800
Matter calcium carbonate.
In such scheme, in addition to according to following components of mass fraction meter：1 part of environmentally friendly solvent, 0.8 part of dispersant, 0.2
Part wetting agent, 0.3 part of defoamer, 0.3 portion of preservative, 0.8 part of mould inhibitor and 0.3 part of thickener.
Further, the environmentally friendly solvent is propane diols or/and ethylene glycol；The dispersant is polyacrylic acid sodium salt, its
Solid content is 40%；The wetting agent is fatty alcohol alkoxy compound；The defoamer is polysiloxane-polyether copolymer breast
Liquid；The preservative is imidazoles；The thickener is that hydrophobically-modified alkali is swelled class thickening.
Preparation process：
Cellulose, aluminium-magnesium silicate and deionized water are added in paint mixing tank, 15- is stirred under 400-600r/min rotating speeds
25min；
Environmentally friendly solvent, dispersant, wetting agent, defoamer, preservative and mould inhibitor are sequentially added into the paint mixing tank,
1-5min is stirred under 400-600r/min rotating speeds；
Under 700-900r/min rotating speeds, Nanometer Titanium Dioxide is added into the paint mixing tank successively, and in 1000-1200r/
Under min rotating speeds, 25-35min is stirred, to fineness≤55um；
Polymer emulsion, coalescents are added under 400-600r/min rotating speeds into the paint mixing tank, 2-5min are stirred, directly
Viscosity is 100-105KU to 21-25 DEG C.
Embodiment 3
A kind of special airless spraying interior wall sealing wax of engineering, it is included according to mass fraction meter, 9 parts of polymer emulsions, 5 parts
Nanometer Titanium Dioxide, 13 parts of kaolin, 35 parts of coarse whitings, 0.4 part of cellulose and 0.15 part of aluminium-magnesium silicate；
Wherein, the mass percent of styrene is 40% in the polymer emulsion, and-OH mass percent is 6%, most
Low film formation temperature<0 DEG C, glass transition temperature is 40 DEG C.
Wherein, the polymer emulsion is gathered by 30 parts of styrene, 7 parts of polyvinyl chloride, 3 parts of butyl epoxy stearates, 13 parts
Acid imide and 22 part of 12 carbon ester composition, wherein, the polyimides is the polyimides containing alkyl side chain and phenyl ring；
Wherein, the alkyl side chain number is 14, and the phenyl ring number is 14.
In such scheme, in addition to organic modified bentonite；
The mass ratio of the Nanometer Titanium Dioxide, the kaolin and the coarse whiting sum and the organic modified bentonite is 1；
0.7。
In such scheme, the kaolin is the calcined kaolin of the mesh of particle diameter 4000, and the coarse whiting is the weight of the mesh of particle diameter 800
Matter calcium carbonate.
In such scheme, in addition to according to following components of mass fraction meter：0.9 part of environmentally friendly solvent, 0.6 part of dispersant,
0.15 part of wetting agent, 0.2 part of defoamer, 0.2 portion of preservative, 0.7 part of mould inhibitor and 0.25 part of thickener.
Further, the environmentally friendly solvent is propane diols or/and ethylene glycol；The dispersant is polyacrylic acid sodium salt, its
Solid content is 40%；
The wetting agent is fatty alcohol alkoxy compound；The defoamer is polysiloxane-polyether copolymer emulsion；It is described
Preservative is imidazoles；The thickener is that hydrophobically-modified alkali is swelled class thickening.
Preparation process：
Cellulose, aluminium-magnesium silicate and deionized water are added in paint mixing tank, 15- is stirred under 400-600r/min rotating speeds
25min；
Environmentally friendly solvent, dispersant, wetting agent, defoamer, preservative and mould inhibitor are sequentially added into the paint mixing tank,
1-5min is stirred under 400-600r/min rotating speeds；
Under 700-900r/min rotating speeds, Nanometer Titanium Dioxide is added into the paint mixing tank successively, and in 1000-1200r/
Under min rotating speeds, 25-35min is stirred, to fineness≤55um；
Polymer emulsion, coalescents are added under 400-600r/min rotating speeds into the paint mixing tank, 2-5min are stirred, directly
Viscosity is 100-105KU to 21-25 DEG C.
Embodiment 4
A kind of special airless spraying interior wall sealing wax of engineering, it is included according to mass fraction meter, 9 parts of polymer emulsions, 3.5
Part Nanometer Titanium Dioxide, 15 parts of kaolin, 28 parts of coarse whitings, 0.35 cellulose and 0.2 part of aluminium-magnesium silicate；
Wherein, the mass percent of styrene is 37% in the polymer emulsion, and-OH mass percent is 5%, most
Low film formation temperature<0 DEG C, glass transition temperature is 33 DEG C.
Wherein, the polymer emulsion include 28 parts of styrene, 8 parts of polyvinyl chloride, 2 parts of butyl epoxy stearates, 12 parts
Polyimides, 23 part of 12 carbon ester, wherein, the polyimides is the polyimides containing alkyl side chain and phenyl ring；
Wherein, the alkyl side chain number is 13, and the phenyl ring number is 14.
In such scheme, in addition to organic modified bentonite；
The mass ratio of the Nanometer Titanium Dioxide, the kaolin and the coarse whiting sum and the organic modified bentonite is 1；
0.8。
In such scheme, the kaolin is the calcined kaolin of the mesh of particle diameter 4000, and the coarse whiting is the weight of the mesh of particle diameter 800
Matter calcium carbonate.
In such scheme, in addition to according to following components of mass fraction meter：
1 part of environmentally friendly solvent, 0.6 part of dispersant, 0.2 part of wetting agent, 0.2 part of defoamer, 0.2 portion of preservative, 0.5 part it is mould proof
Agent and 0.3 part of thickener.
Further, the environmentally friendly solvent is propane diols or/and ethylene glycol；The dispersant is polyacrylic acid sodium salt, its
Solid content is 40%；
The wetting agent is fatty alcohol alkoxy compound；The defoamer is polysiloxane-polyether copolymer emulsion；It is described
Preservative is imidazoles；The thickener is that hydrophobically-modified alkali is swelled class thickening.
Preparation process：
Cellulose, aluminium-magnesium silicate and deionized water are added in paint mixing tank, 15- is stirred under 400-600r/min rotating speeds
25min；
Environmentally friendly solvent, dispersant, wetting agent, defoamer, preservative and mould inhibitor are sequentially added into the paint mixing tank,
1-5min is stirred under 400-600r/min rotating speeds；
Under 700-900r/min rotating speeds, Nanometer Titanium Dioxide is added into the paint mixing tank successively, and in 1000-1200r/
Under min rotating speeds, 25-35min is stirred, to fineness≤55um；
Polymer emulsion, coalescents are added under 400-600r/min rotating speeds into the paint mixing tank, 2-5min are stirred, directly
Viscosity is 100-105KU to 21-25 DEG C.
Embodiment 5
A kind of special airless spraying interior wall sealing wax of engineering, it is included according to mass fraction meter, 10 parts of polymer emulsions, 5
Part Nanometer Titanium Dioxide, 12.5 parts of kaolin, 30 parts of coarse whitings, 0.32 part of cellulose and 0.1 part of aluminium-magnesium silicate；
Wherein, the mass percent of styrene is 42% in the polymer emulsion, and-OH mass percent is 8%, most
Low film formation temperature<0 DEG C, glass transition temperature is 44 DEG C.
Wherein, the polymer emulsion is gathered by 32 parts of styrene, 8 parts of polyvinyl chloride, 4 parts of butyl epoxy stearates, 11 parts
Acid imide and 24 part of 12 carbon ester composition, wherein, the polyimides is the polyimides containing alkyl side chain and phenyl ring；
Wherein, the alkyl side chain number is 12, and the phenyl ring number is 13.
In such scheme, in addition to organic modified bentonite；
The mass ratio of the Nanometer Titanium Dioxide, the kaolin and the coarse whiting sum and the organic modified bentonite is 1:
0.9。
In such scheme, the kaolin is the calcined kaolin of the mesh of particle diameter 4000, and the coarse whiting is the weight of the mesh of particle diameter 800
Matter calcium carbonate.
In such scheme, in addition to according to following components of mass fraction meter：1 part of environmentally friendly solvent, 0.6 part of dispersant,
0.2 part of wetting agent, 0.2 part of defoamer, 0.2 portion of preservative, 0.8 part of mould inhibitor and 0.3 part of thickener.
Further, the environmentally friendly solvent is propane diols or/and ethylene glycol；The dispersant is polyacrylic acid sodium salt, its
Solid content is 40%；
The wetting agent is fatty alcohol alkoxy compound；The defoamer is polysiloxane-polyether copolymer emulsion；It is described
Preservative is imidazoles；The thickener is that hydrophobically-modified alkali is swelled class thickening.
Preparation process：
Cellulose, aluminium-magnesium silicate and deionized water are added in paint mixing tank, 15- is stirred under 400-600r/min rotating speeds
25min；
Environmentally friendly solvent, dispersant, wetting agent, defoamer, preservative and mould inhibitor are sequentially added into the paint mixing tank,
1-5min is stirred under 400-600r/min rotating speeds；
Under 700-900r/min rotating speeds, Nanometer Titanium Dioxide is added into the paint mixing tank successively, and in 1000-1200r/
Under min rotating speeds, 25-35min is stirred, to fineness≤55um；
Polymer emulsion, coalescents are added under 400-600r/min rotating speeds into the paint mixing tank, 2-5min are stirred, directly
Viscosity is 100-105KU to 21-25 DEG C.
Embodiment 6
A kind of special airless spraying interior wall sealing wax of engineering, it is included according to mass fraction meter, 11 parts of polymer emulsions, 6
Part Nanometer Titanium Dioxide, 10 parts of kaolin, 28.7 parts of coarse whitings, 0.3 part of cellulose and 0.1 part of aluminium-magnesium silicate；
Wherein, the mass percent of styrene is 44% in the polymer emulsion, and-OH mass percent is 7%, most
Low film formation temperature<0 DEG C, glass transition temperature is 42 DEG C.
Wherein, the polymer emulsion include 34 parts of styrene, 8 parts of polyvinyl chloride, 4 parts of butyl epoxy stearates, 11 parts
Polyimides, 24 part of 12 carbon ester, wherein, the polyimides is the polyimides containing alkyl side chain and phenyl ring；
Wherein, the alkyl side chain number is 14, and the phenyl ring number is 13.
In such scheme, in addition to organic modified bentonite；
The mass ratio of the Nanometer Titanium Dioxide, the kaolin and the coarse whiting sum and the organic modified bentonite is 1:
0.9。
In such scheme, the kaolin is the calcined kaolin of the mesh of particle diameter 4000, and the coarse whiting is the weight of the mesh of particle diameter 800
Matter calcium carbonate.
In such scheme, in addition to according to following components of mass fraction meter：1 part of environmentally friendly solvent, 0.6 part of dispersant, 0.2
Part wetting agent, 0.2 part of defoamer, 0.2 portion of preservative, 0.8 part of mould inhibitor and 0.3 part of thickener.
Further, the environmentally friendly solvent is propane diols or/and ethylene glycol；The dispersant is polyacrylic acid sodium salt, its
Solid content is 40%；
The wetting agent is fatty alcohol alkoxy compound；The defoamer is polysiloxane-polyether copolymer emulsion；It is described
Preservative is imidazoles；The thickener is that hydrophobically-modified alkali is swelled class thickening.
Preparation process：
Cellulose, aluminium-magnesium silicate and deionized water are added in paint mixing tank, 15- is stirred under 400-600r/min rotating speeds
25min；
Environmentally friendly solvent, dispersant, wetting agent, defoamer, preservative and mould inhibitor are sequentially added into the paint mixing tank,
1-5min is stirred under 400-600r/min rotating speeds；
Under 700-900r/min rotating speeds, Nanometer Titanium Dioxide is added into the paint mixing tank successively, and in 1000-1200r/
Under min rotating speeds, 25-35min is stirred, to fineness≤55um；
Polymer emulsion, coalescents are added under 400-600r/min rotating speeds into the paint mixing tank, 2-5min are stirred, directly
Viscosity is 100-105KU to 21-25 DEG C.
Comparative example 1
A kind of special airless spraying interior wall sealing wax of engineering, it is included according to mass fraction meter, 8.5 parts of polymer emulsions, 3
Part Nanometer Titanium Dioxide, 10 parts of kaolin, 20 parts of coarse whitings, 0.3 part of cellulose and 0.1 part of aluminium-magnesium silicate；
Wherein, the mass percent of styrene is 20% in the polymer emulsion, and-OH mass percent is 20%,
Glass transition temperature is 80 DEG C.
In such scheme, in addition to organic modified bentonite；
The mass ratio of Nanometer Titanium Dioxide, kaolin and coarse whiting sum and the organic modified bentonite is 1；0.5.
In such scheme, the kaolin is the calcined kaolin of the mesh of particle diameter 4000, and the coarse whiting is the weight of the mesh of particle diameter 800
Matter calcium carbonate.
In such scheme, in addition to according to following components of mass fraction meter：0.8 part of environmentally friendly solvent, 0.5 part of dispersant,
0.1 part of wetting agent, 0.1 part of defoamer, 0.1 portion of preservative, 0.5 part of mould inhibitor and 0.2 part of thickener.
Further, the environmentally friendly solvent is propane diols or/and ethylene glycol；The dispersant is polyacrylic acid sodium salt, its
Solid content is 40%；
The wetting agent is fatty alcohol alkoxy compound；The defoamer is polysiloxane-polyether copolymer emulsion；It is described
Preservative is imidazoles；The thickener is that hydrophobically-modified alkali is swelled class thickening.
Comparative example 2
A kind of special airless spraying interior wall sealing wax of engineering, it is included according to mass fraction meter, 11 parts of polymer emulsions, 6
Part Nanometer Titanium Dioxide, 10 parts of kaolin, 28.7 parts of coarse whitings, 0.3 part of cellulose and 0.1 part of aluminium-magnesium silicate；
Wherein, the polymer emulsion includes 12 carbon esters and acrylic emulsion.
In such scheme, in addition to organic modified bentonite；
The mass ratio of the Nanometer Titanium Dioxide, the kaolin and the coarse whiting sum and the organic modified bentonite is 1:
0.9。
In such scheme, the kaolin is the calcined kaolin of the mesh of particle diameter 4000, and the coarse whiting is the weight of the mesh of particle diameter 800
Matter calcium carbonate.
In such scheme, in addition to according to following components of mass fraction meter：1 part of environmentally friendly solvent, 0.6 part of dispersant, 0.2
Part wetting agent, 0.2 part of defoamer, 0.2 portion of preservative, 0.8 part of mould inhibitor and 0.3 part of thickener.
Further, environmentally friendly solvent is propane diols or/and ethylene glycol；The dispersant is polyacrylic acid sodium salt, and it contains admittedly
Measure as 40%；
The wetting agent is fatty alcohol alkoxy compound；The defoamer is polysiloxane-polyether copolymer emulsion；It is described
Preservative is imidazoles；The thickener is that hydrophobically-modified alkali is swelled class thickening.
The special airless spraying interior wall sealing wax of engineering and comparative example 1 that are prepared in above-described embodiment 1-6 and comparative example 2
Interior wall sealing wax the performance test results are as shown in table 1, it can be seen that use the special airless spraying interior wall water of engineering of the present invention
Paint, covering power is respectively positioned in 40-45g/m2 interval range, and the covering power of comparative example is then located at 65-70g/m2 interval model
In enclosing, the covering sealing wax needed for further illustrating the black square that unit area is covered in embodiments of the invention is fewer, that is to say, that
Embodiments of the invention are more preferable than the covering power of comparative example.There is excellent scrubbing resistance, covering power, stream in embodiments of the invention
Levelling, with more prominent fungicidal properties, and during airless spraying, will not occur shrinkage cavity, the film defect such as pinprick.
In the case of without departing substantially from the scope of the present invention or spirit, it can do many to the embodiment of description of the invention
Plant and improve and change, this will be apparent to those skilled in the art.Other realities obtained by the specification of the present invention
It is apparent obtain for technical personnel to apply mode.Present specification and embodiment are only exemplary.
Table 1
Claims (8)
1. a kind of special airless spraying interior wall sealing wax of engineering, it is included according to mass fraction meter, 8.5-11 parts of polymer emulsions,
3-6 parts of Nanometer Titanium Dioxides, 10-15 parts of kaolin, 20-40 parts of coarse whitings, 0.3-0.5 parts of celluloses and 0.1-0.2 parts of aluminium-magnesium silicates；
Wherein, the mass percent of styrene is 35-45% in the polymer emulsion, and-OH mass percents are 4-10%, most
Low film formation temperature<0 DEG C, glass transition temperature is 30-50 DEG C.
2. the special airless spraying interior wall sealing wax of engineering according to claim 1, wherein, the polymer emulsion has 25-35
Part styrene, 5-10 parts of polyvinyl chloride, 1-5 parts of butyl epoxy stearates, 10-15 parts of polyimides and the carbon ester of 20-25 parts 12
Composition.
3. the special airless spraying interior wall sealing wax of engineering according to claim 2, wherein, the polyimides is to contain alkyl
The polyimides of side chain and phenyl ring；
Wherein, the alkyl side chain number is 12-15, and the phenyl ring number is 12-15.
4. the special airless spraying interior wall sealing wax of engineering according to claim 3, wherein, in addition to organic modified bentonite；
And
The mass ratio of the Nanometer Titanium Dioxide, the kaolin and the coarse whiting sum and the organic modified bentonite is 1:0.5-
1.2。
5. the special airless spraying interior wall sealing wax of engineering according to claim 1, wherein, the kaolin is the mesh of particle diameter 4000
Calcined kaolin, the coarse whiting be the mesh of particle diameter 800 powdered whiting.
6. the special airless spraying interior wall sealing wax of engineering according to claim 1, wherein, in addition to according to mass fraction meter
Following components：
0.8-1 parts of environmentally friendly solvents, 0.5-0.8 parts of dispersants, 0.1-0.2 parts of wetting agents, 0.1-0.3 parts of defoamers, 0.1-0.3 parts
Preservative, 0.5-0.8 part mould inhibitor and 0.2-0.3 parts of thickeners.
7. the special airless spraying interior wall sealing wax of engineering according to claim 6, wherein,
The environmentally friendly solvent is propane diols or/and ethylene glycol；
The dispersant is polyacrylic acid sodium salt, and its solid content is 40%；
The wetting agent is fatty alcohol alkoxy compound；
The defoamer is polysiloxane-polyether copolymer emulsion；
The preservative is imidazoles；With
The thickener is that hydrophobically-modified alkali is swelled class thickening.
8. a kind of preparation method of the special airless spraying interior wall sealing wax of engineering, wherein,
Cellulose, aluminium-magnesium silicate and deionized water are added in paint mixing tank, 15-25min is stirred under 400-600r/min rotating speeds；
Environmentally friendly solvent, dispersant, wetting agent, defoamer, preservative and mould inhibitor are sequentially added into the paint mixing tank, in 400-
1-5min is stirred under 600r/min rotating speeds；
Under 700-900r/min rotating speeds, Nanometer Titanium Dioxide is added into the paint mixing tank successively, and turn in 1000-1200r/min
Under speed, 25-35min is stirred, to fineness≤55um；
Polymer emulsion, coalescents are added under 400-600r/min rotating speeds into the paint mixing tank, 2-5min is stirred, until
Viscosity is 100-105KU at 21-25 DEG C.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359337A (en) * | 2018-01-02 | 2018-08-03 | 河北晨阳工贸集团有限公司 | Mould-proof-type interior wall sealing wax and preparation method thereof |
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| CN1039826A (en) * | 1988-07-27 | 1990-02-21 | 孙碧宜 | Polyvinyl chloride water-emulsifying type waterproof coatings and technology |
| JPH03174401A (en) * | 1989-12-04 | 1991-07-29 | Mitsubishi Yuka Badische Co Ltd | Aqueous acrylic resin emulsion composition |
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