CN113106593B - Animal leather fiber wrapped yarn with nanoscale branches, fabric and product - Google Patents
Animal leather fiber wrapped yarn with nanoscale branches, fabric and product Download PDFInfo
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- CN113106593B CN113106593B CN202110437057.8A CN202110437057A CN113106593B CN 113106593 B CN113106593 B CN 113106593B CN 202110437057 A CN202110437057 A CN 202110437057A CN 113106593 B CN113106593 B CN 113106593B
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Images
Classifications
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01B—MECHANICAL TREATMENT OF NATURAL FIBROUS OR FILAMENTARY MATERIAL TO OBTAIN FIBRES OF FILAMENTS, e.g. FOR SPINNING
- D01B9/00—Other mechanical treatment of natural fibrous or filamentary material to obtain fibres or filaments
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/32—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic
- D02G3/328—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic containing elastane
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/38—Threads in which fibres, filaments, or yarns are wound with other yarns or filaments, e.g. wrap yarns, i.e. strands of filaments or staple fibres are wrapped by a helically wound binder yarn
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/449—Yarns or threads with antibacterial properties
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/063—Load-responsive characteristics high strength
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses an animal leather fiber bundle wrapping yarn with nanoscale branches, a fabric and a product. The fasciated yarn comprises a core yarn, the outside of the core yarn is spirally wound with yarn, the yarn comprises animal leather fiber bundles, the animal leather fiber bundles in the yarn and branches thereof are mutually staggered and twisted together, and the branches of the animal leather fiber bundles in the yarn are wound on the core yarn; the branches of the animal leather fiber bundles in the yarn comprise nanoscale branches. The fabric is woven by wrapping yarn, and the product is made by wrapping yarn or fabric. The invention solves the technical problem of low tensile strength of the yarn, the fasciated yarn has independent and separated nanoscale branches, and the fasciated yarn has the characteristics of good antibacterial effect, good adsorption performance and capability of improving mechanical properties.
Description
The application is entitled animal leather fiber wrapped yarn with nanoscale branches, fabric and article
Divisional application with application number 2020104419325 and application date 2020.5.22.
Technical Field
The invention relates to fasciated yarns, fabrics and products made of animal leather fiber bundles.
Background
The fasciated yarn is a special structure yarn formed by wrapping the whole yarn on a core yarn in the yarn forming process. It features uniform yarn, bulkiness, smooth yarn, less filoplume, high strength and less broken ends.
Based on the above advantages, a technique of winding the yarn outside the core yarn is now presented. For example, a comfortable antibacterial composite yarn and a preparation method thereof are disclosed in a patent document with a publication number of 201811220661.X with a publication number of 2019.1.29, and belong to the technical field of textiles. Antibiotic compound yarn of travelling comfort, including yarn core and yarn skin, the yarn skin includes first fibre and second fibre, and the equal spiral winding of first fibre and second fibre is on the sinle silk, and first fibre and second fibre twine in the sinle silk for reverse winding mode. The yarn has the advantages that the mechanical strength and the bending resistance of the yarn are enhanced, the characteristics of softness, smoothness and comfortable hand feeling of the yarn are kept, the yarn has a natural antibacterial and bactericidal effect, the skin is not damaged, and the functions of the yarn are not easy to fade.
The production method of the core-spun yarn and the application thereof are disclosed in the patent document with the Chinese patent application number of 201811111411.2 and the publication number of 2019.2.19, wherein the production method comprises the steps of manufacturing a core wire and a clad wire, the clad wire is a composite fiber wire filled with a cutting-resistant auxiliary agent, 1 core wire and 2 clad wires are selected to be manufactured into the core-spun yarn through a double twisting process, then the core-spun yarn is immersed into the manufactured wear-resistant dipping solution, and finally the core-spun yarn with excellent cutting resistance and wear resistance is obtained through drying.
A wrapping yarn is disclosed in US2019/0085486a1, and in particular a core yarn wrapped with a yarn and a yarn wrapped with an outer yarn.
The yarns are all made of the existing chemical and natural textile fibers, and have obvious differences from the fasciated yarns in structure and performance.
Therefore, in the early years, people began to study fibers which exist in the natural leather and are not fully utilized, such as animal leather fibers (namely collagen fibers), wherein the collagen fibers are the main components of the dermis and account for 95% -89% of the total fiber weight of the dermis, and the leather seen in daily life is manufactured by utilizing the dermis of the animal.
The structure of collagen fibers is as follows: protocollagen molecules → protofibrils (diameter of 1.2 to 1.7 nm) → subfibrils (diameter of 3 to 5 nm) → fibrils (diameter of generally 20 nm) → fibrils (diameter of 2 to 5 μm) → collagen fibers (diameter of 20 to 150 μm). The collagen molecule is a right-handed composite helical structure formed by three left-handed helical collagen peptide chains, the collagen peptide chain is composed of a helical chain and non-helical terminal peptides connected with the helical chain, and the helical chain and the non-helical terminal peptides are composed of amino acid sequences. Although the amino acid composition and sequence of collagen varies somewhat depending on the source and type of collagen, the composition of several major amino acids is roughly the same, namely glycine, alanine, proline and hydroxyproline. While the collagen fibers have non-separable and non-independent protofibrils, subfibrils, and fibrils having a diameter of nanometers in the formation process, there is no independent and separated collagen fiber bundle having nanometer-order branches in the state where the collagen fibers are present in products such as animal skins and leathers.
In daily life and special fields, leather is favored due to the advantages of good air permeability, softness, good tear resistance, bending resistance, corrosion resistance, good antibacterial performance, good flame retardant performance and the like, the main fiber in the leather is collagen fiber, but because the genuine leather has various defects and the genuine leather of the head, the leg and other parts of the animal genuine leather can not be utilized, only 20-40% of the genuine leather is processed into the leather, and the rest is discarded as solid waste; in addition, it is reported that approximately 140 million tons of leather solid wastes are generated in the tanning and leather-making industry in China every year, 15 million tons of leather solid wastes are generated in India every year, and 6 million tons of chromium-containing leather wastes are generated in the United states every year, and the leather solid wastes are one of the important factors causing serious pollution to the leather industry.
Since the 80 s, there has been a reduction in the places available for the landfill of leather solid waste due to the increasingly stringent environmental regulations in developed countries. And the pollution treatment cost is high, on one hand, developed countries transfer the pollution industry to developing countries; on the other hand, research and application of recycling of the tanning solid waste are actively developed. Particularly, since the 90 s, with the increasing severity of global ecological problems such as resources and environment, the development of leather industry is facing the challenge of "sustainable development" strategy. Therefore, the recycling of tannery solid wastes has become an important issue of domestic and foreign concern. The recycling of tannery solid wastes has been a long history, but in the past it has not attracted the general attention of those skilled in the art. In recent 20 years, with the development of molecular biology and the deep understanding of collagen and the properties thereof, the application field of the collagen is wider; therefore, the resource utilization of the tannery solid waste is not only to produce low value-added products such as regenerated leather from waste leather scraps, but is also endowed with new contents, namely, high value-added conversion is pursued. Because the collagen fiber is an important functional substance for constituting the animal body and has incomparable biocompatibility and biodegradability compared with other synthetic polymer materials. Therefore, the importance and economic status of collagen fibers as natural biomass resources for use in industries such as food, medicine, cosmetics, feed, fertilizer, and the like are becoming more and more prominent. However, the method of extracting collagen fibers from leather solid waste to prepare spinnable fibers to be made into textiles and non-woven products so as to fully exert the advantages of the collagen fibers does not appear.
Based on the above background, the present inventors have conducted intensive studies on the reuse of tannery solid wastes, and have applied for domestic and foreign patents, and have been put into practical production, such as chinese patent application nos. 200410034435.4, 200410090255.8, 200410097268.8, 200410097268.8, 200510036778.9, 200710003092.9, 200710090219.5, 201010211811.8, 201020236921.5, 201621302339.8, which relate to collagen fibers. However, there have been some studies on the production of a yarn made of collagen fibers and then weaving the yarn into a fabric, and for example, in chinese patent application No. 200410034435.4, there is disclosed an animal leather collagen fiber yarn and a method for producing the same, which is characterized in that: the yarn is prepared from the following raw materials, by weight, 1-100% of collagen fiber of animal leather and 0-99% of textile fiber, wherein the tanned leather is processed by raw material screening, defibering, grading, mixing, carding into strips, drawing, twisting into yarn, and if the raw leather is used, the raw leather can be made into the collagen fiber yarn by adding the procedures of liming, washing, deliming, tanning softening and dehydrating. The raw material of the yarn is wide, not only all animal hides can be used, but also leather leftover materials and waste leather can be used; good performance, high tensile strength, wear resistance, softness, moisture absorption, oil absorption and flame retardance; the fabric can be woven, knitted and braided to weave high-count high-strength high-grade four-season fabric, so that the application field of animal leather is greatly widened, the utilization rate of the leather is improved, and meanwhile, the spinnable fiber is provided for the textile industry, and is suitable for popularization and application in the textile industry. Although the yarn fully exerts the characteristics of the collagen fibers, the tensile strength of the yarn is found to be insufficient in the practical application process, which brings difficulty to spinning.
In addition, the inventor finds that the nano-scale material can generate the performance which is not the same as the nano-scale material in the research process, so that the research and the implementation of the independent and separated nano-scale animal leather fiber branch and the processing method thereof have important significance.
For this reason, research on natural nanofibers has also been started, and for example, a method for preparing natural nanofibers is disclosed in a patent document published as 200510086251.7 on 2006, 2 and 8, and specifically includes the following steps:
(1) the natural biological material is soaked in a container of a certain solvent.
(2) Starting an ultrasonic device with certain frequency and certain power, inserting an ultrasonic emission probe into a container loaded with natural biological material solution, and performing ultrasonic dissociation for a certain time to prepare the natural nanofiber. The natural biological material comprises spider silk, silkworm silk, wild silkworm silk, wool, fish scales, bamboo fiber, bone collagen fiber and wood fiber.
In the above-mentioned documents, it is disclosed that natural nanofibers can be obtained from collagen fibers, but those skilled in the art know that collagen fibers are distributed in bone tissues and the protein constituting the collagen fibers is type i collagen. Collagen type i constitutes collagen, which has 3000 or more amino acids and a molecular weight of 95000 and is chemically different from connective tissue and collagen type i. The bone I collagen has less cross-linking parts, and the cross-linking is a structure formed by reducing G aldehyde group lysine by sodium borohydride. The bone type I collagen pre N-terminal extension peptide is phosphorylated, while no translationally modified procollagen is found in connective tissue. Collagen, which is also different from cartilage collagen in amino acid composition, contains two specific amino acids, serine and glycine, and a large amount of serine exists in the form of phosphoserine, so that the combination of phosphate and collagen during mineralization is important. In the process of bone matrix mineralization, hydroxyapatite and ossein are combined to form normal bone. The I-type collagen of the bone is mutually crosslinked to form a bone matrix framework; the quality and quantity of ossein are also related to mineralization and a certain deposition ratio is kept. The mineralization process also needs non-collagen in bone matrix, namely osteocalcin, matrix protein and the like, and the type I collagen not only provides a structural site for osteocalcin, but also is combined with the non-collagen such as osteocalcin to form a network scaffold, so that basic conditions are provided for bone mineralization.
In the practical research process, hydroxyapatite crystals are seen to be distributed along the long axis of the collagen fibers on the bone ultrathin section without decalcification. The compression resistance and elasticity of bone collagen fibers are poor, and hydroxyapatite crystals are brittle but have great structural strength when combined together, thereby obtaining strong mechanical properties of bone tissues.
The collagen fibers in the leather are also composed of collagen, but are different from the collagen in the bone collagen fibers, and the collagen fibers in the leather have better compression resistance and elasticity, which shows that the collagen fibers in the leather are obviously different from the bone collagen fibers in composition and performance.
Therefore, it is of far-reaching interest to develop a method for separating collagen fiber bundles of animal leather having nano-scale branches from leather to improve the properties of the separated collagen fiber bundles of animal leather.
Disclosure of Invention
The invention aims to provide an animal leather fiber fasciated yarn with nanoscale branches, which solves the technical problem of low tensile strength of the yarn.
The second purpose of the invention is to provide a fabric woven by animal leather fiber fasciated yarn with nanometer-scale branches, which solves the technical problem of low tensile strength of the yarn.
The third purpose of the invention is to provide an animal leather fiber bundle product with nanometer-scale branches. The technical problem of low tensile strength of the yarn is solved, the animal leather fiber bundle in the product has independent and separated nanoscale branches attached to the animal leather fiber bundle, and the product has the characteristics of good bacteriostatic effect, good adsorption performance and capability of improving mechanical properties.
In order to achieve the first object, the animal leather fiber bundle wrapping yarn with nanoscale branches comprises a core yarn, wherein the core yarn is spirally wound with yarns, the yarns contain animal leather fiber bundles, and the animal leather fiber bundles and the branches in the yarns are mutually staggered and twisted together along the longitudinal direction; the branches of the animal leather fiber bundles in the yarn comprise nanoscale branches.
The fasciated yarn with the structure is prepared by manufacturing fibers including animal leather fiber bundles into yarn, and then spirally winding the yarn on core yarn to form the fasciated yarn; this structure, earlier the irregular fasciculate animal leather fibre bundle that is dispersion form forms animal leather fibre bundle and crisscross each other and along longitudinal arrangement twisting together between branch in the yarn, lets animal leather fibre bundle form a yarn wholly in the yarn under the stress effect between animal leather fibre bundle and branch, after on twining the holistic yarn of this yarn to the core yarn for the tensile strength of fasciated yarn obtains improving.
The animal leather fiber bundle with nanometer branch is formed by a plurality of processes of liquid defibering, opening, carding and the like, compared with protofibril, sub-fibril and fibril in the process of forming collagen fiber, the nanometer branch is independent and separated and attached to the animal leather fiber bundle, the morphological structure of the nanometer branch is obviously different from the morphological structure of the protofibril, the sub-fibril and the fibril in unit length, the specific surface area of the nanometer branch is obviously increased for the animal leather fiber bundle with the nanometer branch, so that the animal leather fiber can play the performance of the animal leather fiber and also generate a new function, namely generate a great adsorption function, and the adsorption function is generated because the independent and separated nanometer branch attached to the animal leather fiber bundle is generated, and the animal leather fiber bundle forms a peptide chain by an amino acid sequence, the peptide chain forms collagen molecules, and the special component in the animal leather fiber bundle enables the animal leather fiber bundle to have a blue shift phenomenon on the optical performance, so that the absorption capacity of the animal leather fiber bundle on ultraviolet light is stronger. The animal leather fiber bundle with nanoscale branches has improved ultraviolet adsorption capacity, and through detection and comparison, the antibacterial effect is very good, the sterilization rate can reach more than 95%, and the antibacterial performance of the fiber bundle greatly exceeds that of the existing fiber material.
The liquid defibering is to extract the animal leather fiber bundle in the leather or the leather leftover material under the mechanical action of the rotor of the liquid defibering machine and the hydraulic shearing action caused by the rotation of the rotor. Specifically, in the rotating process of the rotor of the liquid defibrator, on one hand, the blades on the rotor act with leather or leather leftover materials to generate acting forces such as friction force and the like between the leather or leather leftover materials and the rotor, and on the other hand, because the rotor generates powerful vortex, a turbulent flow area with high speed is formed around the rotor, the flow speed of liquid generated in each area is different, so that the leather or leather leftover materials rub against each other, and finally leather fiber bundles are extracted.
In addition, the collagen molecule is a right-handed complex helix of procollagen composed of three left-handed α -chains intertwined with each other, that is, a collagen helix, which is the secondary structure of collagen. The high stability of the secondary structure of collagen is mainly attributed to inter-chain hydrogen bonds and intra-and intermolecular inter-chain covalent crosslinks, and the first-identified crosslinking structures so far are mainly Schiff base crosslinking, β -aldol crosslinking, aldol-histidine crosslinking, and the like. For the animal leather fiber bundle with nanometer branches, the nanometer branches have high activity and instability due to the increase of surface atomic numbers, insufficient atomic coordination and high surface energy, and are easily combined with other atoms.
Further, the core yarn is elastic core yarn. After the yarn with the yarn integrity is wound on the elastic core yarn with elasticity, the yarn moves axially along with the elastic core yarn instead of an independent animal leather fiber bundle, so that the technical problem that the animal leather fiber bundle cannot be completely rebounded and reset due to a special dispersed structure is solved, namely elasticity is provided for the elastic fasciated yarn, the elastic yarn of the animal leather fiber is realized, and the elastic fasciated yarn achieves the purposes of stability and durability.
Further, the nanoscale branches include nanoscale branches having a diameter of 200nm or less.
Further, the yarn comprises an outer layer core yarn and animal leather fiber bundles wound outside the outer layer core yarn, and the animal leather fiber bundles and branches thereof in the yarn are mutually staggered and twisted together along the longitudinal direction. This structure has solved because of adopting the direct cladding of animal leather tow to cause the unable technical problem that kick-backs completely of animal leather tow to reset on the core yarn, has fully embodied the characteristic of animal leather tow moreover, owing to set up outer core yarn in the yarn simultaneously, consequently, the intensity of fasciated yarn further obtains improving.
Furthermore, the yarns are formed by mutually interlacing animal leather fiber bundles and branches thereof and are longitudinally arranged and twisted together. The structure solves the technical problem that the animal leather fiber bundle cannot be completely rebounded and reset because the animal leather fiber bundle is directly coated on the core yarn, and fully embodies the characteristic of the animal leather fiber.
In order to achieve the second object, a fabric woven by an animal leather fiber bundle wrapping yarn having nanoscale branches comprises the animal leather fiber bundle wrapping yarn having nanoscale branches, the animal leather fiber bundle wrapping yarn having nanoscale branches comprises a core yarn, a yarn is spirally wound outside the core yarn, the yarn contains the animal leather fiber bundle, and the animal leather fiber bundle and the branches in the yarn are mutually staggered and longitudinally arranged and twisted together; the branches of the animal leather fiber bundles in the yarn comprise nanometer-scale branches; the animal leather fiber bundle branches which are mutually staggered and wound are arranged between the adjacent animal leather fiber bundle wrapping yarns with the nanometer-scale branches.
The fabric with the structure adopts the animal leather fiber bundle wrapping yarn with the nanoscale branches, the wrapping yarn is made into yarn by using fibers including the animal leather fiber bundle, and then the yarn is spirally wound on the core yarn to form the wrapping yarn; this structure, earlier the irregular fasciculate animal leather fibre bundle that is dispersion form forms animal leather fibre bundle and crisscross each other and along longitudinal arrangement twisting together between branch in the yarn, lets animal leather fibre bundle form a yarn wholly in the yarn under the stress effect between animal leather fibre bundle and branch, after twining the yarn that should have the yarn is whole to have the core yarn for the tensile strength of fasciated yarn obtains improving.
The animal leather fiber bundle with nanometer branch is formed by a plurality of processes of liquid defibering, opening, carding and the like, compared with protofibril, sub-fibril and fibril in the process of forming collagen fiber, the nanometer branch exists independently and separately and is attached to the animal leather fiber bundle, the morphological structure of the nanometer branch is obviously different from the morphological structure of the protofibril, the sub-fibril and the fibril in unit length, the specific surface area of the nanometer branch is obviously increased for the animal leather fiber bundle with the nanometer branch, so that the animal leather fiber can play the performance of the animal leather fiber and also generate a new function, namely generate a great adsorption function, the adsorption function is generated, because the independent and separated nanometer branch is generated, and the animal leather fiber bundle forms a peptide chain by an amino acid sequence, the peptide chain forms collagen molecules, and the special component in the animal leather fiber bundle enables the animal leather fiber bundle to have a blue shift phenomenon on the optical performance, so that the absorption capacity of the animal leather fiber bundle on ultraviolet light is stronger. The animal leather fiber bundle with nanoscale branches has improved ultraviolet adsorption capacity, and through detection and comparison, the antibacterial effect is very good, the sterilization rate can reach more than 95%, and the antibacterial performance of the fiber bundle greatly exceeds that of the existing fiber material.
The liquid defibering is to extract the animal leather fiber bundle in the leather or the leather leftover material under the mechanical action of the rotor of the liquid defibering machine and the hydraulic shearing action caused by the rotation of the rotor. Specifically, in the rotating process of the rotor of the liquid defibrator, on one hand, the blades on the rotor act with leather or leather leftover materials to generate acting forces such as friction force and the like between the leather or leather leftover materials and the rotor, and on the other hand, because the rotor generates powerful vortex, a turbulent flow area with high speed is formed around the rotor, the flow speed of liquid generated in each area is different, so that the leather or leather leftover materials rub against each other, and finally leather fiber bundles are extracted.
In addition, the collagen molecule is a right-handed complex helix of procollagen composed of three left-handed α -chains intertwined with each other, that is, a collagen helix, which is the secondary structure of collagen. The high stability of the secondary structure of collagen is mainly attributed to inter-chain hydrogen bonds and intra-and intermolecular inter-chain covalent crosslinks, and the first-identified crosslinking structures so far are mainly Schiff base crosslinking, β -aldol crosslinking, aldol-histidine crosslinking, and the like. For the animal leather fiber bundle with nanometer-level branches, the nanometer-level branches have high activity and instability due to the increase of surface atomic numbers, insufficient atomic coordination and high surface energy, and can be easily combined with other atoms.
Furthermore, after the fabric is formed, the animal leather fiber bundles have branches and nanometer-scale branches, so the branches and the nanometer-scale branches of the animal leather fiber bundles exist among the wrapping yarns, the branches and the nanometer-scale branches are mutually interlaced and intertwined, and the nanometer-scale branches are unstable due to the performance of the nanometer-scale branches and are easily combined with other animal leather fiber bundles, branches and nanometer-scale branches, so the fabric has more superior performance compared with the traditional fabric.
Further, the core yarn is elastic core yarn. After the yarn with the yarn integrity is wound on the elastic core yarn with elasticity, the yarn moves axially along with the elastic core yarn instead of an independent animal leather fiber bundle, so that the technical problem that the animal leather fiber bundle cannot be completely rebounded and reset due to a special dispersed structure is solved, namely elasticity is provided for the elastic fasciated yarn, the elastic yarn of the animal leather fiber is realized, and the elastic fasciated yarn achieves the purposes of stability and durability.
Further, the nanoscale branches include nanoscale branches having a diameter of 200nm or less.
Further, the yarn comprises an outer layer core yarn and animal leather fiber bundles wound outside the outer layer core yarn, and the animal leather fiber bundles and branches thereof in the yarn are mutually staggered and twisted together along the longitudinal direction. This structure has solved because of adopting the direct cladding of animal leather tow to cause the unable technical problem that kick-backs completely of animal leather tow to reset on the core yarn, has fully embodied the characteristic of animal leather tow moreover, owing to set up outer core yarn in the yarn simultaneously, consequently, the intensity of fasciated yarn further obtains improving.
Furthermore, the yarns are formed by mutually interlacing animal leather fiber bundles and branches thereof and are longitudinally arranged and twisted together. The structure solves the technical problem that the animal leather fiber bundle cannot be completely rebounded and reset because the animal leather fiber bundle is directly coated on the core yarn, and fully embodies the characteristic of the animal leather fiber.
To achieve the third objective, the animal leather fiber bundle product with nanometer grade branches is manufactured by adopting the fasciated yarn or fabric.
Drawings
Fig. 1 is a schematic view of an animal leather fiber bundle.
Fig. 2 is a schematic view of an animal leather fiber-wrapped yarn with nanoscale branches.
Fig. 3 is a schematic view of a yarn.
Figure 4 is a schematic view of another structure of the yarn.
FIG. 5 is an electron micrograph of animal leather fiber bundles prior to carding.
FIG. 6 is an electron microscope image of the fiber bundles of animal leather after combing having nanometer-scale branching.
FIG. 7 is another electron micrograph of an animal leather fiber bundle having nanoscale branches.
FIG. 8 is a third electron micrograph of a bundle of animal leather fibers having nanoscale branches.
FIG. 9 is an electron micrograph of a wrapped yarn containing bundles of animal leather fibers having nanoscale branches.
Figure 10 is a schematic representation of a woven structure of the fabric.
FIG. 11 is a schematic representation of a knitted structure of the fabric.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings and specific embodiments.
Fig. 1 is a schematic structural view of an animal leather fiber bundle. As shown in fig. 1, the animal leather fiber bundle has an animal leather fiber body 100, and the animal leather fiber body 100 has branches 101 and stepwise branches 102. The branches 101 or the stepwise branches 102 include nanoscale branches, and the animal leather fiber bundles are irregularly divergent. The animal leather fiber bundle is a spinnable animal leather fiber bundle.
Example 1.
As shown in fig. 2, an animal leather fiber bundle-wrapped yarn having nano-scale branching includes a core yarn 1 and a yarn 2. The core yarn 1 is wound with the yarn 2 in a spiral manner, and the yarn 2 can be wound with more than one yarn, and the embodiment includes two yarns. Each yarn 2 has a pitch equal to or greater than the outer diameter of the corresponding yarn.
The core yarn may be a synthetic filament yarn having a high strength and a high elasticity, but may be other filaments.
As shown in fig. 3, the yarn 2 includes an outer core yarn 21 and animal leather fiber bundles 3 wound on the outer core yarn, in this embodiment, 100% of the animal leather fiber bundles are used as the fibers wound on the outer core yarn, but the fibers wound on the outer core yarn may also include 80-99% of the animal leather fiber bundles and 1-20% of other textile fibers except for the animal leather fiber bundles, and the animal leather fiber bundles and their branches in the yarn are interlaced with each other and twisted together in a longitudinal arrangement. This structure has solved because of adopting the direct cladding of animal leather tow to cause the unable technical problem that kick-backs completely of animal leather tow to reset on the core yarn, has fully embodied the characteristic of animal leather tow moreover, owing to set up outer core yarn in the yarn simultaneously, consequently, the intensity of fasciated yarn further obtains improving.
As shown in fig. 4, another structure of the yarn is a yarn formed by twisting the animal leather fiber bundle 3. The structure solves the technical problem that the animal leather fiber bundle cannot be completely rebounded and reset because the animal leather fiber bundle is directly coated on the core yarn, and fully embodies the excellent characteristics of the animal leather fiber bundle. It is of course also possible to incorporate small amounts of other textile fibres for the yarns of this construction.
Due to the dispersed structure of the animal leather fiber bundles, a part of the animal leather fiber bundles among the yarns wound on the core yarn are branched and wound on the core yarn 1.
FIG. 9 is an electron micrograph of a wrapped yarn with a core yarn.
In this embodiment, the animal leather fiber bundle having nano-grade branches is a spinnable fiber bundle formed by various processes such as liquid defibering, opening and carding, and the nano-grade branches exist independently and separately and attach to the main body of the animal leather fiber, compared with the protofibrils, sub-fibrils and fibrils which cannot be separated independently in the formation process of the collagen fiber, the number of the nano-grade branches is obviously different from the number of the protofibrils, sub-fibrils and fibrils in the unit length, and for the animal leather fiber bundle having nano-grade branches, the specific surface area of the nano-grade branches is obviously increased, so that the animal leather fiber bundle exerts its own performance and also generates a new function, namely, a great adsorption function, which is generated because of the generation of the independent, The special component in the animal leather fiber bundle causes the animal leather fiber bundle to have a blue shift phenomenon on the optical property, thereby having stronger ultraviolet absorption capability. The adsorption capacity of the animal leather fiber bundle with the nanoscale branches to ultraviolet light is improved, so that the adsorption capacity of the fasciated yarn to the ultraviolet light is improved, the bacteriostatic effect is very good through detection and comparison, the sterilization rate can reach more than 95%, the antibacterial performance of the fasciated yarn is greatly improved, and the antibacterial performance of the fasciated yarn is improved.
The liquid defibering is to extract the animal leather fiber bundle in the leather or the leather leftover material under the mechanical action of the rotor of the liquid defibering machine and the hydraulic shearing action caused by the rotation of the rotor. Specifically, in the rotating process of the rotor of the liquid defibrator, on one hand, the blades on the rotor act with leather or leather leftover materials to generate acting forces such as friction force and the like between the leather or leather leftover materials and the rotor, and on the other hand, because the rotor generates powerful vortex, a turbulent flow area with high speed is formed around the rotor, the flow speed of liquid generated in each area is different, so that the leather or leather leftover materials rub against each other, and finally leather fiber bundles are extracted.
As can be seen from fig. 5, the animal leather fibers are substantially in a thicker fiber bundle structure after being defibered and opened by liquid before carding, and as shown in fig. 6 to 8, nanometer-scale animal leather fiber branches appear after carding.
The following is a bacteriostatic test report made by the applicant company guangdong spinning detection and measurement technology, entitled bacteriostatic test report in 2019, 4 and 8 days, and issued in 2019, 4 and 18 days, and the number is (No.): 19F02538, anti-counterfeiting code: VBTU-IN1L-S8, report anti-counterfeiting query web site: report. gztzs. com, the contents of the detection report are as follows:
the detection report shows that the bacteriostatic effect is very high. Which is higher than the bacteriostatic effect of the prior animal leather.
In addition, the collagen molecule is a right-handed complex helix of procollagen composed of three left-handed α -chains intertwined with each other, that is, a collagen helix, which is the secondary structure of collagen. The high stability of the secondary structure of collagen is mainly attributed to inter-chain hydrogen bonds and intra-and intermolecular inter-chain covalent crosslinks, and the first-identified crosslinking structures so far are mainly Schiff base crosslinking, β -aldol crosslinking, aldol-histidine crosslinking, and the like. For the animal leather fiber bundle with nanometer branches, the nanometer branches have high activity and instability due to the increase of surface atomic numbers, insufficient atomic coordination and high surface energy, and can be easily combined with other atoms.
The fasciated yarn with the structure is prepared by manufacturing fibers including animal leather fiber bundles into yarn, and then spirally winding the yarn on core yarn to form the fasciated yarn; this structure, earlier the irregular fasciculate animal leather fibre bundle that is dispersion form forms animal leather fibre bundle and crisscross each other and along longitudinal arrangement twisting together between branch in the yarn, lets animal leather fibre bundle form a yarn wholly in the yarn under the stress effect between animal leather fibre bundle and branch, after twining the yarn that should have the yarn is whole to have the core yarn for the tensile strength of fasciated yarn obtains improving. Because the animal leather fiber bundle is provided with branches, the branches wound with the animal leather fiber bundle are also arranged on the core yarn, so that the binding force between the yarn and the core yarn is increased, and the strength of the wound yarn and the stability of the animal leather fiber bundle in the elastic yarn are improved.
Example 2.
As shown in fig. 2, an animal leather fiber bundle wrapping yarn with nanometer-scale branching includes a core yarn 1 and a yarn 2, the core yarn is an elastic core yarn, and the elastic core yarn can be made of spandex silk. The elastic core yarn is spirally wound with more than one yarn 2, and the number of the yarns 2 is two in the embodiment. The thread pitch of each yarn 2 is larger than or equal to the outer diameter of the corresponding yarn, so that enough space is reserved for resilience of the wrapping yarn with elasticity, and the wrapping yarn can be better restored in the resilience.
As shown in fig. 3, the yarn 2 includes an outer core yarn 21 and animal leather fiber bundles 3 wound on the outer core yarn, in this embodiment, 100% of the animal leather fiber bundles are used as the fibers wound on the outer core yarn, but the fibers wound on the outer core yarn may also include 80-99% of the animal leather fiber bundles and 1-20% of other textile fibers except for the animal leather fiber bundles, and the animal leather fiber bundles and their branches in the yarn are interlaced with each other and twisted together in a longitudinal arrangement. This structure has solved because of adopting the direct cladding of animal leather tow to cause the unable technical problem that kick-backs completely of animal leather tow to reset on the core yarn, has fully embodied the characteristic of animal leather tow moreover, owing to set up outer core yarn in the yarn simultaneously, consequently, the intensity of fasciated yarn further obtains improving.
As shown in fig. 4, another structure of the yarn is a yarn formed by twisting the animal leather fiber bundle 3. The structure solves the technical problem that the animal leather fiber bundle cannot be completely rebounded and reset because the animal leather fiber bundle is directly coated on the core yarn, and fully embodies the excellent characteristics of the animal leather fiber bundle. It is of course also possible to incorporate small amounts of other textile fibres for the yarns of this construction.
Due to the dispersed structure of the animal leather fiber bundles, a part of the branches of the animal leather fiber bundles among the yarns wound on the elastic core yarn are wound on the elastic core yarn.
In this embodiment, the animal leather fiber bundle having nano-grade branches is a spinnable fiber bundle formed by various processes such as liquid defibering, opening and carding, and the nano-grade branches exist independently and separately and are connected to the main body of the animal leather fiber, compared with the protofibrils, sub-fibrils and fibrils which cannot be separated independently in the formation process of the collagen fiber, the number of the nano-grade branches is obviously different from the number of the protofibrils, sub-fibrils and fibrils in unit length, and the specific surface area of the nano-grade branches is obviously increased for the animal leather fiber bundle having nano-grade branches, so that the animal leather fiber bundle exerts its own performance and also generates a new function, namely, an extremely large adsorption function, which is generated due to the generation of the independent protofibrils, sub-fibrils and fibrils, The special component in the animal leather fiber bundle makes the animal leather fiber bundle have blue shift phenomenon in optical performance, so that the animal leather fiber bundle has stronger ultraviolet light absorbing capacity. The adsorption capacity of the animal leather fiber bundle with the nanoscale branches to ultraviolet light is improved, so that the adsorption capacity of the fasciated yarn to the ultraviolet light is improved, the bacteriostatic effect is very good through detection and comparison, the sterilization rate can reach more than 95%, the antibacterial performance of the fasciated yarn is greatly improved, and the bacteriostatic performance of the fasciated yarn is improved.
The liquid defibering is to extract the animal leather fiber bundle in the leather or the leather leftover material under the mechanical action of the rotor of the liquid defibering machine and the hydraulic shearing action caused by the rotation of the rotor. Specifically, in the rotating process of the rotor of the liquid defibrator, on one hand, the blades on the rotor act with leather or leather leftover materials to generate acting forces such as friction force and the like between the leather or leather leftover materials and the rotor, and on the other hand, because the rotor generates powerful vortex, a turbulent flow area with high speed is formed around the rotor, the flow speed of liquid generated in each area is different, so that the leather or leather leftover materials rub against each other, and finally leather fiber bundles are extracted.
As can be seen from fig. 5, the animal leather fibers are substantially in a thicker fiber bundle structure after being defibered and opened by liquid before carding, and as shown in fig. 6 to 8, nanometer-scale animal leather fiber branches appear after carding.
The following is a bacteriostatic test report made by the applicant company guangdong spinning detection and measurement technology, entitled bacteriostatic test report in 2019, 4 and 8 days, and issued in 2019, 4 and 18 days, and the number is (No.): 19F02538, anti-counterfeiting code: VBTU-IN1L-S8, report anti-counterfeiting query web site: report. gztzs. com, the contents of the detection report are as follows:
the detection report shows that the bacteriostatic effect is very high. Which is higher than the bacteriostatic effect of the prior animal leather.
In addition, the collagen molecule is a right-handed complex helix of procollagen composed of three left-handed α -chains intertwined with each other, that is, a collagen helix, which is the secondary structure of collagen. The high stability of the secondary structure of collagen is mainly attributed to inter-chain hydrogen bonds and intra-and intermolecular inter-chain covalent crosslinks, and the first-identified crosslinking structures so far are mainly Schiff base crosslinking, β -aldol crosslinking, aldol-histidine crosslinking, and the like. For the animal leather fiber bundle with nanometer branches, the nanometer branches have high activity and instability due to the increase of surface atomic numbers, insufficient atomic coordination and high surface energy, and can be easily combined with other atoms.
The elastic fasciated yarn with the structure is prepared by firstly utilizing fibers including animal leather fiber bundles to prepare yarns, and then spirally winding the yarns on the elastic core yarn to form the elastic fasciated yarn; the structure is characterized in that firstly, the animal leather fiber bundles in irregular dispersed shapes are formed in the yarns and are mutually staggered and twisted together along the longitudinal arrangement, so that the animal leather fiber bundles form a yarn whole in the yarns under the stress action between the animal leather fiber bundles and the branches thereof, after the yarn with the yarn whole is wound on the elastic core yarn with elasticity, the yarn moves along the axial direction of the elastic core yarn instead of an independent animal leather fiber bundle, and therefore the technical problem that the animal leather fiber bundles cannot be completely rebounded and reset due to the special dispersed structures is solved, namely, elasticity is provided for the elastic fasciated yarn, the elastic fasciated yarn of the animal leather fiber bundle is realized, and the purpose of stabilizing and durable is achieved. Compared with the existing common elastic yarn, the fasciated yarn of the invention fully exerts the excellent characteristics of the animal leather fiber bundle, and because the animal leather fiber bundle has branches, the branches wound with the animal leather fiber bundle are also arranged on the elastic core yarn, so that the binding force between the yarn and the elastic core yarn is increased, and the strength of the elastic fasciated yarn and the stability of the animal leather fiber bundle in the elastic fasciated yarn are improved.
Example 3.
As shown in fig. 10 and 11, a fabric woven by the animal leather fiber bundle-wrapping yarn 200 having nano-scale branching includes the animal leather fiber bundle-wrapping yarn 200 having nano-scale branching described in example 1. As shown in fig. 10, for the woven fabric, the fabric includes warp and weft, wherein at least one of the warp and weft may be an animal leather fiber bundle wrapping yarn 200 having nano-scale branching.
After the fabric is formed, animal leather fiber bundle branches which are mutually staggered and wound are arranged between adjacent animal leather fiber bundle wrapping yarns with nanoscale branches, and the animal leather fiber bundle branches comprise the nanoscale branches, and the nanoscale branches have large specific surface area and are unstable as recorded in embodiment 1, so that the animal leather fiber bundle branches are easily combined with other nanoscale branches, branches and animal leather fiber bundles, a net-shaped structure which is mutually staggered and wound is formed among the wrapping yarns, and the mechanical property of the fabric is better.
Example 4.
As shown in fig. 10 and 11, a fabric woven by the animal leather fiber bundle-wrapping yarn 200 having nano-scale branching includes the animal leather fiber bundle-wrapping yarn 200 having nano-scale branching described in example 2. The wrapped yarn in example 2 was an elastic wrapped yarn, and therefore the fabric also formed an elastic fabric. As shown in fig. 10, for the woven fabric, the fabric includes warp and weft, wherein at least one of the warp and weft may be an animal leather fiber bundle wrapping yarn 200 having nano-scale branching.
After the fabric is formed, animal leather fiber bundle branches which are mutually staggered and wound are arranged between adjacent animal leather fiber bundle wrapping yarns with nanoscale branches, and the animal leather fiber bundle branches comprise the nanoscale branches, and the nanoscale branches have large specific surface area and are unstable as recorded in embodiment 1, so that the animal leather fiber bundle branches are easily combined with other nanoscale branches, branches and animal leather fiber bundles, a net-shaped structure which is mutually staggered and wound is formed among the wrapping yarns, and the mechanical property of the fabric is better.
Example 5.
An article manufactured by the animal leather fiber bundle-wrapped yarn having nano-scale branching described in example 1. The product can be clothing, trousers, shoes, socks, hats, gloves and other wearing articles, and can also be bedding, decorative materials, special industrial materials and the like.
Example 6.
An article manufactured by the animal leather fiber bundle-wrapped yarn having nano-scale branching described in example 2. The product can be clothing, trousers, shoes, socks, hats, gloves and other wearing articles, and can also be bedding, decorative materials, special industrial materials and the like.
Example 7.
An article produced by using the animal leather fiber bundle-wrapped yarn having nano-scale branching described in example 3 as a fabric. The product can be clothing, trousers, shoes, socks, hats, gloves and other wearing articles, and can also be bedding, decorative materials, special industrial materials and the like.
Example 8.
An article produced by using the animal leather fiber bundle-wrapped yarn having nano-scale branching described in example 4 as a fabric. The product can be clothing, trousers, shoes, socks, hats, gloves and other wearing articles, and can also be bedding, decorative materials, special industrial materials and the like.
Claims (9)
1. Animal leather fiber bundle wrapping yarn with nanoscale branches is characterized in that: the yarn comprises a core yarn, wherein the core yarn is spirally wound with yarn, the yarn comprises animal leather fiber bundles, and the animal leather fiber bundles and branches thereof in the yarn are mutually staggered and twisted together along the longitudinal direction; the branches of the animal leather fiber bundles in the yarn comprise nanometer-scale branches which are independent, separated and attached to the animal leather fiber bundles; nanoscale branches include nanoscale branches having a diameter of 200nm or less.
2. The animal leather fiber bundle wrapping yarn with nanoscale branches according to claim 1, characterized in that: the core yarn is elastic core yarn.
3. The animal leather fiber bundle-wrapped yarn with nanoscale branches according to claim 1 or 2, characterized in that: the yarn comprises an outer layer core yarn and animal leather fiber bundles wound outside the outer layer core yarn, wherein the animal leather fiber bundles and branches thereof in the yarn are mutually staggered and twisted together along the longitudinal direction.
4. The animal leather fiber bundle-wrapped yarn with nanoscale branches according to claim 1 or 2, characterized in that: the yarn is twisted together along the longitudinal direction by the mutual staggered arrangement of the animal leather fiber bundles and the branches thereof.
5. A fabric woven by an animal leather fiber bundle wrapping yarn having nanoscale branches, comprising the animal leather fiber bundle wrapping yarn having nanoscale branches, characterized in that: the animal leather fiber bundle wrapping yarn with the nanometer grade branches comprises elastic core yarn, yarn is spirally wound outside the core yarn, the yarn comprises animal leather fiber bundles, and the animal leather fiber bundles and the branches thereof in the yarn are mutually staggered and twisted together along the longitudinal direction; the branches of the animal leather fiber bundles in the yarns comprise nanoscale branches which are independent, separated and attached to the animal leather fiber bundles, and the nanoscale branches comprise nanoscale branches with the diameter of less than 200 nm; the animal leather fiber bundle branches which are mutually staggered and wound are arranged between the adjacent animal leather fiber bundle wrapping yarns with the nanometer-scale branches.
6. The fabric woven by the animal leather fiber bundle wrapping yarn having nano-scale branching as claimed in claim 5, wherein: the yarn comprises an outer layer core yarn and animal leather fiber bundles wound outside the outer layer core yarn, wherein the animal leather fiber bundles and branches thereof in the yarn are mutually staggered and twisted together along the longitudinal direction.
7. The fabric woven by the animal leather fiber bundle wrapping yarn having nano-scale branching as claimed in claim 5, wherein: the yarn is twisted together along the longitudinal direction by the mutual staggered arrangement of the animal leather fiber bundles and the branches thereof.
8. An animal leather fiber bundle product with nanoscale branches is characterized in that: manufactured by using the animal leather fiber bundle wrapping yarn with nano-scale branching of claim 1 or 2.
9. An animal leather fiber bundle product with nanoscale branches is characterized in that: is manufactured by using the fabric of claim 5 or 6.
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| CN2019104478763 | 2019-05-27 | ||
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| CN202010441932.5A CN111455515B (en) | 2019-05-27 | 2020-05-22 | Animal leather fiber wrapping yarn with nanoscale branches, fabric and product |
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| CN113106592B (en) * | 2019-05-27 | 2021-12-07 | 广东五源新材料科技集团有限公司 | Animal leather fiber bundle with nanoscale branches, yarn, core-spun yarn and product |
| CN117702344B (en) * | 2024-02-05 | 2024-04-09 | 昆山东利新材料科技有限公司 | High-strength cut-resistant outdoor fabric and preparation method thereof |
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| CN111455515A (en) | 2020-07-28 |
| CN111455515B (en) | 2024-02-13 |
| CN113106593A (en) | 2021-07-13 |
| CN213804142U (en) | 2021-07-27 |
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