WO2023027258A1 - Leather fiber for leather spun yarn having improved physical properties - Google Patents

Abstract

The present invention relates to leather fiber for leather spun yarn, the leather fiber being included in leather spun yarn comprising leather fiber and synthetic fiber and, to leather spun yarn, wherein the leather fiber has an average length of 15 mm or more, the amount of fiber having a length of more than 15 mm is 40% or more, and leather fiber longer than conventional leather fiber is included, and thus the physical properties of leather spun yarn are improved.

Description

Leather fiber for leather spinning with improved physical properties

The present invention relates to a leather spun yarn with improved physical properties, and relates to a leather spun yarn in which the physical properties of the leather spun yarn are improved by containing leather fibers having a longer length than conventional leather fibers.

Natural leather is a tough shell that surrounds the body of an animal and is widely used in various fields such as bags, shoes, and furniture due to its excellent physical properties. Natural leather is manufactured as a product through chemical and physical processing after being separated from the animal's body. Among the various stages of processing, the process of cutting according to the design of the desired product is essential. However, a large amount of leather waste is generated during the cutting process, and most of the leather waste is treated by incineration and landfill, resulting in serious environmental problems. Therefore, various research and development related to the recycling method of leather waste is required.

Conventional methods of using leather waste are used as materials for spinning by using shaving scraps generated during the leather tanning process, such as Korean Patent Registration No. 765549 and Patent Publication No. 2018-0118386, or shaving scraps ( A method of manufacturing a web-type recycled leather sheet using shaving scrap) is mainly used.

The above prior art uses shaving scraps generated during the tanning process, and is not a method of utilizing plate/flake leather waste discharged as cutting or cutting waste substantially generated in the cutting process, and It is a technology that uses process by-products generated in the early stages of formation.

In addition, in Korean Patent Registration No. 2034218, a spun leather yarn containing leather fibers produced by carding mixed fibers of leather fibers, general fibers, and polymer fibers to produce slivers, and twisting and drafting the slivers. has been initiated.

However, the conventional leather fiber has a problem in that the length is about 10 mm on average, and it is difficult to manufacture it as a spun yarn, and the physical properties such as tensile strength are not high due to the short length of the leather fiber.

Accordingly, the present inventors developed leather fibers capable of producing leather spun yarn from leather waste, enabling the production of fabrics, knitted fabrics, and lace products including the properties of leather, and replacing existing leather materials used in bags and sneakers for seasonal changes. The present invention was completed by discovering that high-quality leather spun yarn including heat retention and general flame retardancy of natural leather can be produced without being affected.

The present invention was invented to solve the problems of the prior art as described above, and by improving the length, thickness, strength, fineness, etc. of leather fibers contained in leather spun yarns such as synthetic fibers, leather fibers longer than conventional leather fibers It is an object of the present invention to provide a leather fiber capable of producing leather spun yarn having improved physical properties by containing the present invention.

In addition, an object of the present invention is to provide a leather fiber capable of producing leather spun yarn having improved physical properties that can adjust the thickness because the length/thickness ratio of the leather fiber contained in the leather spun yarn is excellent.

The present invention is a leather fiber for leather spinning contained in leather spun yarn formed by containing leather fiber and synthetic fiber, wherein the leather fiber has an average length of 15 mm or more, and a fiber content exceeding 15 mm is 40% or more. It provides a leather fiber for leather spinning with improved physical properties.

In addition, the leather fiber provides a leather fiber for leather spinning with improved physical properties, characterized in that the average thickness is 0.05 ~ 0.15 mm.

In addition, the leather fiber provides a leather fiber for leather spinning with improved physical properties, characterized in that the length / thickness ratio is 130 or more on average.

In addition, the leather fiber provides a leather fiber for leather spinning with improved physical properties, characterized in that the length / thickness ratio exceeds 200 and the fiber content is 15% or more.

In addition, the leather spun yarn provides a leather fiber for leather spinning with improved physical properties, characterized in that the leather fiber contains 10% by weight or more.

In addition, the synthetic fibers include polyamide-based fibers, polyester-based fibers, polyurethane-based fibers, polyurea-based fibers, polyacrylic fibers, polyvinyl alcohol-based fibers, polyvinyl chloride-based fibers, polyvinylidene chloride-based fibers, and polypropylene. It provides a leather fiber for leather spinning with improved physical properties, characterized in that any one or two or more of based fibers, polyethylene fibers, polystyrene fibers, and polyfluoroethylene fibers.

In addition, the leather fiber provides a leather fiber for leather spinning with improved physical properties, characterized in that it is contained in the leather spinning yarn in an amount of 10% by weight or more.

In addition, it provides a leather article characterized in that it comprises the leather fiber for leather spinning.

As described above, the leather spun yarn with improved physical properties according to the present invention improves the length of leather fibers contained in the leather spun yarn, such as synthetic fibers, and contains leather fibers longer than conventional leather fibers to improve physical properties such as tensile strength. there is

In addition, the length / thickness ratio of the leather fibers contained in the leather spun yarn is excellent, so that the thickness can be adjusted.

In addition, the leather fiber used in the present invention has a beneficial effect on the environment by being able to utilize the discarded leather as a leather fiber after being cut.

1 is a view showing the length distribution of leather fibers according to the present invention.

2 is a diagram showing the thickness distribution of leather fibers according to the present invention.

3 is a diagram showing the length / thickness ratio distribution of leather fibers according to the present invention.

Hereinafter, a preferred embodiment of the present invention will be described in detail with reference to the accompanying drawings. First of all, it should be noted that in the drawings, the same components or parts are denoted by the same reference numerals as much as possible. In describing the present invention, detailed descriptions of related known functions or configurations are omitted in order not to obscure the gist of the present invention.

As used herein, the terms 'about', 'substantially', and the like are used in a sense at or approximating that number when manufacturing and material tolerances inherent in the stated meaning are given, and are intended to convey an understanding of the present invention. Accurate or absolute figures are used to help prevent exploitation by unscrupulous infringers of the disclosed disclosure.

The 'leather fiber' in the leather fiber used for leather spinning of the present invention means a set of leather fibers contained in the leather spinning yarn.

In the present invention, when the numerical range is described as a range of 'X ~ Y (Y>X)', if a limiting phrase such as less than, less than, more than, or more is not disclosed after X and Y, 'more than X, less than Y' define it as

In addition, in the present invention, when the content of fibers is described as '%', when limiting phrases such as 'jungrang' and 'volume' are not disclosed, it means the content ratio according to the total number of fibers.

The present invention relates to a leather fiber for leather spinning contained in leather spun yarn formed by containing leather fiber and synthetic fiber, wherein the leather fiber contained in the leather spun yarn has an average length of 15 mm or more, and a fiber content exceeding 15 mm. It is characterized in that this is 40% or more.

In general, spun yarn is prevented from unraveling due to frictional force between fibers and maintains its thread state, and the longer the length of the fiber contained, the higher the frictional force and thus the strength is improved.

The average length of the leather fibers contained in the leather spun yarn of the present invention is 15 mm or more, and the friction between the leather fibers can be improved by being included in the leather spun yarn.

In addition, the leather fibers contained in the leather spun yarn of the present invention contain a lot of longer leather fibers with a fiber content of more than 15 mm and more than 40%, so the frictional force between fibers will be further improved.

In addition, the leather fiber contained in the leather spun yarn of the present invention is characterized in that the average thickness is 0.05 ~ 0.15 mm and the length / thickness ratio is 130 or more on average.

If the thickness of the leather fiber is too thick, it is difficult to control the thickness of the leather spun yarn, and the texture of the leather spun yarn may be impaired, and if the leather fiber is too thin, fairness may be deteriorated. mm would be preferred.

In addition, the larger the length / thickness ratio of leather fibers contained in the leather spun yarn, the longer and thinner the leather fibers, which improves fairness and makes it easier to control the thickness of the leather yarn. will be.

The leather fiber contained in the leather spun yarn of the present invention preferably has a length/thickness ratio greater than 200 and a fiber content of 15% or more in order to improve the smoothness of thickness control and physical properties of the leather spun yarn.

When the length/thickness ratio of the leather fibers exceeds 200, the higher the fiber content, the greater the content of long and thin leather fibers, which improves fairness and improves physical properties.

The leather fiber used in the present invention is obtained from leather, and the leather is a piece/plate-shaped scrap and has a certain length, so that the fiber form can be extracted.

The method for obtaining the leather fibers can be obtained by crushing the leather with a leather waste treatment device of Republic of Korea Patent No. 1804099 to destroy the bonding strength between fibers, and then separating the leather fibers from the shredded leather through a separation process.

In order to obtain a long leather fiber, the leather fiber of the present invention is preferably obtained by using a scrap having a length of one side of about 100 mm or more and an area of 50 to 250 cm 2 .

The separation process separates leather fibers and separates uniform leather fibers to improve the physical properties of leather spun yarn and uniformity of leather products including leather spun yarn.

In the micronized leather formed by the leather waste treatment device, leather fibers having a uniform length and thickness must be separated through a separation process in a state in which leather fibers in powder form and irregular leather fibers ranging in thickness from several μm to hundreds of μm are mixed. .

The separation process is a process of separating leather fibers through air pressure, and air pressure is applied to leather fibers, and the leather fibers can be separated through a moving distance of the leather fibers due to the air pressure.

The separation process may be performed by moving the leather fibers vertically or horizontally with the ground through air pressure to separate the leather fibers, and moving them vertically to obtain leather fibers suspended at a certain height.

The air pressure of the separation process is preferably 4 to 10 bar, more preferably 5 to 8 bar air pressure.

The separation process is possible to uniformly classify the thickness and length of fibers as the number of times increases, but it is preferable to carry out 2 to 8 times for process efficiency, and more preferably 3 to 5 times.

As an example of the separation process, it may be carried out in a manner in which leather fibers are lifted with air pressure of 4 to 10 bar in a pipe formed perpendicular to the ground, and then leather fibers supported by 1 to 4 m are obtained.

In the present invention, it is possible to obtain leather fibers with a thin thickness and a long length by obtaining leather fibers by inhaling the leather fibers selected by floatation with a suction device of 2 to 8 bar.

Various leathers such as cowhide, sheepskin, and pigskin can be used as the leather that can be used in the present invention. However, sheepskin or pigskin is thinner and has lower strength than cowhide, so the length of leather fibers is too short, making it difficult to manufacture with spun yarn. Therefore, it would be desirable to extract leather fibers from cowhide.

The synthetic fiber contained in the leather spun yarn like the leather fiber is polyamide-based fiber, polyester-based fiber, polyurethane-based fiber, polyurea-based fiber, polyacrylic fiber, polyvinyl alcohol-based fiber, polyvinyl chloride-based fiber, poly Vinylidene chloride-based fibers, polypropylene-based fibers, polyethylene-based fibers, polystyrene-based fibers and polyfluoroethylene-based fibers can be used, and various synthetic fibers can be used depending on the purpose and purpose of use, and one or more than two synthetic fibers would be usable with

As for the synthetic fiber, it would be preferable to use regenerated synthetic fiber for eco-friendliness.

The leather spun yarn of the present invention is formed of leather spun yarn including leather fibers and synthetic fibers, but depending on the use and purpose of the leather spun yarn, it may be used together with natural fibers or regenerated fibers to produce leather spun yarn.

The leather fiber contained in the leather spun yarn is preferably contained in an amount of 10% by weight or more, and when it is contained in less than 10% by weight, sensibility such as a unique touch of leather may be deteriorated.

The leather spun yarn of the present invention may be manufactured using a carding machine, a drawing machine, a spinning machine, and a spinning machine using leather fibers and synthetic fibers, and may be manufactured by a general spun yarn manufacturing process.

As described above, the leather spun yarn having improved physical properties of the present invention containing the long leather fibers will be used for various leather articles due to improved physical properties.

Hereinafter, leather fibers and leather spun yarns for leather spinning with improved physical properties were manufactured according to Examples according to the present invention. The present invention is not limited to these examples.

Example 1

After pulverizing the cowhide scraps using a leather waste treatment device, each leather fiber was obtained by a separate process.

As the cowhide scrap, a scrap having one side of 100 mm or more and an area of about 50 to 200 cm 2 was used.

The separation process is carried out in such a way as to lift the leather fibers with an air pressure of about 6 bar in a tube formed perpendicular to the ground, and then to obtain leather fibers that are inhaled by a suction device of about 4 bar from the leather fibers that are supported at least about 1.8 m. A total of two runs were performed to obtain leather fibers.

A leather spun yarn of 600 denier (Nm 15 count) was prepared by mixing the obtained leather fiber with a fineness of 1.5 denier and a polyester staple fiber having a fiber length of 51 mm at a weight ratio of 35:65.

Example 2

It was prepared in the same manner as in Example 1, but after the leather fibers were lifted with an air pressure of about 7 bar in the separation process, the leather fibers suspended for about 2 m or more were sucked into a suction device of about 4.5 bar to make leather fibers into leather fibers. manufactured.

Example 3

It was prepared in the same manner as in Example 1, but after the leather fiber was lifted with an air pressure of about 8 bar in the separation process, the leather fiber suspended at about 2.2 m or more was sucked into a suction device of about 4.5 bar, and the leather fiber was used as a leather spun yarn. was manufactured.

comparative example

It was prepared in the same manner as in Example 1, but after the leather fiber was lifted with an air pressure of about 5 bar in the separation process, a leather fiber floating about 2 m or more was obtained to prepare a leather spun yarn.

◈ 1.5 g of the leather fibers obtained in Examples 1 to 3 and Comparative Example were collected, and the number of leather fibers contained in 1.5 g and the length and thickness of each leather fiber were measured, and the length in Table 1, the thickness in Table 2, Table 3 shows the length/thickness ratio.

Length (mm)	comparative example	Example 1	Example 2		Example 3	average of examples
5 or less	469	76	32	39		49
5 to 10	489	249	237	322		269.33
10 to 15	221	358	341	402		367
15 to 20	152	265	305	293		287.67
20 to 25	86	171	140	221		177.33
25 to 30	25	59	113	59		77
30 to 35	23	13	58	51		40.67
35 to 40	6	51	19	14		28
40-45	3	17	5	3		8.33
45 to 50	0	One	5	3		3
50 to 55	One	2	6	0		2.67
over 55	0	2	2	One		1.67
total number of fibers	1475	1264	1252	1408		1308
average	9.52	15.21	15.65	15.36		15.41
Fiber content above 15 mm (%)	20.07	45.97	52.16	45.81		47.89

Figure 1 is a graph showing the length distribution of leather fibers according to the present invention, as shown in Table 1 and Figure 1, the leather fibers according to the present invention had the most leather fibers with a length of 10 to 15 mm, and exceeded 15 mm. It can be seen that the leather fibers of the comparative example are 5 to 10 mm leather fibers the most, 5 mm or less leather fibers are also contained a lot, and leather fibers exceeding 15 mm are 20.07%. It can be seen that there is a large difference between the leather fibers of the examples.

It can be seen that the leather fiber of the present invention has an average length of 15.41 mm, which is much longer than the 9.52 mm of the comparative example.

Thickness (mm)	comparative example	Example 1	Example 2	Example 3	average of examples
0.05 or less	13	2	9	One	4
0.05~0.1	309	273	323	285	293.67
0.10~0.15	902	785	696	889	790
0.15~0.2	222	165	182	221	189.33
0.20.25	28	32	34	9	25
0.25~0.3	One	7	6	2	5
greater than 0.3	0	0	2	One	One
total number of fibers	1475	1264	1252	1408	1308
average	0.122	0.1154	0.1205	0.124	0.12

Figure 2 is a graph showing the thickness distribution of leather fibers according to the present invention, as shown in Table 2 and Figure 2, the thickness of the leather fibers according to the present invention and the leather fibers of the comparative examples are all 0.1 ~ 0.15 mm, the most, and the examples and It can be seen that all of the comparative examples have a similar average thickness of about 0.115 to 0.125 mm.

length/thickness ratio	comparative example	Example 1	Example 2	Example 3	average of examples
less than 50	205	96	89	102	95.67
50 to 100	332	325	342	356	351
100 to 150	435	406	375	401	394
150 to 200	305	215	223	258	232
200-250	139	99	162	130	120.33
250 to 300	45	64	35	102	67
300 to 350	13	29	18	29	25.33
350~400	0	18	2	23	14.33
400 to 450	One	4	3	4	3.67
450~500	0	6	2	One	3
500 to 550	0	2	0	One	One
over 550	0	0	One	One	0.67
total number of fibers	1475	1264	1252	1408	1308
average	115.05	140.58	132.47	135.1	136.05
length/thickness ratio More than 200 fibers content(%)	13.42	17.56	17.81	20.67	17.99

Figure 3 is a graph showing the length / thickness ratio distribution of leather fibers according to the present invention, as shown in Table 3 and Figure 3, the length / thickness ratio of the leather fibers according to the present invention and the leather fibers of the comparative examples are all 150 to 200 It can be seen that many leather fibers in the examples have a small number of leather fibers having a length / thickness ratio of 50 or less, and a large number of leather fibers with a large length / thickness ratio, and have an average length / thickness ratio of 130 or more, and a length / thickness ratio of 200 It can be seen that the excess fiber content is 15% or more.

However, in the comparative example, the number of leather fibers having a value of 50 or less is large, and the number of fibers decreases significantly as the length/thickness ratio increases, so there is a big difference between the example with an average length/thickness ratio of 115.05, and the length/thickness ratio of fibers exceeding 200. It can be seen that the content is 13.42%, which is significantly lower than that of the Example.

◈ The tensile strength of the leather spun yarns prepared in Examples 1 to 3 and Comparative Examples was measured and shown in Table 4.

Tensile strength was measured using Instron's universal testing machine (UTM, Universal Testing Machine) under a measurement temperature of 20 ° C and a humidity of 65% in accordance with the ASTM D2256 standard.

division	comparative example	Example 1	Example 2	Example 3
Tensile strength (g/d)	0.8	2.7	2.5	3.0

As shown in Table 4, it can be seen that the tensile strength of the improved physical properties according to the present invention is 2.5 to 3.0 g / d, which is much better than the 0.8 g / d of the comparative example. This is because the length of the leather fiber contained in the leather spun yarn of the present invention is It can be seen that the tensile strength of the leather spun yarn is greatly improved by increasing the frictional force between the fibers forming the leather spun yarn due to the presence of a large number of long leather fibers having a large length/thickness ratio.

Claims (8)

1. In the leather fiber for leather spinning contained in the leather spun yarn formed by containing leather fiber and synthetic fiber,

   The leather fiber has an average length of 15 mm or more, and a fiber content of more than 15 mm is 40% or more.
2. According to claim 1,

   The leather fiber is a leather fiber for leather spinning with improved physical properties, characterized in that the average thickness is 0.05 ~ 0.15 mm.
3. According to claim 1,

   The leather fiber is a leather fiber for leather spinning with improved physical properties, characterized in that the length / thickness ratio is 130 or more on average.
4. According to claim 1,

   The leather fiber has a length / thickness ratio exceeding 200 and a fiber content of 15% or more.
5. According to claim 1,

   The leather spun yarn is leather fiber for leather spinning with improved physical properties, characterized in that the leather fiber contains 10% by weight or more.
6. According to claim 1,

   The synthetic fibers are polyamide fibers, polyester fibers, polyurethane fibers, polyurea fibers, polyacrylic fibers, polyvinyl alcohol fibers, polyvinyl chloride fibers, polyvinylidene chloride fibers, and polypropylene fibers. Fiber, polyethylene-based fiber, polystyrene-based fiber, leather fiber for leather spinning with improved physical properties, characterized in that any one or two or more of polyfluoroethylene-based fiber.
7. According to claim 1,

   The leather fiber is leather fiber for leather spinning with improved physical properties, characterized in that it is contained in the leather spinning yarn in an amount of 10% by weight or more.
8. A leather article comprising the leather spun yarn of any one of claims 1 to 7.

Images