CN1587468A - Animal leather yarn and its producing method - Google Patents

Animal leather yarn and its producing method Download PDF

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Publication number
CN1587468A
CN1587468A CNA2004100514073A CN200410051407A CN1587468A CN 1587468 A CN1587468 A CN 1587468A CN A2004100514073 A CNA2004100514073 A CN A2004100514073A CN 200410051407 A CN200410051407 A CN 200410051407A CN 1587468 A CN1587468 A CN 1587468A
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fiber
leather
animal skin
yarn
animal
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CNA2004100514073A
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CN1291084C (en
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刘立进
宋进清
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TIANWEI TEXTILE Tech SHENZHEN Co Ltd
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Individual
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Priority to US11/571,882 priority Critical patent/US20080072628A1/en
Application filed by Individual filed Critical Individual
Priority to CNB2004100514073A priority patent/CN1291084C/en
Publication of CN1587468A publication Critical patent/CN1587468A/en
Priority to JP2007530571A priority patent/JP2008512574A/en
Priority to PCT/CN2005/000350 priority patent/WO2006026899A1/en
Priority to EP05729005A priority patent/EP1795634A4/en
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Publication of CN1291084C publication Critical patent/CN1291084C/en
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/10Yarns or threads formed from collagenous materials, e.g. catgut

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The animal leather yarn consists of mechanically opened animal leather fiber in 1-100 wt% and other textile fiber in 0-99 wt%, and the animal leather fiber and other textile fiber in the same weight ratio are crossed and twisted to form the animal leather yarn. Leather processed through traditional leather processing process is further processed through sorting, swelling, opening, deguming, decolorizing, impurity eliminating, grading, mixing, finishing, carding into sliver, twisting and spinning to produce the animal leather yarn. The present invention raises the utilization of leather, expands leather application and, especially, solves the problem of waste leather utilization.

Description

A kind of Animal Skin yarn and production method thereof
Technical field
The present invention relates to a kind of textile yarn and production technology thereof, be meant a kind of yarn and production method thereof of utilizing the Animal Skin fiber to make especially.
Background technology
Animal classification, various in style on the earth, the Animal Skin resource is very abundant.Animal Skin mainly is made up of collagenous fibres.This fiber weaves mutually, closely twines with the pencil form, and each bundle collagenous fibres is made up of many fine collagenous fibres.Animal Skin is divided epidermal area, skin corium and hypodermis again.Wherein skin corium accounts for more than 90%, skin corium is made of papillaris pars and lamina reticularis again, the collagenous fibres braiding is loose in the papillaris pars, the collagenous fibres braiding closely in the lamina reticularis, collagenous fibres account for more than 95% of whole dermatotome fiber, and with crisscross in corium, the mutual intersection of the form of fibre bundle, be woven into three-dimensional network structure, constitute the main body of corium; Also have a spot of reticular fibre, elastomer and keratin fiber (reticular fibre is enclosed in the collagenous fiber bundle outside, forms a net collagenous fiber bundle is entangled, and elastomer and keratin fiber distribute therebetween); In addition, also have fat (various albumen) between fiber, fat, various line body to be full of and in fibre gap, be gel.
Human utilization to Animal Skin mainly is that the animal raw hide is processed into leather, be used for making clothes, shoes and hats, furniture, stomacher, automobile decoration material etc. then, the use of this leather requires very high to the selection of animal raw hide, both required size, require thin and thick even again, the every bit defective of leather as: scald note, fertile wrinkle, cut thorn, scratch, lice stings wound etc., all can make product become substandard products and waste product, by raw hide to leather, again by leather to finished product, the raw hide utilization rate of final animal has only 20~40%, and most of Animal Skin has become defect ware and tailing.
Tailing and the waste and old leather processing powdering with the animal's leather that have both at home and abroad be mixed and made into regenerative leather with other flour again, but product specification are low, and of poor quality, consumption is few, makes a large amount of natural animal skin serious waste of resources.
Summary of the invention
One of them purpose of the present invention is at the low problem of tailing utilization rate of the inferior skin of animal or leather particularly of Animal Skin in the prior art, and the problem of waste and old leather reclaiming utilization, provide and utilize machinery to open fine the fiber bundle-like collagenous fibres of Animal Skin to be processed into the Animal Skin fiber of monofilament shape, to utilize this Animal Skin fiber to be spun into a kind of Animal Skin yarn of the usefulness of weaving cotton cloth again.
Another object of the present invention provides a kind of production method of producing above-mentioned Animal Skin fiber yarn.
Last purpose of the present invention is achieved in that a kind of Animal Skin fiber yarn, wherein: this yarn opens fine Animal Skin fiber by 1~100% weight portion machinery and other textile fabric of 0~99% weight portion is formed, and Animal Skin fiber, the textile fabric vertical arrangement of quantity one-tenth according to the above ratio also interlaced, cross lay lumps together the formation yarn.
The Animal Skin fiber is the fiber that adopts Animal Skin such as ox, horse, mule, donkey, camel, deer, sheep, pig, dog, wolf, rabbit, mouse, kangaroo, crocodile, fish and snake or leather to make among the present invention, and the length of Animal Skin fiber is 10~45mm, fineness 0.3D~2.5D;
Other textile fabric among the present invention can be long fiber, it also can be staple fibre, both can be natural textile fiber as cotton, fiber crops, silk, Cashmere and Woolens, camel's hair camel hair, the rabbit suede rabbit hair, dog suede dog hair, Down and Feather etc., also can be chemical fibre such as terylene, acrylic fibers, spandex, polyamide fibre, polypropylene fibre etc. or by artificial refine as fibers such as viscose glue, day silk, soybean, milk, bamboo, crust fat.
Back of the present invention one purpose is achieved in that a kind of production method of Animal Skin yarn, comprise following processing step: by the conventional leather processing technology Animal Skin is processed into leather, then through sorting, swelling, open fibre, come unstuck, decolouring, removal of impurities, classification, be mixed, blowing, combing slivering, drafting, spinning.
The present invention compared with prior art has the following advantages:
(1) but the scope of application of Animal Skin has been widened in Animal Skin fiber yarn tatting, knitting and knit out various high, medium and low shelves fabrics and lining.
(2) Animal Skin fiber yarn tensile strength height, good springiness with its tatting, knitting and the various high, medium and low shelves fabric and the lining that knit out, have stronger elasticity, ABRASION RESISTANCE, thermal insulation, anti-flammability, sound absorption properties, water imbibition.
(3) raw material abundance, with low cost, the utilization rate of animal raw hide has only 20~40%, and all the other 60~80% are cheap defect ware, and the tailing resource of animal's leather is also very abundant, price is cheaper, also exists a large amount of cheap waste and old leathers to remain to be recycled simultaneously in the society.
(4) the invention provides a kind of Animal Skin or production Animal Skin fiber yarns such as cheap leather tailing, waste and old leather of utilizing, the production method of feasible process makes natural resources obtain utilizing more effectively and reasonably.
Description of drawings
Below in conjunction with drawings and Examples the present invention is further described.
Fig. 1 is the cross-sectional structure schematic diagram of Animal Skin fiber yarn among the present invention;
Fig. 2 is a process chart of the present invention;
Fig. 3 is the structural representation of fiber-opening apparatus among the present invention.
The specific embodiment
As shown in Figure 1, Animal Skin fiber yarn of the present invention, this yarn opens fine Animal Skin fiber 1 by 1~100% weight portion machinery and other textile fabric 2 of 0~99% weight portion is formed, and the length of Animal Skin fiber 1 is 10~45mm, fineness 0.3D~2.5D; Animal Skin fiber 1, the textile fabric 2 vertical arrangement of quantity one-tenth according to the above ratio also interlaced, cross lay lumps together the formation yarn.
Because of the Animal Skin fiber has very strong coherent, and have fine gap between fiber and the fiber, fiber can vertically be arranged, and twisted is together separately.Also gapped between the fiber of textile fabric and the fiber, fiber has coherent, and fiber also can vertically be arranged, and Animal Skin fiber and textile fabric can evenly be mixed twisted together.
Animal Skin fiber 1 is at least a Animal Skin that adopts in ox, horse, mule, donkey, camel, deer, sheep, pig, dog, wolf, rabbit, mouse, kangaroo, crocodile, fish and all animals of snake, conventional leather processing technologys such as, dehydration softening through raw material screening, liming, washing, deliming, tanning are finished (the waste and old leather that has formed leather defect ware, tailing and the recovery of animal's leather no longer passes through above-mentioned technology), and then through sorting, swelling, open fibre, come unstuck, decolouring, removal of impurities, classification, be mixed, blowing, combing slivering, drafting, spun yarn.Textile fabric 2 can adopt chemical fibre such as natural fabric such as cotton, fiber crops, silk, Cashmere and Woolens, camel's hair camel hair, the rabbit suede rabbit hair, dog suede dog hair, Down and Feather and terylene, acrylic fibers, spandex, polyamide fibre, polypropylene fibre and viscose glue, day silk, soybean, milk, bamboo, crust fat etc. to pass through the fiber of artificial, refinement.
As shown in Figure 2, the production method of Animal Skin fiber yarn is: at first with the animal's leather swelling, open fibre, come unstuck, decolour, making it form length is the Animal Skin fiber that 10~45mm, fineness are 0.3D~2.5D resilient beam, pulling force is big, be mixed equably together with textile fabric then, be spun into the Animal Skin fibre blending yarn through blowing, combing slivering, drafting; Below each step is elaborated.
1. by the conventional leather processing technology Animal Skin is processed into leather.The conventional leather processing technology is: raw material screening → liming → washing → deliming → tanning is softening → dehydration etc., above-mentioned technology belongs to maturation process, is not described further (the waste and old leather to the leather defect ware, tailing and the recovery that form animal's leather no longer passes through above-mentioned technology) at this.
2. the technology that forms of animal's leather fiber and yarn is: sorting → swelling → open fibre → come unstuck → decolour → removal of impurities → classification → be mixed → blowing → combing slivering → drafting → spin finished product.
(1) sorting: classification, classification are carried out in kind, shape, size, thin and thick by the animal leather.
(2) swelling: with the animal's leather that sub-elects, according to different classifications, with different swellers, the thunderous rice A (oleoyl amino acid sodium) of group, bleeding agent (as sulfosuccinate dibutyl ester sodium salt), efficient wetting agent (as aliphatic alcohol polyethenoxy base ether), lime, protease carry out swelling, make leather bulk.As swelling: goat upper leather is put into the aqueous solution of 28~30 ℃ of liquor ratios 600%, the A1.5% of thunder rice group, efficient wetting agent 1%, temperature and evenly stir, soaked 15~25 hours, clean then, dry to goat upper leather.
(3) open fibre: this step is a committed step of the present invention, adopt the Animal Skin and the leather fiber fiber-opening apparatus of development voluntarily, as shown in Figure 3, this device is made up of frame 10, the flat curtain 11 of feeding, feed roller 12, feed roller 13, dish plate 14, licker-in 15, the leakage end 16, dust cage 17 and hired roughneck 18; Leather after will handling when opening fibre is sent into feed roller 12 by the flat curtain 11 of feeding, compress by the feed roller 13 on the dish plate 14 and to send into licker-in 15, licker-in 15 by rotation at a high speed becomes fibrous to the leather shredding, be adsorbed on the dust cage 17 by the blower fan of dust cage 17 by the fiber of shredding, part is not opened fine fritter animal's leather and 16 is cut down at the bottom of the leakage below the licker-in 15.Be adsorbed on fiber on the dust cage 17 again through hired roughneck 18 revolution admission, fall from the blanking port of hired roughneck 18 belows.After opening fine the processing, can be processed into length to raw material is that 10~45mm, fineness are the Animal Skin fiber of 0.3D~2.5D.
(4) come unstuck: Animal Skin is through after opening fibre, also have between small amount of fibers fat (various albumen), fat, various line bodies etc. to be the processing of need coming unstuck of gelatinous surplus materials in its fiber, can adopt AT leather degreasing agent, KN leather degreasing agent, AD leather degreasing agent etc. to come unstuck.As can put into the aqueous solution (pH value 7.0~8.0) of the AD leather degreasing agent that contains 10% weight portion under the normal temperature to the goat upper leather fiber, evenly stirred 15~60 minutes, anhydrate then, dry.
(5) decolouring: animal's leather defect ware or leftover bits and pieces, and the fiber that the waste and old leather that reclaims is split into has shades of colour, need be with the processing of decolouring of bleaching powder or bleaching water, as the goat upper leather fiber that reclaims being put into 5% bleaching water (clorox) solution, 25~30 ℃ of temperature, evenly stirred 20~30 minutes, anhydrate then, dry.
(6) removal of impurities: remove other impurity in the Animal Skin fiber.
(7) classification:, the Animal Skin fiber is divided into different brackets by the air current classifying case.
(8) be mixed: be mixed with the Animal Skin fiber and the textile fabric of ratio after as required, to reach the even cross one another purpose of Animal Skin fiber and textile fabric with classification.For weakening the coherent of Animal Skin fiber, make yarn bar bar even, can in being mixed process, the Animal Skin fiber spray finish (finish refers to animal oil, vegetable oil, mineral oil, synthetic lipid) by 0.1~5% part by weight, or mix the talcum powder of 0.5~0.8% weight portion, to reach the Animal Skin fiber uniform purpose that is mixed.
(9) blowing: the fiber that will be mixed is by traditional blowing process, further removal of impurities and evenly being mixed, rolling then.
(10) combing slivering:, make the Animal Skin fiber or the blend fibre slivering of rolling by traditional carding process.
(11) drafting:, become the qualified sliver that enters spinning equipment by traditional drawing process (5-8 drafting continuously).
(12) spinning: according to the different size of leather fiber and different requirements, can select for use technologies such as traditional ring spinning, rotor spinning, air-jet spinning, friction spun yarn to carry out respectively, obtain the Animal Skin fiber yarn at last to yarn.
Embodiment 1: the production of kraft fibers
Sorting: with the waste and old ox-hide leather sifting sort of ox-hide leather, tailing or the recovery of different grammes per square metres, different-thickness, different sizes.
Swelling: well-graded ox-hide is put into the aqueous solution of 28~30 ℃ of the A2% of liquor ratio 500%, thunder rice group, efficient wetting agent 1.5%, temperature, stir evenly, soak that 18 hours, clear water are washed, dehydration, airing.
Open fibre: adopt homemade fibre separating machine to open fibre, the ox-hide leather processing after the swelling is become 15~45mm, the kraft fibers of fineness 1D~2.3D.
Come unstuck: the kraft fibers that shredding is good is put into the anionic and nonionic surfactant that is added with 5% weight portion and the degreasing aqueous solution (pH value 7.5~9.0) of 6% organic solvent, evenly stirs at normal temperatures, soaks 60 minutes, clear water and washes, dries.
Decolouring: the kraft fibers after will coming unstuck is put into the aqueous solution that is added with 5% weight portion bleaching water, and 35~37 ℃ of temperature soak that 35 minutes, clear water are washed, hot-air seasoning.
Removal of impurities: carry out combing by traditional carding machine, remove other impurity in the kraft fibers.
Classification:, kraft fibers is divided into different brackets by thickness length by the air-flow branch mailbox.
Embodiment 2: the production of pigskin fiber
Swelling: the aqueous solution that well-graded pigskin is put into 28~30 ℃ of the A1.8% of liquor ratio 550%, thunder rice group, efficient wetting agent 1.3%, temperature stirs evenly, soaks that 16 hours, clear water are washed, dehydration, airing.
Open fibre: adopt homemade fibre separating machine to open fibre, the pigskin leather processing after the swelling is become 10~40mm, the pigskin fiber of fineness 0.8D~2D.
Come unstuck: the pigskin fiber that shredding is good is put into the degreasing aqueous solution (pH value 6.0~8.0) that is added with 5% weight portion surfactant and 5% organic solvent, evenly stirs at normal temperatures, soaks 45 minutes, clear water and washes, dries.
Decolouring: the pigskin fiber after will coming unstuck is put into the aqueous solution that is added with 5% weight portion bleaching water, and 35~37 ℃ of temperature soak that 30 minutes, clear water are washed, hot-air seasoning.
Other sorting, removal of impurities, classification operation are with embodiment 1.
Embodiment 3: the production of goat skin fiber
Swelling: well-graded goat skin is put into the aqueous solution of 28~30 ℃ of the A1.5% of liquor ratio 600%, thunder rice group, efficient wetting agent 1%, temperature, stir evenly, soak that 15 hours, clear water are washed, dehydration, airing.
Open fibre: adopt homemade fibre separating machine to open fibre, the goat skin leather processing after the swelling is become 16~30mm, the goat skin fiber of fineness 0.3D~1D.
Come unstuck: the goat skin fiber that shredding is good is put into the normal-temperature water solution (pH value 7.0~8.0) that is added with 10% weight portion AD leather degreasing agent, evenly stirs, and soaks 20 minutes, clear water and washes, dries.
Decolouring: the goat skin fiber after will coming unstuck is put into the aqueous solution that is added with 5% weight portion bleaching water, and 25~30 ℃ of temperature stir evenly that 30 minutes, clear water are washed, hot-air seasoning.
Other sorting, removal of impurities, classification operation are with embodiment 1.
Embodiment 4: the production of carp skin fiber
Swelling: the aqueous solution that well-graded carp skin is put into 25~30 ℃ of the A1.5% of liquor ratio 700%, thunder rice group, efficient wetting agent 1.2%, temperature stirs evenly, soaks that 8 hours, clear water are washed, dehydration, airing.
Open fibre: adopt homemade fibre separating machine to open fibre, the carp skin leather processing after the swelling is become 10~30mm, the carp skin fiber of fineness 0.3D~1D.
Come unstuck: the carp skin fiber that shredding is good is put into the aqueous solution (pH value 6.5~7.5) that is added with 4% weight portion surfactant and 4% weight portion organic solvent, evenly stirs, and soaks 15 minutes, clear water and washes, dries.
Decolouring: the carp skin fiber after will coming unstuck is put into the aqueous solution that is added with 3% weight portion bleaching water, and 35~37 ℃ of temperature stir evenly that 20 minutes, clear water are washed, hot-air seasoning.
Other sorting, removal of impurities, classification operation are with embodiment 1.
Embodiment 5: the production of python skin fiber
Swelling: the aqueous solution of well-graded python skin being put into 25~30 ℃ of the A1.5% of liquor ratio 800%, thunder rice group, efficient wetting agent 1%, temperature evenly stirred, soaks 10 hour, then clear water wash, dehydration, airing.
Open fibre: adopt homemade fibre separating machine to open fibre, the python skin leather processing after the swelling is become 10~35mm, the python skin fiber of fineness 0.5D~1.8D.
Come unstuck: the python skin fiber that shredding is good is put into the aqueous solution (pH value 7.0~8.0) that is added with 10% weight portion AP degreasing agent, evenly stirs, and soaks 20 minutes, clear water and washes, dries.
Decolouring: the python skin fiber after will coming unstuck is put into the aqueous solution that is added with 3% weight portion bleaching water, and 35~37 ℃ of temperature stir evenly that 25 minutes, clear water are washed, hot-air seasoning.
Other sorting, removal of impurities, classification operation are with embodiment 1.
Embodiment 6: the production of kraft fibers yarn
Be mixed: kraft fibers (20~40mm that embodiment 1 is processed, 1.0D~2.0D), evenly sprinkling is added with the 2% palmitic aqueous solution, and evenly mixes the talcum powder of 0.8% weight portion, with the continuous shredding twice of traditional opener, at stuffy place airtight 24 hours.
Blowing: the kraft fibers that will be mixed is through traditional blowing process, further removal of impurities, is mixed evenly, then rolling.
Combing slivering:, make the kraft fibers slivering of rolling by traditional carding process.
Drafting:, make it become the qualified sliver that enters Weaving device with continuous 8 draftings of traditional drawing frame.
Spinning: decide spinning equipment twisting spun yarn with traditional ring.
Embodiment 7: the production of kraft fibers blended yarn
Be mixed: the kraft fibers (20mm-40mm that embodiment 1 is processed; 1.0D-2.0D), be mixed by the cotton fiber (38mm, 1.5D) of 65% weight portion and 35% weight portion, and evenly mix 0.5% talcum powder, with the continuous shredding twice of traditional opener, at stuffy place airtight 20 hours.
All the other operation blowings, combing slivering, drafting, spinning are identical with embodiment 6.
Embodiment 8: the production of goat skin fibre blending yarn
Be mixed: with the goat skin fiber (16mm-30mm that processes among the embodiment 3,0.3D-1.2D) be mixed by the spun ramee (38mm, 1.5D) of 50% weight portion and 50% weight portion, evenly spray and be added with the 1% palmitic aqueous solution, and evenly mix 0.5% talcum powder, with the continuous shredding twice of traditional opener, at stuffy place airtight 18 hours.
All the other operation blowings, combing slivering, drafting, identical with embodiment 6.
Spinning: with traditional rotor spinning equipment twisting spun yarn.
Embodiment 9: the production of python skin fibre blending yarn
Be mixed: (28mm~35mmm, 0.8D~1.8D) the spun polyster fibre (38mm, 1.5D) by 45% weight portion and 55% weight portion is mixed the python skin fiber that embodiment 5 is processed, evenly mix 0.6% talcum powder, with the continuous shredding twice of traditional opener, at stuffy place airtight 15 hours.
All the other operation blowings, combing slivering, drafting, identical with embodiment 6.
Spinning: with traditional air-jet spinning equipment twisting spun yarn.
Embodiment 10: the production of pigskin fibre blending yarn
Be mixed: (28mm~35mmm, 1.0D~1.8D) the spinnable viscose fiber (38mm, 1.5D) by 45% weight portion and 55% weight portion is mixed the pigskin fiber that embodiment 2 is processed, evenly mix 0.6% talcum powder, with the continuous shredding twice of traditional opener, at stuffy place airtight 15 hours.
All the other operation blowings, combing slivering, drafting, identical with embodiment 6.
Spinning: with traditional friction spinning machine twisting spun yarn.
Various yarn properties see attached list 1 in the foregoing description.
Subordinate list 1: Animal Skin yarn property table
Figure A20041005140700091

Claims (5)

1. Animal Skin fiber yarn, it is characterized in that: this yarn opens the Animal Skin fiber (1) of fibre by 1~100% weight portion machinery and other textile fabric (2) of 0~99% weight portion is formed, and the vertical arrangement of quantity one-tenth according to the above ratio of Animal Skin fiber (1), textile fabric (2) is also interlaced, the also mutual cross lay of the vertical arrangement of one-tenth lumps together the formation yarn.
2. Animal Skin fiber yarn according to claim 1 is characterized in that: the length of Animal Skin fiber (1) is 10~45mm, fineness 0.3D~2.5D.
3. Animal Skin fiber yarn according to claim 1 and 2 is characterized in that: the Animal Skin fiber is meant the fiber that at least a leather in the animals such as ox, horse, mule, donkey, camel, deer, sheep, pig, dog, wolf, rabbit, mouse, kangaroo, crocodile, fish and snake becomes.
4. Animal Skin fiber yarn according to claim 1 and 2 is characterized in that: textile fabric is meant that chemical fibre such as natural fabric such as cotton, fiber crops, silk, Cashmere and Woolens, camel's hair camel hair, the rabbit suede rabbit hair, dog suede dog hair, Down and Feather or terylene, acrylic fibers, spandex, polyamide fibre, polypropylene fibre and viscose glue, day silk, soybean, milk, bamboo, crust fat etc. pass through at least a in the fiber of artificial, refinement.
5. the production method of an Animal Skin yarn, comprise following processing step: by the conventional leather processing technology Animal Skin is processed into leather, then through sorting, swelling, open fibre, come unstuck, decolouring, removal of impurities, classification, be mixed, blowing, combing slivering, drafting, spinning.
CNB2004100514073A 2004-09-09 2004-09-09 Animal leather yarn and its producing method Expired - Fee Related CN1291084C (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US11/571,882 US20080072628A1 (en) 2004-09-09 2003-03-21 Kind of Yarn of Leather and Its Production Process
CNB2004100514073A CN1291084C (en) 2004-09-09 2004-09-09 Animal leather yarn and its producing method
JP2007530571A JP2008512574A (en) 2004-09-09 2005-03-21 Spinning of animal skin fiber and method for producing the same
PCT/CN2005/000350 WO2006026899A1 (en) 2004-09-09 2005-03-21 Yarn of leather and the process thereof
EP05729005A EP1795634A4 (en) 2004-09-09 2005-03-21 Yarn of leather and the process thereof

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Application Number Priority Date Filing Date Title
CNB2004100514073A CN1291084C (en) 2004-09-09 2004-09-09 Animal leather yarn and its producing method

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CN1587468A true CN1587468A (en) 2005-03-02
CN1291084C CN1291084C (en) 2006-12-20

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US (1) US20080072628A1 (en)
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CN1291084C (en) 2006-12-20
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