CN1589197A - 具有可转动模型配件的模具中模制品上涂料的喷涂和硬化 - Google Patents
具有可转动模型配件的模具中模制品上涂料的喷涂和硬化 Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
- B29C37/0028—In-mould coating, e.g. by introducing the coating material into the mould after forming the article
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0053—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/26—Moulds
- B29C45/33—Moulds having transversely, e.g. radially, movable mould parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B13/00—Machines or plants for applying liquids or other fluent materials to surfaces of objects or other work by spraying, not covered by groups B05B1/00 - B05B11/00
- B05B13/02—Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work
- B05B13/0221—Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work characterised by the means for moving or conveying the objects or other work, e.g. conveyor belts
- B05B13/0242—Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work characterised by the means for moving or conveying the objects or other work, e.g. conveyor belts the objects being individually presented to the spray heads by a rotating element, e.g. turntable
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/002—Processes for applying liquids or other fluent materials the substrate being rotated
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
- B05D3/065—After-treatment
- B05D3/067—Curing or cross-linking the coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0827—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0053—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
- B29C2045/0075—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping curing or polymerising by irradiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0053—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
- B29C2045/0079—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping applying a coating or covering
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/03—Injection moulding apparatus
- B29C45/04—Injection moulding apparatus using movable moulds or mould halves
- B29C45/0441—Injection moulding apparatus using movable moulds or mould halves involving a rotational movement
- B29C45/045—Injection moulding apparatus using movable moulds or mould halves involving a rotational movement mounted on the circumference of a rotating support having a rotating axis perpendicular to the mould opening, closing or clamping direction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/1701—Component parts, details or accessories; Auxiliary operations using a particular environment during moulding, e.g. moisture-free or dust-free
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Coating Apparatus (AREA)
- Moulding By Coating Moulds (AREA)
- Mechanical Pencils And Projecting And Retracting Systems Therefor, And Multi-System Writing Instruments (AREA)
Abstract
本发明涉及一种用于向优选由塑料制成的预先模制物品(2)喷涂/上漆且随后使涂料/漆料硬化的方法和机构。本发明的特征在于,所述工序全部在同一模具中进行,该模具对将要喷涂/上漆并硬化的物品(2)进行模制。其可以通过呈单件或多件式工具的模具实现,该模具设有至少一个可转动模型配件(1),其通过步进转动例如分别转动90度将物品导引通过四个工作站,该物品在各工作站处被分别模制、涂漆、硬化且最终从可转动模型配件(1)中抽出,其中,它们在模制后直到抽出为止一直位于适当的位置上。
Description
本发明涉及一种模制品上涂料/漆料的喷涂/上漆以及连续硬化的方法和机构,其中在该喷涂/上漆的同时该模制品仍保持处于设有至少一个可转动模型配件的模具中,该模具可以是单件式和多件式工具。
已知有多种方法用于模制塑料物品,且随后向模制品喷涂/上漆并使涂料/漆料硬化。不过,这些迄今所了解的方法牵涉到很多在无尘环境中用机械手对物品进行处理和传输的工作。采用本发明的新方法,可以在给物品喷涂/上漆并使之硬化的同时,使它们仍保留在对其进行模制的模具中,从而通过更快、更安全的生产以及更易控制的无尘环境而大大节省成本。
本发明的方法和机构的特征在于,在模制成型之后,优选在闭合模具的同时,在至少一个工作站/工作阶段的位置上将涂料/漆料施加到物品上,此后,优选在可转动模型配件进一步向前转动至少一个工作站之后,通过来自紫外线光源或其他类型能源的受控光照使被喷涂/上漆的物品硬化。
本发明的方法和机构的其他实施例和优点将从附图中变得更加显而易见,其中:
图1示出了自上方观察的本发明的模具的横截面,同时示出了生产周期中的全部四个工作站;
图2示出了一个施加涂料/漆料的机构的横截面,在此,一喷嘴位于一个双壁套筒中,该套筒配有掩罩件,以覆盖物品。
在图1中自上方观察地示出了位于闭合位置上的本发明的模具的横截面。可转动模型配件1在此被示出为一个具有切角的正方形,物品2、2′、2″和2被显示处在位于可转动模型配件1的四个侧面的每一个上的四个不同工作站(阶段)上。物品2刚刚经由入口4在可转动模型配件1与固定模型配件3之间模制。在打开模具、使可转动模型配件1沿顺时针方向转动90度、接着闭合模具之后,物品2′被示出位于一个进一步向前的工作站上。物品2′在图中被示出位于可转动模型配件1的最低位置上,它仍牢固地位于可转动模型配件1上,在此情况下,从一个特定的施涂装置5将优选为一薄层的涂料/漆料施加到物品2′上。就物品2″而言,在打开模具且随后再闭合之后,它向前又转动90度,且位于活动模型配件6和可转动模型配件1之间,该活动模型配件6内设有紫外线光源7,且物品2″仍位于可转动模型配件1中。在该工作站上,使所施加的涂料/漆料层硬化。最后,在可转动模型配件再顺时针转动90度之后且在完全模制的、喷涂/上漆且硬化的物品即将通过脱模板8从可转动模型配件1中抽出之前,物品2被示出位于图中的最高位置上。可以看出,物品2、2′、2″和2表示了模制的、喷涂/上漆且硬化的物品的整个生产周期。当再一次打开模具、再转动90度以及闭合模具之后,本发明的模具返回到其初始位置上且等待进入下一个周期,下一个周期是从通过入口4将新材料注入固定模型配件3中开始的。
图2示出了将涂料/漆料层施加到物品上的特定机构5。它由一个喷嘴9构成,其位于一个双壁套筒机构10内,其中可生成负压、超压、湍流或其他形式的气流,当处于打开且转动状态时,其可用于将与涂料/漆料相适应的受控气氛施加到物品2′的周围,还防止多余的涂料/漆料散开到模具中。此外,图中示出了一掩蔽件11,其用于覆盖物品上不应施加涂料/漆料的区域。
图中还应该可以示出本发明的机构的其他实施例,例如将可转动模型配件大体设计成正六角形或正八角形。因而会在转动过程中存在更多的工作站,在此例如可额外地使涂料/漆料冷却或硬化。这一点也可改用一个具有多个工作站的转盘或分度盘系统来进行,而非所示的具有可转动中间截面的系统。也可使模具具有两个或多个可转动模型配件,正如本发明的模具可具有两个或多个入口一样,这样便可进行多部件的模制。不过,图中所示的内容已经充分说明了本发明方法和机构中的基本原理。
上述的模制品主要是塑料物品。但本发明的方法和机构也可应用到采用金属(如铝和镁)、不同的合金或其他可模制材料模制的物品上。
Claims (8)
1、用于向模制物品(2)喷涂/上漆且随后使涂料/漆料硬化的方法和机构,其中在喷涂/上漆和硬化的同时,模制物品仍保留在设有至少一个可转动模型配件(1)的模具中,该模具可以是单件式和多件式工具,其特征在于,在模制之后且优选在闭合模具的同时,在至少一个工作站的位置上将涂料/漆料施加到物品上,此后,优选在可转动模型配件(1)进一步向前转动至少一个工作站之后,通过来自紫外线光源(7)或其他类型能源的受控光照使涂上涂料/漆料的物品硬化。
2、如权利要求1所述的方法和机构,其特征在于,用于施加涂料/漆料的机构(5)具有一个双壁套筒机构(10)或类似机构,其中可生成负压、超压以及其他类型气流,其用于在物品(2)的周围建立与涂料/漆料相适应的受控气氛。
3、如其他权利要求中至少一项所述的方法和机构,其特征在于,用于喷涂/上漆和硬化的物品在从模制到完成加工而从模具中抽出的整个周期中牢固地位于可转动模型配件(1)中。
4、如其他权利要求中至少一项所述的方法和机构,其特征在于,通过紫外线光源(7)或其他类型能源实施硬化的机构被放置在一个套筒机构或类似的封闭环境中,以获得硬化的最佳环境。
5、如其他权利要求中至少一项所述的方法和机构,其特征在于,该模具被设计成具有一个封壳或类似物,从而喷涂/上漆过后的物品(2)可经受负压、加热、冷却或其他影响,从而最大程度地减少所用涂料/漆料中溶剂和/或增塑剂蒸发的时间。
6、如其他权利要求中至少一项所述的方法和机构,其特征在于,模具被设计成具有一个无尘封壳或类似物,从而物品(2)在整个生产周期中就会经受负压、加热、冷却或其他影响,从而最大程度地减少灰尘或其他污染物的数量。
7、如其他权利要求中至少一项所述的方法和机构,其特征在于,模具被设计成具有附加的工作站、掩蔽件或类似物,从而可施加一层以上相同或不同种类的涂料/漆料。
8、如其他权利要求中至少一项所述的方法和机构,其特征在于,模具被设计成具有执行静电喷涂/上漆的机构,从而最大程度地减少涂料/漆料的用量,且将灰尘和其他污染物的形成降到最小。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DKPA200101722 | 2001-11-17 | ||
DKPA200101722 | 2001-11-19 |
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CN1589197A true CN1589197A (zh) | 2005-03-02 |
CN1319724C CN1319724C (zh) | 2007-06-06 |
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US (1) | US7524538B2 (zh) |
EP (1) | EP1458555B1 (zh) |
JP (1) | JP4303118B2 (zh) |
KR (1) | KR20050044514A (zh) |
CN (1) | CN1319724C (zh) |
AT (1) | ATE516143T1 (zh) |
AU (1) | AU2002351719A1 (zh) |
MX (1) | MXPA04004727A (zh) |
WO (1) | WO2003049929A1 (zh) |
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CN101844389A (zh) * | 2009-03-27 | 2010-09-29 | 金宇轩 | 模内涂装整合系统的加工方法 |
CN102112238A (zh) * | 2008-07-29 | 2011-06-29 | 杜尔系统有限公司 | 用于暂存待涂漆物品的暂存装置 |
CN106985331A (zh) * | 2017-05-23 | 2017-07-28 | 昆山正工模具有限公司 | 一种模内真空喷涂装置 |
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WO2005075170A1 (en) | 2004-02-03 | 2005-08-18 | Linde Aktiengesellschaft | Surface coating device |
US20060118999A1 (en) | 2004-12-06 | 2006-06-08 | Bayer Materialscience Llc | Method of preparing a coated molded article |
DE102004062510A1 (de) * | 2004-12-24 | 2006-07-06 | Bayer Materialscience Ag | Verfahren zum Formen und Beschichten eines Substrats |
EP1683626A1 (en) * | 2005-01-25 | 2006-07-26 | Linde Aktiengesellschaft | Method and apparatus for treating injection moulded articles with gas |
US7314590B2 (en) * | 2005-09-20 | 2008-01-01 | Bayer Materialscience Llc | Method of preparing a coated molded plastic article |
DE102006020083A1 (de) * | 2006-04-29 | 2007-10-31 | Adcuram Maschinenbauholding Gmbh | Spritzgießmaschine für Reinraumtechnik |
US7951322B2 (en) * | 2006-06-13 | 2011-05-31 | Electroform Company | Method and apparatus for molding and assembling plural-part plastic assemblies |
TWI423873B (en) * | 2009-03-27 | 2014-01-21 | Method for in-mould coating and integration | |
DE102010019625B4 (de) * | 2009-05-27 | 2017-08-24 | Engel Austria Gmbh | Verfahren zur Herstellung einer Verbund- oder Hybridkonstruktion |
EP2579108B1 (fr) * | 2011-10-04 | 2014-05-14 | ETA SA Manufacture Horlogère Suisse | Procédé de réalisation et de décoration d'un composant transparent d'horlogerie |
US9312432B2 (en) * | 2012-03-13 | 2016-04-12 | Tsmc Solid State Lighting Ltd. | Growing an improved P-GaN layer of an LED through pressure ramping |
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JPS5952626A (ja) * | 1982-09-17 | 1984-03-27 | Sumitomo Chem Co Ltd | 成形方法 |
JPH0798341B2 (ja) * | 1986-11-28 | 1995-10-25 | 橋本フオ−ミング工業株式会社 | 装飾成形品の製造方法 |
US5254164A (en) * | 1992-06-15 | 1993-10-19 | Nordson Corp. | Coating system including indexing turret rotatable in the vertical and horizontal planes about a stationary shaft with loading and unloading of containers and closures from the edges of the turret |
JPH0880456A (ja) * | 1994-09-13 | 1996-03-26 | Suzuki Motor Corp | スプレーガン |
US5817345A (en) * | 1996-03-06 | 1998-10-06 | Husky Injection Molding System Ltd. | Turrent article molding machine and method of use |
FR2778134B1 (fr) * | 1998-04-29 | 2000-08-11 | Oreal | Procede et dispositif pour la fabrication de pieces peintes ou vernies en matiere plastique moulee |
US6468458B1 (en) * | 1998-10-23 | 2002-10-22 | Textron Automotive Company Inc, | Method for forming a composite product |
-
2002
- 2002-11-15 JP JP2003550968A patent/JP4303118B2/ja not_active Expired - Fee Related
- 2002-11-15 AU AU2002351719A patent/AU2002351719A1/en not_active Abandoned
- 2002-11-15 EP EP02787435A patent/EP1458555B1/en not_active Expired - Lifetime
- 2002-11-15 WO PCT/DK2002/000769 patent/WO2003049929A1/en active Application Filing
- 2002-11-15 US US10/496,042 patent/US7524538B2/en not_active Expired - Fee Related
- 2002-11-15 CN CNB028229819A patent/CN1319724C/zh not_active Expired - Fee Related
- 2002-11-15 MX MXPA04004727A patent/MXPA04004727A/es not_active Application Discontinuation
- 2002-11-15 AT AT02787435T patent/ATE516143T1/de not_active IP Right Cessation
-
2004
- 2004-05-18 KR KR1020047007547A patent/KR20050044514A/ko not_active Application Discontinuation
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102112238A (zh) * | 2008-07-29 | 2011-06-29 | 杜尔系统有限公司 | 用于暂存待涂漆物品的暂存装置 |
CN102112238B (zh) * | 2008-07-29 | 2013-10-23 | 杜尔系统有限公司 | 用于暂存待涂漆物品的暂存装置 |
US9481001B2 (en) | 2008-07-29 | 2016-11-01 | Dürr Systems GmbH | Intermediate storage unit for the intermediate storage of objects to be painted |
CN101844389A (zh) * | 2009-03-27 | 2010-09-29 | 金宇轩 | 模内涂装整合系统的加工方法 |
WO2010108455A1 (zh) * | 2009-03-27 | 2010-09-30 | Jin Yu-Syuan | 模内涂装整合系统的加工方法 |
CN101844389B (zh) * | 2009-03-27 | 2013-02-06 | 金宇轩 | 模内涂装整合系统的加工方法 |
CN106985331A (zh) * | 2017-05-23 | 2017-07-28 | 昆山正工模具有限公司 | 一种模内真空喷涂装置 |
CN106985331B (zh) * | 2017-05-23 | 2019-03-05 | 昆山正工模具有限公司 | 一种模内真空喷涂装置 |
Also Published As
Publication number | Publication date |
---|---|
AU2002351719A1 (en) | 2003-06-23 |
JP2005511290A (ja) | 2005-04-28 |
US7524538B2 (en) | 2009-04-28 |
CN1319724C (zh) | 2007-06-06 |
WO2003049929A1 (en) | 2003-06-19 |
MXPA04004727A (es) | 2004-08-12 |
KR20050044514A (en) | 2005-05-12 |
ATE516143T1 (de) | 2011-07-15 |
EP1458555B1 (en) | 2011-07-13 |
EP1458555A1 (en) | 2004-09-22 |
JP4303118B2 (ja) | 2009-07-29 |
US20050003100A1 (en) | 2005-01-06 |
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