CN1478065A - 双酚a的完全纯化 - Google Patents
双酚a的完全纯化 Download PDFInfo
- Publication number
- CN1478065A CN1478065A CN01818787.0A CN01818787A CN1478065A CN 1478065 A CN1478065 A CN 1478065A CN 01818787 A CN01818787 A CN 01818787A CN 1478065 A CN1478065 A CN 1478065A
- Authority
- CN
- China
- Prior art keywords
- phenol
- bpa
- section
- adducts
- crystallization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 238000000746 purification Methods 0.000 title claims 16
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 111
- 238000000034 method Methods 0.000 claims abstract description 44
- 238000002425 crystallisation Methods 0.000 claims abstract description 30
- 238000005406 washing Methods 0.000 claims abstract description 28
- 230000008025 crystallization Effects 0.000 claims abstract description 26
- 238000012545 processing Methods 0.000 claims abstract description 15
- 239000000047 product Substances 0.000 claims abstract description 15
- 239000006227 byproduct Substances 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 239000006210 lotion Substances 0.000 claims description 24
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 19
- 239000012452 mother liquor Substances 0.000 claims description 18
- 239000012535 impurity Substances 0.000 claims description 14
- 238000011144 upstream manufacturing Methods 0.000 claims description 10
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- 238000009833 condensation Methods 0.000 claims description 7
- 230000005494 condensation Effects 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 5
- PBEHQFUSQJKBAS-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;phenol Chemical class OC1=CC=CC=C1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 PBEHQFUSQJKBAS-UHFFFAOYSA-N 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims 12
- 238000007865 diluting Methods 0.000 claims 2
- 230000018044 dehydration Effects 0.000 claims 1
- 238000006297 dehydration reaction Methods 0.000 claims 1
- 238000011282 treatment Methods 0.000 claims 1
- 238000013461 design Methods 0.000 abstract description 3
- 239000000706 filtrate Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 238000004821 distillation Methods 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 238000006482 condensation reaction Methods 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- PQNFLJBBNBOBRQ-UHFFFAOYSA-N indane Chemical compound C1=CC=C2CCCC2=C1 PQNFLJBBNBOBRQ-UHFFFAOYSA-N 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229920003247 engineering thermoplastic Polymers 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
- C07C37/84—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by crystallisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/685—Processes comprising at least two steps in series
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (26)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US24930600P | 2000-11-16 | 2000-11-16 | |
US60/249,306 | 2000-11-16 | ||
PCT/US2001/044249 WO2002040435A1 (en) | 2000-11-16 | 2001-11-14 | Economical purification of bisphenol a |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1478065A true CN1478065A (zh) | 2004-02-25 |
CN100537504C CN100537504C (zh) | 2009-09-09 |
Family
ID=22942903
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB018187870A Expired - Lifetime CN100537504C (zh) | 2000-11-16 | 2001-11-14 | 双酚a的完全纯化 |
Country Status (6)
Country | Link |
---|---|
US (1) | US6806394B2 (zh) |
JP (1) | JP2004513932A (zh) |
KR (1) | KR100868168B1 (zh) |
CN (1) | CN100537504C (zh) |
AU (1) | AU2002219868A1 (zh) |
WO (1) | WO2002040435A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108083987A (zh) * | 2017-12-13 | 2018-05-29 | 西陇科学股份有限公司 | 一种超高纯双酚a的提纯方法 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4419492B2 (ja) * | 2002-10-28 | 2010-02-24 | 三菱化学株式会社 | 改善された連続晶析方法 |
JP4604562B2 (ja) * | 2003-06-18 | 2011-01-05 | 三菱瓦斯化学株式会社 | スピログリコールの製造方法 |
JP2005232134A (ja) * | 2004-02-23 | 2005-09-02 | Mitsubishi Chemicals Corp | ビスフェノールaの製造方法 |
DE102005025788A1 (de) | 2005-06-04 | 2006-12-07 | Bayer Materialscience Ag | Verfahren zur Herstellung von hochreinem Bisphenol A |
US8039679B2 (en) * | 2005-10-07 | 2011-10-18 | Badger Licensing Llc | Bisphenol-A plant yield enhancement |
PL2142491T5 (pl) * | 2007-05-09 | 2017-01-31 | Badger Licensing Llc | Ulepszenie procesu wytwarzania BPA |
WO2017044229A1 (en) * | 2015-09-11 | 2017-03-16 | Sabic Global Technologies B.V. | A method of recovering phenol from a bpa production plant and the plant for recovering the same |
US20190308921A1 (en) | 2016-07-12 | 2019-10-10 | Sabic Global Technologies B.V. | Manufacture of bisphenol a |
WO2018015923A1 (en) | 2016-07-22 | 2018-01-25 | Sabic Global Technologies B.V. | Manufacture of bisphenol a |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01146839A (ja) * | 1987-12-04 | 1989-06-08 | Mitsui Toatsu Chem Inc | 高純度の2,2−ビス(4−ヒドロキシフェニル)プロパンを製造する方法 |
EP0522700B1 (en) | 1991-07-10 | 1997-01-29 | Chiyoda Corporation | Process for the production of crystalline adduct of bisphenol A and phenol and apparatus therefor |
EP0526964B1 (en) * | 1991-08-05 | 1996-10-23 | Chiyoda Corporation | Process for the production of bisphenol A |
-
2001
- 2001-11-14 AU AU2002219868A patent/AU2002219868A1/en not_active Abandoned
- 2001-11-14 US US10/415,428 patent/US6806394B2/en not_active Expired - Lifetime
- 2001-11-14 KR KR1020037006669A patent/KR100868168B1/ko active IP Right Grant
- 2001-11-14 WO PCT/US2001/044249 patent/WO2002040435A1/en active Application Filing
- 2001-11-14 CN CNB018187870A patent/CN100537504C/zh not_active Expired - Lifetime
- 2001-11-14 JP JP2002542765A patent/JP2004513932A/ja active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108083987A (zh) * | 2017-12-13 | 2018-05-29 | 西陇科学股份有限公司 | 一种超高纯双酚a的提纯方法 |
CN108083987B (zh) * | 2017-12-13 | 2020-10-02 | 西陇科学股份有限公司 | 一种超高纯双酚a的提纯方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2002040435A1 (en) | 2002-05-23 |
CN100537504C (zh) | 2009-09-09 |
JP2004513932A (ja) | 2004-05-13 |
KR20040004439A (ko) | 2004-01-13 |
KR100868168B1 (ko) | 2008-11-12 |
US20040044254A1 (en) | 2004-03-04 |
US6806394B2 (en) | 2004-10-19 |
AU2002219868A1 (en) | 2002-05-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Free format text: FORMER OWNER: BORDEN CHEM INC. Owner name: BADGER LICENSING LLC Free format text: FORMER OWNER: STON-WIBST CO., LTD. Effective date: 20110118 Owner name: BORDEN CHEM INC. Free format text: FORMER OWNER: RESOLUTION PERFORMANCE PRODUCTS CO., LTD. |
|
C41 | Transfer of patent application or patent right or utility model | ||
C56 | Change in the name or address of the patentee | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: TEXAS, UNITED STATES TO: MASSACHUSETTS, UNITED STATES |
|
CP03 | Change of name, title or address |
Address after: Texas, USA Co-patentee after: Rizzo Luxun Performance Products Ltd. Patentee after: WASHINGTON GROUP INTERNATIONAL, Inc. Address before: Texas, USA Co-patentee before: RESOLUTION PERFORMANCE PRODUCT Patentee before: WASHINGTON GROUP INTERNATIONAL, Inc. |
|
TR01 | Transfer of patent right |
Effective date of registration: 20110118 Address after: Massachusetts, USA Patentee after: BADGER LICENSING LLC Address before: Texas, USA Co-patentee before: HEXION SPECIALTY CHEMICALS Inc. Patentee before: WASHINGTON GROUP INTERNATIONAL, Inc. Effective date of registration: 20110118 Address after: Texas, USA Co-patentee after: HEXION SPECIALTY CHEMICALS Inc. Patentee after: WASHINGTON GROUP INTERNATIONAL, Inc. Address before: Texas, USA Co-patentee before: Rizzo Luxun Performance Products Ltd. Patentee before: WASHINGTON GROUP INTERNATIONAL, Inc. |
|
CX01 | Expiry of patent term |
Granted publication date: 20090909 |
|
CX01 | Expiry of patent term |