CN1491922A - Active humic acid biological organic compound fertilizer and its preparing method - Google Patents
Active humic acid biological organic compound fertilizer and its preparing method Download PDFInfo
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- CN1491922A CN1491922A CNA031110584A CN03111058A CN1491922A CN 1491922 A CN1491922 A CN 1491922A CN A031110584 A CNA031110584 A CN A031110584A CN 03111058 A CN03111058 A CN 03111058A CN 1491922 A CN1491922 A CN 1491922A
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Abstract
The active organic compound fertilizer consists of humic acid, water, oxidant, probiotics, saccharide, animal excrement or harmless sludge, nitrogen fertilizer, phosphate fertilizer, potash fertilizer, etc. and is produced through serial technological steps. It has no smell, no harm, nitrogen fixing, phosphate decomposing and potash decomposing functions, and can improve soil, raise crop yield and quality.
Description
Affiliated technical field
The present invention relates to a kind of technical field of organic fertilizer, especially a kind of activated humic acid biological organic composite mixing fertilizer and preparation method thereof.
Background technology
China is large agricultural country; because in the past few decades traditional inorganic agriculture; all be to adopt inorganic or inorganic compounding chemical fertilizer; the simple high yield of pursuing does not pay attention to protecting ecological environment of soil, after repeatedly using such chemical fertilizer for a long time; cause agricultural product quality low; cause soil compaction, fertility decline, abominable, the organic content reduction of tilth, destroyed the soil ecology balance, and soil is polluted.In order to develop the ecological organic agricultural of China, walk the road of Sustainable development agricultural, must on fertilizer, use corresponding organic fertilizer, it is best one of a kind of wherein using " saprophytic fertilizer ".
Summary of the invention
Technical problem at above-mentioned existence, the invention provides a kind of is main raw material with activated humic acid (HA), be aided with effective organic matter (or humic acid biological fertilizer) and the monomer reactivity humic acids nutrient substance inner complex (or the biological chelating fertilizer of monomer reactivity humic acids nutrient substance) made through oxidation, fermentation, hydrolysis process, fowl and animal excrement or harmless mud, mix the beneficial microbe colony matrix liquid that connects some amount again, the tasteless harmless granular activated humic acid biological organic composite mixing fertilizer that makes is called for short by " saprophytic fertilizer ".It has long-acting, strong stress resistance, and can improve the soil, and eliminates soil compaction, culture fertility, and the pollution of residual toxicity etc. also can be eliminated, raising agricultural product quality, functions such as increasing both production and income in transformation salinity ground.
The present invention is made up of following component (by weight):
(1) oxidation of humic acids, activating ligand ratio are:
Humic acids (dry weight): water: oxygenant=100: 40-80: 5-30
(2) proportioning of beneficial microbe colony matrix liquid is:
Beneficial microbe colony stoste: carbohydrate=100: 100
(3) proportioning of monomer reactivity humic acids nutrient substance inner complex is:
Humic acids (dry weight) after oxidation, the activation: monomer nutrient substance=100: 10-80
(4) effectively organic proportioning is:
Humic acids (dry weight): fowl and animal excrement or harmless mud (dry weight): oxygenant=100: 30-80: 5-30
(5) proportioning of activated humic acid mixed organic manure is:
Contain pure N+P
2O
5+ K
2Each monomer reactivity humic acids nutrient substance inner complex gross dry weight of O≤20: effective organic dry weight=60: 40
(6) spraying its proportioning of beneficial microorganism flora matrix liquid is:
Raw material gross dry weights such as compound fertilizer: beneficial microbe colony matrix liquid=1000: 0.5-1.5
Preparation method of the present invention is:
(1) presses oxidation, the activating ligand ratio of humic acids, at first in reactor, add entry and humic acids, under constantly stirring, injecting oxygenant, be heated to 60-95 ℃ of insulation 10-70 minute;
(2) according to the proportioning of monomer reactivity humic acids nutrient substance inner complex, add the monomer nutrient substance, fully stir and be incubated 10-70 minute, blowing, oven dry, standby;
(3) by effectively organic proportioning, in reactor, start stirring, drop into fowl and animal excrement or harmless mud and humic acids, begin to heat up; Oxidation, the activating ligand ratio of pressing humic acids simultaneously add oxygenant, when temperature reaches 60-95 ℃, are incubated 10-70 minute, react the blowing that finishes, and obtain the dynamic effectively organic matter of semi-fluid, and it is effectively organic, standby just to obtain coccoid after the oven dry;
(4) press the proportioning of activated humic acid biological organic composite mixing fertilizer, various monomer reactivity humic acids nutrient substance inner complexs and effective organic matter are put in the batch mixing pond, start stirring, and then according to the proportioning of spraying beneficial microbe colony matrix liquid, spray beneficial microbe colony matrix liquid, after fully stirring evenly, adjust humidity, granulation, low temperature, oven dry, cool off, sieve, promptly obtain the activated humic acid biological organic composite mixing fertilizer.
Described oxygenant refers to O
2, O
3, H
2O
2, H
2SO
4, HNO
3, KMnO
4Deng.
Described beneficial microbe colony refers to photosynthetic bacteria group, lactobacillus, yeast group, Gram positive actinomycetes group etc.
Described fertile raw material refers to compound fertilizer, chelating fertilizer, fertilizer.
Described carbohydrate refers to brown sugar, sucrose, cotton white sugar etc.
Described monomer nutrient substance refers to N, P, K and each nutrient substance of middle trace.
This activated humic acid biological organic composite mixing fertilizer has that cost is low, effect of increasing production outstanding feature very, food crop can be increased production more than 10%, the fruit and vegetable aspect can increase production more than 30%, and improving a lot qualitatively of agricultural-food: 1. Vc content improves 2-4mg/100g; 2. the total reducing sugar amount improves 1-4%, is up to 10%; 3. protein content improves 1-2%; 4. starch content improves 1-2%; 2,000,000 mu of arable lands are protected and soil improvement, and aspects such as soil porosity, retentiveness are much improved.If every mu of fertilising 50kg can execute 2,000,000 mu, wherein there are 1,500,000 mu to be food crop, every mu of volume increase 50kg then can overcharge more than grain 7,500 ten thousand kg every year; Wherein 500,000 mu is fruit and vegetable ground, calculates by volume increase 30%, and its benefit is considerable.
Advantageous effect of the present invention is: this saprophytic fertilizer is grey black, is rich in activated humic acid and effective organic and a large amount of beneficial microbe colony and an amount of HA nutrient substance inner complex.Have fixed nitrogen, phosphorus decomposing, potassium decomposing, detoxifying properties; Can hold storage, controlled release nutrient substance, prevent nutrition leak, and can prevent antagonistic action between the nutrient substance, so fertilizer efficiency heightens, and long-acting, can realize that disposable bulk application satisfies required nutrient substance of each stage of plant growth, and growth is steadily and surely healthy and strong, strong stress resistance, drought resisting, waterlogging-resistant, resistant to lodging, anti-continuous cropping etc.; Simultaneously can also eliminate NH
3, H
2The pollution of the stench of S, methyl mercaptan class, elimination residual toxicity etc. improves resistance of oxidation, strengthening immunity; Can improve the soil, improve crumb structure, eliminate soil compaction, culture fertility, improve ecological environment of soil, transformation salinity ground; The stalk precocity of can also living improves agricultural product quality, increasing both production and income; Have vast market and economic benefit and social benefit.
This activated humic acid biological organic composite mixing fertilizer can be widely used on all farm crop and the flowers, plants and trees; Especially it is more suitable to be used on fruit and vegetable and the various cash crop.
Embodiment
Embodiment 1:
A kind of activated humic acid biological organic composite mixing fertilizer, its preparation method is:
Proportioning by the activated humic acid mixed organic manure: contain pure N+P
2O
5+ K
2Each monomer reactivity humic acids nutrient substance inner complex gross dry weight of O≤20: effective organic dry weight=60: 40, in the batch mixing pond, add the monomer reactivity corruption and plant nitrogen inner complex 250kg, add monomer reactivity phosphorus humic acid phosphorus inner complex 170kg, add monomer reactivity potassium humate inner complex 230kg, add effective organic 350kg again, mix, spray beneficial microbe colony matrix liquid 1kg simultaneously, fully stir after 20 minutes, after going out the multiple membrane stack in pond and putting one day, adjust humidity, granulation, oven drying at low temperature, cooling is sieved, and forms the particulate state grey black, tasteless harmless activated humic acid biological organic composite mixing fertilizer
This fertilizer standard is: organic content 〉=50%, humic acids 〉=30%, N 〉=8%, P
2O
5〉=5%, K
2O 〉=7%, moisture content≤18%, PH5-6, granularity Φ 1-6mm 〉=80%, beneficial microbe strain＞2 * 10
8Individual/kg fertilizer.
Embodiment 2:
The proportioning of monomer reactivity humic acids nutrient substance inner complex is:
Humic acids (dry weight) after oxidation, the activation: monomer nutrient substance=100: 10-80
Its preparation method is:
(1) oxidation of humic acids, activation, press humic acids (dry weight): water: the proportioning of oxygenant=100: 60: 15 is injected water 60kg in reactor, start stirring, drops into the 100kg humic acids again, and heating slowly adds the HNO of 15kg then
3, be warming up to 90 ℃, be incubated 30 minutes, oxidation, activation finish; Press the proportioning of monomer reactivity humic acids nutrient substance inner complex again, add KCl 100kg, continue to stir, be incubated after 30 minutes, stop heating and stirring, blowing, oven dry just obtain monomer reactivity potassium humate inner complex coccoid (other monomer nutrient substance, also way makes by that analogy), can be as the raw material of producing the activated humic acid biological organic composite mixing fertilizer;
(2) the powdery inner complex is put in the batch mixing pond, under whipped state, sprayed 0.2kg beneficial microbe colony matrix liquid, abundant mixing, blowing, oven drying at low temperature just obtains the biological chelating fertilizer of powdery monomer reactivity potassium humate, and the potassium of the usefulness of can topdressing is special-purpose fertile.
Embodiment 3:
Effectively organic proportioning is:
Humic acids (dry weight): fowl and animal excrement or harmless mud (dry weight): oxygenant=100: 30-80: 5-30
Its preparation method is:
Prescription by effective organic matter: humic acids (dry weight): fowl and animal excrement or harmless mud (dry weight): oxygenant=100: 50: 15, in reactor, inject water 30kg, start stirring, add dry rot phytic acid 100kg, fowl and animal excrement or harmless mud (dry weight) 50kg, slowly add the HNO of 15kg then
3Continue to stir, be heated to 90 ℃, be incubated 30 minutes, reaction finishes, and the blowing cooling enters the batch mixing pond, stir, spray 0.2kg beneficial microbe colony matrix liquid, fully the multiple membrane stack of mixing (20 minutes) back discharging was put one day, adjusted humidity again, granulation, oven drying at low temperature, cooling is sieved, and promptly obtains granular activated humic acid biological organic fertilizer; It is effectively organic that maybe the material that reaction is finished directly is dried into powdery, uses as the raw material of producing the humic acid biological mixed organic manure.
Claims (8)
1, a kind of activated humic acid biological organic composite mixing fertilizer and preparation method thereof is characterized in that it is made up of following component (by weight):
(1) oxidation of humic acids, activating ligand ratio are:
Humic acids (dry weight): water: oxygenant=100: 40-80: 5-30
(2) proportioning of beneficial microbe colony matrix liquid is:
Beneficial microbe colony stoste: carbohydrate=100: 100
(3) proportioning of monomer reactivity humic acids nutrient substance inner complex is:
Humic acids (dry weight) after oxidation, the activation: monomer nutrient substance=100: 10-80
(4) effectively organic proportioning is:
Humic acids (dry weight): fowl and animal excrement or harmless mud (dry weight): oxygenant=100: 30-80: 5-30
(5) proportioning of activated humic acid mixed organic manure is:
Contain pure N+P
2O
5+ K
2Each monomer reactivity humic acids nutrient substance inner complex gross dry weight of O≤20: effective organic dry weight=60: 40
(6) spraying its proportioning of beneficial microorganism flora matrix liquid is:
Raw material gross dry weights such as compound fertilizer: beneficial microbe colony matrix liquid=1000: 0.5-1.5
Preparation method of the present invention is:
(1) presses oxidation, the activating ligand ratio of humic acids, at first in reactor, add entry and humic acids, under constantly stirring, injecting oxygenant, be heated to 60-95 ℃ of insulation 10-70 minute;
(2) according to the proportioning of monomer reactivity humic acids nutrient substance inner complex, add the monomer nutrient substance, fully stir and be incubated 10-70 minute, blowing, oven dry, standby;
(3) by effectively organic proportioning, in reactor, start stirring, drop into fowl and animal excrement or harmless mud and humic acids, begin to heat up; Oxidation, the activating ligand ratio of pressing humic acids simultaneously add oxygenant, when temperature reaches 60-95 ℃, are incubated 10-70 minute, react the blowing that finishes, and obtain the dynamic effectively organic matter of semi-fluid, and it is effectively organic, standby just to obtain coccoid after the oven dry;
(4) press the proportioning of activated humic acid biological organic composite mixing fertilizer, various monomer reactivity humic acids nutrient substance inner complexs and effective organic matter are put in the batch mixing pond, start stirring, and then according to the proportioning of spraying beneficial microbe colony matrix liquid, spray beneficial microbe colony matrix liquid, after fully stirring evenly, adjust humidity, granulation, low temperature, oven dry, cool off, sieve, promptly obtain the activated humic acid biological organic composite mixing fertilizer.
2, a kind of activated humic acid biological organic composite mixing fertilizer according to claim 1 and preparation method thereof is characterized in that described monomer reactivity humic acids nutrient substance inner complex, and its preparation method is:
(1) press oxidation, the activatory proportioning of humic acids, humic acids (dry weight): water: oxygenant=100: 60: 15, in reactor, inject water 60kg, start stirring, drop into the 100kg humic acids again, heating slowly adds the HNO of 15kg then
3, be warming up to 90 ℃, be incubated 30 minutes, oxidation, activation finish; Press the proportioning of monomer reactivity humic acids nutrient substance inner complex again, add KCl100kg, continue to stir, be incubated after 30 minutes, stop heating and stir blowing, oven dry, just obtain monomer reactivity potassium humate inner complex coccoid, can be as the raw material of producing the activated humic acid biological organic composite mixing fertilizer;
(2) the powdery inner complex is put in the batch mixing pond, under whipped state, sprayed 0.2kg beneficial microbe colony matrix liquid, abundant mixing, blowing, oven drying at low temperature just obtains the biological chelating fertilizer of powdery monomer reactivity potassium humate, and the potassium of the usefulness of can topdressing is special-purpose fertile.
3, a kind of activated humic acid biological organic composite mixing fertilizer according to claim 1 and preparation method thereof is characterized in that described effective organic matter, and its preparation method is:
By effectively organic proportioning, humic acids (dry weight): fowl and animal excrement or harmless mud (dry weight): oxygenant=100: 50: 15, in reactor, inject water 30kg, start stirring, add dry rot phytic acid 100kg, fowl and animal excrement or harmless mud (dry weight) 50kg, slowly add the HNO of 15kg then
3Continue to stir, be heated to 90 ℃, be incubated 30 minutes, reaction finishes, and the blowing cooling enters the batch mixing pond, stir, spray 0.2kg beneficial microbe colony matrix liquid, fully mixing, after 20 minutes, the multiple membrane stack of discharging was put one day, adjusted humidity again, granulation, oven drying at low temperature, cooling is sieved, and promptly obtains granular activated humic acid biological organic fertilizer; It is effectively organic that maybe the material that reaction is finished directly is dried into powdery, can be used as the raw material of producing the humic acid biological mixed organic manure and use.
4, a kind of activated humic acid biological organic composite mixing fertilizer according to claim 1 and preparation method thereof is characterized in that described oxygenant refers to O
2, O
3, H
2O
2, H
2SO
4, HNO
3, KMnO
4
5, a kind of activated humic acid biological organic composite mixing fertilizer according to claim 1 and preparation method thereof is characterized in that described beneficial microbe colony refers to photosynthetic bacteria group, lactobacillus, yeast group, Gram positive actinomycetes group.
6, a kind of activated humic acid biological organic composite mixing fertilizer according to claim 1 and preparation method thereof is characterized in that described fertile raw material refers to compound fertilizer, chelating fertilizer, fertilizer.
7, a kind of activated humic acid biological organic composite mixing fertilizer according to claim 1 and preparation method thereof is characterized in that described carbohydrate refers to brown sugar, sucrose, cotton white sugar.
8, a kind of activated humic acid biological organic composite mixing fertilizer according to claim 1 and preparation method thereof is characterized in that described monomer nutrient substance refers to N, P, K and each nutrient substance of middle trace.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031110584A CN1491922A (en) | 2003-02-26 | 2003-02-26 | Active humic acid biological organic compound fertilizer and its preparing method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031110584A CN1491922A (en) | 2003-02-26 | 2003-02-26 | Active humic acid biological organic compound fertilizer and its preparing method |
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| Publication Number | Publication Date |
|---|---|
| CN1491922A true CN1491922A (en) | 2004-04-28 |
Family
ID=34239230
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100419003C (en) * | 2006-05-22 | 2008-09-17 | 东北大学 | Preparation of oil sand asphalt texture separating agent using natural humic acid |
| CN102234204A (en) * | 2010-04-23 | 2011-11-09 | 罗林松 | Nitrogen source fertilizer |
| CN102459131A (en) * | 2009-06-15 | 2012-05-16 | 双子贸易开放式股份公司 | Method for producing an organic mineral fertilizer mixture |
| CN103588519A (en) * | 2013-10-16 | 2014-02-19 | 天津市瑞物有机肥有限公司 | MS preparation organic bio-fertilizer and preparation method thereof |
| CN105801298A (en) * | 2016-03-14 | 2016-07-27 | 潘福忠 | Microorganism targeted flora solid organic and inorganic compound fertilizer |
| CN107216186A (en) * | 2017-02-21 | 2017-09-29 | 杨凌玉鲲生物技术有限公司 | Production method and application process with disease-resistant growth-promoting functions functional biological organic fertilizer |
| CN112851436A (en) * | 2021-03-29 | 2021-05-28 | 东华大学 | Method for quickly converting pig manure into organic fertilizer |
-
2003
- 2003-02-26 CN CNA031110584A patent/CN1491922A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100419003C (en) * | 2006-05-22 | 2008-09-17 | 东北大学 | Preparation of oil sand asphalt texture separating agent using natural humic acid |
| CN102459131A (en) * | 2009-06-15 | 2012-05-16 | 双子贸易开放式股份公司 | Method for producing an organic mineral fertilizer mixture |
| CN102234204A (en) * | 2010-04-23 | 2011-11-09 | 罗林松 | Nitrogen source fertilizer |
| CN103588519A (en) * | 2013-10-16 | 2014-02-19 | 天津市瑞物有机肥有限公司 | MS preparation organic bio-fertilizer and preparation method thereof |
| CN105801298A (en) * | 2016-03-14 | 2016-07-27 | 潘福忠 | Microorganism targeted flora solid organic and inorganic compound fertilizer |
| CN107216186A (en) * | 2017-02-21 | 2017-09-29 | 杨凌玉鲲生物技术有限公司 | Production method and application process with disease-resistant growth-promoting functions functional biological organic fertilizer |
| CN112851436A (en) * | 2021-03-29 | 2021-05-28 | 东华大学 | Method for quickly converting pig manure into organic fertilizer |
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