CN1504094A - 草甘膦异丙胺盐水溶液的制备方法及其除草剂的组成物 - Google Patents
草甘膦异丙胺盐水溶液的制备方法及其除草剂的组成物 Download PDFInfo
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- CN1504094A CN1504094A CNA021341907A CN02134190A CN1504094A CN 1504094 A CN1504094 A CN 1504094A CN A021341907 A CNA021341907 A CN A021341907A CN 02134190 A CN02134190 A CN 02134190A CN 1504094 A CN1504094 A CN 1504094A
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- Prior art keywords
- glyphosate
- amine salt
- isopropyl amine
- glyphosate isopropyl
- isopropylamine
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000004009 herbicide Substances 0.000 title claims abstract description 29
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 23
- 239000000203 mixture Substances 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims description 25
- 239000012266 salt solution Substances 0.000 title 1
- 239000005562 Glyphosate Substances 0.000 claims abstract description 31
- 229940097068 glyphosate Drugs 0.000 claims abstract description 31
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 30
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims abstract description 30
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 19
- 239000007864 aqueous solution Substances 0.000 claims abstract description 18
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 15
- 239000002253 acid Substances 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000470 constituent Substances 0.000 claims description 13
- 239000000243 solution Substances 0.000 claims description 12
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 241000241551 Philoxerus vermicularis Species 0.000 claims description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 239000003093 cationic surfactant Substances 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 abstract description 12
- 238000006243 chemical reaction Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 2
- -1 glyphosate 2-aminopropane salt Chemical class 0.000 abstract 1
- 229920003266 Leaf® Polymers 0.000 description 6
- 241001598107 Imperata Species 0.000 description 4
- 238000009313 farming Methods 0.000 description 4
- 241000207199 Citrus Species 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 235000020971 citrus fruits Nutrition 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 241001582888 Lobus Species 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 208000024891 symptom Diseases 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- PDYXIVPKOMYDOK-UHFFFAOYSA-N Glyphosate-monoammonium Chemical compound [NH4+].OC(=O)CNCP(O)([O-])=O PDYXIVPKOMYDOK-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 244000037671 genetically modified crops Species 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000003971 tillage Methods 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
实施例序号 | 草甘膦原药(草甘膦原酸%) | 异丙胺水溶液的配制 | 草甘膦氨水溶液的配制 | 草甘膦异丙胺盐水剂的配制 | 现 象 | |||||
异丙胺∶水(质量) | 温度(℃) | 草甘膦∶氨水*(质量) | 温度(℃) | 助 剂 | 氨(%) | 草甘膦异丙胺盐(%) | ||||
种类 | 质量% | |||||||||
1234567891011 | 9095959598989595959595 | 80∶2070∶3055∶4545∶5530∶7020∶8070∶3060∶4050∶5040∶6030∶70 | 3030252020153030252020 | 100∶30100∶30100∶33100∶33100∶35100∶35100∶30100∶33100∶33100∶33100∶33 | 2525303030302525252525 | WG | 15101010851010101010 | 443.53.5323.53.53.53.53.5 | 3035414145504141414141 | 放热剧烈,放置分层放热剧烈,放置分层反应平稳,放置不分层反应平稳,放置不分层反应平稳,放置有少许固体物析出反应平稳,放置固体物析出放热剧烈,放置不分层放热剧烈,放置不分层反应平稳,放置不分层反应平稳,放置不分层反应平稳,放置有分层现象 |
序号 | 处理 | 制剂用量(g/亩) | 药后15天 | 药后30天 | 药后50天 |
症状描述 | 症状描述 | 鲜重防效(%) | |||
1 | 41%草甘膦 | 250 | 多数杂草茎叶枯死,白茅叶片黄化、未枯死。 | 一年生杂草出苗2-3叶,白茅长出心叶1.5叶。 | 94.5 |
2 | 41%农达 | 250 | 全部杂草茎叶枯死,白茅根存活。 | 一年生杂草出苗2-3叶,白茅长出心叶1.5叶。 | 92.3 |
3 | CK | / | 杂草生长茂盛。 | 杂草生长进入成熟。 | / |
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 02134190 CN1235479C (zh) | 2002-11-28 | 2002-11-28 | 草甘膦异丙胺盐水剂的制备方法 |
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CN 02134190 CN1235479C (zh) | 2002-11-28 | 2002-11-28 | 草甘膦异丙胺盐水剂的制备方法 |
Publications (2)
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CN1504094A true CN1504094A (zh) | 2004-06-16 |
CN1235479C CN1235479C (zh) | 2006-01-11 |
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CN 02134190 Expired - Fee Related CN1235479C (zh) | 2002-11-28 | 2002-11-28 | 草甘膦异丙胺盐水剂的制备方法 |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007067472A3 (en) * | 2005-12-06 | 2008-01-10 | Bayer Cropscience Lp | Novel complex for use in stabilizing herbicidal compositions and methods for synthesizing and using the same |
CN101874505A (zh) * | 2009-04-28 | 2010-11-03 | 苏州佳辉化工有限公司 | 一种草甘膦水剂的调配方法 |
CN1958594B (zh) * | 2006-11-17 | 2011-08-10 | 浙江新安化工集团股份有限公司 | 一种制备草甘膦异丙胺盐固体的方法 |
CN102396521A (zh) * | 2011-12-09 | 2012-04-04 | 四川省乐山市福华通达农药科技有限公司 | 一种草甘膦异丙胺盐水剂及其制备方法 |
CN101336075B (zh) * | 2005-12-06 | 2012-11-28 | 拜尔作物科学有限合伙公司 | 用于稳定除草组合物的新络合物及其合成方法和用途 |
CN103271083A (zh) * | 2005-10-07 | 2013-09-04 | 阿拉巴马大学 | 多功能离子液体组合物 |
CN104031085A (zh) * | 2014-05-14 | 2014-09-10 | 江苏泰仓农化有限公司 | 一种草甘膦异丙胺盐水溶液的制备方法 |
CN108576046A (zh) * | 2018-06-12 | 2018-09-28 | 允发化工(上海)有限公司 | 一种草甘膦除草剂及其制备工艺 |
CN111820235A (zh) * | 2020-08-13 | 2020-10-27 | 陕西标正作物科学有限公司 | 含异丙胺的草甘膦三价盐、其制备方法、除草剂和除草方法 |
CN113207874A (zh) * | 2021-03-25 | 2021-08-06 | 安徽瑞然生物药肥科技有限公司 | 草甘膦异丙胺盐水剂及其生产方法 |
CN114680130A (zh) * | 2020-12-25 | 2022-07-01 | 南通泰禾化工股份有限公司 | 一种草甘膦异丙胺盐可溶液剂及其制备方法 |
-
2002
- 2002-11-28 CN CN 02134190 patent/CN1235479C/zh not_active Expired - Fee Related
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103271083A (zh) * | 2005-10-07 | 2013-09-04 | 阿拉巴马大学 | 多功能离子液体组合物 |
CN103271083B (zh) * | 2005-10-07 | 2017-08-11 | 阿拉巴马大学 | 多功能离子液体组合物 |
EA017795B1 (ru) * | 2005-12-06 | 2013-03-29 | БАЙЕР КРОПСАЙЕНС ЭлПи | Комплекс для стабилизации гербицидных композиций и способ его получения |
AU2006322122B2 (en) * | 2005-12-06 | 2012-07-19 | Bayer Cropscience Aktiengesellschaft | Novel complex for use in stabilizing herbicidal compositions and methods for synthesizing and using the same |
CN101336075B (zh) * | 2005-12-06 | 2012-11-28 | 拜尔作物科学有限合伙公司 | 用于稳定除草组合物的新络合物及其合成方法和用途 |
WO2007067472A3 (en) * | 2005-12-06 | 2008-01-10 | Bayer Cropscience Lp | Novel complex for use in stabilizing herbicidal compositions and methods for synthesizing and using the same |
CN1958594B (zh) * | 2006-11-17 | 2011-08-10 | 浙江新安化工集团股份有限公司 | 一种制备草甘膦异丙胺盐固体的方法 |
CN101874505A (zh) * | 2009-04-28 | 2010-11-03 | 苏州佳辉化工有限公司 | 一种草甘膦水剂的调配方法 |
CN102396521A (zh) * | 2011-12-09 | 2012-04-04 | 四川省乐山市福华通达农药科技有限公司 | 一种草甘膦异丙胺盐水剂及其制备方法 |
CN104031085A (zh) * | 2014-05-14 | 2014-09-10 | 江苏泰仓农化有限公司 | 一种草甘膦异丙胺盐水溶液的制备方法 |
CN108576046A (zh) * | 2018-06-12 | 2018-09-28 | 允发化工(上海)有限公司 | 一种草甘膦除草剂及其制备工艺 |
CN111820235A (zh) * | 2020-08-13 | 2020-10-27 | 陕西标正作物科学有限公司 | 含异丙胺的草甘膦三价盐、其制备方法、除草剂和除草方法 |
CN114680130A (zh) * | 2020-12-25 | 2022-07-01 | 南通泰禾化工股份有限公司 | 一种草甘膦异丙胺盐可溶液剂及其制备方法 |
CN114680130B (zh) * | 2020-12-25 | 2023-12-22 | 南通泰禾化工股份有限公司 | 一种草甘膦异丙胺盐可溶液剂及其制备方法 |
CN113207874A (zh) * | 2021-03-25 | 2021-08-06 | 安徽瑞然生物药肥科技有限公司 | 草甘膦异丙胺盐水剂及其生产方法 |
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