CN107739243A - A kind of charcoal base bioorganic compound fertilizer and preparation method thereof - Google Patents
A kind of charcoal base bioorganic compound fertilizer and preparation method thereof Download PDFInfo
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- CN107739243A CN107739243A CN201711092066.8A CN201711092066A CN107739243A CN 107739243 A CN107739243 A CN 107739243A CN 201711092066 A CN201711092066 A CN 201711092066A CN 107739243 A CN107739243 A CN 107739243A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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Abstract
The invention provides a kind of charcoal base bioorganic compound fertilizer and preparation method thereof, using by Kiwi berry beta pruning, Wood leftover, cogongrass, Chinese pennisetum, Chinese medicine dreg charing after with fermenting plant powder, MAP, potassium chloride, indolebutyric acid, thiocarbamide, triacontanol, zinc chloride, Magnesium Borate Ore Powder mixes, catalyst is used as using phosphoric acid and niobium pentaoxide, dicetyl peroxydicarbonate diisobutyl ester is initiator, spray ureaformaldehyde reaction solution, granulating and drying obtains charcoal base bioorganic compound fertilizer, preparation process of the present invention is simple to operation, good economy performance, condensation reaction transformation ratio is high, obtained charcoal base bioorganic compound fertilizer can meet all kinds of soil and the needs of various crops.
Description
Technical field
The invention belongs to technical field of fertilizers, and in particular to a kind of charcoal base bioorganic compound fertilizer and preparation method thereof.
Background technology
In recent years, biomass carbon turns into the research field focus of attention such as agricultural, environment and the energy, biomass carbon be
Under hypoxemia or oxygen-free environment, by Pintsch process by the product of plant carbide.With the fast development of China's traditional Chinese medicine, in
The discarded dregs of a decoction of medicine are increasing, and according to the preliminary statistics, the annual caused discarded dregs of a decoction are up to during herbal pharmaceutical industrialization production
Millions of tons.The water quality of surrounding, soil and air can be caused using measures such as landfill, burning, FX stackings serious
Pollution, environmental quality is influenceed, and expend substantial contribution, influence the normal production in pharmaceutical factory.In recent years, further prominent and serious medicine
Slag discharges and process problem, just turns into one of bottleneck problem for restricting herbal pharmaceutical industry development.Ureaformaldehyde is also known as urea-formaldehyde fertilizer,
Nineteen fifty-five is produced by BASF at first, is the slow-release nitrogen fertilizer of first merchandized handling.It is formed by urea and formaldehyde condensation, is white
Color, tasteless powder or graininess.It is different from the mol ratio of formaldehyde according to urea, the urea of different condensation degrees (acquisition time) can be made
Formaldehyde fertilizer.
Patent CN1343186 discloses a kind of preparation technology of granular composite fertilizer compositions and products thereof, applies artificial beautiful
Delaware State OMS Investment Co. of state；The technology is related to a kind of preparation of granular composite fertilizer compositions, and it is by urea and first
The liquid mixture of aldehyde is applied to dry substrate such as phosphorus source, potassium resource, aid nutrition source, micronutrient source or its mixture
On, make liquid mixture situ reaction formed methylene urea reaction product, so as to promote the bonding of substrate and particle composites,
And substrate is granulated while liquid mixture reacts, to form granular composite fertilizer compositions.Patent CN201410812768.9
The ureaformaldehyde semi-finished product using the processing of clearance-type method are disclosed as one of raw material, are added by livestock and poultry fermentation muck pulvis, biomass
The dispersant of raw material pulvis and biological powdered carbon composition, and mix and be made with phosphate fertilizer or potash fertilizer.Patent CN201510117731.9
Disclose using the agriculture and forestry organic waste materials such as rice husk, stalk, blade pyrolysis production charcoal, then mixed with diatomite and fertilizer, sprayed
Ureaformaldehyde solution is prepared.Patent CN201610816939.4 discloses a kind of composite water conservation ureaformaldehyde slow-release rice fertilizer,
Ammonium persulfate is used as initiator, acid amides dispersion liquid, pretreatment ureaformaldehyde etc. are introduced while polymer is prepared.Patent
CN201310347441.4 disclose dregs of a decoction fermentation composite fertilizer by nitro humus acid, Chinese medicine slag, nano-sized carbon, urea, chlorination
The raw materials such as potassium, potassium dihydrogen phosphate, multielement slow-release fertilizer are made.Patent CN201410491900.0 is disclosed containing button mushroom dregs
Fertilizer be made up of raw materials such as bacteria residue, Chinese medicine slag, glycerine, zinc sulfate, MAP, potassium chloride, ureaformaldehyde composite fertilizers.
Prior art, which has fertilizer, can not meet all kinds of soil and the needs of various crops, and nutrient is lost in comparatively fast in soil
The problems such as.Although prior art using Chinese medicine dreg fermentation using more as bio-organic fertilizer research, it is current do not have also by
Chinese medicine dreg charing sprays ureaformaldehyde reaction solution and is mixed with the research of biological organic fertilizer with fermenting plant powder again.Though prior art
So there is the research of formaldehyde and biomass carbon mixing as mixed fertilizer, but the physicochemical properties of biomass carbon are by raw material and heat
Very big difference be present, how to find out in the influence of cracking process, the physical arrangement and chemical property of the biomass carbon of different material
The soil property of all kinds of soil can be improved, meets the nutritional need of all kinds of crops, is research emphasis of today.In addition, ureaformaldehyde reacts
It is complicated in the presence of reaction, the problems such as cost is higher, and cross-linking reaction is excessive, how ureaformaldehyde reaction and biomass carbon cleverly to be combined
Prepare long-acting compound fertilizer and be also one and urgently solve the problems, such as.
The content of the invention
In order to solve the above technical problems, the invention provides a kind of charcoal base bioorganic compound fertilizer and preparation method thereof,
The defects of its method overcomes existing planting technology, by by Kiwi berry beta pruning, Wood leftover, cogongrass, Chinese pennisetum, Chinese medicines
Mixed after slag charing with fermenting plant powder, MAP, potassium chloride, indolebutyric acid, thiocarbamide, triacontanol, zinc chloride, Magnesium Borate Ore Powder
Close, using phosphoric acid and niobium pentaoxide as catalyst, dicetyl peroxydicarbonate diisobutyl ester is initiator, sprinkling ureaformaldehyde reaction
Liquid, granulating and drying obtain charcoal base bioorganic compound fertilizer, and charcoal base bioorganic compound fertilizer scientific formula of the present invention is reasonable, prepare
Step is simple to operation, good economy performance, and condensation reaction transformation ratio is high, and obtained charcoal base bioorganic compound fertilizer can meet all kinds of
Soil and the needs of various crops.
Specifically, charcoal base bioorganic compound fertilizer is by the beta pruning of 200-300 parts by weight Kiwi berrys, 200-300 parts by weight wood
Material leftover bits and pieces, 100-200 parts by weight cogongrass, 100-200 parts by weight Chinese pennisetum, the ammonium of 30-50 parts by weight of phosphoric acid one, 20-30 weight
Part potassium chloride, 200-300 parts by weight Chinese medicine dreg, 200-300 parts by weight fermenting plants powder, 50-80 parts by weight of urea, 60-100
Parts by weight of formaldehyde, 10-16 weight parts of quicklime, 3-7 parts by weight dicetyl peroxydicarbonates diisobutyl ester, 5-9 parts by weight acidic catalysts
Agent, 2-4 parts by weight indolebutyric acid, 2-4 parts by weight thiocarbamide, 2-4 parts by weight triacontanol, 1-3 parts by weight zinc chloride, 8-10 weight
Part Magnesium Borate Ore Powder is made
Preferably, charcoal base bioorganic compound fertilizer by 250 parts by weight Kiwi berry beta prunings, 250 parts by weight Wood leftovers,
150 parts by weight cogongrass, 150 parts by weight Chinese pennisetums, the ammonium of 40 parts by weight of phosphoric acid one, 25 parts sulfuric acid potassium, 250 parts by weight Chinese medicines
Slag, 250 parts by weight fermenting plant powder, 65 parts by weight of urea, 80 parts by weight of formaldehyde, 14 weight parts of quicklime, 5 parts by weight peroxidating
Two carbonic acid diisobutyl esters, 7 parts by weight acidic catalysts, 3 parts by weight indolebutyric acids, 3 parts by weight thiocarbamides, 3 parts by weight triacontanols,
2 parts by weight zinc chloride, 9 parts by weight Magnesium Borate Ore Powders are made.
Charcoal base bioorganic compound fertilizer preparation method comprises the following steps：
(1) Kiwi berry beta pruning, Wood leftover, cogongrass, Chinese pennisetum, Chinese medicine dreg are put into isolation air in retort to add
It is standby to obtain charcoal matrix to 450-500 DEG C of charing for heat；
(2) quick lime and water are added in reactive tank, urea and formaldehyde are added after quick lime dissolving, setting speed of agitator is
100-200r/min, 30-60min is reacted, obtains ureaformaldehyde reaction solution；
(3) by charcoal matrix, fermenting plant powder, MAP, potassium chloride, indolebutyric acid, thiocarbamide, triacontanol, zinc chloride,
Magnesium Borate Ore Powder, acidic catalyst, dicetyl peroxydicarbonate diisobutyl ester are put into reaction tank, uniformly spray ureaformaldehyde reaction solution, are mixed
After closing uniformly, composite fertilizer's slurry is granulated with being pumped into spray granulation drier, dries, obtains charcoal base biological organic complex fertilizer
Material.
Preferably, charcoal base bioorganic compound fertilizer preparation method comprises the following steps：
(1) Kiwi berry beta pruning, Wood leftover, cogongrass, Chinese pennisetum, Chinese medicine dreg are put into isolation air in retort to add
It is standby to obtain charcoal matrix to 475 DEG C of charings for heat；
(2) quick lime and water are added in reactive tank, urea and formaldehyde are added after quick lime dissolving, setting speed of agitator is
150r/min, 45min is reacted, obtains ureaformaldehyde reaction solution；
(3) by charcoal matrix, fermenting plant powder, MAP, potassium chloride, indolebutyric acid, thiocarbamide, triacontanol, zinc chloride,
Magnesium Borate Ore Powder, acidic catalyst, dicetyl peroxydicarbonate diisobutyl ester are put into reaction tank, uniformly spray ureaformaldehyde reaction solution, are mixed
After closing uniformly, composite fertilizer's slurry is granulated with being pumped into spray granulation drier, dries, obtains charcoal base biological organic complex fertilizer
Material.
Further, the mass ratio of described charcoal matrix and water is 1:10-13.
Further, described Chinese medicine dreg is by 20-30 parts by weight PERICARPIUM TRICHOSANTHIS, 40-50 parts by weight sargentodoxa cuneata, 10-20 weights
Amount part Semen Cuscutae, 10-20 parts by weight field pennycress are mixed.
Further, described Chinese medicine dreg is by 25 parts by weight PERICARPIUM TRICHOSANTHISs, 45 parts by weight sargentodoxa cuneata, 15 parts by weight Tu silks
Son, 15 parts by weight field pennycress are mixed.
Further, described fermenting plant powder is：20-30 parts by weight motherwort, 50-60 parts by weight mugwort wormwood artemisias are cut into
2-4cm is grown, and is put into fermentation vat, and the maceration extract stack retting for being inoculated with cellulolytic enzyme, maceration extract submergence, every 4 are put into pond
Its agitation once, after 30~40 days, clears motherwort, wild artemisia argyi plant, dried, and crushes, and obtains fermenting plant powder.
Further, described acidic catalyst is by 1-3 parts by weight of phosphoric acid and 5-7 parts by weight niobium pentaoxide mixing system
Into.
The principle and beneficial effect of the present invention：
The present invention after Kiwi berry beta pruning, Wood leftover, cogongrass, Chinese pennisetum, Chinese medicine dreg charing with fermentation by will plant
Thing powder, MAP, potassium chloride, indolebutyric acid, thiocarbamide, triacontanol, zinc chloride, Magnesium Borate Ore Powder mixing, with phosphoric acid and five oxygen
Change two niobiums as catalyst, dicetyl peroxydicarbonate diisobutyl ester is initiator, sprays ureaformaldehyde reaction solution, and granulating and drying obtains charcoal base
Bioorganic compound fertilizer, there are following features：
(1) scientific formula of the present invention is reasonable, and Chinese medicine dreg directly charing can effectively remove irritating gas such as stench, foul
Taste, and the loss of active ingredient in fermentation process is avoided, caused Chinese medicine dreg biomass carbon has more preferable use value,
Carbonized using using Kiwi berry beta pruning, Wood leftover, cogongrass, Chinese pennisetum, Chinese medicine dreg as charcoal matrix, by motherwort and mugwort
Wormwood artemisia fermentation is used as fertilizer components, can effectively reduce the soil weight, improves soil pH value, improves soil aggregation and soil water retention energy
Power, meet the needs of all kinds of soil, can also adsorb and load fertilizer nutrient, delay release and reduction of the fertilizer in soil to support
Divide leaching loss.In addition, the present invention can make crop growth more preferable using indolebutyric acid, thiocarbamide, triacontanol as fertilizer additive,
Diseases and insect pests resistance significantly increases, and yield is higher.
(2) present invention uses in urea and formaldehyde course of reaction is dissolved in water as reaction dissolvent, quick lime using quick lime
It is dissolved in the heat release of water nature and generates base catalyst calcium hydroxide, meets the requirement of urea and formaldehyde reaction, simplify reaction
The step of, save reaction cost.
(3) long-acting nitrogen fertilizer polymerisation of the present invention, which uses, mixes charcoal matrix and MAP, potassium sulfate, with phosphoric acid and five
Two niobiums are aoxidized as catalyst, dicetyl peroxydicarbonate diisobutyl ester is initiator, the reaction solution polymerization of sprinkling ureaformaldehyde, can make reaction
It is more rapid, avoid that cross-linking reaction is excessive, greatly increase the charcoal base biological organic complex fertilizer water retention property of production, simplify
Reactions steps, have saved production cost, and are more suitable for large-scale production, improve reaction efficiency and product quality.
Beneficial effect of the present invention is investigated：
The applicant has found during experiment, is added without catalyst reaction, and its reaction time is long, and reacts conversion not
Completely, only adding phosphoric acid can be carried out immediately as catalyst, reaction, but react too violent, produced sudden and violent poly- reaction, added phosphorus
Acid and niobium pentaoxide mixing are used as catalyst, and reaction conversion ratio is high, and reacts more steady.The present invention is by with phosphoric acid and five
Aoxidize the mixing of two niobiums and be used as catalyst, carrier of the niobium pentaoxide as phosphoric acid, be added in reaction, make long-acting nitrogen fertilizer polymerization anti-
Should be more rapid, improve reaction efficiency.The applicant has surprisingly been found that during experiment, and it is different to add dicetyl peroxydicarbonate two
Butyl ester avoids excessive cross-linking reaction, improves the validity of fertilizer nutrient, make the quality of product more excellent as initiator.
The applicant will add indolebutyric acid, thiocarbamide, charcoal base bioorganic compound fertilizer made from triacontanol and be added without indoles fourth
Acid, thiocarbamide, charcoal base bioorganic compound fertilizer is contrasted made from triacontanol, plants radix pseudostellariae respectively, finds to add Yin
Diindyl butyric acid, thiocarbamide, triacontanol are compared with indolebutyric acid, thiocarbamide, triacontanol system is added without, and radix pseudostellariae growing way is luxuriant, life
Power is strong, and diseases and insect pests resistance is more excellent, adds indolebutyric acid, thiocarbamide, the radix pseudostellariae survival rate ratio of triacontanol plantation and is added without Yin
Diindyl butyric acid, thiocarbamide, triacontanol plantation radix pseudostellariae survival rate it is high by 10%, applicant further found that only add indolebutyric acid or
Thiocarbamide or triacontanol, or add indolebutyric acid and thiourea combination, indolebutyric acid and triacontanol combination, thiocarbamide and melissane
Alcohol combines good without indolebutyric acid, thiocarbamide, triacontanol is added to the growing way and diseases and insect pests resistance of radix pseudostellariae.
Test 1 component screening test
Test group 1：By the beta pruning of 250g Kiwi berrys, 250g Wood leftovers, 150g cogongrass, 150g Chinese pennisetums, 40g phosphoric acid one
Ammonium, 25g potassium sulfates, 250g Chinese medicine dregs, 250g fermenting plants powder, 65g urea, 80g formaldehyde, 14g quick limes, 5g peroxidating two
Carbonic acid diisobutyl ester, 7g acidic catalysts, 3g indolebutyric acids, 3g thiocarbamides, 3g triacontanols, 2g zinc chloride, 9g Magnesium Borate Ore Powder systems
The charcoal base bioorganic compound fertilizer obtained.
Test group 2：By in the beta pruning of 250g Kiwi berrys, 250g Wood leftovers, 40g MAPs, 25g potassium sulfates, 250g
The medicine dregs of a decoction, 250g fermenting plants powder, 65g urea, 80g formaldehyde, 14g quick limes, 5g dicetyl peroxydicarbonates diisobutyl ester, 7g are acid
Catalyst, 3g indolebutyric acids, 3g thiocarbamides, 3g triacontanols, 2g zinc chloride, charcoal base biological organic is compound made from 9g Magnesium Borate Ore Powders
Fertilizer.(subtracting cogongrass, Chinese pennisetum)
Test group 3：By the beta pruning of 250g Kiwi berrys, 250g Wood leftovers, 150g cogongrass, 150g Chinese pennisetums, 40g phosphoric acid one
Ammonium, 25g potassium sulfates, 250g fermenting plants powder, 65g urea, 80g formaldehyde, 14g quick limes, 5g dicetyl peroxydicarbonates diisobutyl ester,
7g acidic catalysts, 3g indolebutyric acids, 3g thiocarbamides, 3g triacontanols, 2g zinc chloride, charcoal base biology has made from 9g Magnesium Borate Ore Powders
Machine compound fertilizer (subtracts Chinese medicine dreg)
Test group 4：By the beta pruning of 250g Kiwi berrys, 250g Wood leftovers, 150g cogongrass, 150g Chinese pennisetums, 40g phosphoric acid one
Ammonium, 25g potassium sulfates, 250g Chinese medicine dregs, 65g urea, 80g formaldehyde, 14g quick limes, 5g dicetyl peroxydicarbonates diisobutyl ester, 7g
Acidic catalyst, 3g indolebutyric acids, 3g thiocarbamides, 3g triacontanols, 2g zinc chloride, charcoal base biological organic made from 9g Magnesium Borate Ore Powders
Compound fertilizer.(subtracting fermenting plant powder)
4 pieces of fields similar in selecting soil property, enter according to charcoal base bioorganic compound fertilizer made from above-mentioned test group 1-4 respectively
Row fertilizing and planting rice, testing result is shown in Table 1 after rice harves：
Table 1：Rice test result
As can be seen from the above table, prescription of the present invention deletes cogongrass and Chinese pennisetum, Chinese medicine dreg or fermenting plant powder makes
Rice quality declines, yield reduction, and soil CEC values reduce, and therefore, the charcoal base biological organic obtained by instant component is compound
Fertilizer scientific formula is reasonable, can effectively submit rice quality and yield, improves soil CEC values.
Experiment 2：Check experiment
Trial crops：Corn
Experiment packet：
Test group 1：According to charcoal base biological organic complex fertilizer produced by the present invention.
Test group 2：According to fertilizer made from patent CN1343186.
Test group 3：According to fertilizer made from patent CN201410812768.9.
Test group 4：According to fertilizer made from patent CN201510117731.9.
Test group 5：According to fertilizer made from patent CN201610816939.4.
Test group 6：According to fertilizer made from patent CN201310347441.4.
Test group 7：According to fertilizer made from patent CN201410491900.0.
Soil similar in selection soil property is divided into 7 pieces, according to identical implantation methods and fertilization mode maize planting, after ripe
Testing result, statistical analysis, it the results are shown in Table 2：
Table 2：Corn trials result
As can be seen from the above table, using charcoal base biological organic complex fertilizer produced by the present invention compared with compareing fertilizer,
It is higher to improve the ability of P in soil H, water holding capacity, sticking and the commutative nutrient of supply, makes corn quality more excellent, yield is bigger, more
The requirement of corn growth can be met.
Embodiment：
The preparation of acidic catalyst：200g phosphoric acid and 600g niobium pentaoxides is taken to be mixed to prepare.
The preparation of Chinese medicine dreg：25g PERICARPIUM TRICHOSANTHISs, 45g sargentodoxa cuneata, 15g Semen Cuscutaes, 15g field pennycress is taken to be mixed to prepare.
The preparation of fermenting plant powder：Take 25kg motherworts, 55kg mugwort wormwood artemisias to be cut into 3cm length, be put into fermentation vat, Chi Lifang
Enter to be inoculated with the maceration extract stack retting of cellulolytic enzyme, maceration extract submergence, every agitation in 4 days once, after 35 days, motherwort,
Wild artemisia argyi plant clears, and dries, and crushes, obtains fermenting plant powder.
The preparation of the charcoal base bioorganic compound fertilizer of embodiment 1
Formula：The beta pruning of 200g Kiwi berrys, 200g Wood leftovers, 100g cogongrass, 100g Chinese pennisetums, 30g MAPs,
20g potassium chloride, 200g Chinese medicine dregs, 200g fermenting plants powder, 50g urea, 60g formaldehyde, 10g quick limes, the carbon of 3g peroxidating two
Sour diisobutyl ester, 5g acidic catalysts, 2g indolebutyric acids, 2g thiocarbamides, 2g triacontanols, 1g parts zinc chloride, 8g Magnesium Borate Ore Powders；
Preparation method：
(1) Kiwi berry beta pruning, Wood leftover, cogongrass, Chinese pennisetum, Chinese medicine dreg are put into isolation air in retort to add
It is standby to obtain charcoal matrix to 475 DEG C of charings for heat；
(2) quick lime and water are added in reactive tank, urea and formaldehyde are added after quick lime dissolving, setting speed of agitator is
150r/min, 45min is reacted, obtains ureaformaldehyde reaction solution；
(3) by charcoal matrix, fermenting plant powder, MAP, potassium chloride, indolebutyric acid, thiocarbamide, triacontanol, zinc chloride,
Magnesium Borate Ore Powder, acidic catalyst, dicetyl peroxydicarbonate diisobutyl ester are put into reaction tank, uniformly spray ureaformaldehyde reaction solution, are mixed
After closing uniformly, composite fertilizer's slurry is granulated with being pumped into spray granulation drier, dries, obtains charcoal base biological organic complex fertilizer
Material.
The preparation of the charcoal base bioorganic compound fertilizer of embodiment 2
Formula：The beta pruning of 250g Kiwi berrys, 250g Wood leftovers, 150g cogongrass, 150g Chinese pennisetums, 40g MAPs,
25g potassium sulfates, 250g Chinese medicine dregs, 250g fermenting plants powder, 65g urea, 80g formaldehyde, 14g quick limes, the carbon of 5g peroxidating two
Sour diisobutyl ester, 7g acidic catalysts, 3g indolebutyric acids, 3g thiocarbamides, 3g triacontanols, 2g zinc chloride, 9g Magnesium Borate Ore Powders；
Preparation method：
(1) Kiwi berry beta pruning, Wood leftover, cogongrass, Chinese pennisetum, Chinese medicine dreg are put into isolation air in retort to add
It is standby to obtain charcoal matrix to 475 DEG C of charings for heat；
(2) quick lime and water are added in reactive tank, urea and formaldehyde are added after quick lime dissolving, setting speed of agitator is
150r/min, 45min is reacted, obtains ureaformaldehyde reaction solution；
(3) by charcoal matrix, fermenting plant powder, MAP, potassium chloride, indolebutyric acid, thiocarbamide, triacontanol, zinc chloride,
Magnesium Borate Ore Powder, acidic catalyst, dicetyl peroxydicarbonate diisobutyl ester are put into reaction tank, uniformly spray ureaformaldehyde reaction solution, are mixed
After closing uniformly, composite fertilizer's slurry is granulated with being pumped into spray granulation drier, dries, obtains charcoal base biological organic complex fertilizer
Material.
The preparation of the charcoal base bioorganic compound fertilizer of embodiment 3
Formula：The beta pruning of 300g Kiwi berrys, 300g Wood leftovers, 200g cogongrass, 200g Chinese pennisetums, 50g MAPs,
30g potassium chloride, 300g Chinese medicine dregs, 300g fermenting plants powder, 80g urea, 100g formaldehyde, 16g quick limes, the carbon of 7g peroxidating two
Sour diisobutyl ester, 9g acidic catalysts, 4g indolebutyric acids, 4g thiocarbamides, 4g triacontanols, 3g zinc chloride, 10g Magnesium Borate Ore Powders；
Preparation method：
(1) Kiwi berry beta pruning, Wood leftover, cogongrass, Chinese pennisetum, Chinese medicine dreg are put into isolation air in retort to add
It is standby to obtain charcoal matrix to 475 DEG C of charings for heat；
(2) quick lime and water are added in reactive tank, urea and formaldehyde are added after quick lime dissolving, setting speed of agitator is
150r/min, 45min is reacted, obtains ureaformaldehyde reaction solution；
(3) by charcoal matrix, fermenting plant powder, MAP, potassium chloride, indolebutyric acid, thiocarbamide, triacontanol, zinc chloride,
Magnesium Borate Ore Powder, acidic catalyst, dicetyl peroxydicarbonate diisobutyl ester are put into reaction tank, uniformly spray ureaformaldehyde reaction solution, are mixed
After closing uniformly, composite fertilizer's slurry is granulated with being pumped into spray granulation drier, dries, obtains charcoal base biological organic complex fertilizer
Material.
Claims (9)
1. a kind of charcoal base bioorganic compound fertilizer, it is characterised in that by the beta pruning of 200-300 parts by weight Kiwi berrys, 200-300 weights
Measure part Wood leftover, 100-200 parts by weight cogongrass, 100-200 parts by weight Chinese pennisetum, the ammonium of 30-50 parts by weight of phosphoric acid one, 20-
30 parts by weight potassium chloride, 200-300 parts by weight Chinese medicine dreg, 200-300 parts by weight fermenting plants powder, 50-80 parts by weight of urea,
60-100 parts by weight of formaldehyde, 10-16 weight parts of quicklime, 3-7 parts by weight dicetyl peroxydicarbonates diisobutyl ester, 5-9 parts by weight acid
Property catalyst, 2-4 parts by weight indolebutyric acid, 2-4 parts by weight thiocarbamide, 2-4 parts by weight triacontanol, 1-3 parts by weight zinc chloride, 8-
10 parts by weight Magnesium Borate Ore Powders are made.
2. charcoal base bioorganic compound fertilizer according to claim 1, it is characterised in that cut by 250 parts by weight Kiwi berrys
Branch, 250 parts by weight Wood leftovers, 150 parts by weight cogongrass, 150 parts by weight Chinese pennisetums, the ammonium of 40 parts by weight of phosphoric acid one, 25 weight
Part potassium sulfate, 250 parts by weight Chinese medicine dregs, 250 parts by weight fermenting plant powder, 65 parts by weight of urea, 80 parts by weight of formaldehyde, 14 weights
Measure part quick lime, 5 parts by weight dicetyl peroxydicarbonate diisobutyl esters, 7 parts by weight acidic catalysts, 3 parts by weight indolebutyric acids, 3 weights
Amount part thiocarbamide, 3 parts by weight triacontanols, 2 parts by weight zinc chloride, 9 parts by weight Magnesium Borate Ore Powders are made.
3. a kind of preparation method of charcoal base bioorganic compound fertilizer, it is characterised in that comprise the following steps：
(1) Kiwi berry beta pruning, Wood leftover, cogongrass, Chinese pennisetum, Chinese medicine dreg are put into isolation air in retort to be heated to
450-500 DEG C of charing, it is standby to obtain charcoal matrix；
(2) quick lime and water are added in reactive tank, it is 100- to add urea and formaldehyde, setting speed of agitator after quick lime dissolving
200r/min, 30-60min is reacted, obtains ureaformaldehyde reaction solution；
(3) by charcoal matrix, fermenting plant powder, MAP, potassium chloride, indolebutyric acid, thiocarbamide, triacontanol, zinc chloride, boron magnesium
Stone flour, acidic catalyst, dicetyl peroxydicarbonate diisobutyl ester are put into reaction tank, uniformly spray ureaformaldehyde reaction solution, and mixing is equal
After even, composite fertilizer's slurry is granulated with being pumped into spray granulation drier, dries, obtains charcoal base bioorganic compound fertilizer.
4. the preparation method of charcoal base bioorganic compound fertilizer according to claim 3, it is characterised in that including following step
Suddenly：
(1) Kiwi berry beta pruning, Wood leftover, cogongrass, Chinese pennisetum, Chinese medicine dreg are put into isolation air in retort to be heated to
475 DEG C of charings, it is standby to obtain charcoal matrix；
(2) quick lime and water are added in reactive tank, urea and formaldehyde are added after quick lime dissolving, setting speed of agitator is
150r/min, 45min is reacted, obtains ureaformaldehyde reaction solution；
(3) by charcoal matrix, fermenting plant powder, MAP, potassium chloride, indolebutyric acid, thiocarbamide, triacontanol, zinc chloride, boron magnesium
Stone flour, acidic catalyst, dicetyl peroxydicarbonate diisobutyl ester are put into reaction tank, uniformly spray ureaformaldehyde reaction solution, and mixing is equal
After even, composite fertilizer's slurry is granulated with being pumped into spray granulation drier, dries, obtains charcoal base bioorganic compound fertilizer.
5. the preparation method of the charcoal base bioorganic compound fertilizer according to claim 3 or 4, it is characterised in that described
The mass ratio of charcoal matrix and water is 1:10-13.
6. the preparation method of the charcoal base bioorganic compound fertilizer according to claim 3 or 4, it is characterised in that described
Chinese medicine dreg is lost by 20-30 parts by weight PERICARPIUM TRICHOSANTHIS, 40-50 parts by weight sargentodoxa cuneata, 10-20 parts by weight Semen Cuscutae, 10-20 parts by weight
Sauce grass is mixed.
7. the preparation method of charcoal base bioorganic compound fertilizer according to claim 6, it is characterised in that described Chinese medicine
The dregs of a decoction are mixed by 25 parts by weight PERICARPIUM TRICHOSANTHISs, 45 parts by weight sargentodoxa cuneata, 15 parts by weight Semen Cuscutaes, 15 parts by weight field pennycress.
8. the preparation method of the charcoal base bioorganic compound fertilizer according to claim 3 or 4, it is characterised in that described
Fermenting plant powder is：20-30 parts by weight motherwort, 50-60 parts by weight mugwort wormwood artemisias are cut into 2-4cm length, are put into fermentation vat, pond
In be put into the maceration extract stack retting for being inoculated with cellulolytic enzyme, maceration extract submergence, every agitation in 4 days once, after 30~40 days,
Motherwort, wild artemisia argyi plant clear, and dry, and crush, and obtain fermenting plant powder.
9. the preparation method of the charcoal base bioorganic compound fertilizer according to claim 3 or 4, it is characterised in that described
Acidic catalyst is mixed by 1-3 parts by weight of phosphoric acid and 5-7 parts by weight niobium pentaoxides.
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