CN1429488A - Insecticide having antiseptic function and its preparation method and application of said insecticide in paint - Google Patents
Insecticide having antiseptic function and its preparation method and application of said insecticide in paint Download PDFInfo
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- CN1429488A CN1429488A CN 01145009 CN01145009A CN1429488A CN 1429488 A CN1429488 A CN 1429488A CN 01145009 CN01145009 CN 01145009 CN 01145009 A CN01145009 A CN 01145009A CN 1429488 A CN1429488 A CN 1429488A
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- insecticide
- ethanol
- sterilizing function
- interior wall
- sterilization
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Abstract
An insecticide with disinfecting function for the paint of internal wall is prepared from disinfecting emulsifier, C12-C18 ampholytic surfactant, non-ionic surfactant; pyrethrin insecticides (tetramethrin, broflurthrinate, etc.); other insecticides (chlorobenzene, thion, etc.); synergistic agent (piperonyl butylether oxide, etc.), alcohol, phenylmethanol and water. Its advantages are sure disinfecting action and no poison.
Description
Technical field
The invention belongs to the biocide, the insects repellant that contain organic compound, particularly a kind of insecticide and preparation method thereof and the application of this insecticide in coating with sterilizing function.
Background technology
Usually, the effect insecticide of sterilizing function is arranged if be medium with water, medium-term and long-term " sterilization-anti-, desinsection " effect is arranged again, often repelled by traditional concept, because the limitation that specialty defines is thought: under aqueous conditions, no matter be sterilization, still anti-, desinsection, its long-lasting and powerful effect is a mutual restriction; That is to say, under the water situation, embody brute force, the high efficiency of disinfectant for a long time, must be under relative alkaline case (pH＞9), and the brute force of insecticide, quick-acting, and the overwhelming majority can only be in neutrality, even is just embodied in slant acidity.And under alkaline case, most of insecticide particularly is outstanding properties with the safety non-toxic, and pyrethroid etc. are main component, and the stability of hygienic insecticide is relatively poor relatively again, can not be long-acting and can't commercialization.
In view of technical merit is not now found " sterilization-anti-, desinsection " powerful compound of holding concurrently and imitating as yet, therefore, so far commercial aerosol bomb such as aerial fog pesticide, most is solvent with deodorized kerosine or ethanol, be aided with hydrocarbon propellant such as aerosol is formed, not only excitant is bigger, and does not also have sterilization, bactericidal effect, and tangible use limitation is arranged.
Chinese patent 85107492 discloses a kind of " insecticidal paint and manufacture method thereof ", is mainly resinae polymer, calcium carbonate, inorganic powder and water, also contains the insecticide that pyrethroid and carbamate are main component.This coating has rapid killing effect to insect, and people and animals are not constituted harm.But this technology does not have sterilizing function, and because of carbamate has moderate toxicity, be only applicable to outdoor, if interior wall uses, influential to health for a long time.
Chinese patent 1039700 discloses a kind of " its manufacture method of long-acting hygiene spraying insecticide ", this spraying insecticide is except that the insecticide that contains pyrethroid, carbamate and solvent, emulsification and composition, also contain resinae polymer as film forming agent, this resinae compound through urea ammoniated handle the back mix with above-mentioned insecticide stirring levigate product.To the person poultry harmless, can be sprayed at the metope and the various furniture surface of any material.This technology is except that having the moderate toxicity of being low to moderate, and its application is not to be mixed in the coating, because of poor stability, so its drug effect is only kept about half a year.
Summary of the invention
The present invention provides a kind of safe without toxic side effect in order to solve the deficiencies in the prior art, is beneficial to the insecticide with sterilizing function and preparation method thereof and the application of this insecticide in coating of healthy and ecotope.
Of the present invention by following technical scheme realization:
A kind of insecticide with sterilizing function, by the bactericidal activity emulsifier, composite insecticide and solvent make up, and make by following components in weight percentage:
Sterilization, emulsifier, C
12-C
18The amphoteric surfactant 1-25% of carbochain,
Non-ionic surface active agent 1-10%;
Composite insecticide, 1. insecticide, tetramethrin 0.1-5%, ethanol 2-8%,
Bromine-Flumethrin 0-1.5%, Permanone 0-1.5%,
Other chrysanthemum esters 0-1.5%, phenmethylol 1-8%;
2. drive, desinsection hold concurrently to be imitated agent,
Dichloro-benzenes 0.05-0.45%, the Phosphorus 0.01-0.45% of sulphur,
Repefral 0-0.45%;
3. synergist,
Oxidation of piperonyl butoxide 0-5%, Octachlorodipropyl Ether 1-10%,
Other synergist 0-4.5%.
4. solvent: ethanol 2-8%, phenmethylol 2-6%.
Solvent, ethanol 7-13% water 55-70%
Described insecticide is prepared by following components in weight percentage:
Empgen BB 6%, dodecyl phenol polyethenoxy ether 6%,
Tetramethrin 1.2%, bromine-Flumethrin 0.2%,
Permanone 0.2%, methothrin 0.2%,
Swebate 0.3%, Octachlorodipropyl Ether 6%, phenmethylol 3%,
Ethanol 20%, dichloro-benzenes 0.1% repefral 0.2%;
Water 59.6%.
A kind of method for producing insecticide with sterilizing function: each components based on weight percentage is calculated,
The first step is fully dissolved the tetramethrin 0.1-5% of percentage by weight with the ethanol 5% of percentage by weight, adds phenmethylol 1-8% subsequently;
In second step, under stirring state, add dichloro-benzenes 0.05-0.45% successively, bromine-Flumethrin 0-1.5%, Permanone 0-1.5%, other chrysanthemum ester 0-1.5%, the Phosphorus 0-0.45% of sulphur, repefral 0-0.45%; Oxidation of piperonyl butoxide 0-5%, Octachlorodipropyl Ether 1-10%, Octacide 264 N 0-4.5% makes compound insect disinfestation component;
The 3rd step in temperature more than 25 ℃, with compound insecticide component total amount, being higher than under 1500 rev/mins the high-speed stirred, be added to slowly among the dodecyl phenol polyethenoxy ether 1-10%, and continues stirring 10 minutes, made the emulsified insecticide component;
In the 4th step, the emulsified insecticide component that will make adds ethanol 1-10% and phenmethylol 2-6% solubilising.
In the 5th step, the emulsified insecticide component total amount that solubilising is good joins slowly among the empgen BB 1-25% and makes " sterilization-anti-, desinsection " mother liquor under slowly stirring;
In the 6th step, 7-13% ethanol is joined in the water of 55-70% standby; Solvent is the aqueous solution of ethanol, and its amount is 55-80%;
The 7th step under slowly stirring, added mother liquor in the ethanol water for preparing slowly, promptly got " sterilization-anti-, the insecticide " of higher concentration.
It is medium with water that the present invention has just explained this, " sterilization-anti-, desinsection " the goods technology under the weak acid situation, and this " sterilization-anti-, desinsection " goods, its pH value＜5.5.
Ratio with the insecticide of sterilizing function and interior wall coating preparation 0.5-2.5%, fully stir " long-acting fungi-proofing-expelling parasite interior wall coating ".
The described application of insecticide in coating with sterilizing function will have the ratio preparation in 0.5-2.5% of the insecticide of sterilizing function and polyvinyl acetate class interior wall coating, fully stir " long-acting fungi-proofing-expelling parasite interior wall coating ".
When using with the water dilution of proper proportion, the acidity-basicity ph value that presents is 6-7.5, under this acid-base value situation, is particularly conducive to the existence growth conditions of nearly all biology, helps the improvement of healthy and ecotope.This insecticide has technology, market prospects extremely widely.
Zhi Bei insecticide insecticide and preparation method thereof and the application of this insecticide in coating like this with sterilizing function, make insecticide have sterilizing function, and can practical application in interior wall coating, nontoxic to human body, for building coating provides new kind.
Embodiment
The first step is fully dissolved the 6kg tetramethrin with 25kg ethanol, adds phenmethylol 10kg subsequently;
Second step, (together following) adds 1 kilogram of bromine-Flumethrin, 1 kilogram of Permanone, 1 kilogram of methothrin, 0.5 kilogram of dichloro-benzenes, 1.5 kilograms of Swebates, 1 kilogram of repefral, 30 kilograms of Octachlorodipropyl Ethers successively under stirring state, makes the composite insecticidal component; Add 25 kilograms of bulking agent ethanol, 5 kilograms of phenmethylols;
The 3rd step in temperature more than 25 ℃, with composite insecticide component total amount, being higher than under 1500 rev/mins the high-speed stirred, was added to slowly in the dodecyl phenol polyethenoxy ether, and continues to stir 10 minutes, made the emulsified insecticide component;
The 4th goes on foot, and the emulsified insecticide component that makes is added 5 kilograms of increase-volumes of phenmethylol of 25 kilograms of ethanol and 3%;
In the 5th step, the emulsified insecticide component total amount that solubilising is good joins concentration slowly and is in 100 kilograms of 30% empgen BBs and make " sterilization-anti-, desinsection " mother liquor under slowly stirring;
In the 6th step, it is standby to add 50 kilograms of increase-volumes of ethanol at last;
The 7th step under slowly stirring, will add in 213 kg of water slowly through the mother liquor of repeatedly increase-volume, promptly get " sterilization-anti-, desinsection " commodity of higher concentration;
During its actual use, can use the indication explanation to add the doubly natural water of 120-80, be used for " sterilization-anti-, desinsection " purpose under the multiple occasion after the dilution according to commodity.Also sprayable to interior wall, under the situation of enough accumulations, " sterilization-insect protected " effect can be arranged.The application of insecticide in coating with sterilizing function,
If need preparation long-acting " fungi-proofing-expelling parasite " interior wall coating, then can be in the ratio of 0.5-2.5%, 1 kilogram in insecticide is added to 99 kilograms of high speeds of polyvinyl acetate class interior wall coating stirs.
Interior wall coating can be a polyacrylate.
Interior wall coating can be the polyvinyl acetate class.
Interior wall coating can be the copolymer of polyacrylate and polyvinyl acetate class.
Practical proof, this " sterilization-anti-, desinsection " technology that contains novel disinfection technology has good effect.Its result of use, can embody very soon or gradually with the concentration height that uses liquid, and long-acting relatively, then be outstanding feature of the present invention, detection shows the sterilization and insect prevention effect that it is good through units such as Tianjin Center for Disease Control and Prevention, Tianjin quarantine station for animals, Nankai University's school of life and health sciences.This insecticide stoste or under the situation of finite concentration and time of contact (concentration and time of contact are inversely proportional to), can be in 60 minutes fast and 100% kill quasi-anthrax bud cell and Bacillus subtillis; Can in 5 minutes, drip concentration higher H BsAg hepatitis B surface antigen by quick inactivating; Under hundred times even thousand times of level diluting conditions, in 1 minute or a little longer time 100% kill staphylococcus aureus, Escherichia coli, salmonella, gonococcus, pseudomonas aeruginosa, skin wire-like bacteria, aspergillus flavus, and the new eqpidemic disease poison of chicken NDV, pig parvoviral PPV.Particularly more be applicable to the food hygiene industry because its economy and brute force are long-lasting, plant husbandry, occasion and indoor health decorations such as aquaculture and calamity epidemic situation can be developed multi-series, many kinds special product.
Claims (10)
1. the insecticide with sterilizing function is characterized in that this insecticide by sterilization emulsifier, composite insecticide and solvent combination, and makes by following components in weight percentage:
Sterilization, emulsifier, C
12-C
18The amphoteric surfactant 1-25% of carbochain,
Non-ionic surface active agent 1-10%;
Composite insecticide, 1. insecticide, tetramethrin 0.1-5%, ethanol 2-8%,
Bromine-Flumethrin 0-1.5%, Permanone 0-1.5%,
Other chrysanthemum esters 0-1.5%, phenmethylol 1-8%;
2. drive, desinsection hold concurrently to be imitated agent, dichloro-benzenes 0.05-0.45%,
The Phosphorus 0.01-0.45% of sulphur, repefral 0-0.45%;
3. synergist, oxidation of piperonyl butoxide 0-5%, Octachlorodipropyl Ether 1-10%,
Other synergist 0-4.5%.
4. solvent: ethanol 2-8%, phenmethylol 2-6%.
Solvent, ethanol 7-13% water 55-70%
2. insecticide according to claim 1 is characterized in that this insecticide is prepared by following components in weight percentage:
Empgen BB 6%, dodecyl phenol polyethenoxy ether 6%, tetramethrin 1.2%,
Bromine-Flumethrin 0.2%, Permanone 0.2%, methothrin 0.2%,
Swebate 0.3%, Octachlorodipropyl Ether 6%, phenmethylol 3%,
Ethanol 20%, dichloro-benzenes 0.1% repefral 0.2%;
Water 59.6%.
3. method for producing insecticide with sterilizing function is characterized in that: the first step, the tetramethrin 0.1-5% of percentage by weight is fully dissolved with the ethanol 5% of percentage by weight, and add phenmethylol 1-8% subsequently;
In second step, under stirring state, add dichloro-benzenes 0.05-0.45% successively, bromine-Flumethrin 0-1.5%, Permanone 0-1.5%, other chrysanthemum ester 0-1.5%, the Phosphorus 0-0.45% of sulphur, repefral 0-0.45%; Oxidation of piperonyl butoxide 0-5%, Octachlorodipropyl Ether 1-10%, Octacide 264 N 0-4.5% makes compound insect disinfestation component;
The 3rd step in temperature more than 25 ℃, with compound insecticide component total amount, being higher than under 1500 rev/mins the high-speed stirred, be added to slowly among the dodecyl phenol polyethenoxy ether 1-10%, and continues stirring 10 minutes, made the emulsified insecticide component;
In the 4th step, the emulsified insecticide component that will make adds ethanol 1-10% and phenmethylol 2-6% solubilising.
In the 5th step, the emulsified insecticide component total amount that solubilising is good joins slowly among the empgen BB 1-25% and makes " sterilization-anti-, desinsection " mother liquor under slowly stirring;
In the 6th step, 7-13% ethanol is joined in the water of 55-70% standby;
In the 7th step, under slowly stirring, mother liquor is added slowly " sterilization-anti-, desinsection " commodity that promptly get higher concentration in the ethanol water that has prepared.
4. the application of insecticide in coating that has sterilizing function is characterized in that having the ratio of the insecticide and the interior wall coating preparation 0.5-2.5% of sterilizing function, high-speed stirred " long-acting fungi-proofing-expelling parasite interior wall coating ".
5. insecticide according to claim 4, it is characterized in that the described application of insecticide in coating with sterilizing function, be to have the ratio preparation of the insecticide of sterilizing function and polyvinyl acetate class interior wall coating in 0.5-2.5%, fully stir " long-acting fungi-proofing-expelling parasite interior wall coating ".
6. insecticide according to claim 4, it is characterized in that the described application of insecticide in coating with sterilizing function, be to have of the ratio preparation of the copolymer analog interior wall coating of the insecticide of sterilizing function and polyacrylate or polyacrylate and polyvinyl acetate class in 0.5-2.5%, fully stir " long-acting fungi-proofing-expelling parasite interior wall coating ".
7. insecticide according to claim 1 is characterized in that sterilization, emulsifier are cationic surfactants, and its weight portion is 1-25%.
8. insecticide according to claim 1 is characterized in that other chrysanthemum ester is methothrin or terallethrin, or the trans third chrysanthemum ester of rich dextrorotation, or the dextrorotation cyphenothrin, or allethrin, or resmethrin, or cypermethrin.
9. insecticide according to claim 1, it is characterized in that sulphur Phosphorus be phoxim, or phoxiom_methyl, or fenthion, or Swebate, or malathion, and its weight portion 0.01-0.45%.
10. according to claim 1,3 described insecticides, it is characterized in that this pesticide product pH＜5.5, be formulated as pH6-7.5 during use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011450096A CN100405911C (en) | 2001-12-30 | 2001-12-30 | Insecticide having antiseptic function and its preparation method and application of said insecticide in paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011450096A CN100405911C (en) | 2001-12-30 | 2001-12-30 | Insecticide having antiseptic function and its preparation method and application of said insecticide in paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1429488A true CN1429488A (en) | 2003-07-16 |
| CN100405911C CN100405911C (en) | 2008-07-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011450096A Expired - Fee Related CN100405911C (en) | 2001-12-30 | 2001-12-30 | Insecticide having antiseptic function and its preparation method and application of said insecticide in paint |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102349510A (en) * | 2011-08-15 | 2012-02-15 | 赣州八维生物科技有限公司 | Composite disinfectant for livestock and poultry and using method |
| CN106212501A (en) * | 2016-07-21 | 2016-12-14 | 启东明光企业管理有限公司 | Disinfestation and deratization complexing agent |
| CN106724286A (en) * | 2016-11-18 | 2017-05-31 | 广西大学 | A kind of chair for fishing |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1006397B (en) * | 1985-09-23 | 1990-01-10 | 上海华东新型建筑材料厂 | Processing of insecticide coating |
| CN1067421C (en) * | 1997-07-29 | 2001-06-20 | 深圳市特成科工贸发展有限公司 | Insecticidal emulsion paint |
-
2001
- 2001-12-30 CN CNB011450096A patent/CN100405911C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102349510A (en) * | 2011-08-15 | 2012-02-15 | 赣州八维生物科技有限公司 | Composite disinfectant for livestock and poultry and using method |
| CN106212501A (en) * | 2016-07-21 | 2016-12-14 | 启东明光企业管理有限公司 | Disinfestation and deratization complexing agent |
| CN106724286A (en) * | 2016-11-18 | 2017-05-31 | 广西大学 | A kind of chair for fishing |
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| Publication number | Publication date |
|---|---|
| CN100405911C (en) | 2008-07-30 |
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Granted publication date: 20080730 Termination date: 20101230 |