CN104844373B - A kind of Water Soluble Compound fertilizer and preparation method thereof - Google Patents
A kind of Water Soluble Compound fertilizer and preparation method thereof Download PDFInfo
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- CN104844373B CN104844373B CN201510266741.9A CN201510266741A CN104844373B CN 104844373 B CN104844373 B CN 104844373B CN 201510266741 A CN201510266741 A CN 201510266741A CN 104844373 B CN104844373 B CN 104844373B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 42
- 239000003337 fertilizer Substances 0.000 title claims abstract description 41
- 150000001875 compounds Chemical class 0.000 title claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 235000001014 amino acid Nutrition 0.000 claims abstract description 73
- 239000002699 waste material Substances 0.000 claims abstract description 61
- 239000007788 liquid Substances 0.000 claims abstract description 55
- 239000012141 concentrate Substances 0.000 claims abstract description 53
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 52
- -1 Rare-earth Aminoacid Chemical class 0.000 claims abstract description 47
- 150000001413 amino acids Chemical class 0.000 claims abstract description 38
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 36
- 239000000047 product Substances 0.000 claims abstract description 35
- 239000000843 powder Substances 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 27
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 24
- 239000011707 mineral Substances 0.000 claims abstract description 24
- 239000000706 filtrate Substances 0.000 claims abstract description 22
- 241000894006 Bacteria Species 0.000 claims abstract description 20
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 210000003608 fece Anatomy 0.000 claims abstract description 14
- 239000004021 humic acid Substances 0.000 claims abstract description 14
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004202 carbamide Substances 0.000 claims abstract description 13
- 239000010902 straw Substances 0.000 claims abstract description 13
- 238000000855 fermentation Methods 0.000 claims description 23
- 230000004151 fermentation Effects 0.000 claims description 23
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 20
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 20
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 13
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 13
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- 239000012530 fluid Substances 0.000 claims description 11
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- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 11
- 240000002900 Arthrospira platensis Species 0.000 claims description 10
- 235000016425 Arthrospira platensis Nutrition 0.000 claims description 10
- 238000000227 grinding Methods 0.000 claims description 10
- 229940082787 spirulina Drugs 0.000 claims description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 229910021536 Zeolite Inorganic materials 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 238000005086 pumping Methods 0.000 claims description 7
- 239000010457 zeolite Substances 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 6
- 239000002367 phosphate rock Substances 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
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- 235000015097 nutrients Nutrition 0.000 abstract description 7
- 230000003750 conditioning effect Effects 0.000 abstract description 2
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
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- 230000001965 increasing effect Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 4
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- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 235000001465 calcium Nutrition 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
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- 241000193830 Bacillus <bacterium> Species 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- 108010082495 Dietary Plant Proteins Proteins 0.000 description 3
- 235000011430 Malus pumila Nutrition 0.000 description 3
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- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
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- 238000002474 experimental method Methods 0.000 description 3
- 235000020232 peanut Nutrition 0.000 description 3
- 150000003839 salts Chemical group 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 2
- 102000012286 Chitinases Human genes 0.000 description 2
- 108010022172 Chitinases Proteins 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 244000017020 Ipomoea batatas Species 0.000 description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 244000000231 Sesamum indicum Species 0.000 description 2
- 235000003434 Sesamum indicum Nutrition 0.000 description 2
- 244000300264 Spinacia oleracea Species 0.000 description 2
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- 239000007864 aqueous solution Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 235000019691 monocalcium phosphate Nutrition 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000000050 nutritive effect Effects 0.000 description 2
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- 235000014786 phosphorus Nutrition 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 102000003846 Carbonic anhydrases Human genes 0.000 description 1
- 108090000209 Carbonic anhydrases Proteins 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 101710121765 Endo-1,4-beta-xylanase Proteins 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
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- 108010044091 Globulins Proteins 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
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- 102000035195 Peptidases Human genes 0.000 description 1
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- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
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- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
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- 241000607598 Vibrio Species 0.000 description 1
- 206010047400 Vibrio infections Diseases 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- 206010048259 Zinc deficiency Diseases 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
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- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 229910001748 carbonate mineral Inorganic materials 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000004697 chelate complex Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
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- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
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- 238000007598 dipping method Methods 0.000 description 1
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- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
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- 229910017053 inorganic salt Inorganic materials 0.000 description 1
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- 235000014655 lactic acid Nutrition 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- 244000005700 microbiome Species 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000015816 nutrient absorption Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002686 phosphate fertilizer Substances 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
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- 230000007096 poisonous effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 235000019833 protease Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000010496 root system development Effects 0.000 description 1
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- 239000010703 silicon Substances 0.000 description 1
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- 238000002791 soaking Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a kind of Water Soluble Compound fertilizer, including following material in parts by weight：30 50 parts of 40 60 parts of superfine mineral powder, 30 50 parts of agricultural product waste liquid, 35 50 parts of cow dung, 20 35 parts of straw, 10 20 parts of compound biological bacterium, 10 15 parts of humic acid, 20 40 parts of urea, 30 50 parts of metal ion amino acid complex concentrate and Rare-earth Aminoacid Complexes concentrate.The preparation method of above-mentioned Water Soluble Compound fertilizer, comprises the following steps：Described Rare-earth Aminoacid Complexes concentrate, metal ion amino acid complex concentrate, superfine mineral powder and ferment filtrate are mixed by above-mentioned parts by weight, it is sufficiently stirred for 15 minutes, adjust pH to 89, under normal temperature and pressure conditionses agricultural product waste liquid and compound biological bacterium are added by above-mentioned parts by weight, it is sufficiently stirred for 1 hour, gets product.This Water Soluble Compound fertilizer has that nutrient is safer, fertilizer efficiency fast, fertilizer efficiency period is long, effectively the advantage of conditioning and improved soil quality.
Description
Technical field
The present invention relates to fertilizer field, and in particular to a kind of Water Soluble Compound fertilizer and preparation method thereof.
Background technology
Rational Application phosphate fertilizer can increase the yield of crops, improve the quality of crop, accelerate cereal crops tiller and rush
Enter full seed, promote yielding positive results for cotton, melon, solanaceous vegetables and fruit tree, improve fruiting rate, increase beet, sugarcane,
The sugar of watermelon and the oil content of rapeseed.Wherein calcium superphosphate as base manure in peasant household using more, but calcium superphosphate
Nutrient is relatively simple, the need for can not meeting crop growth nutrient at initial stage, and chemical fertilizer, which is used for a long time, makes soil easily hardened
Change, the organic principle in farmland is reduced, crop growth lacks organic matter fertilizer efficiency and slow-growing, but it is fertile directly to apply organic matter
Expect and be easy to make the problems such as crops produce soil-borne disease insect pest in farmland.
Rare earth element can improve the chlorophyll content of plant, strengthen photosynthesis, promote root system development, increase root system pair
Nutrient Absorption.Rare earth can also promote seed to sprout, and improve percentage of seedgermination, promote growth of seedling.In addition to above main function,
Also having makes some crops strengthen disease-resistant, cold-resistant, the ability of drought resisting.But rare-earth salts can not be directly absorbed by plants, therefore
Plant is relatively low to the absorptivity of rare-earth salts.The trace element of inorganic salt form, its utilization rate is easily given birth to by pH value, fiber, oxalic acid, dimension
The influence of element, phosphoric acid and phytic acid etc., and the trace element of aminoacid chelate is due to its stable chemical performance, intramolecular electricity
Lotus tends to be neutral, can effectively prevent trace element ion from forming undissolved compound, or prevent it is attracted to from hindering element
On the insoluble colloid absorbed, thus be conducive to plant absorption.Numerous studies show, the absorption of trace elements through chelating amino acids
Rate is 2-6 times of inorganic microelement.Chelating element can be prevented effectively from simultaneously adds excessive inorganic elements institute band in feed
The poisoning come and wasting phenomenon, and it can effectively be discharged when body needs, to meet body needs.Meanwhile, amino
Sour chelate is that a kind of form of salt of access expansion circle is present, and dissolubility is good under the conditions of body environment, can be by peptide or ammonia
Base acid absorption features, without elder generation with other materials combine, thus it faster than inorganic absorption 30% or so.
Cerine is a kind of zoisite race mineral containing higher rare earth component.Wherein cerium may be up to 11%, additionally often contain
There are yttrium, thorium, lanthanum etc., beryllium is up to 3.8%, and magnesium, manganese etc. are mixed into.
Smithsonite is carbonate mineral calcite race smithsonite, main to contain zinc carbonate, zinc in plant primarily as
The metal activation agent of enzyme.The zinc-containing metal enzyme found earliest is carbonic anhydrase, and this enzyme is distributed very extensively in plant, mainly deposits
It is in chloroplaset.It is catalyzed the aquation of carbon dioxide, promotes the fixation of carbon dioxide in photosynthesis, and zinc-deficiency makes carbonic acid
The activity reduction of acid anhydride enzyme.Therefore, formation of the zinc to carbohydrate is important.
Fertilising idea in the past is to give crop root fertilising, and nutrient is transported to crop whole body from root, and such effect is very slow；
Crop whole body can directly absorb nutrient in fact, and Liquid Fertilizer exactly make use of this point, spray crop whole body, and crop absorbs
It hurry up, it is more fresh and tender tasty.
China is large agricultural country, adequately and reasonably effect of the water soluble fertilizer to crops, develops safe efficient, environmental protection
Fertilizer, be significant.
The content of the invention
In view of the above-mentioned problems, being rich in Rare-earth Aminoacid Complexes, safe and efficient water it is an object of the invention to provide one kind
Dissolubility organic composite fertilizer, the fertilizer is applied suitable for foliage-spray, seed soaking, root dipping, injection, drenches and apply, pour and apply, spray and apply, drip
Filling the various modes such as is applied and used, and applies fertilizer highly uniform, and concentration is convenient to be adjusted, and to seedling stage crop using safety, will not be caused
Burn seedlings.It is a further object to provide a kind of preparation method of water-soluble organic type compound fertilizer, this water solubility is organic
Type compound fertilizer nutrient is safer, fertilizer efficiency fast, fertilizer efficiency period is long, effectively the quality of conditioning and improved soil.
The technical scheme that the present invention is provided is：A kind of Water Soluble Compound fertilizer, including following material in parts by weight：It is super
Trickle mineral powder 40-60 parts, 30-50 parts of agricultural product waste liquid, 35-50 parts of cow dung, 20-35 parts of straw, compound biological bacterium
10-20 parts, 10-15 parts of humic acid, 8-12 parts of zeolite, 20-40 parts of urea, metal ion amino acid complex concentrate 30-50
30-50 parts of part and Rare-earth Aminoacid Complexes concentrate.
Preferably, the Rare-earth Aminoacid Complexes concentrate includes following material in parts by weight：Leather waste 30-
50 parts, 100 parts of sulfuric acid solution, 40-60 parts of the perchloric acid of 30-50 parts of cerine, concentration for 40%.
Preferably, the metal ion amino acid complex concentrate includes following material in parts by weight：Dregs of beans 30-
50 parts, 50-100 parts, 30-50 parts of the hydrochloric acid solution that concentration is 40%.
Preferably, the agricultural product waste liquid includes following material in parts by weight：Cane molasses zymotic fluid 70-90
Part, 30-50 parts of methane waste liquor, 20-40 parts of spirulina waste liquid.
A kind of preparation method for preparing above-mentioned Water Soluble Compound fertilizer, comprises the following steps：By described Rare Earth Amino-Acid
Complex compound concentrate, metal ion amino acid complex concentrate, superfine mineral powder and ferment filtrate are mixed by above-mentioned parts by weight
Close, be sufficiently stirred for 15 minutes, adjust pH to 8-9, under normal temperature and pressure conditionses by above-mentioned parts by weight add agricultural product waste liquid and
Compound biological bacterium, is sufficiently stirred for 1 hour, gets product.
Preferably, the preparation method of the Rare-earth Aminoacid Complexes concentrate comprises the following steps：
The leather waste of above-mentioned parts by weight is crushed to fineness for 200 mesh, placed it in autoclave, in addition
The concentration for stating parts by weight is 40% sulfuric acid solution, is 110-125 DEG C in temperature, and pressure is hydrolysis 8 hours under conditions of 20MP,
Animal protein factor digest is obtained after filtering, it is standby；
The cerine powder of above-mentioned parts by weight is dissolved at normal temperatures in 40-60 part perchloric acid in parts by weight, at 100 DEG C
Under the conditions of react 1 hour, filter out the impurity in solution, obtain rare earth ion settled solution；
Gained rare earth ion clarified solution is mixed with above-mentioned animal protein factor digest, stirred in one direction, in 90 DEG C of bars
Reacted 1 hour under part, obtain Rare-earth Aminoacid Complexes solution, shifted the pumping in evaporator and be concentrated into the 1/4 of original volume,
Obtain the Rare-earth Aminoacid Complexes concentrate.
Preferably, the preparation method of the metal ion amino acid complex concentrate has steps of：Will be above-mentioned heavy
The dregs of beans of amount part is crushed to fineness for 200 mesh, throws into the hydrochloric acid solution of above-mentioned parts by weight, boils to boiling and add above-mentioned weight
The smithsonite of part, stirs 1 hour, metal ion amino acid complex is obtained after filtering, is transferred in evaporator in one direction
Pumping is concentrated into the 1/4 of original volume, obtains metal ion amino acid complex concentrate.
Preferably, the preparation method of the ferment filtrate has steps of：The straw of above-mentioned parts by weight is crushed
It is 3-6cm to length, is well mixed with cow dung, humic acid, is placed in after being irradiated 6 hours using ultraviolet lamp in fermentation vat, then to
The urea of above-mentioned parts by weight is added in fermentation vat, pH is 6-7 before fermentation, temperature is 60-65 DEG C, is turned within every 24 hours after starting fermentation
Heap once, control water content be maintained at 60%, to material completely without stool odor when stop fermentation, using plate and frame filter press will
Tunning separation of solid and liquid, obtains the ferment filtrate.
Preferably, the preparation method of the superfine mineral powder has steps of：Rock phosphate in powder and zeolite are pressed 2: 1 weight
Amount is positioned in ball mill than well mixed and is crushed to fineness for 100-200 mesh, then pours into fine grinding 1 time in super fine grinding machine,
Superfine mineral powder is obtained, its fineness is 2000-2500 mesh.
Preferably, the preparation of the agricultural product waste liquid is included：With 70 parts of cane molasses zymotic fluid by weight,
30 parts of methane waste liquor, the ratio that 30 part of spirulina waste liquid mixing, is used in 100 DEG C and boils 1 hour, and regulation pH is between 7-8, from
Right cooled and filtered, slagging-off, filtrate is agricultural product waste liquid.
Beneficial effects of the present invention are as follows：
(1), this Water Soluble Compound fertilizer contains metal ion amino acid complex and Rare-earth Aminoacid Complexes, Ji Nengbao
Hold the slow release of rare earth element and metal ion and make full use of, also can guarantee that the steady effect and long-acting of trace element；
(2), the preparation for the Rare-earth Aminoacid Complexes that the present invention is used employs leather waste as amino acid source, saves
Resource, and easily collect, it is adapted to large-scale production.
(3), the preparation for the metal ion amino acid complex that the present invention is used is using dregs of beans as amino acid source, and dregs of beans is rich
Containing protein there is very high nutritive value to be a kind of good vegetable protein resource, its protein overwhelming majority is ball egg
In vain, amino acid content is more stable.
(4), the preparation for the agricultural product waste liquid that the present invention is used employs cane molasses zymotic fluid, methane waste liquor and spiral shell
Algae three kinds of waste materials of waste liquid are revolved, these three waste materials contain nitrogen, phosphorus, calcium, sodium, trace element and vitamin in a balanced way, but
Due to containing substantial amounts of harmful bacteria in these waste liquids, so needing high-temperature sterilization, and pH is adjusted to alkalescence, suppress bacterium
Existence.
(5), superfine mineral powder is mixed using rock phosphate in powder and zeolite in 2: 1 ratio, makes the weight ratio of wherein each element
For：Phosphorus: iron: magnesium: calcium: potassium=10: 2: 4: 4: 3, confirmed by field experiment, it is now the most favourable to crop growth.And it is super
The ore of trickle fineness is easier to be dissolved in soil and solution, is absorbed using crops.
(6), the raw material of ferment filtrate use straw, cow dung and humic acid, make the burned resource wasted originally
Sufficiently make use of, after being irradiated by ultraviolet can kill straw and cow dung in bacterium, it is to avoid C
Element and the unnecessary consumption of N element, while fertilizer is also more clean, undergo no deterioration.Wrapped up using humic acid and urea
The chemical reaction occurred in journey and physical absorption, delay urea to decompose, and reduce volatilization, gradually discharge nitrogen, extend fertilizer efficiency, and
Utilize humic acid and middle trace element：Sulphur, zinc, calcium, magnesium, silicon improve fertilizer nutrient utilization, reduction soil salt content, improvement
Soil, is kept soil from packing together, and crop quality and yield are improved to reach, strengthens the purpose of crop disease-resistant ability.
Biological compound fungi in this Water Soluble Compound fertilizer includes bacillus, photosynthetic bacteria, lactic acid bacteria etc., bacillus pair
The harmful microorganisms such as vibrios, Escherichia coli and baculoviral in aquatic products have very strong inhibitory action.Secreted from bacillus is a large amount of
Chitinase, the cell membrane of chitinase decomposable asymmetric choice net disease fungus and suppress fungal disease, the poisonous and harmful substance in decomposition water,
Purify water；
The pH of this Water Soluble Compound fertilizer is 8-9, it is adaptable to basic soil, and can improve soil property；It is dilute in the present invention
The ratio of earth elements and metallic element is the optimal proportion obtained by field experiment, can make wheat increase yield 17.5%, corn
Volume increase 18.3%, peanut yield increasing 27.2%, apple volume increase 14.8%, Yield Increase In Cotton 21.32%, spinach volume increase 25.4%, sweet potato
Volume increase 18.2%, soybean yield-increasing 16.9%, sesame volume increase 12.4%.
Embodiment
With reference to embodiment, the present invention is described in further detail, to make those skilled in the art with reference to specification
Word can be implemented according to this.
Embodiment 1：
A kind of Water Soluble Compound fertilizer, including following material in parts by weight：40 parts of superfine mineral powder, agricultural product give up
Abandon 30 parts of liquid, 35 parts of cow dung, 20 parts of straw, 10 parts of compound biological bacterium, 10 parts of humic acid, 20 parts of urea, metal ion ammonia
30 parts of 30 parts of base acid complex concentrate and Rare-earth Aminoacid Complexes concentrate.
Wherein, the Rare-earth Aminoacid Complexes concentrate includes following material in parts by weight：30 parts of leather waste,
100 parts of sulfuric acid solution, 40 parts of the perchloric acid of 30 parts of cerine, concentration for 40%.
Wherein, the metal ion amino acid complex concentrate includes following material in parts by weight：30 parts of dregs of beans,
Hydrochloric acid solution 50 part, smithsonite 30 part of the concentration for 40%.
Wherein, the agricultural product waste liquid includes following material in parts by weight：70 parts of cane molasses zymotic fluid, biogas
30 parts of waste liquid, 20 parts of spirulina waste liquid.
A kind of preparation method for preparing above-mentioned Water Soluble Compound fertilizer, comprises the following steps：By described Rare Earth Amino-Acid
Complex compound concentrate, metal ion amino acid complex concentrate, superfine mineral powder and ferment filtrate are mixed by above-mentioned parts by weight
Close, be sufficiently stirred for 15 minutes, adjust pH to 8, agricultural product waste liquid is added and multiple by above-mentioned parts by weight under normal temperature and pressure conditionses
Biological bacteria is closed, is sufficiently stirred for 1 hour, gets product.
Wherein, the preparation method of the Rare-earth Aminoacid Complexes concentrate comprises the following steps：
The leather waste of above-mentioned parts by weight is crushed to fineness for 200 mesh, placed it in autoclave, in addition
The concentration for stating parts by weight is 40% sulfuric acid solution, is 110 DEG C in temperature, pressure passes through to be hydrolyzed 8 hours under conditions of 20MP
Animal protein factor digest is obtained after filter, it is standby；
The cerine powder of above-mentioned parts by weight is dissolved at normal temperatures in 40 parts of perchloric acid in parts by weight, in 100 DEG C of bars
Reacted 1 hour under part, filter out the impurity in solution, obtain rare earth ion settled solution；
Gained rare earth ion clarified solution is mixed with above-mentioned animal protein factor digest, stirred in one direction, in 90 DEG C of bars
Reacted 1 hour under part, obtain Rare-earth Aminoacid Complexes solution, shifted the pumping in evaporator and be concentrated into the 1/4 of original volume,
Obtain the Rare-earth Aminoacid Complexes concentrate.
Wherein, the preparation method of the metal ion amino acid complex concentrate has steps of：By above-mentioned weight
The dregs of beans of part is crushed to fineness for 200 mesh, throws into the hydrochloric acid solution of above-mentioned parts by weight, boils to boiling and add above-mentioned parts by weight
Smithsonite, in one direction stir 1 hour, after filtering metal ion amino acid complex, be transferred in evaporator and take out
Gas is concentrated into the 1/4 of original volume, obtains metal ion amino acid complex concentrate.
Wherein, the preparation method of the ferment filtrate has steps of：The straw of above-mentioned parts by weight is crushed to
Length is 3-6cm, is well mixed with cow dung, humic acid, is placed in after being irradiated 6 hours using ultraviolet lamp in fermentation vat, then to hair
Add the urea of above-mentioned parts by weight in ferment pond, pH is 6 before fermentation, and temperature is 60 DEG C, start after fermentation every turning in 24 hours once,
Control water content be maintained at 60%, to material completely without stool odor when stop fermentation, using plate and frame filter press by ferment produce
Thing separation of solid and liquid, obtains the ferment filtrate.
Wherein, the preparation method of the superfine mineral powder has steps of：Rock phosphate in powder and zeolite are pressed 2: 1 weight
Than well mixed, it be positioned in ball mill and be crushed to fineness for 100 mesh, then pour into fine grinding 1 time in super fine grinding machine, is surpassed
Trickle mineral powder, its fineness is 2000 mesh.
Wherein, the preparation of the agricultural product waste liquid is included：With 70 parts of cane molasses zymotic fluid by weight, natural pond
30 parts of gas waste liquid, the ratio that 30 part of spirulina waste liquid mixing, is used in 100 DEG C and boils 1 hour, and regulation pH is between 7, naturally cold
But filter, remove the gred afterwards, filtrate is agricultural product waste liquid.
Embodiment 2
A kind of Water Soluble Compound fertilizer, including following material in parts by weight：60 parts of superfine mineral powder, agricultural product give up
Abandon 50 parts of liquid, 50 parts of cow dung, 35 parts of straw, 20 parts of compound biological bacterium, 15 parts of humic acid, 40 parts of urea, metal ion ammonia
50 parts of 50 parts of base acid complex concentrate and Rare-earth Aminoacid Complexes concentrate.
Wherein, the Rare-earth Aminoacid Complexes concentrate includes following material in parts by weight：50 parts of leather waste,
100 parts of sulfuric acid solution, 60 parts of the perchloric acid of 50 parts of cerine, concentration for 40%.
Wherein, the metal ion amino acid complex concentrate includes following material in parts by weight：50 parts of dregs of beans,
Hydrochloric acid solution 100 part, smithsonite 50 part of the concentration for 40%.
Wherein, the agricultural product waste liquid includes following material in parts by weight：90 parts of cane molasses zymotic fluid, biogas
50 parts of waste liquid, 40 parts of spirulina waste liquid.
A kind of preparation method for preparing above-mentioned Water Soluble Compound fertilizer, comprises the following steps：By described Rare Earth Amino-Acid
Complex compound concentrate, metal ion amino acid complex concentrate, superfine mineral powder and ferment filtrate are mixed by above-mentioned parts by weight
Close, be sufficiently stirred for 15 minutes, adjust pH to 9, agricultural product waste liquid is added and multiple by above-mentioned parts by weight under normal temperature and pressure conditionses
Biological bacteria is closed, is sufficiently stirred for 1 hour, gets product.
Wherein, the preparation method of the Rare-earth Aminoacid Complexes concentrate comprises the following steps：
The leather waste of above-mentioned parts by weight is crushed to fineness for 200 mesh, placed it in autoclave, in addition
The concentration for stating parts by weight is 40% sulfuric acid solution, is 125 DEG C in temperature, pressure passes through to be hydrolyzed 8 hours under conditions of 20MP
Animal protein factor digest is obtained after filter, it is standby；
The cerine powder of above-mentioned parts by weight is dissolved at normal temperatures in 60 parts of perchloric acid in parts by weight, in 100 DEG C of bars
Reacted 1 hour under part, filter out the impurity in solution, obtain rare earth ion settled solution；
Gained rare earth ion clarified solution is mixed with above-mentioned animal protein factor digest, stirred in one direction, in 90 DEG C of bars
Reacted 1 hour under part, obtain Rare-earth Aminoacid Complexes solution, shifted the pumping in evaporator and be concentrated into the 1/4 of original volume,
Obtain the Rare-earth Aminoacid Complexes concentrate.
Wherein, the preparation method of the metal ion amino acid complex concentrate has steps of：By above-mentioned weight
The dregs of beans of part is crushed to fineness for 200 mesh, throws into the hydrochloric acid solution of above-mentioned parts by weight, boils to boiling and add above-mentioned parts by weight
Smithsonite, in one direction stir 1 hour, after filtering metal ion amino acid complex, be transferred in evaporator and take out
Gas is concentrated into the 1/4 of original volume, obtains metal ion amino acid complex concentrate.
Wherein, the preparation method of the ferment filtrate has steps of：The straw of above-mentioned parts by weight is crushed to
Length is 6cm, is well mixed with cow dung, humic acid, is placed in after being irradiated 6 hours using ultraviolet lamp in fermentation vat, then to fermentation
The urea of above-mentioned parts by weight is added in pond, pH is 7 before fermenting, and temperature is 65 DEG C, start every turning in 24 hours after fermentation and once, control
Water content processed is maintained at 60%, to material completely without stool odor when stop fermentation, using plate and frame filter press by tunning
Separation of solid and liquid, obtains the ferment filtrate.
Wherein, the preparation method of the superfine mineral powder has steps of：Rock phosphate in powder and zeolite are pressed 2: 1 weight
Than well mixed, it be positioned in ball mill and be crushed to fineness for 200 mesh, then pour into fine grinding 1 time in super fine grinding machine, is surpassed
Trickle mineral powder, its fineness is 2500 mesh.
Wherein, the preparation of the agricultural product waste liquid is included：With 70 parts of cane molasses zymotic fluid by weight, natural pond
30 parts of gas waste liquid, the ratio that 30 part of spirulina waste liquid mixing, is used in 100 DEG C and boils 1 hour, and regulation pH is between 8, naturally cold
But filter, remove the gred afterwards, filtrate is agricultural product waste liquid.
Embodiment 3
A kind of Water Soluble Compound fertilizer, including following material in parts by weight：45 parts of superfine mineral powder, agricultural product give up
Abandon 40 parts of liquid, 40 parts of cow dung, 25 parts of straw, 15 parts of compound biological bacterium, 15 parts of humic acid, 30 parts of urea, metal ion ammonia
40 parts of 40 parts of base acid complex concentrate and Rare-earth Aminoacid Complexes concentrate.The weight of the rare earth element and metallic element
Than for lanthanum: cerium: yttrium: iron: magnesium: calcium: manganese=10: 7: 5: 5: 6: 10: 3, under this weight ratio, this Water Soluble Compound fertilizer can be maximum
Increase to degree drought resisting, the cold tolerance of the plants such as corn, peanut, millet, apple, while the speed of growth and the root of plant
Absorbability is most strong.
Wherein, the Rare-earth Aminoacid Complexes concentrate includes following material in parts by weight：40 parts of leather waste,
100 parts of sulfuric acid solution, 50 parts of the perchloric acid of 40 parts of cerine, concentration for 40%.Wherein, the parts by weight of animal protein and Zn-ef ficiency
Number, than being 1: 1.2, is the optimal result by test of many times, and now the yield of amino acids metal ion chelate complex is maximum, and miscellaneous
Matter is less..
Wherein, the metal ion amino acid complex concentrate includes following material in parts by weight：40 parts of dregs of beans,
Hydrochloric acid solution 80 part, smithsonite 40 part of the concentration for 40%.Dregs of beans rich in protein there is very high nutritive value to be a kind of good
Good vegetable protein resource, its protein overwhelming majority is globulin, and amino acid content is more stable.Wherein, vegetable protein
Ratio of weight and number with Zn-ef ficiency is 1: 1.5.
Wherein, the agricultural product waste liquid includes following material in parts by weight：80 parts of cane molasses zymotic fluid, biogas
40 parts of waste liquid, 30 parts of spirulina waste liquid.
A kind of preparation method for preparing above-mentioned Water Soluble Compound fertilizer, comprises the following steps：By described Rare Earth Amino-Acid
Complex compound concentrate, metal ion amino acid complex concentrate, superfine mineral powder and ferment filtrate are mixed by above-mentioned parts by weight
Close, be sufficiently stirred for 15 minutes, adjust pH to 8.5, under normal temperature and pressure conditionses by above-mentioned parts by weight add agricultural product waste liquid and
Compound biological bacterium, is sufficiently stirred for 1 hour, gets product.
Wherein, the preparation method of the Rare-earth Aminoacid Complexes concentrate comprises the following steps：
The leather waste of above-mentioned parts by weight is crushed to fineness for 200 mesh, placed it in autoclave, in addition
The concentration for stating parts by weight is 40% sulfuric acid solution, is 115 DEG C in temperature, pressure passes through to be hydrolyzed 8 hours under conditions of 20MP
Animal protein factor digest is obtained after filter, it is standby；
The cerine powder of above-mentioned parts by weight is dissolved at normal temperatures in 50 parts of perchloric acid in parts by weight, in 100 DEG C of bars
Reacted 1 hour under part, filter out the impurity in solution, obtain rare earth ion settled solution；
Gained rare earth ion clarified solution is mixed with above-mentioned animal protein factor digest, stirred in one direction, in 90 DEG C of bars
Reacted 1 hour under part, obtain Rare-earth Aminoacid Complexes solution, shifted the pumping in evaporator and be concentrated into the 1/4 of original volume,
Obtain the Rare-earth Aminoacid Complexes concentrate.
Wherein, the preparation method of the metal ion amino acid complex concentrate has steps of：By above-mentioned weight
The dregs of beans of part is crushed to fineness for 200 mesh, throws into the hydrochloric acid solution of above-mentioned parts by weight, boils to boiling and add above-mentioned parts by weight
Smithsonite, in one direction stir 1 hour, after filtering metal ion amino acid complex, be transferred in evaporator and take out
Gas is concentrated into the 1/4 of original volume, obtains metal ion amino acid complex concentrate.
Wherein, the preparation method of the ferment filtrate has steps of：The straw of above-mentioned parts by weight is crushed to
Length is 4cm, is well mixed with cow dung, humic acid, is placed in after being irradiated 6 hours using ultraviolet lamp in fermentation vat, then to fermentation
Add the urea of above-mentioned parts by weight in pond, pH is 6.5 before fermentation, and temperature is 63 DEG C, start after fermentation every turning in 24 hours once,
Control water content be maintained at 60%, to material completely without stool odor when stop fermentation, using plate and frame filter press by ferment produce
Thing separation of solid and liquid, obtains the ferment filtrate.
Wherein, the preparation method of the superfine mineral powder has steps of：Rock phosphate in powder and zeolite are pressed 2: 1 weight
Than well mixed, it be positioned in ball mill and be crushed to fineness for 150 mesh, then pour into fine grinding 1 time in super fine grinding machine, is surpassed
Trickle mineral powder, its fineness is 2200 mesh.
Wherein, the preparation of the agricultural product waste liquid is included：With 70 parts of cane molasses zymotic fluid by weight, natural pond
30 parts of gas waste liquid, the ratio that 30 part of spirulina waste liquid mixing, is used in 100 DEG C and boils 1 hour, and regulation pH is between 7.5, natural
Cooled and filtered, slagging-off, filtrate are agricultural product waste liquid.
The experiment at Beihai clay fertilizer station shows that each crops are applied after this aqueous solution compound fertilizer, wheat increase yield can be made
17.5%th, corn yield increasing 18.3%, peanut yield increasing 27.2%, apple volume increase 14.8%, Yield Increase In Cotton 21.32%, spinach volume increase
25.4%th, sweet potato production increasing 18.2%, soybean yield-increasing 16.9%, sesame volume increase 12.4%.
After soil application this aqueous solution compound fertilizer, microbial activity enhancing, intensity of soil respiration is carried than control after measured
High 5-10 times, 8%-30%, 12%-34%, 18%-43% is respectively increased in soil xylanase, phosphatase and proteinase activity.
The beneficial dimension biomass such as amonifying bacteria, nitrogen-fixing bacteria, cellulose-decomposing bacteria averagely increases by 45% in soil, reaches as high as 130%.
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed
With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art
Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, the present invention is not limited
In specific details and shown here as the legend with description.
Claims (6)
1. a kind of Water Soluble Compound fertilizer, it is characterised in that including following material in parts by weight：Superfine mineral powder 40-
60 parts, 30-50 parts of agricultural product waste liquid, 35-50 parts of cow dung, 20-35 parts of straw, 10-20 parts of compound biological bacterium, humic acid
10-15 parts, 20-40 parts of urea, 30-50 parts of metal ion amino acid complex concentrate and Rare-earth Aminoacid Complexes concentrate
30-50 parts；The Rare-earth Aminoacid Complexes concentrate includes following material in parts by weight：It is 30-50 parts of leather waste, brown
100 parts of sulfuric acid solution, 40-60 parts of the perchloric acid of 30-50 parts of zoisite, concentration for 40%；The metal ion amino acid complex
Concentrate includes following material in parts by weight：50-100 parts of hydrochloric acid solution, the water chestnut zinc of 30-50 parts of dregs of beans, concentration for 40%
30-50 parts of ore deposit；The agricultural product waste liquid includes following material in parts by weight：70-90 parts of cane molasses zymotic fluid, biogas
30-50 parts of waste liquid, 20-40 parts of spirulina waste liquid.
2. a kind of preparation method of Water Soluble Compound fertilizer as claimed in claim 1, it is characterised in that comprise the following steps：
By described Rare-earth Aminoacid Complexes concentrate, metal ion amino acid complex concentrate, superfine mineral powder and fermentation
Filtrate is mixed by above-mentioned parts by weight, is sufficiently stirred for 15 minutes, adjusts pH to 8-9, and above-mentioned parts by weight are pressed under normal temperature and pressure conditionses
Agricultural product waste liquid and compound biological bacterium are added, is sufficiently stirred for 1 hour, gets product；
The preparation method of the ferment filtrate has steps of：The straw of above-mentioned parts by weight is crushed to length for 3-
6cm, is well mixed with cow dung, humic acid, is placed in after being irradiated 6 hours using ultraviolet lamp in fermentation vat, then adds into fermentation vat
Enter the urea of above-mentioned parts by weight, pH is 6-7 before fermenting, temperature is 60-65 DEG C, start every turning in 24 hours after fermentation and once, control
Water content processed is maintained at 60%, to material completely without stool odor when stop fermentation, using plate and frame filter press by tunning
Separation of solid and liquid, obtains the ferment filtrate.
3. preparation method as claimed in claim 2, it is characterised in that the preparation side of the Rare-earth Aminoacid Complexes concentrate
Method comprises the following steps：
The leather waste of above-mentioned parts by weight is crushed to fineness for 200 mesh, places it in autoclave, adds above-mentioned heavy
The concentration for measuring part is 40% sulfuric acid solution, is 110-125 DEG C in temperature, pressure passes through to be hydrolyzed 8 hours under conditions of 20MP
Animal protein factor digest is obtained after filter, it is standby；
The cerine powder of above-mentioned parts by weight is dissolved at normal temperatures in 40-60 part perchloric acid in parts by weight, in 100 DEG C of conditions
Lower reaction 1 hour, filters out the impurity in solution, obtains rare earth ion settled solution；
Gained rare earth ion clarified solution is mixed with above-mentioned animal protein factor digest, stirred in one direction, under the conditions of 90 DEG C
Reaction 1 hour, obtains Rare-earth Aminoacid Complexes solution, is shifted the pumping in evaporator and is concentrated into the 1/4 of original volume, obtained
The Rare-earth Aminoacid Complexes concentrate.
4. preparation method as claimed in claim 3, it is characterised in that the system of the metal ion amino acid complex concentrate
Preparation Method has steps of：The dregs of beans of above-mentioned parts by weight is crushed to fineness for 200 mesh, the hydrochloric acid of throwing to above-mentioned parts by weight is molten
In liquid, boil to boiling and add the smithsonite of above-mentioned parts by weight, stir in one direction 1 hour, metal ion is obtained after filtering
Amino acid complex, is transferred to pumping in evaporator and is concentrated into the 1/4 of original volume, obtain the concentration of metal ion amino acid complex
Liquid.
5. preparation method as claimed in claim 4, it is characterised in that the preparation method of the superfine mineral powder has following
Step：Rock phosphate in powder and zeolite are pressed 2:1 weight is positioned in ball mill than well mixed and is crushed to fineness for 100-200 mesh,
Fine grinding 1 time in super fine grinding machine is poured into again, superfine mineral powder is obtained, and its fineness is 2000-2500 mesh.
6. preparation method as claimed in claim 5, it is characterised in that also include the preparation of the agricultural product waste liquid：With by
70 parts of the cane molasses zymotic fluid of parts by weight meter, 30 parts of methane waste liquor, the ratio mixing that 30 parts of spirulina waste liquid is used in 100
DEG C boil 1 hour, regulation pH is between 7-8, to filter, remove the gred after natural cooling, filtrate is agricultural product waste liquid.
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| CN106083307A (en) * | 2016-06-07 | 2016-11-09 | 吉林省农业科学院 | A kind of solubility compound fertilizer |
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| CN112374940A (en) * | 2020-11-18 | 2021-02-19 | 朱孟越 | Cold-resistant antibacterial liquid cultivating fertilizer and processing method thereof |
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| CN1566036A (en) * | 2003-06-26 | 2005-01-19 | 罗宪章 | Production method of amino acid chelate compound environmental protection fertilizer |
| CN1785925A (en) * | 2004-12-06 | 2006-06-14 | 邵建华 | Chelated multielement composite fertilizer and its production |
| CN101200389A (en) * | 2006-12-13 | 2008-06-18 | 中国科学院沈阳应用生态研究所 | Active amino acid composite liquid fertilizer and preparation thereof |
| CN104151011A (en) * | 2014-06-05 | 2014-11-19 | 宁波龙兴生态农业科技开发有限公司 | Concentrated biogas slurry composite active liquid leaf fertilizer and preparation method thereof |
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