CN104844373A - Water-soluble compound fertilizer and preparation method thereof - Google Patents
Water-soluble compound fertilizer and preparation method thereof Download PDFInfo
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- CN104844373A CN104844373A CN201510266741.9A CN201510266741A CN104844373A CN 104844373 A CN104844373 A CN 104844373A CN 201510266741 A CN201510266741 A CN 201510266741A CN 104844373 A CN104844373 A CN 104844373A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 43
- 150000001875 compounds Chemical class 0.000 title claims abstract description 42
- 239000003337 fertilizer Substances 0.000 title claims abstract description 40
- 239000007788 liquid Substances 0.000 claims abstract description 57
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 53
- -1 rare earth amino acid Chemical class 0.000 claims abstract description 47
- 150000001413 amino acids Chemical class 0.000 claims abstract description 43
- 239000002699 waste material Substances 0.000 claims abstract description 39
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 28
- 238000000855 fermentation Methods 0.000 claims abstract description 26
- 230000004151 fermentation Effects 0.000 claims abstract description 26
- 239000000706 filtrate Substances 0.000 claims abstract description 22
- 210000003608 fece Anatomy 0.000 claims abstract description 18
- 241000894006 Bacteria Species 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 17
- 239000004021 humic acid Substances 0.000 claims abstract description 14
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004202 carbamide Substances 0.000 claims abstract description 13
- 239000010902 straw Substances 0.000 claims abstract description 13
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000047 product Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 235000001014 amino acid Nutrition 0.000 claims description 74
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 239000010794 food waste Substances 0.000 claims description 26
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 22
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 20
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 13
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 13
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 12
- 240000002900 Arthrospira platensis Species 0.000 claims description 11
- 235000016425 Arthrospira platensis Nutrition 0.000 claims description 11
- 229910052873 allanite Inorganic materials 0.000 claims description 11
- 239000010985 leather Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 235000013379 molasses Nutrition 0.000 claims description 11
- 229940082787 spirulina Drugs 0.000 claims description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- 235000021120 animal protein Nutrition 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 10
- 238000000227 grinding Methods 0.000 claims description 10
- 239000001117 sulphuric acid Substances 0.000 claims description 10
- 235000011149 sulphuric acid Nutrition 0.000 claims description 10
- 239000006200 vaporizer Substances 0.000 claims description 10
- 229910021536 Zeolite Inorganic materials 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 239000010457 zeolite Substances 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 6
- 239000002367 phosphate rock Substances 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- 239000002689 soil Substances 0.000 abstract description 12
- 235000015097 nutrients Nutrition 0.000 abstract description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 3
- 239000011707 mineral Substances 0.000 abstract description 3
- 230000003750 conditioning effect Effects 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 58
- 241000196324 Embryophyta Species 0.000 description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 7
- 239000011573 trace mineral Substances 0.000 description 7
- 235000013619 trace mineral Nutrition 0.000 description 7
- 239000011701 zinc Substances 0.000 description 7
- 229910052725 zinc Inorganic materials 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 230000012010 growth Effects 0.000 description 5
- 239000010871 livestock manure Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 235000001465 calcium Nutrition 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 235000018102 proteins Nutrition 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- 235000017060 Arachis glabrata Nutrition 0.000 description 3
- 244000105624 Arachis hypogaea Species 0.000 description 3
- 235000010777 Arachis hypogaea Nutrition 0.000 description 3
- 235000018262 Arachis monticola Nutrition 0.000 description 3
- 241000193830 Bacillus <bacterium> Species 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- 108010082495 Dietary Plant Proteins Proteins 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 235000011430 Malus pumila Nutrition 0.000 description 3
- 235000015103 Malus silvestris Nutrition 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 240000008042 Zea mays Species 0.000 description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 3
- 235000005822 corn Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 235000020232 peanut Nutrition 0.000 description 3
- 150000003839 salts Chemical group 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 102000003846 Carbonic anhydrases Human genes 0.000 description 2
- 108090000209 Carbonic anhydrases Proteins 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- 102000012286 Chitinases Human genes 0.000 description 2
- 108010022172 Chitinases Proteins 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 244000017020 Ipomoea batatas Species 0.000 description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 244000000231 Sesamum indicum Species 0.000 description 2
- 235000003434 Sesamum indicum Nutrition 0.000 description 2
- 244000300264 Spinacia oleracea Species 0.000 description 2
- 235000009337 Spinacia oleracea Nutrition 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 244000098338 Triticum aestivum Species 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 235000011089 carbon dioxide Nutrition 0.000 description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 235000019691 monocalcium phosphate Nutrition 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000000050 nutritive effect Effects 0.000 description 2
- 239000003895 organic fertilizer Substances 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 229960004838 phosphoric acid Drugs 0.000 description 2
- 235000014786 phosphorus Nutrition 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 150000003722 vitamin derivatives Chemical class 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- 108010013043 Acetylesterase Proteins 0.000 description 1
- 108091005508 Acid proteases Proteins 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 101710121765 Endo-1,4-beta-xylanase Proteins 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
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- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 241000607598 Vibrio Species 0.000 description 1
- 206010047400 Vibrio infections Diseases 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 241000385540 bacterium 10 Species 0.000 description 1
- 241001609931 bacterium 20 Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 229910001748 carbonate mineral Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 150000004697 chelate complex Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 210000003763 chloroplast Anatomy 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
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- 238000005538 encapsulation Methods 0.000 description 1
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- 244000053095 fungal pathogen Species 0.000 description 1
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- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 229940116315 oxalic acid Drugs 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002686 phosphate fertilizer Substances 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 230000010496 root system development Effects 0.000 description 1
- 230000007226 seed germination Effects 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000004158 soil respiration Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
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- 241000701447 unidentified baculovirus Species 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a water-soluble compound fertilizer. The water-soluble compound fertilizer comprises the following materials in parts by weight: 40-60 parts of ultrafine mineral powder, 30-50 parts of agricultural product waste liquid, 35-50 parts of cow dung, 20-35 parts of plant straw, 10-20 parts of compound biological bacteria, 10-15 parts of humic acid, 20-40 parts of urea, 30-50 parts of metal ion amino acid complex concentrated solution and 30-50 parts of rare earth amino acid complex concentrated solution. A preparation method of the water-soluble compound fertilizer comprises the following steps: mixing the rare earth amino acid complex concentrated solution, the metal ion amino acid complex concentrated solution, the ultrafine mineral powder and fermentation filtrate in the parts by weight, sufficiently stirring for 15 minutes, adjusting the pH to be 8-9, adding the agricultural product waste liquid and the compound biological bacteria in the parts by weight under the conditions of normal pressure and temperature, sufficiently stirring for 1 hour, and thus obtaining the finished product. The water-soluble compound fertilizer has the advantages of being safer in nutrients, quick in fertilizer efficiency and long in fertilizer efficiency period and capable of effectively conditioning and improving the soil texture.
Description
Technical field
The present invention relates to fertilizer field, be specifically related to a kind of Water Soluble Compound fertilizer and preparation method thereof.
Background technology
Rational Application phosphate fertilizer can increase the output of farm crop, improve the quality of crop, accelerate cereal crop and tiller and promote full seed, impel cotton, the yielding positive results of melon, solanaceous vegetables and fruit tree, improve fruiting rate, increase beet, sugarcane, the sugar of watermelon and the oleaginousness of Semen Brassicae campestris.Wherein calcium superphosphate uses more as base manure in peasant household, but calcium superphosphate nutrient is more single, the needs of crop growth initial stage nutrient can not be met, and life-time service chemical fertilizer makes soil easily hardening, the organic composition in farmland reduces, crop growth lacks organic fertilizer efficiency and poor growth, but directly uses in organic fertilizer to farmland and be easy to make farm crop produce the problems such as soil-borne disease insect pest.
Rare earth element can improve the chlorophyll content of plant, strengthens photosynthesis, promotes root system development, increases root system to nutrition absorption.Rare earth can also promote seed germination, improves rate of emergence, promotes growth of seedling.Except above Main Function, also have and make some crop strengthen ability that is disease-resistant, cold-resistant, drought resisting.But rare-earth salts can not directly be absorbed by plants, therefore the specific absorption of plant to rare-earth salts is lower.The trace element of inorganic salt form, its utilization ratio is subject to the impact of pH value, fiber, oxalic acid, VITAMIN, phosphoric acid and phytic acid etc., and the trace element of aminoacid chelate is due to its stable chemical performance, intramolecular charge is tending towards neutral, can effectively prevent trace element ion from forming undissolved compound, or prevent from it to be attracted to hindering on the insoluble solution colloid of element absorption, be thus conducive to plant absorption.Large quantity research shows, the absorption of trace elements rate through chelating amino acids is 2-6 times of inorganic microelement.Simultaneously chelating element effectively can avoid adding in feed the poisoning and wasting phenomenon that too much inorganic elements brings, and when body requirement, it can discharge effectively, to meet body requirement.Meanwhile, amino-acid chelate be a kind of salt of access expansion circle form exist, under body environment condition, solvability is good, by peptide or amino acid whose absorption features, and need not first can combine with other materials, thus it faster than inorganic absorption about 30%.
Orthite is a kind of zoisite race mineral containing higher rare earth component.Wherein cerium can up to 11%, and in addition often containing yttrium, thorium, lanthanum etc., beryllium can reach 3.8%, being mixed into of magnesium, manganese etc.
Smithsonite is carbonate mineral calcite race smithsonite, main containing zinc carbonate, the metal activation agent of zinc mainly as enzyme in plant materials.The zinc-containing metal enzyme found the earliest is carbonic anhydrase, and this enzyme is very wide at plant distribution in vivo, is mainly present in chloroplast(id).The hydration of its catalysis carbonic acid gas, in promotion photosynthesis, carbonic acid gas is fixing, and scarce zinc makes the activity of carbonic anhydrase reduce.Therefore, the formation of zinc to carbohydrate is important.
Fertilising idea is in the past that nutrient is transported to crop whole body from root, and such effect is very slow to crop root fertilising; Crop whole body directly can absorb nutrient in fact, and Liquid Fertilizer make use of this point just, sprays crop whole body, and Crop is fast, more fresh and tender good to eat.
China is large agricultural country, and adequately and reasonably water soluble fertilizer is to the effect of farm crop, and exploitation is safe, efficient, the fertilizer of environmental protection, is significant.
Summary of the invention
For the problems referred to above, the object of this invention is to provide one and be rich in Rare-earth Aminoacid Complexes, safety, efficient water-soluble organic composite fertilizer, this fertilizer is applicable to foliage-spray, soak seed, dip in root, injection is used, drench and execute, water and execute, spray and the various mode such as to execute, drip irrigation is executed and use, apply fertilizer very even, working concentration is convenient to be regulated, to crop use safety in seedling stage, burning seedling can not be caused.Another object of the present invention is to provide a kind of preparation method of water-soluble organic type compound manure, and this water-soluble organic type compound manure nutrient is safer, fertilizer efficiency is fast, fertilizer efficiency period is long, effectively the quality of conditioning and improvement soil.
Technical scheme provided by the invention is: a kind of Water Soluble Compound fertilizer, comprises the following material with parts by weight: superfine ore powder 40-60 part, agricultural-food waste liquid 30-50 part, cow dung 35-50 part, straw 20-35 part, compound biological bacterium 10-20 part, humic acid 10-15 part, zeolite 8-12 part, urea 20-40 part, metal ion amino acid complex concentrated solution 30-50 part and Rare-earth Aminoacid Complexes concentrated solution 30-50 part.
Preferably, described Rare-earth Aminoacid Complexes concentrated solution comprises the following material with parts by weight: leather waste 30-50 part, orthite 30-50 part, concentration are sulphuric acid soln 100 parts, perchloric acid 40-60 part of 40%.
Preferably, described metal ion amino acid complex concentrated solution comprises the following material with parts by weight: dregs of beans 30-50 part, concentration are hydrochloric acid soln 50-100 part, 30-50 part of 40%.
Preferably, described agricultural-food waste liquid comprises the following material with parts by weight: cane molasses fermented liquid 70-90 part, methane waste liquor 30-50 part, spirulina waste liquid 20-40 part.
A kind of preparation method preparing above-mentioned Water Soluble Compound fertilizer, comprise the following steps: described Rare-earth Aminoacid Complexes concentrated solution, metal ion amino acid complex concentrated solution, superfine ore powder and ferment filtrate are mixed by above-mentioned weight part, abundant stirring 15 minutes, regulate pH to 8-9, agricultural-food waste liquid and compound biological bacterium is added by above-mentioned weight part under normal temperature and pressure conditions, abundant stirring 1 hour, gets product.
Preferably, the preparation method of described Rare-earth Aminoacid Complexes concentrated solution comprises the following steps:
It is 200 orders that the leather waste of above-mentioned weight part is crushed to fineness, places it in autoclave, and the concentration adding above-mentioned weight part is the sulphuric acid soln of 40%, be 110-125 DEG C in temperature, pressure is the Water Under solution 8 hours of 20MP, after filtering animal protein factor digest, for subsequent use;
At normal temperatures the orthite powder of above-mentioned weight part is dissolved in the 40-60 part perchloric acid with parts by weight, reacts 1 hour under 100 DEG C of conditions, filter out the impurity in solution, obtain rare earth ion settled solution;
Gained rare earth ion clear liquor is mixed with above-mentioned animal protein factor digest, stir along a direction, react 1 hour under 90 DEG C of conditions, obtain Rare-earth Aminoacid Complexes solution, being shifted bleeds in vaporizer is concentrated into 1/4 of original volume, obtains described Rare-earth Aminoacid Complexes concentrated solution.
Preferably, the preparation method of described metal ion amino acid complex concentrated solution has following steps: the bean cake powder of above-mentioned weight part being broken to fineness is 200 orders, throw in the hydrochloric acid soln of above-mentioned weight part, boil the smithsonite adding above-mentioned weight part to boiling, 1 hour is stirred along a direction, obtain metal ion amino acid complex after filtering, being transferred in vaporizer bleeds is concentrated into 1/4 of original volume, obtains metal ion amino acid complex concentrated solution.
Preferably, the preparation method of described ferment filtrate has following steps: the straw of above-mentioned weight part being crushed to length is 3-6cm, mix with cow dung, humic acid, ultraviolet lamps irradiates is adopted to be placed in fermentation vat in 6 hours, the urea of above-mentioned weight part is added again in fermentation vat, before fermentation, pH is 6-7, temperature is 60-65 DEG C, after starting fermentation, turning in every 24 hours once, control water content and remain on 60%, stop fermentation when there is no stool odor completely to material, adopt plate-and-frame filter press by tunning solid-liquid separation, obtain described ferment filtrate.
Preferably, the preparation method of described superfine ore powder has following steps: by Rock Phosphate (72Min BPL) and zeolite by 2: 1 weight ratio mix, being positioned in ball mill and being crushed to fineness is 100-200 order, to pour in ultra-fine micropowder grinding machine fine grinding again into 1 time, obtain superfine ore powder, its fineness is 2000-2500 order.
Preferably, also comprise the preparation of described agricultural-food waste liquid: with cane molasses fermented liquid 70 parts by weight, methane waste liquor 30 parts, the ratio mixing that spirulina waste liquid is 30 parts, be used in 100 DEG C and boil 1 hour, regulate pH to be between 7-8, filter after naturally cooling, remove the gred, filtrate is agricultural-food waste liquid.
Beneficial effect of the present invention is as follows:
(1), this Water Soluble Compound fertilizer contains metal ion amino acid complex and Rare-earth Aminoacid Complexes, can keep the slow releasing of rare earth element and metal ion and make full use of, and also can ensure the steady effect of trace element and long-acting;
(2), the preparation of Rare-earth Aminoacid Complexes that adopts of the present invention have employed leather waste as amino acid source, economizes on resources, and easily collects, be applicable to scale operation.
(3), the preparation of the metal ion amino acid complex of the present invention's employing adopts dregs of beans as amino acid source, it is a kind of good vegetable protein resource that dregs of beans rich in proteins has very high nutritive value, its protein overwhelming majority is sphaeroprotein, and aminoacids content is more stable.
(4), the preparation of the agricultural-food waste liquid of the present invention's employing have employed cane molasses fermented liquid, methane waste liquor and spirulina waste liquid three kinds of waste materials, these three kinds of waste materials contain balanced nitrogen, phosphorus, calcium, sodium, trace element and VITAMIN, but due in these waste liquids containing a large amount of harmful bacteria, so need high-temperature sterilization, and pH is adjusted to alkalescence, the existence of anti-bacteria.
(5), superfine ore powder adopt Rock Phosphate (72Min BPL) and zeolite in 2: 1 ratio mix, make the weight ratio of wherein each element be: phosphorus: iron: magnesium: calcium: potassium=10: 2: 4: 4: 3, through field experiment confirmation, now favourable to crop growth.And the ore of superfine fineness is more easily dissolved in soil and solution, farm crop are utilized to absorb.
(6), the starting material of ferment filtrate adopt straw, cow dung and humic acid, the resource of burned waste originally be make use of fully, on the bacterium can killed in straw and cow dung after uviolizing, avoid C element and the unnecessary consumption of N element, fertilizer is also more clean simultaneously, undergoes no deterioration.The chemical reaction utilizing humic acids and urea to occur in encapsulation process and physical adsorption, delay urea decomposition, reduce volatilization, discharge nitrogen gradually, fertilizer efficiency is extended, and utilizes humic acids and medium trace element: sulphur, zinc, calcium, magnesium, silicon improve fertilizer nutrient utilization, reduce soil salt content, improve soil, keep soil from packing together, improve crop quality and output to reach, strengthen the object of crop disease-resistant ability.
Biological compound fungi in this Water Soluble Compound fertilizer comprises genus bacillus, photosynthetic bacteria, milk-acid bacteria etc., and genus bacillus has very strong restraining effect to harmful microorganisms such as the vibrios in aquatic products, intestinal bacteria and baculoviruss.The a large amount of chitinase of secreted from bacillus, the cell walls of chitinase decomposable asymmetric choice net pathogenic fungi and Antifungi disease, the hazardous and noxious substances in water of decomposition, purifies water;
The pH of this Water Soluble Compound fertilizer is 8-9, is applicable to alkaline soil, and can improve soil property; The ratio of rare earth elements of the present invention and metallic element is through the optimum proportion that field experiment obtains, wheat increase yield 17.5%, corn yield increasing 18.3%, peanut yield increasing 27.2%, apple can be made to increase production 14.8%, Yield Increase In Cotton 21.32%, spinach volume increase 25.4%, sweet potato production increasing 18.2%, soybean yield-increasing 16.9%, sesame volume increase 12.4%.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, can implement according to this with reference to specification sheets word to make those skilled in the art.
Embodiment 1:
A kind of Water Soluble Compound fertilizer, comprises the following material with parts by weight: superfine ore powder 40 parts, agricultural-food waste liquid 30 parts, cow dung 35 parts, straw 20 parts, compound biological bacterium 10 parts, humic acid 10 parts, 20 parts, urea, metal ion amino acid complex concentrated solution 30 parts and Rare-earth Aminoacid Complexes concentrated solution 30 parts.
Wherein, described Rare-earth Aminoacid Complexes concentrated solution comprises the following material with parts by weight: leather waste 30 parts, orthite 30 parts, concentration are sulphuric acid soln 100 parts, 40 parts, the perchloric acid of 40%.
Wherein, described metal ion amino acid complex concentrated solution comprises the following material with parts by weight: dregs of beans 30 parts, concentration are hydrochloric acid soln 50 parts, 30 parts, the smithsonite of 40%.
Wherein, described agricultural-food waste liquid comprises the following material with parts by weight: cane molasses fermented liquid 70 parts, methane waste liquor 30 parts, spirulina waste liquid 20 parts.
A kind of preparation method preparing above-mentioned Water Soluble Compound fertilizer, comprise the following steps: described Rare-earth Aminoacid Complexes concentrated solution, metal ion amino acid complex concentrated solution, superfine ore powder and ferment filtrate are mixed by above-mentioned weight part, abundant stirring 15 minutes, regulate pH to 8, agricultural-food waste liquid and compound biological bacterium is added by above-mentioned weight part under normal temperature and pressure conditions, abundant stirring 1 hour, gets product.
Wherein, the preparation method of described Rare-earth Aminoacid Complexes concentrated solution comprises the following steps:
It is 200 orders that the leather waste of above-mentioned weight part is crushed to fineness, places it in autoclave, and the concentration adding above-mentioned weight part is the sulphuric acid soln of 40%, it is 110 DEG C in temperature, pressure is the Water Under solution 8 hours of 20MP, after filtering animal protein factor digest, for subsequent use;
At normal temperatures the orthite powder of above-mentioned weight part is dissolved in in 40 of parts by weight parts of perchloric acid, reacts 1 hour under 100 DEG C of conditions, filter out the impurity in solution, obtain rare earth ion settled solution;
Gained rare earth ion clear liquor is mixed with above-mentioned animal protein factor digest, stir along a direction, react 1 hour under 90 DEG C of conditions, obtain Rare-earth Aminoacid Complexes solution, being shifted bleeds in vaporizer is concentrated into 1/4 of original volume, obtains described Rare-earth Aminoacid Complexes concentrated solution.
Wherein, the preparation method of described metal ion amino acid complex concentrated solution has following steps: the bean cake powder of above-mentioned weight part being broken to fineness is 200 orders, throw in the hydrochloric acid soln of above-mentioned weight part, boil the smithsonite adding above-mentioned weight part to boiling, 1 hour is stirred along a direction, obtain metal ion amino acid complex after filtering, being transferred in vaporizer bleeds is concentrated into 1/4 of original volume, obtains metal ion amino acid complex concentrated solution.
Wherein, the preparation method of described ferment filtrate has following steps: the straw of above-mentioned weight part being crushed to length is 3-6cm, mix with cow dung, humic acid, ultraviolet lamps irradiates is adopted to be placed in fermentation vat in 6 hours, the urea of above-mentioned weight part is added again in fermentation vat, before fermentation, pH is 6, temperature is 60 DEG C, after starting fermentation, turning in every 24 hours once, control water content and remain on 60%, stop fermentation when there is no stool odor completely to material, adopt plate-and-frame filter press by tunning solid-liquid separation, obtain described ferment filtrate.
Wherein, the preparation method of described superfine ore powder has following steps: by Rock Phosphate (72Min BPL) and zeolite by 2: 1 weight ratio mix, being positioned in ball mill and being crushed to fineness is 100 orders, then to pour in ultra-fine micropowder grinding machine fine grinding into 1 time, obtain superfine ore powder, its fineness is 2000 orders.
Wherein, also comprise the preparation of described agricultural-food waste liquid: with cane molasses fermented liquid 70 parts by weight, methane waste liquor 30 parts, the ratio mixing that spirulina waste liquid is 30 parts, be used in 100 DEG C and boil 1 hour, regulate pH to be between 7, filter after naturally cooling, remove the gred, filtrate is agricultural-food waste liquid.
Embodiment 2
A kind of Water Soluble Compound fertilizer, comprises the following material with parts by weight: superfine ore powder 60 parts, agricultural-food waste liquid 50 parts, cow dung 50 parts, straw 35 parts, compound biological bacterium 20 parts, humic acid 15 parts, 40 parts, urea, metal ion amino acid complex concentrated solution 50 parts and Rare-earth Aminoacid Complexes concentrated solution 50 parts.
Wherein, described Rare-earth Aminoacid Complexes concentrated solution comprises the following material with parts by weight: leather waste 50 parts, orthite 50 parts, concentration are sulphuric acid soln 100 parts, 60 parts, the perchloric acid of 40%.
Wherein, described metal ion amino acid complex concentrated solution comprises the following material with parts by weight: dregs of beans 50 parts, concentration are hydrochloric acid soln 100 parts, 50 parts, the smithsonite of 40%.
Wherein, described agricultural-food waste liquid comprises the following material with parts by weight: cane molasses fermented liquid 90 parts, methane waste liquor 50 parts, spirulina waste liquid 40 parts.
A kind of preparation method preparing above-mentioned Water Soluble Compound fertilizer, comprise the following steps: described Rare-earth Aminoacid Complexes concentrated solution, metal ion amino acid complex concentrated solution, superfine ore powder and ferment filtrate are mixed by above-mentioned weight part, abundant stirring 15 minutes, regulate pH to 9, agricultural-food waste liquid and compound biological bacterium is added by above-mentioned weight part under normal temperature and pressure conditions, abundant stirring 1 hour, gets product.
Wherein, the preparation method of described Rare-earth Aminoacid Complexes concentrated solution comprises the following steps:
It is 200 orders that the leather waste of above-mentioned weight part is crushed to fineness, places it in autoclave, and the concentration adding above-mentioned weight part is the sulphuric acid soln of 40%, it is 125 DEG C in temperature, pressure is the Water Under solution 8 hours of 20MP, after filtering animal protein factor digest, for subsequent use;
At normal temperatures the orthite powder of above-mentioned weight part is dissolved in in 60 of parts by weight parts of perchloric acid, reacts 1 hour under 100 DEG C of conditions, filter out the impurity in solution, obtain rare earth ion settled solution;
Gained rare earth ion clear liquor is mixed with above-mentioned animal protein factor digest, stir along a direction, react 1 hour under 90 DEG C of conditions, obtain Rare-earth Aminoacid Complexes solution, being shifted bleeds in vaporizer is concentrated into 1/4 of original volume, obtains described Rare-earth Aminoacid Complexes concentrated solution.
Wherein, the preparation method of described metal ion amino acid complex concentrated solution has following steps: the bean cake powder of above-mentioned weight part being broken to fineness is 200 orders, throw in the hydrochloric acid soln of above-mentioned weight part, boil the smithsonite adding above-mentioned weight part to boiling, 1 hour is stirred along a direction, obtain metal ion amino acid complex after filtering, being transferred in vaporizer bleeds is concentrated into 1/4 of original volume, obtains metal ion amino acid complex concentrated solution.
Wherein, the preparation method of described ferment filtrate has following steps: the straw of above-mentioned weight part being crushed to length is 6cm, mix with cow dung, humic acid, ultraviolet lamps irradiates is adopted to be placed in fermentation vat in 6 hours, the urea of above-mentioned weight part is added again in fermentation vat, before fermentation, pH is 7, temperature is 65 DEG C, after starting fermentation, turning in every 24 hours once, control water content and remain on 60%, stop fermentation when there is no stool odor completely to material, adopt plate-and-frame filter press by tunning solid-liquid separation, obtain described ferment filtrate.
Wherein, the preparation method of described superfine ore powder has following steps: by Rock Phosphate (72Min BPL) and zeolite by 2: 1 weight ratio mix, being positioned in ball mill and being crushed to fineness is 200 orders, then to pour in ultra-fine micropowder grinding machine fine grinding into 1 time, obtain superfine ore powder, its fineness is 2500 orders.
Wherein, also comprise the preparation of described agricultural-food waste liquid: with cane molasses fermented liquid 70 parts by weight, methane waste liquor 30 parts, the ratio mixing that spirulina waste liquid is 30 parts, be used in 100 DEG C and boil 1 hour, regulate pH to be between 8, filter after naturally cooling, remove the gred, filtrate is agricultural-food waste liquid.
Embodiment 3
A kind of Water Soluble Compound fertilizer, comprises the following material with parts by weight: superfine ore powder 45 parts, agricultural-food waste liquid 40 parts, cow dung 40 parts, straw 25 parts, compound biological bacterium 15 parts, humic acid 15 parts, 30 parts, urea, metal ion amino acid complex concentrated solution 40 parts and Rare-earth Aminoacid Complexes concentrated solution 40 parts.The weight ratio of described rare earth element and metallic element is lanthanum: cerium: yttrium: iron: magnesium: calcium: manganese=10: 7: 5: 5: 6: 10: 3, under this weight ratio, this Water Soluble Compound fertilizer farthest can increase drought resisting, the cold tolerance of the plants such as corn, peanut, millet, apple, simultaneously the speed of growth of plant and the receptivity of root the strongest.
Wherein, described Rare-earth Aminoacid Complexes concentrated solution comprises the following material with parts by weight: leather waste 40 parts, orthite 40 parts, concentration are sulphuric acid soln 100 parts, 50 parts, the perchloric acid of 40%.Wherein, the ratio of weight and number of animal proteinum and zinc element is 1: 1.2, is through the optimal result of test of many times, and now the productive rate of amino acids metal ion chelate complex is maximum, and impurity is less.。
Wherein, described metal ion amino acid complex concentrated solution comprises the following material with parts by weight: dregs of beans 40 parts, concentration are hydrochloric acid soln 80 parts, 40 parts, the smithsonite of 40%.It is a kind of good vegetable protein resource that dregs of beans rich in proteins has very high nutritive value, and its protein overwhelming majority is sphaeroprotein, and aminoacids content is more stable.Wherein, the ratio of weight and number of vegetable-protein and zinc element is 1: 1.5.
Wherein, described agricultural-food waste liquid comprises the following material with parts by weight: cane molasses fermented liquid 80 parts, methane waste liquor 40 parts, spirulina waste liquid 30 parts.
A kind of preparation method preparing above-mentioned Water Soluble Compound fertilizer, comprise the following steps: described Rare-earth Aminoacid Complexes concentrated solution, metal ion amino acid complex concentrated solution, superfine ore powder and ferment filtrate are mixed by above-mentioned weight part, abundant stirring 15 minutes, regulate pH to 8.5, agricultural-food waste liquid and compound biological bacterium is added by above-mentioned weight part under normal temperature and pressure conditions, abundant stirring 1 hour, gets product.
Wherein, the preparation method of described Rare-earth Aminoacid Complexes concentrated solution comprises the following steps:
It is 200 orders that the leather waste of above-mentioned weight part is crushed to fineness, places it in autoclave, and the concentration adding above-mentioned weight part is the sulphuric acid soln of 40%, it is 115 DEG C in temperature, pressure is the Water Under solution 8 hours of 20MP, after filtering animal protein factor digest, for subsequent use;
At normal temperatures the orthite powder of above-mentioned weight part is dissolved in in 50 of parts by weight parts of perchloric acid, reacts 1 hour under 100 DEG C of conditions, filter out the impurity in solution, obtain rare earth ion settled solution;
Gained rare earth ion clear liquor is mixed with above-mentioned animal protein factor digest, stir along a direction, react 1 hour under 90 DEG C of conditions, obtain Rare-earth Aminoacid Complexes solution, being shifted bleeds in vaporizer is concentrated into 1/4 of original volume, obtains described Rare-earth Aminoacid Complexes concentrated solution.
Wherein, the preparation method of described metal ion amino acid complex concentrated solution has following steps: the bean cake powder of above-mentioned weight part being broken to fineness is 200 orders, throw in the hydrochloric acid soln of above-mentioned weight part, boil the smithsonite adding above-mentioned weight part to boiling, 1 hour is stirred along a direction, obtain metal ion amino acid complex after filtering, being transferred in vaporizer bleeds is concentrated into 1/4 of original volume, obtains metal ion amino acid complex concentrated solution.
Wherein, the preparation method of described ferment filtrate has following steps: the straw of above-mentioned weight part being crushed to length is 4cm, mix with cow dung, humic acid, ultraviolet lamps irradiates is adopted to be placed in fermentation vat in 6 hours, the urea of above-mentioned weight part is added again in fermentation vat, before fermentation, pH is 6.5, temperature is 63 DEG C, after starting fermentation, turning in every 24 hours once, control water content and remain on 60%, stop fermentation when there is no stool odor completely to material, adopt plate-and-frame filter press by tunning solid-liquid separation, obtain described ferment filtrate.
Wherein, the preparation method of described superfine ore powder has following steps: by Rock Phosphate (72Min BPL) and zeolite by 2: 1 weight ratio mix, being positioned in ball mill and being crushed to fineness is 150 orders, then to pour in ultra-fine micropowder grinding machine fine grinding into 1 time, obtain superfine ore powder, its fineness is 2200 orders.
Wherein, also comprise the preparation of described agricultural-food waste liquid: with cane molasses fermented liquid 70 parts by weight, methane waste liquor 30 parts, the ratio mixing that spirulina waste liquid is 30 parts, be used in 100 DEG C and boil 1 hour, regulate pH to be between 7.5, filter after naturally cooling, remove the gred, filtrate is agricultural-food waste liquid.
The test at clay fertilizer station, Beihai shows, after each farm crop use this aqueous solution compound manure,, wheat increase yield 17.5%, corn yield increasing 18.3%, peanut yield increasing 27.2%, apple volume increase 14.8%, Yield Increase In Cotton 21.32%, spinach volume increase 25.4%, sweet potato production increasing 18.2%, soybean yield-increasing 16.9%, sesame volume increase 12.4% can be made.
After this aqueous solution of soil application compound manure, microorganism active strengthens, and intensity of soil respiration improves 5-10 doubly than contrast after measured, and soil xylanase, Phosphoric acid esterase and protease activity improve 8%-30% respectively, 12%-34%, 18%-43%.In soil, the useful dimension biomass such as Ammonifying bacteria, vinelandii, cellulose-decomposing bacteria on average increases by 45%, reaches as high as 130%.
Although embodiment of the present invention are open as above, but it is not restricted to listed in specification sheets and embodiment utilization, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details and illustrates here and the legend described.
Claims (10)
1. a Water Soluble Compound fertilizer, it is characterized in that, comprise the following material with parts by weight: superfine ore powder 40-60 part, agricultural-food waste liquid 30-50 part, cow dung 35-50 part, straw 20-35 part, compound biological bacterium 10-20 part, humic acid 10-15 part, urea 20-40 part, metal ion amino acid complex concentrated solution 30-50 part and Rare-earth Aminoacid Complexes concentrated solution 30-50 part.
2. Water Soluble Compound fertilizer as claimed in claim 1, it is characterized in that, described Rare-earth Aminoacid Complexes concentrated solution comprises the following material with parts by weight: leather waste 30-50 part, orthite 30-50 part, concentration are sulphuric acid soln 100 parts, perchloric acid 40-60 part of 40%.
3. Water Soluble Compound fertilizer as claimed in claim 2, it is characterized in that, described metal ion amino acid complex concentrated solution comprises the following material with parts by weight: dregs of beans 30-50 part, concentration are hydrochloric acid soln 50-100 part, smithsonite 30-50 part of 40%.
4. Water Soluble Compound fertilizer as claimed in claim 3, it is characterized in that, described agricultural-food waste liquid comprises the following material with parts by weight: cane molasses fermented liquid 70-90 part, methane waste liquor 30-50 part, spirulina waste liquid 20-40 part.
5. the preparation method as the Water Soluble Compound fertilizer as described in arbitrary in claim 1-4, it is characterized in that, comprise the following steps: described Rare-earth Aminoacid Complexes concentrated solution, metal ion amino acid complex concentrated solution, superfine ore powder and ferment filtrate are mixed by above-mentioned weight part, abundant stirring 15 minutes, regulate pH to 8-9, under normal temperature and pressure conditions, add agricultural-food waste liquid and compound biological bacterium by above-mentioned weight part, fully stir 1 hour, get product.
6. preparation method as claimed in claim 5, it is characterized in that, the preparation method of described Rare-earth Aminoacid Complexes concentrated solution comprises the following steps:
It is 200 orders that the leather waste of above-mentioned weight part is crushed to fineness, places it in autoclave, and the concentration adding above-mentioned weight part is the sulphuric acid soln of 40%, be 110-125 DEG C in temperature, pressure is the Water Under solution 8 hours of 20MP, after filtering animal protein factor digest, for subsequent use;
At normal temperatures the orthite powder of above-mentioned weight part is dissolved in the 40-60 part perchloric acid with parts by weight, reacts 1 hour under 100 DEG C of conditions, filter out the impurity in solution, obtain rare earth ion settled solution;
Gained rare earth ion clear liquor is mixed with above-mentioned animal protein factor digest, stir along a direction, react 1 hour under 90 DEG C of conditions, obtain Rare-earth Aminoacid Complexes solution, being shifted bleeds in vaporizer is concentrated into 1/4 of original volume, obtains described Rare-earth Aminoacid Complexes concentrated solution.
7. preparation method as claimed in claim 6, it is characterized in that, the preparation method of described metal ion amino acid complex concentrated solution has following steps: the bean cake powder of above-mentioned weight part being broken to fineness is 200 orders, throw in the hydrochloric acid soln of above-mentioned weight part, boil the smithsonite adding above-mentioned weight part to boiling, 1 hour is stirred along a direction, obtain metal ion amino acid complex after filtering, being transferred in vaporizer bleeds is concentrated into 1/4 of original volume, obtains metal ion amino acid complex concentrated solution.
8. preparation method as claimed in claim 7, it is characterized in that, the preparation method of described ferment filtrate has following steps: the straw of above-mentioned weight part being crushed to length is 3-6cm, with cow dung, humic acid mixes, ultraviolet lamps irradiates is adopted to be placed in fermentation vat in 6 hours, the urea of above-mentioned weight part is added again in fermentation vat, before fermentation, pH is 6-7, temperature is 60-65 DEG C, after starting fermentation, turning in every 24 hours once, control water content and remain on 60%, fermentation is stopped when there is no stool odor completely to material, adopt plate-and-frame filter press by tunning solid-liquid separation, obtain described ferment filtrate.
9. preparation method as claimed in claim 8, it is characterized in that, the preparation method of described superfine ore powder has following steps: by Rock Phosphate (72Min BPL) and zeolite by 2: 1 weight ratio mix, being positioned in ball mill and being crushed to fineness is 100-200 order, to pour in ultra-fine micropowder grinding machine fine grinding again into 1 time, obtain superfine ore powder, its fineness is 2000-2500 order.
10. preparation method as claimed in claim 9, it is characterized in that, also comprise the preparation of described agricultural-food waste liquid: with cane molasses fermented liquid 70 parts by weight, methane waste liquor 30 parts, the ratio mixing that spirulina waste liquid is 30 parts, is used in 100 DEG C and boils 1 hour, regulate pH to be between 7-8, filter after naturally cooling, remove the gred, filtrate is agricultural-food waste liquid.
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