CN1594212A - 多壁碳纳米管/无定形二氧化锰复合物及其制法和用途 - Google Patents
多壁碳纳米管/无定形二氧化锰复合物及其制法和用途 Download PDFInfo
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- CN1594212A CN1594212A CNA2004100413566A CN200410041356A CN1594212A CN 1594212 A CN1594212 A CN 1594212A CN A2004100413566 A CNA2004100413566 A CN A2004100413566A CN 200410041356 A CN200410041356 A CN 200410041356A CN 1594212 A CN1594212 A CN 1594212A
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- Prior art keywords
- amorphous
- carbon nano
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- manganse dioxide
- tubes
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- 239000002048 multi walled nanotube Substances 0.000 title claims abstract description 32
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims description 10
- -1 manganese dioxide compound Chemical class 0.000 title claims description 9
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 21
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims description 34
- 239000012153 distilled water Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 17
- 239000012286 potassium permanganate Substances 0.000 claims description 12
- 230000036571 hydration Effects 0.000 claims description 8
- 238000006703 hydration reaction Methods 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical class [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- SCHVCYHZLQELIS-UHFFFAOYSA-H [C+4].C(C)(=O)[O-].[Mn+2].C(C)(=O)[O-].C(C)(=O)[O-].C(C)(=O)[O-].C(C)(=O)[O-].C(C)(=O)[O-] Chemical compound [C+4].C(C)(=O)[O-].[Mn+2].C(C)(=O)[O-].C(C)(=O)[O-].C(C)(=O)[O-].C(C)(=O)[O-].C(C)(=O)[O-] SCHVCYHZLQELIS-UHFFFAOYSA-H 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 2
- 239000007772 electrode material Substances 0.000 abstract description 16
- 239000003990 capacitor Substances 0.000 abstract description 8
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000011572 manganese Substances 0.000 description 14
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 8
- 239000004810 polytetrafluoroethylene Substances 0.000 description 8
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 230000006698 induction Effects 0.000 description 4
- 239000006210 lotion Substances 0.000 description 4
- 238000002411 thermogravimetry Methods 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 3
- 238000002848 electrochemical method Methods 0.000 description 3
- 239000008151 electrolyte solution Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000002484 cyclic voltammetry Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- GOPYZMJAIPBUGX-UHFFFAOYSA-N [O-2].[O-2].[Mn+4] Chemical class [O-2].[O-2].[Mn+4] GOPYZMJAIPBUGX-UHFFFAOYSA-N 0.000 description 1
- 238000000627 alternating current impedance spectroscopy Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000002001 electrolyte material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229940071125 manganese acetate Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2004100413566A CN1261387C (zh) | 2004-07-13 | 2004-07-13 | 多壁碳纳米管/无定形二氧化锰复合物的制法 |
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CNB2004100413566A CN1261387C (zh) | 2004-07-13 | 2004-07-13 | 多壁碳纳米管/无定形二氧化锰复合物的制法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1594212A true CN1594212A (zh) | 2005-03-16 |
CN1261387C CN1261387C (zh) | 2006-06-28 |
Family
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CNB2004100413566A Expired - Fee Related CN1261387C (zh) | 2004-07-13 | 2004-07-13 | 多壁碳纳米管/无定形二氧化锰复合物的制法 |
Country Status (1)
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CN (1) | CN1261387C (zh) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008112650A2 (en) * | 2007-03-15 | 2008-09-18 | Yazaki Corporation | Capacitor electrodes comprising carbon nanotubes filled with one or more non- carbon materials |
CN101409152B (zh) * | 2008-09-16 | 2010-12-01 | 上海第二工业大学 | 一种超级电容器用元素掺杂二氧化锰电极材料的制备方法 |
CN101916667A (zh) * | 2010-09-19 | 2010-12-15 | 西安交通大学 | 基于MnO2与PPy/F-CNTs复合物材料的非对称超级电容器 |
CN101923960A (zh) * | 2010-08-18 | 2010-12-22 | 东华大学 | 一种瓣状二氧化锰纳米晶包覆碳纳米管复合电极材料的制备方法 |
CN101497435B (zh) * | 2008-02-03 | 2011-01-26 | 中国科学院化学研究所 | 金属氧化物/碳纳米管复合材料及其制备方法与应用 |
CN103400701A (zh) * | 2013-07-11 | 2013-11-20 | 燕山大学 | 一种二氧化锰/碳纳米管复合材料及其制备方法 |
CN103413691A (zh) * | 2013-07-31 | 2013-11-27 | 清华大学 | 一种用于超级电容器的MnO2/碳复合材料的制备方法 |
CN103545122A (zh) * | 2013-10-30 | 2014-01-29 | 中国第一汽车股份有限公司 | 一种超级电容器用二氧化锰/碳复合材料的制备方法 |
CN103972518A (zh) * | 2013-02-05 | 2014-08-06 | 中国科学院大连化学物理研究所 | 一种二氧化锰/碳纳米复合材料及其制备方法和应用 |
CN104396054A (zh) * | 2012-05-23 | 2015-03-04 | 巴斯夫欧洲公司 | 制备碳负载的锰氧化物催化剂的方法及其在可再充电锂-空气电池组中的用途 |
CN104392849A (zh) * | 2014-11-20 | 2015-03-04 | 中南大学 | 一种二氧化锰/碳复合材料的制备方法 |
CN107045943A (zh) * | 2017-03-06 | 2017-08-15 | 清华大学深圳研究生院 | 一种超级电容器用电极材料 |
-
2004
- 2004-07-13 CN CNB2004100413566A patent/CN1261387C/zh not_active Expired - Fee Related
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008112650A3 (en) * | 2007-03-15 | 2009-03-12 | Yazaki Corp | Capacitor electrodes comprising carbon nanotubes filled with one or more non- carbon materials |
US7794840B2 (en) | 2007-03-15 | 2010-09-14 | Yazaki Corporation | Capacitors comprising organized assemblies of carbon and non-carbon compounds |
US7943238B2 (en) | 2007-03-15 | 2011-05-17 | Yazaki Corporation | Capacitors comprising organized assemblies of carbon and non-carbon compounds |
WO2008112650A2 (en) * | 2007-03-15 | 2008-09-18 | Yazaki Corporation | Capacitor electrodes comprising carbon nanotubes filled with one or more non- carbon materials |
CN101497435B (zh) * | 2008-02-03 | 2011-01-26 | 中国科学院化学研究所 | 金属氧化物/碳纳米管复合材料及其制备方法与应用 |
CN101409152B (zh) * | 2008-09-16 | 2010-12-01 | 上海第二工业大学 | 一种超级电容器用元素掺杂二氧化锰电极材料的制备方法 |
CN101923960A (zh) * | 2010-08-18 | 2010-12-22 | 东华大学 | 一种瓣状二氧化锰纳米晶包覆碳纳米管复合电极材料的制备方法 |
CN101923960B (zh) * | 2010-08-18 | 2012-05-23 | 东华大学 | 一种瓣状二氧化锰纳米晶包覆碳纳米管复合电极材料的制备方法 |
CN101916667A (zh) * | 2010-09-19 | 2010-12-15 | 西安交通大学 | 基于MnO2与PPy/F-CNTs复合物材料的非对称超级电容器 |
CN101916667B (zh) * | 2010-09-19 | 2012-07-25 | 西安交通大学 | 基于MnO2与PPy/F-CNTs复合物材料的非对称超级电容器 |
CN104396054A (zh) * | 2012-05-23 | 2015-03-04 | 巴斯夫欧洲公司 | 制备碳负载的锰氧化物催化剂的方法及其在可再充电锂-空气电池组中的用途 |
CN103972518A (zh) * | 2013-02-05 | 2014-08-06 | 中国科学院大连化学物理研究所 | 一种二氧化锰/碳纳米复合材料及其制备方法和应用 |
CN103400701A (zh) * | 2013-07-11 | 2013-11-20 | 燕山大学 | 一种二氧化锰/碳纳米管复合材料及其制备方法 |
CN103400701B (zh) * | 2013-07-11 | 2015-11-18 | 燕山大学 | 一种二氧化锰/碳纳米管复合材料及其制备方法 |
CN103413691A (zh) * | 2013-07-31 | 2013-11-27 | 清华大学 | 一种用于超级电容器的MnO2/碳复合材料的制备方法 |
CN103413691B (zh) * | 2013-07-31 | 2016-12-28 | 清华大学 | 一种用于超级电容器的MnO2/碳复合材料的制备方法 |
CN103545122A (zh) * | 2013-10-30 | 2014-01-29 | 中国第一汽车股份有限公司 | 一种超级电容器用二氧化锰/碳复合材料的制备方法 |
CN104392849A (zh) * | 2014-11-20 | 2015-03-04 | 中南大学 | 一种二氧化锰/碳复合材料的制备方法 |
CN104392849B (zh) * | 2014-11-20 | 2017-03-08 | 中南大学 | 一种二氧化锰/碳复合材料的制备方法 |
CN107045943A (zh) * | 2017-03-06 | 2017-08-15 | 清华大学深圳研究生院 | 一种超级电容器用电极材料 |
CN107045943B (zh) * | 2017-03-06 | 2018-11-16 | 清华大学深圳研究生院 | 一种超级电容器用电极材料 |
Also Published As
Publication number | Publication date |
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CN1261387C (zh) | 2006-06-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Jianghai Capacitor Co., Ltd., Nantong Assignor: Nanjing University Contract fulfillment period: 2007.4.15 to 2013.4.15 contract change Contract record no.: 2008320000177 Denomination of invention: Multi-wall carbon nano-tube/amorphous manganese dioxide compound and its preparation method and application Granted publication date: 20060628 License type: Exclusive license Record date: 2008.9.22 |
|
LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.4.15 TO 2013.4.15 Name of requester: NANTONG JIANGHAI CAPACITOR CO. Effective date: 20080922 |
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C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060628 Termination date: 20110713 |