CN1549828A - 淀粉的改性方法、淀粉及其应用 - Google Patents
淀粉的改性方法、淀粉及其应用 Download PDFInfo
- Publication number
- CN1549828A CN1549828A CNA02817108XA CN02817108A CN1549828A CN 1549828 A CN1549828 A CN 1549828A CN A02817108X A CNA02817108X A CN A02817108XA CN 02817108 A CN02817108 A CN 02817108A CN 1549828 A CN1549828 A CN 1549828A
- Authority
- CN
- China
- Prior art keywords
- starch
- surperficial
- dry matter
- sizing material
- paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002472 Starch Polymers 0.000 title claims abstract description 154
- 235000019698 starch Nutrition 0.000 title claims abstract description 154
- 239000008107 starch Substances 0.000 title claims abstract description 154
- 238000000034 method Methods 0.000 title claims abstract description 47
- 230000004048 modification Effects 0.000 title claims abstract description 10
- 238000012986 modification Methods 0.000 title claims abstract description 10
- 238000004513 sizing Methods 0.000 claims abstract description 131
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims abstract description 18
- 230000015556 catabolic process Effects 0.000 claims abstract description 15
- 238000006731 degradation reaction Methods 0.000 claims abstract description 15
- 230000003647 oxidation Effects 0.000 claims abstract description 12
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 8
- 238000010306 acid treatment Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 130
- 239000003292 glue Substances 0.000 claims description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 238000004026 adhesive bonding Methods 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 9
- 238000001704 evaporation Methods 0.000 claims description 8
- 230000008020 evaporation Effects 0.000 claims description 8
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 6
- 238000003892 spreading Methods 0.000 claims description 6
- 230000007480 spreading Effects 0.000 claims description 6
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 6
- 230000032050 esterification Effects 0.000 claims description 5
- 238000005886 esterification reaction Methods 0.000 claims description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 2
- 230000000593 degrading effect Effects 0.000 claims 1
- 238000005259 measurement Methods 0.000 claims 1
- 230000006641 stabilisation Effects 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 67
- 239000000243 solution Substances 0.000 description 52
- 230000008901 benefit Effects 0.000 description 9
- 238000001035 drying Methods 0.000 description 9
- 239000010408 film Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229920000945 Amylopectin Polymers 0.000 description 4
- 229920000856 Amylose Polymers 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- 239000011111 cardboard Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000011087 paperboard Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 230000000630 rising effect Effects 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000002939 deleterious effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- -1 or be side chain Polymers 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
- C08B30/18—Dextrin, e.g. yellow canari, white dextrin, amylodextrin or maltodextrin; Methods of depolymerisation, e.g. by irradiation or mechanically
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/18—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/18—Oxidised starch
- C08B31/185—Derivatives of oxidised starch, e.g. crosslinked oxidised starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
Description
Claims (30)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20011722 | 2001-08-28 | ||
FI20011722A FI20011722A0 (fi) | 2001-08-28 | 2001-08-28 | Menetelmä tärkkelyksen modifioimiseksi, tärkkelys ja sen käyttö |
FI20012544A FI113658B (fi) | 2001-12-21 | 2001-12-21 | Menetelmä tärkkelyksen modifioimiseksi, tärkkelys ja sen käyttö |
FI20012544 | 2001-12-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1549828A true CN1549828A (zh) | 2004-11-24 |
CN100549032C CN100549032C (zh) | 2009-10-14 |
Family
ID=26161209
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB02817108XA Expired - Fee Related CN100549032C (zh) | 2001-08-28 | 2002-08-28 | 表面上胶方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20070225489A1 (zh) |
EP (1) | EP1456245A1 (zh) |
CN (1) | CN100549032C (zh) |
AU (1) | AU2002321349A1 (zh) |
CA (1) | CA2457887C (zh) |
WO (1) | WO2003018638A1 (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102115501A (zh) * | 2010-12-29 | 2011-07-06 | 哈尔滨商业大学 | 一种酸解乙酰化复合变性淀粉的制备方法 |
CN103242459A (zh) * | 2013-05-27 | 2013-08-14 | 江西鑫川实业有限公司 | 一种交联两性淀粉及制备方法 |
CN103526637A (zh) * | 2013-10-31 | 2014-01-22 | 东莞理文造纸厂有限公司 | 一种高抗水性的环保箱板纸的表面施胶染色方法 |
CN104497153A (zh) * | 2014-11-24 | 2015-04-08 | 广东中轻枫泰生化科技有限公司 | 一种低粘度季铵型阳离子淀粉的制备方法 |
CN107326730A (zh) * | 2017-06-30 | 2017-11-07 | 常州思宇环保材料科技有限公司 | 一种改性淀粉基表面施胶剂的制备方法 |
CN111278866A (zh) * | 2017-08-11 | 2020-06-12 | 瑞典淀粉生产者协会 | 用于制备抑制淀粉的方法 |
WO2021086273A3 (en) * | 2019-10-29 | 2021-07-08 | Sms Corporation Co., Ltd. | Modified-acetylated distarch adipate and products containing thereof |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE60333856D1 (de) * | 2002-09-13 | 2010-09-30 | Int Paper Co | Papier mit verbesserter steifigkeit und fülle und dessen herstellung |
FI113482B (fi) * | 2002-10-09 | 2004-04-30 | Metso Paper Inc | Menetelmä paperin tai kartongin valmistamiseksi ja menetelmän avulla valmistettu tuote |
WO2007048720A1 (en) * | 2005-10-24 | 2007-05-03 | Ciba Specialty Chemicals Holding Inc. | A composition for whitening paper |
US20090173775A1 (en) * | 2008-01-04 | 2009-07-09 | Dixie Consumer Products Llc | Disposable pressware prepared from paperboard sized with nano starch |
KR101708955B1 (ko) | 2009-06-05 | 2017-02-21 | 솔베이(소시에떼아노님) | 산화전분의 제조 방법, 산화전분 및 그 용도 |
EP2719826A1 (en) * | 2012-10-09 | 2014-04-16 | Metso Paper Inc. | Process for producing a fiber web and arrangement for producing a fiber web |
US11732057B2 (en) | 2015-03-30 | 2023-08-22 | Vomm Impianti E Processi S.P.A. | Process for the oxidation of starch-based materials |
SE543447C2 (en) * | 2019-02-01 | 2021-02-23 | Sveriges Staerkelseproducenter Foerening U P A | Method for preparing inhibited starch |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2989521A (en) * | 1959-06-30 | 1961-06-20 | Frederic R Senti | Method of cross-linking and oxidizing starch |
US3338735A (en) * | 1965-12-09 | 1967-08-29 | Us Plywood Champ Papers Inc | Production of coated paper utilizing aqueous coatings containing particulate filler and resins having an affinity for water and utilizing nonequilibrium moisture conditions and shearing forces |
CA1008069A (en) | 1973-03-01 | 1977-04-05 | A.E. Staley Manufacturing Company | Temperature stable large granule starch product |
US4052226A (en) * | 1975-09-25 | 1977-10-04 | A. E. Staley Manufacturing Company | Directed enzymolysis of starch |
DE2758635A1 (de) * | 1977-12-29 | 1979-07-05 | Gfv Ges Fuer Verfahrenstechnik | Verfahren zur herstellung von oxydativ abgebauter staerkeloesung in 2 stufen |
US4838944A (en) * | 1987-06-17 | 1989-06-13 | National Starch And Chemical Corporation | Degradation of granular starch |
DE4125122C2 (de) * | 1991-07-30 | 1994-06-23 | Henkel Kgaa | Klebestift auf Stärkeetherbasis |
US5362573A (en) * | 1993-01-28 | 1994-11-08 | Pandian Vernon E | Use of zirconium salts to improve the surface sizing efficiency in paper making |
FR2734005B1 (fr) * | 1995-05-12 | 1997-07-18 | Roquette Freres | Composition et procede pour le collage du papier |
SE504641C2 (sv) * | 1995-07-17 | 1997-03-24 | Sveriges Staerkelseproducenter | Användning av stärkelse av amylopektintyp som ytbehandlingsmedel vid papperstillverkning |
AUPO017196A0 (en) | 1996-05-30 | 1996-06-27 | George Weston Foods Limited | Novel wet end processing aid |
FI105334B (fi) * | 1997-09-10 | 2000-07-31 | Raisio Chem Oy | Tärkkelysmodifikaatti |
GB0021225D0 (en) * | 2000-08-31 | 2000-10-18 | Cerestar Holding Bv | Enzymatic conversion of starch |
-
2002
- 2002-08-28 CA CA2457887A patent/CA2457887C/en not_active Expired - Fee Related
- 2002-08-28 AU AU2002321349A patent/AU2002321349A1/en not_active Abandoned
- 2002-08-28 CN CNB02817108XA patent/CN100549032C/zh not_active Expired - Fee Related
- 2002-08-28 WO PCT/FI2002/000699 patent/WO2003018638A1/en not_active Application Discontinuation
- 2002-08-28 EP EP02755048A patent/EP1456245A1/en not_active Withdrawn
-
2007
- 2007-04-05 US US11/784,116 patent/US20070225489A1/en not_active Abandoned
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102115501A (zh) * | 2010-12-29 | 2011-07-06 | 哈尔滨商业大学 | 一种酸解乙酰化复合变性淀粉的制备方法 |
CN103242459A (zh) * | 2013-05-27 | 2013-08-14 | 江西鑫川实业有限公司 | 一种交联两性淀粉及制备方法 |
CN103242459B (zh) * | 2013-05-27 | 2015-07-15 | 江西鑫川实业有限公司 | 一种交联两性淀粉及制备方法 |
CN103526637A (zh) * | 2013-10-31 | 2014-01-22 | 东莞理文造纸厂有限公司 | 一种高抗水性的环保箱板纸的表面施胶染色方法 |
CN104497153A (zh) * | 2014-11-24 | 2015-04-08 | 广东中轻枫泰生化科技有限公司 | 一种低粘度季铵型阳离子淀粉的制备方法 |
CN107326730A (zh) * | 2017-06-30 | 2017-11-07 | 常州思宇环保材料科技有限公司 | 一种改性淀粉基表面施胶剂的制备方法 |
CN107326730B (zh) * | 2017-06-30 | 2018-12-28 | 马鞍山市泰博化工科技有限公司 | 一种改性淀粉基表面施胶剂的制备方法 |
CN111278866A (zh) * | 2017-08-11 | 2020-06-12 | 瑞典淀粉生产者协会 | 用于制备抑制淀粉的方法 |
CN111278866B (zh) * | 2017-08-11 | 2022-03-25 | 瑞典淀粉生产者协会 | 用于制备抑制淀粉的方法 |
US11566084B2 (en) | 2017-08-11 | 2023-01-31 | Sveriges Stärkelseproducenter, förening u.p.a. | Method for preparing an inhibited starch |
WO2021086273A3 (en) * | 2019-10-29 | 2021-07-08 | Sms Corporation Co., Ltd. | Modified-acetylated distarch adipate and products containing thereof |
Also Published As
Publication number | Publication date |
---|---|
EP1456245A1 (en) | 2004-09-15 |
US20070225489A1 (en) | 2007-09-27 |
CA2457887C (en) | 2011-09-20 |
AU2002321349A1 (en) | 2003-03-10 |
CN100549032C (zh) | 2009-10-14 |
CA2457887A1 (en) | 2003-03-06 |
WO2003018638A9 (en) | 2004-02-12 |
WO2003018638A1 (en) | 2003-03-06 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: CIBA SPECIALTY CHEMICALS HOLDING INC. Free format text: FORMER OWNER: XIBA SPECIALTY CHEMICALS CO., LTD. Effective date: 20080425 |
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C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20080425 Address after: Basel, Switzerland Applicant after: CIBA SPECIALTY CHEMICALS HOLDING Inc. Address before: Finland Raisio Applicant before: Siba Special Chemicals Co.,Ltd. |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: KANMI GAITE CO., LTD. Free format text: FORMER OWNER: CIBA SC HOLDING AG Effective date: 20110906 |
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C41 | Transfer of patent application or patent right or utility model | ||
C56 | Change in the name or address of the patentee |
Owner name: CIBA SC HOLDING AG Free format text: FORMER NAME: CIBA SPECIALTY CHEMICALS HOLDING INC. |
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