CN1779002B - Reducing leather base cloth with collagenous fiber and processing method thereof - Google Patents

Reducing leather base cloth with collagenous fiber and processing method thereof Download PDF

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Publication number
CN1779002B
CN1779002B CN2004100972688A CN200410097268A CN1779002B CN 1779002 B CN1779002 B CN 1779002B CN 2004100972688 A CN2004100972688 A CN 2004100972688A CN 200410097268 A CN200410097268 A CN 200410097268A CN 1779002 B CN1779002 B CN 1779002B
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leather
liquid
raw material
base cloth
processing method
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CN1779002A (en
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张立文
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Zhejiang Hongzhan New Materials Co Ltd
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张立文
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Abstract

The invention is about the reduced-leather based cloth of the collagenous fibers and its process. The based cloth is made of the collagenous fibers, and the fibers cross with each other to form the stereoscopic graticule as the real leather structure. The based cloth has the good wear-resisting and high tensile strength; also it has the character of the moisture absorption, aeration, fire retardant and comfort. So it can be used to the clothing, shoe or hat, sofa and the bed clothes.

Description

Collagen fiber reducing leather base cloth and processing method thereof
Technical field
The present invention relates to the dermatine material, is a kind of reducing leather base cloth and processing method thereof of utilizing Animal Skin or animal's leather collagenous fibres to make.
At present, traditional imitative leather goods have artificial leather, synthetic leather, regenerated leather.Wherein artificial leather and synthetic leather are respectively that pvc, pu are coated on woven cloth or knitted cloth or the nonwoven fabric; Regenerated leather is the leftover pieces of various leathers to be pulverized form powder by adhesive or meldable fibre adhering and pressing together.
Animal Skin is a kind of material that covers above the animal health, it is a kind of very complicated biological tissue, the animal raw hide could form leather through a series of machineries of existing tanning technology and the processing of chemistry, different types of Animal Skin has different features, but its structure all is similar to, and the main histological structure of Animal Skin is divided into:
1, epidermal area, this layer accounts for the 0.5%-5% of skin thickness according to different skin kinds, arranged by difform cell to form, and this layer will be removed together with hair in the process hides process.
2, skin corium accounts for more than 90% of whole cortex according to different its thickness of skin kind or weight, is unique processing object of existing tanning technology, and leather is processed into by skin corium in other words.Corium is compact connective, mainly form by collagenous fibres, elastomer, reticular fibre, wherein collagenous fibres account for 95%-98%, collagenous fibres are that pencil can branch, interspersed mutually interweaving in corium, crisscross, this bundle fiber is divided into several strands thinner fibre bundle sometimes, these thinner fibre bundles merge with other fibre bundle again and interweave, and form a kind of special space network.Therefore this special structure makes skin or leather have very high mechanics brute force.In addition, also contain non-fibre composition in the corium, as: blood vessel, adipose gland, interfibrillar substance and adipocyte etc.These materials major part in the process hides process is removed.
3, below the corium be hypodermis layer, it mainly is made up of braiding loose collagenous fibres and part elastomer.This layer is too loose owing to collagenous fibres weave mutually, is the discommodity in the existing leather industry.But this cortex is well to use object for the technology of the present invention.
Utilization for Animal Skin mainly is process hides at present, leather industry is an ancient industry, it is that low output with the high investment of raw material and product is a feature, has only the raw material skin of 20%-40% to change finished leather in leather-making technology, and all the other become discarded object or byproduct.Have many tailings to form discarded object in addition in the process of leather goods again, these skins or leather castoff cause serious pollution to ecological environment.
The length that collagenous fiber bundle exists in skin or leather is considerably beyond the desired length of weaving, but because collagenous fiber bundle removes braiding is tangled mutually the while and is sticked together by materials such as interfibrillar substance are bonding under the nature in skin or leather, its cohesive force is very firm, substantially exceeds the tension brute force of its fiber itself.Therefore, utilize existing shredding technology or can only be processed into very short flour by other any prior aries under nature, the moulding of can't tangling each other of this flour does not more have spinnability.Use present regenerated leather process technology above flour adhering and pressing to be formed regenerated leather together by adhesive or meldable fibre, the structure of this regenerated leather material and composition and former animal's leather all have very big difference, therefore, regenerated leather in gas permeability, hygroscopicity, tensile strength, ABRASION RESISTANCE and feel and comfortableness all not as former animal's leather, still belong to low grade products, this natural precious resources can not be made the best use of everything.But the intrinsic size of former animal's leather is restricted, particularly the size of thickness unanimity, count unanimity is subjected to stricter restriction on selecting for use, therefore former animal's leather can not be wide as, the scope of application as the textiles Crop From when making goods, and especially various leftover pieces and occurring in nature meiofauna skin kind various in style more can't be used.
Summary of the invention
The purpose of this invention is to provide a kind of utilization size, variform any Animal Skin or leather, its tailing particularly, the collagenous fiber bundle of natural woven condition is resolved into the collagenous fiber bundle that can spin length that has of the shape that looses, and having rebulid a kind of collagenous fiber bundle and branch thereof interts mutually and interweaves, crisscross solid netted braided structure, identical with the institutional framework in the former animal's leather, and have enough width as textile fabric, length is consistent with each position braiding tightness, a kind of collagenous fiber bundle reducing leather base cloth and the processing method thereof of minimal thickness unanimity are to solve existing artificial leather, synthetic leather, the shortcoming and defect that regenerated leather and leather exist.
The object of the present invention is achieved like this: this base cloth is made up of collagenous fiber bundle, and collagenous fiber bundle and branch thereof intert mutually and interweave, the solid netted braided structure of crisscross formation.
With the various leftover bits and pieces before the tanning in animal raw hide and the leather-making technology, its processing method comprises following processing step: raw material screening, dipping, depilation, liquid are separated fibre, degreasing, washing and sterilizing, dewatered drying, are mixed, shredding, combing, lapping, thorn are solid.Liquid is separated fibre and is carried out in the liquid fiber uncoiling machine.
With various animal's leathers and leftover bits and pieces thereof and waste and old leather is that its processing method of raw material comprises following processing step: raw material screening, dipping, liquid are separated fibre, washing and sterilizing, dewatered drying, are mixed, shredding, combing lapping, thorn are solid.Liquid is separated fibre and is carried out in the liquid fiber uncoiling machine.
Collagenous fibres are the diffusing shape collagenous fiber bundles that adopt at least a Animal Skin in ox, sheep, pig, horse, dog, deer, rabbit, crocodile and all animals of snake or leather and leftover bits and pieces and waste and old leather thereof to make.
This invention compared with prior art has the following advantages, and the braided structure and the animal corium of (1) this base cloth collagenous fiber bundle are extremely similar, have the ABRASION RESISTANCE identical with animal's leather, hygroscopicity, gas permeability, advantages such as anti-flammability and comfort property; (2) wide in variety, utilize different types of Animal Skin or leather can form the product of multiple different appearance characteristics, also various animals skin or leather collagen fiber can be mixed to use and learn from other's strong points to offset one's weaknesses, form various different-thickness for raw material, different in width, the various products of different counts.(3) the wide cost of raw material is low, available Animal Skin or the blanking of leather corner, the Animal Skin and the waste and old leather and fur products discarded object of not enough any use size, it is strong price advantage, (4) of many uses, the back processing of this base cloth can be adopted existing artificial leather arbitrarily, technologies such as synthetic leather form various new products, the characteristic that also can utilize collagenous fibres simultaneously is by pickling or caustic dip or immerse rapidly and make the collagenous fibres surface form gel in the hot water to restore, formation adds a kind of heavy leather of going back of bonded structure as the winding of corium, (5) this technology advanced person, particularly liquid is separated fine technology, making the bulk fiber bundle that obtains have enough length, is fiber-spinnable, arbitrarily carding, give full play to existing dry non-woven equipment and technology, make product design freely.
Description of drawings
Fig. 1. collagenous fiber bundle reducing leather base cloth cross section structure schematic diagram;
Fig. 2. collagenous fiber bundle reducing leather base cloth processing process figure.
Among Fig. 1,1 collagenous fiber bundle, 2 collagenous fiber bundle branches, 3 base cloth surface fiber heads.
Embodiment one. and collagenous fiber bundle 100% by weight; Own a small amount of or micro-elastomer in other raw hide, reticular fibre, sweat gland, adipose gland, blood vessel, and the artificial a small amount of non-fibrous material that adds is ignored in material such as non-fiber and the preceding road of the process hides technology.
Technological process: raw material screening → dipping → depilation → liquid is separated the solid finished product of fibre → degreasing → washing and sterilizing → dewatered drying → be mixed → shredding → combing → lapping → thorn.
Specification
1, raw material screening: select at least a animal raw hide in ox, pig, horse, sheep dog, deer, rabbit, crocodile and all animals of snake or the process hides process corner blanking for use without tanning.
2, dipping: dipping is 1-48 hour in liquid, and fluid temperature is a normal temperature, makes rawhide or graywall revert to the fresh hide shape.
3, depilation: adopt existing alkaline process or enzyme unhairing technical matters.
4, liquid is separated fibre: adopt the liquid fiber uncoiling machine, make above cladding in the liquid fiber uncoiling machine, under the state of liquid infiltration, be subjected to reciprocating type repeatedly freely impacting and/or combing, collagenous fiber bundle is loosened fully or form single pencil collagenous fiber bundle, it is that the hired roughneck of more than one existing shredding equipment employing and/or the opening box of carding machines are installed in container that the liquid fiber uncoiling machine can be made by oneself, and the hired roughneck is card wire formula, serration type, blade type or hybrid.
5, degreasing: adopt existing emulsification or saponification technology, above-mentioned material carries out degreasing in the liquid fiber uncoiling machine, be subjected to further free style shredding simultaneously.
6, washing and sterilizing: with the fibre bundle of degreasing by existing scouring of wool technology clean remove saponified or emulsion again with pickling method and/or the sterilization of fungi-proofing liquid dipping.Its sterilization technology is same as the prior art.
7, dewatered drying: adopt the drier dehydration, dry with dryer, bake out temperature is 30 ℃-60 ℃.
8, be mixed: require to select for use variety classes or different classes of raw material to carry out mixed preparing according to product design.
9, shredding: adopt existing wool spinning or cotton spinning apparatus technology shredding removal of impurities.
10, combing: adopt existing carding process to carry out.
11, lapping: same as the prior art.
12, thorn is solid: adopt existing acupuncture or water thorn technical equipment.
Example two. collagenous fiber bundle 100% by weight; Intrinsic micro-elastomer in the former leather, the artificial non-fibrous material that adds in residue such as reticular fibre and non-fibrous material and the leather-making technology is ignored.
Technological process: raw material screening → dipping → liquid is separated the solid finished product of fibre → dewatered drying → be mixed → shredding → combing → lapping → thorn.
Specification:
1, raw material screening: select various various types of leather and corner blanking and waste and old leathers for use through the process for tanning tanning.
2, dipping: dipping is more than 10 hours in 15 ℃-60 ℃ liquid, and all the other technologies are with example one
It is water that embodiment one and two maceration extracts and liquid are separated fine used liquid, according to skin or leather material difference, adds at least a in the alkaloids of the bleeding agent of grease, 0.2-1.5% of washing agent, the 1-10% of 0.2-2% and 0.03-1% again by water weight.

Claims (2)

1. the processing method of a collagen fiber reducing leather base cloth, it is characterized in that: it is to expect to be raw material with Animal Skin and underfooting, limit thereof, and comprise following processing step: raw material screening, dipping, depilation, liquid is separated fibre, degreasing, washing and sterilizing, dewatered drying, be mixed, shredding, combing, lapping, the solid finished product of thorn, liquid in the above-mentioned processing step is separated fine and degreasing is carried out in liquid fiber uncoiling machine kind, described liquid fiber uncoiling machine is that the hired roughneck of more than one existing shredding equipment employing and/or the opening box of carding machines are installed in container, and the hired roughneck is the card wire formula, serration type, blade type or hybrid.
2. the processing method of a collagen fiber reducing leather base cloth, it is characterized in that: it is to expect and discard leather to be raw material with leather and underfooting, limit thereof, and comprise following processing step: raw material screening, dipping, liquid are separated fibre, dewatered drying, are mixed, shredding, combing, lapping, the solid finished product of thorn, liquid in the above-mentioned processing step is separated fibre and is carried out in liquid fiber uncoiling machine kind, described liquid fiber uncoiling machine is that the hired roughneck of more than one existing shredding equipment employing and/or the opening box of carding machines are installed in container, and the hired roughneck is card wire formula, serration type, blade type or hybrid.
CN2004100972688A 2004-11-20 2004-11-20 Reducing leather base cloth with collagenous fiber and processing method thereof Expired - Fee Related CN1779002B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102182015A (en) * 2011-05-06 2011-09-14 浙江弘扬无纺新材料有限公司 Method for producing artificial leather base material by compounding collagen fibers by utilizing spun-laced water jetting

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120295505A1 (en) 2010-01-16 2012-11-22 Zhejiang Hongzhan New Materials Co., Ltd. Reducing leather and method for preparing the same
CN101906718A (en) * 2010-07-23 2010-12-08 浙江宏展新材料有限公司 Collagen fiber reducing leather
CN102267253A (en) * 2011-05-26 2011-12-07 欣龙控股(集团)股份有限公司 Simulated leather base cloth and preparation method thereof
CN102660844A (en) * 2012-05-28 2012-09-12 朱晓华 Method for producing cowhide fiber base fabric
CN102660780A (en) * 2012-05-28 2012-09-12 朱晓华 Method for extracting long cowhide fibers
CN103233326A (en) * 2013-04-08 2013-08-07 江阴骏华纺织科技有限公司 Collagen fiber regenerated leather and manufacturing method thereof
CN103266425A (en) * 2013-04-08 2013-08-28 江阴骏华纺织科技有限公司 High-pressure high-density collagenous fiber regenerated leather and manufacturing method thereof
CN103276531B (en) * 2013-04-25 2016-09-07 江阴骏华纺织科技有限公司 A kind of method of the Collagenous fiber bonded leather manufacturing low production cost
CN103696031A (en) * 2013-11-20 2014-04-02 邱占伟 Method for preparing collagen fibers, collagen fibers and use of collagen fibers
CN103627825A (en) * 2013-11-20 2014-03-12 邱占伟 Method for carrying out softening treatment on leather
CN104894695B (en) * 2015-05-07 2016-05-25 徐琦 Can direct spinning with preparation method and the corium fabric leather of collagenous fibres
CN108951178A (en) * 2017-05-23 2018-12-07 天守(福建)超纤科技股份有限公司 Resin microfiber synthetic leather and preparation method thereof can be breathed
CN113106594B (en) * 2019-05-27 2022-03-25 广东五源新材料科技集团有限公司 Product with nano-grade branch animal leather fiber bundle
CN213013330U (en) * 2019-05-31 2021-04-20 广东五源新材料科技集团有限公司 Hot melt cotton formed by animal leather fiber bundles with nanoscale branches

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CN1440818A (en) * 1998-06-11 2003-09-10 清水庆彦 Collagen material and its producing method

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
CN2304399Y (en) * 1997-01-16 1999-01-20 重庆西南医院 Slow degradated collagen membrane net for medical uses
CN1440818A (en) * 1998-06-11 2003-09-10 清水庆彦 Collagen material and its producing method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102182015A (en) * 2011-05-06 2011-09-14 浙江弘扬无纺新材料有限公司 Method for producing artificial leather base material by compounding collagen fibers by utilizing spun-laced water jetting
CN102182015B (en) * 2011-05-06 2013-06-05 浙江弘扬无纺新材料有限公司 Method for producing artificial leather base material by compounding collagen fibers by utilizing spun-laced water jetting

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