CN102334502A - Preparation and application of multifunctional atomization agent for controlling pests in sealed container - Google Patents
Preparation and application of multifunctional atomization agent for controlling pests in sealed container Download PDFInfo
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Abstract
The invention discloses a multifunctional atomization agent for controlling pests in a sealed container. The multifunctional atomization agent comprises the following components in percentage by mass: 0.01 to 10 percent of disinfection composition, 0.1 to 15 percent of pesticidal composition, 0.1 to 15 percent of novel deratization composition, 1 to 40 percent of surfactant, 0 to 40 percent of atomization agent, 1 to 10 percent of cosolvent and the balance of water. The invention has the characteristics that: the multifunctional atomization agent for controlling the pests in the sealed container is harmless to human and livestock, cannot produce harmful substances or corrode substances and fabrics, cannot pollute the environment or irritate the skin mucous membrane, does not have pungent smell or color, is safe and environment-friendly, is not influenced by the environment, organics, acid, alkali and other physical and chemical factors, and has high durability, low cost and the like.
Description
Technical field
The invention belongs to customs examination and quarantine system disinfection, desinsection and the product scope that kills mouse; Relate to and be used for sealed container control pest multipotency Alevaire, wherein contain of preparation and the application of the composition of disinfection composition, Pesticidal combination, novel mouse-killing composition, surfactant, Alevaire, cosolvent as sealed container control pest multipotency Alevaire.
Background technology
For a long time, be used for sealed container control pest field in customs examination and quarantine system and extensively adopt fumigant such as Celfume, vikane always.
Celfume is a kind of liquid of colorless and odorless; It has strong fumigation action, can be efficient, kill various pests wide spectrum, soil is had very strong penetration capacity; Can be penetrated in the organism that rots to decompose, thereby reach the purpose of deinsectization, diseases prevention, weeding.Along with closing on of World Earth Day, this methyl bromide fumigation agent that is widely used has caused global concern.Since the forties in 20th century, just be widely used by various countries always.Because it has plurality of advantages, thereby very popular; Caused many environment and soil issues because of it again, thus controversial.Rise the nineties in 20th century; Countries in the world government all is tending towards stopping using this fumigant from security consideration; Also halted by United Nations Environment Programme for the previous period, it is a kind of material of ozone layer depletion, according to " Montreal Protocol Copenhagen amendment "; Developed country eliminated in 2005, and developing country also will eliminate in 2015.
Vikane is no color or smell gas at normal temperatures and pressures; Have that diffusion permeability is strong, broad spectrum disinfestation, dosage are economized, residual quantity is low, desinsection speed fast, the gas time of loosing is short, low temperature is easy to use, to germination rate characteristics such as influence and toxicity is not lower, be applied to the survive the winter control of insect, the tree moth dryness insect that lives of warehouse, freighter, container and building, reservoir dam, termite control and gardens more and more widely.China has just begun to manufacture experimently vikane the beginning of the eighties.But U.S.'s scientist's current research shows, can become a kind of strong effect greenhouse gases after being dispersed into air, and it endangers greater than the previous judgement of scientist, and its acute toxic action mainly damages central nervous system, causes convulsions.Environment there is harm, can pollutes, must not be used for lived plant, fruit, vegetables and all food according to " SN/T 1281-2003 " vikane to water body.It is reported that it is 4800 times of one kilogram of carbonic acid gas that one kilogram of vikane is discharged in the atmosphere effect to global warming, but it is increasing with annual 5% speed.
Summary of the invention
The objective of the invention is to be used for sealed container control pest multipotency Alevaire to the various drawbacks of existing sealed container control pest with for the technical problem that exists in the solution known technology provides; Especially with the composition of disinfection composition, Pesticidal combination, novel mouse-killing composition, surfactant, Alevaire, cosolvent as the preparation and the application that are used for sealed container control pest multipotency Alevaire, it has characteristics such as safety, efficient, wide spectrum, convenient, low toxicity, environmental protection.
One of the object of the invention provides and is used for sealed container control pest multipotency Alevaire, and especially a kind of composition with disinfection composition, Pesticidal combination, novel mouse-killing composition, surfactant, Alevaire, cosolvent is as being used for the preparation that sealed container prevents and treats pest multipotency Alevaire.
The sealed container control pest multipotency Alevaire that is used for of the present invention contains following component by mass percent:
| Component | Mass percent % |
| The disinfection composition | 0.01~10 |
| Pesticidal combination | 0.1~15 |
| Novel mouse-killing composition | 0.1~15 |
| Surfactant | 10~40 |
| Alevaire | 1~40 |
| Cosolvent | 1~10 |
| Water | Surplus |
Sanitizing composition described in the component is selected from: the mixture of one or more of quaternary ammonium compound, guanidine compound; Quaternary ammonium compound comprises one or more mixture of benzalkonium bromide, benzalkonium chloride, n-zephiran, n-alkyl dimethyl ethylbenzylammonium chloride and two n-alkyl-dimethyl ammonium chlorides; Guanidine compound comprises polyhexamethylene guanide, poly hexamethylene biguanide, gather and encircle guanidine, gather one or more the mixture in [2-(2-ethyoxyl)-ethyoxyl second fat] guanidine, or one or more one or more mixture of mixture quaternary ammonium compound and guanidine compound of above-mentioned each guanidine compound pharmaceutically acceptable salt.
Wherein the n in the n-zephiran is 8 ~ 18, like cetalkonium chloride, and molecular formula: C
25H
46NCl is white or light yellow solid.Soluble in water, ethanol are insoluble to benzene, ether.The fusing point of pure article is 68 ℃, has cleaning, bactericidal action.Character with typical cationic surfactants can produce significant foam during its aqueous solution brute force vibration.Good dispersion is arranged, peel off the foundry loam effect.Stable in properties, fast light, heat-resisting, non-volatility, but long term storage.
N in wherein two n-alkyl-dimethyl ammonium chlorides is 8 ~ 14.Two n-alkyl-dimethyl ammonium chlorides are two long chain quaternaries.Product type has multiple combining forms such as two octyl groups, two certain herbaceous plants with big flowers base, two dodecyls, octyl group certain herbaceous plants with big flowers base, and its bactericidal effect obviously strengthens.As: two certain herbaceous plants with big flowers base dimethyl ammonium bromides, two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride etc.
Wherein the n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18, molecular formula: N-C
23H
42Cl, molecular weight: 368.0393, can be used as hospital, the nursing home; Disinfectant in public place and the industry, and the Biocidal algae-killing agent in swimming pool and the Treatment of Industrial Water, wood preservation, and the sterilization of medicine equipment; Can be used as deodorant simultaneously, product is: alkyl (50%C12,30%C14,17%C16; 3%C18) dimethyl ethyl benzyl ammonium chloride, alkyl (60%C14,30%C16,5%C12; 5%C18) dimethyl ethyl benzyl ammonium chloride, as: dodecyl dimethyl ethylbenzylammonium chloride, myristyl dimethyl ethyl benzyl ammonium chloride etc., the structural formula of n-alkyl dimethyl ethylbenzylammonium chloride is following:
Wherein benzalkonium chloride is claimed the dimethyl benzyl alkyl ammomium chloride again, molecular formula: C
17H
30ClN; Belong to cationic surfactant; Belong to non-oxidizable bactericide, have wide spectrum, sterilization algae removal ability efficiently, can control bacterium algae propagation and foundry loam growth in the water effectively; And have the effect of peeling off of good foundry loam and certain dispersion, osmosis, have simultaneously certain deoil, deodorizing capability and corrosion inhibition.
Wherein benzalkonium bromide is claimed dodecyl dimethyl benzyl ammonium bromide again, molecular formula: C
21H
38BrN is white waxy solid or yellow colloid, and the aqueous solution shows neutrality or faintly alkaline reaction; Soluble in water, be slightly soluble in ethanol, be one of surfactant of using always; Have cleaning, sterilizing and algae removal effect; Being widely used in aspects such as sterilization, sterilization, anticorrosion, emulsification, de-sludging, solubilising, is industrial cycle water treatment non-oxidizable Biocidal algae-killing agent commonly used, glutinous mud remover and cleaning agent, also can be used for the control of microorganisms and the cleaning of circulation.
Guanidine compound comprises polyhexamethylene guanide, poly hexamethylene biguanide, gather and encircle guanidine, gather one or more the mixture in [2-(2-ethyoxyl)-ethyoxyl second fat] guanidine, or one or more mixture of above-mentioned each guanidine compound pharmaceutically acceptable salt.
Wherein the hydrochloride in the polyhexamethylene guanide is a kind of white amorphous powder, and no special odor is soluble in water, and the aqueous solution is colourless to faint yellow, tasteless, does not fire not quick-friedly, and metal material is not had corrosion basically, and decomposition temperature is greater than 400 ℃, and molecular formula is (C
7H
16N
3Cl)
n, to the handle no discoloration in surface, undergoing no deterioration in 2 years, the aqueous solution of 0.1 % concentration has the taste of little hardship.Very extensive in the every field application, can be used as the candida albicans disinfectant of various body surfaces, and can make daily mould inhibitor; Can be widely used in beverage and food-processing industry; Drinking water and swimming pool; Lake water, pool, cooling tower, fountain, remove algae, oil exploitation, construction material mildewproof additive; Plant's sterilization, and be used for textile industry, paper-making industry, wood-processing industry, rubber industry, agricultural etc., also can be used as the flocculant of waste water treatment.
Poly hexamethylene biguanide wherein, its colorless and odorless, water-soluble fully, stable in properties, its bactericidal mechanism is different with chlorine-containing disinfectant; Strong oxidation reaction does not take place in the sterilization process; Produce precipitation in the cell, the quantity of endocellular phosphorus rises simultaneously, thereby block cell wall and nucleic acid is synthetic; Reduce the cell permeability of the membrane, stop phosphorus to cell exocrine, and the ability bind protein, this disinfectant is widely used in pharmaceuticals industry, has when reporting it as mouthwash, and is very strong to the Gram-negative bacteria property killed.
Insecticide described in the component is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
Es-EXTHIN wherein, chemical name: dextrorotation-trans-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid-(R, S)-2-methyl-3-pi-allyl-4-oxo-ring penta-2-alkenyl esters, molecular formula: C
19H
26O
3, molecular weight: 302.41, be the former medicine of a kind of wide spectrum pyrethroid, for upsetting the contact killing type never poison of aixs cylinder conduction; Act on insect and cause the violent paralysis effect of ordering, reclining falls, and until death, very strong tagging and repellent action is arranged; The power of knocking down is stronger, and it is strong 2 times that its insecticidal toxicity is executed allethrin than the right side, and knocks down the active tetramethrin that surpasses; Mainly be used for preventing and treating flying pests such as mosquito, fly, mosquito, fly, wasp, cockroach, flea, ant are had special effect, structural formula is following:
S-bioallethrin wherein, chemical name: (1R)-trans-chrysanthemate-(S)-and 2-methyl-3-pi-allyl-4-oxo-ring penta-2-alkenyl esters, molecular formula: C
19H
26O
3, molecular weight: 302.41, be a kind of wide spectrum pyrethroid insecticides, very strong tagging and repellent action arranged, the power of knocking down is stronger, and insecticidal toxicity is 4.9 times of allethrin, and structural formula is following:
The trans phenothrin of wherein rich dextrorotation is claimed d-phenothrin again, chemical name: (1R)-trans-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic)-cyclopropane-carboxylic acid-3-phenoxy benzyl ester, molecular formula: C
23H
26O
3, molecular weight: 350.45, these article are unique nontoxic products in the pyrethroid, are that the unique allowance of the U.S. is used for the insecticide that civil aviaton uses, and are one of insecticides of world health organisation recommendations.These article have for insect tags and stomach poison function, and insecticidal spectrum is wide, high 8.5 ~ 20 times than the Dalmatian chrysanthemum class to the deadly power of insect, can be widely used in the control of household, warehousing, public health, industrial area insect.
Tetrafluoro methothrin wherein, chemical name: 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid 2,3,5,6-tetrafluoro-4-(methoxy) benzyl ester, molecular formula: C
19H
22F
4O
3, molecular weight: the 374.37th, suck and the contact killing type insecticide agent, knock down and kill activity to what sanitary insect pests such as mosquito, fly had a brilliance.In the experimental concentration scope; The acute toxicity and chronic toxicity of tetrafluoro methothrin is extremely low, and teratogenesis, carcinogenic do not observe, to Aedes aegypti, housefly, Groton bug, that a curtain casemaking clothes moth is knocked down speed is fast; Consumption is little; Be suitable for the hygienic biocide goods, belong to broad spectrum pesticide, ability effectively preventing sanitary insect pest and storage insect; Dipteral insect such as mosquito class there are quick knockdown effect, and cockroach, bedbug are had good residual effect.
Transfluthrin wherein, chemical name: 2,3,5, the 6-ptfe benzyl (1R, 3S)-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
15H
12Cl
2F
4O
2, molecular weight: 371.16, this article desinsection wide spectrum, ability effectively preventing sanitary insect pest and storage insect; Dipteral insect such as mosquito class there are quick knockdown effect, and cockroach, bedbug are had good residual effect.
Seven fluorobenzene chrysanthemum esters wherein.Chemical name: 2,3,5,6-tetrafluoro-4-methyl-benzyl (Z)-(1RS, 3RS)-3-(2-chloro-2,3,3-trifluoropropyl-1-thiazolinyl)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
17H
14ClF
7O
2, molecular weight: 418.73, these article belong to pyrethroid insecticides, are soil insecticides, can prevent and treat coleoptera and the Lepidoptera and some Diptera pest that perch in soil well, than transfluthrin stronger killing action are arranged.
Novel mouse-killing composition described in the component is selected from: seven fluorine methothrins, seven fluorine methyl ethers go permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to remove one or more the mixture in permethrin etc.
Seven fluorine methothrins wherein, chemical name: 2,3,5,6-tetrafluoro-4-methoxyl methyl carbobenzoxy-3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
17H
15ClF
7O
3Molecular weight: the 448.6th, a type agricultural chemicals is killed in a kind of novel disappearing, and is mainly used in hygienic insecticides such as preparation aerosol and propellant, with pests such as control cockroach, mosquito, ant, flea, dirt mite, silverfish, cricket, spider, mouse; Have the very strong suction and the ability of tagging, structural formula is following:
Wherein seven fluorine methyl ethers remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxyl methyl carbobenzoxy ester, molecular formula: C
18H
17F
7O
3, molecular weight: 414.1, belong to novel disappearing and kill a type agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Wherein seven fluorine methoxies remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxy benzyl ester, molecular formula: C
17H
15F
7O
3, molecular weight: 400.1, belong to novel disappearing and kill a type agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Wherein seven fluorine remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methyl benzyl ester, molecular formula: C
17H
15F
7O
2, molecular weight: 384.1, belong to novel disappearing and kill a type agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Wherein seven fluorine go first to remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-ptfe benzyl, molecular formula: C
16H
13F
7O
2, molecular weight: 370.1, belong to novel disappearing and kill a type agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Seven fluorine methoxy chrysanthemum esters wherein, chemical name: 3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxy benzyl ester, molecular formula: C
17H
15ClF
7O
3, molecular weight: 434.6, belong to novel disappearing and kill a type agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Wherein seven fluorine remove first chrysanthemum ester, chemical name: 3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methyl benzyl ester, molecular formula: C
16H
13ClF
7O
2, molecular weight: 434.6, belong to novel pyrethroid pesticide, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Surfactant described in the component is selected from: (TX/NP)-and one or more mixture in n, OP-10, AEO-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc.
(TX/NP)-n wherein, chemical name: NPE, have been widely used at washing agent, printing and dyeing, chemical industry, good penetration, emulsification, dispersion, antiacid, alkali resistant, anti-hard water, anti-reduction, oxidation resistance are arranged; (TX/NP)-n among the n is 3,4,6; 7,10,15..
OP-10 wherein; Chemical name: APES; Main with the emulsifier on the used as pesticides, also be the good finishing agent of textile industry, antifoaming agent, washing agent, dispersant, emulsifier, softening agent, dyeing assistant, fibre finishing, crude oil demulsifier etc.
AEO-n wherein, chemical name: AEO, chemical composition: natural fatty alcohol and oxirane synthetic; Wherein the n among the AEO-n is 3 or 9; AEO-3 can make water-in-oil emulsifier, and AEO-9 is mainly used in Wool detergent, woolen industry degreasing agent, and general industry is used emulsifier.
Isomery alcohol APEO wherein, chemical composition: isomery alcohol and polymers of ethylene oxide belong to nonionic surface active agent; Structural formula: RO-(C2H4O) n H: (general R is C8, C11, C13); Performance: these article are colourless or weak yellow liquid, and emulsifying capacity is strong, and surface-active is high; Anti-hard water, the washing performance is strong, and chemical stability and Environmental compatibility are good in the pH value scope of broad.Can be used as dispersant, wetting agent, bleeding agent, washing agent, be widely used in family expenses and industrial washing field, leather is had tangible degreasing; Be specially adapted to do emulsifier, better performances.
Wherein isomery alcohol polyoxyethylene poly-oxygen propylene aether is to react in proportion with oxirane, expoxy propane with isomery alcohol to form, and is one and has 100% biodegradable novel, low bubble, efficient, environment-friendly type non-ionic surface active agent.Good, acidproof, alkaline-resisting, anti-oxidant with various surfactants, auxiliary agent, additive, solvent compatibility.Characteristics: have excellent emulsification, dispersibility; Have excellent permeation property and alkali tolerance; Have excellent washing, dirt-removing power; Extremely low foam belongs to ultralow bubble interfacial agent, does not use antifoaming agent, does not therefore have silicon spot problem; Nontoxic, non-stimulated, free from extraneous odour, nonflammable explosive, safe in utilization.
Alevaire described in the component is: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.
Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.It has passed through the U.S. FDA authentication, meets American Pharmacopeia (USP), NF (NF), and Food Chemistry code (FCC) standard is widely used in the production of industries such as food, pharmacy, feed, personal care articles, chemistry.It is the water white transparency thick liquid, and it is sweet to distinguish the flavor of, and has hygroscopicity, and is miscible with water, lower aliphatic alcohols, glycerine, acetic acid, acetone, can be used as solvent, dispersant, lubricant, emulsifier etc. and is used for cosmetics, agricultural chemicals, food, medicine and other fields.
Wherein 1; The 2-dihydroxypropane is the stable water imbibition liquid of colourless thickness, and almost tasteless odorless is with water, ethanol and multiple immiscible organic solvent; As gas-chromatography fixer, solvent, antifreeze, plasticizer, dehydrating agent, carrier solvent, wetting agent, NMF, anticaking agent, antioxidant, surface-active, stabilizing agent, thickener, emulsifier, processing aid; It classifies food processing aid as among the GB 2760-96, and its aqueous solution is effective antifreeze, can be used as NMF in the cosmetics; Softening agent, solvent etc.
Wherein trihydroxy propane outward appearance is the water white transparency thick liquid; Odorless, tasteless, have hygroscopicity, humectation property, a property of softening; It is neutral that the aqueous solution is; Can mix arbitrarily with water, ethanol, methyl alcohol, have good freeze-proof, be widely used in industries such as weaving, printing and dyeing, papermaking, printing, washing agent, daily use chemicals, system wine, food, cigarette, glassine paper, enamel, oil, electronics, rubber, plastics, process hides, chemistry, chemical fibre.Main as NMF, humectant, hygroscopic agent, lubricant, softening agent, softening agent, thickener, plasticizer, thinner, antifreezing agent etc.
Wherein the triethylene-glycol outward appearance is that no color or smell has the hygroscopicity thick liquid, can be miscible with water, ethanol, benzene, toluene, be insoluble in ethers, and be insoluble to benzinum, have hygroscopicity, have the character of pure and mild ether.As solvent, extractant, desiccant, air disinfection agent etc.The toxicity data are little poison, LD
50(rat oral) 16.8ml/kg. is to eyes and skin nonirritant.
Cosolvent described in the component is selected from: 95% ethanol.
Water described in the component is deionized water.
Each component is role in the present invention:
Disinfection composition described in the component is the environmental protection and safety type disinfectant, has the quick sterilization effect, to mucocutaneous nonirritant, to metal and fabric non-corrosiveness, does not receive organic substance influence, good stability.
Pesticidal combination described in the component for sucking and the contact killing type insecticide agent, has and knocks down fast and the quick-acting lethal effects of killing, and to mucocutaneous nonirritant, to metal and fabric non-corrosiveness, receives organic substance influence slight, good stability.
Novel mouse-killing composition described in the component for sucking and the contact killing type rat-bane, has and knocks down fast and the quick-acting lethal effects of killing, to mucocutaneous nonirritant, good stability.
Surfactant described in the component plays emulsification, dissolution.
Alevaire described in the component plays good dispersion, atomizing and synergistic effect, to mucocutaneous non-stimulated, good stability is harmless to article, to metal and fabric non-corrosiveness.
Cosolvent described in the component plays dissolution and antifreeze effect, and synergistic effect is arranged simultaneously.
The present invention is used for the most preferably proportioning of following mass percent of sealed container control pest multipotency Alevaire:
| Component | Mass percent % |
| The disinfection composition | 0.1~7 |
| Pesticidal combination | 1~10 |
| Novel mouse-killing composition | 1~10 |
| Surfactant | 15~35 |
| Alevaire | 5~35 |
| Cosolvent | 2~8 |
| Water | Surplus |
Sanitizing composition described in the component is selected from: the mixture of one or more of quaternary ammonium compound, guanidine compound, quaternary ammonium compound comprise one or more mixture of benzalkonium bromide, benzalkonium chloride, n-zephiran, n-alkyl dimethyl ethylbenzylammonium chloride and two n-zephirans; Guanidine compound comprises polyhexamethylene guanide, poly hexamethylene biguanide, gather and encircle guanidine, gather one or more the mixture in [2-(2-ethyoxyl)-ethyoxyl second fat] guanidine; Or one or more mixture of above-mentioned each guanidine compound pharmaceutically acceptable salt (wherein the n in the n-zephiran is 8 ~ 18; N in two n-alkyl-dimethyl ammonium chlorides is 8 ~ 14, and the n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18).
Pesticidal combination described in the component is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
Novel mouse-killing composition described in the component is selected from: seven fluorine methothrins, seven fluorine methyl ethers go permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to remove one or more the mixture in permethrin etc.
Surfactant described in the component is selected from: (TX/NP)-one or more mixture in n, OP-10, AEO-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc., wherein the n among (TX/NP)-n is 3,4; 6; 7,10,15; N among the AEO-n is 3 or 9.
Alevaire described in the component is: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
Cosolvent described in the component is selected from: 95% ethanol.
Water described in the component is: deionized water.
Another object of the present invention is; Be provided for the compound method of sealed container control pest multipotency Alevaire, it mainly be adopt sanitizing composition, Pesticidal combination, novel mouse-killing composition, surfactant, Alevaire, cosolvent and water through mix, reaction, stir, leave standstill formulated.
The above-mentioned compound method that is used for sealed container control pest multipotency Alevaire that contains the mass percent component is following:
1, Pesticidal combination, novel mouse-killing composition, surfactant and cosolvent are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, disinfection composition and Alevaire are mixed with the water of above-mentioned mass percent remaining 50% to stir by above-mentioned mass percent be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
The object of the invention also comprises provides the above-mentioned application that is used for sealed container control pest multipotency Alevaire:
Through the multi-functional atomizer (patent No.: 201020662097.X) with the Portable atomizer patent No.: 201020682031.7) be applied to disinfection, the desinsection in sealed container space and PCO such as kill mouse, can effectively prevent and pests such as pathogenic microbe killing, mosquitos and flies, cockroach, mouse.
Combination matching between each component that is used for sealed container control pest multipotency Alevaire of the present invention has the effect of Synergistic, and has following advantage and good effect:
1, harmless to people, animal, can not produce harmful substance, do not pollute the environment safety and environmental protection;
2, non-stimulated to skin and mucosa, article and fabric are not had corrosivity;
3, have no irritating odor, colourless, do not receive the influence of environment, organic matter, acid, alkali and other physics, chemical factor.
The experimental study that the multipotency Alevaire product of sealed container PCO according to the invention is carried out:
The disinfection composition of experimental example 1 said component and the sterilization experiment of one-component thimerosal contrast (cooperative synergism effect experiment):
1, the prescription of one-component thimerosal and component disinfection composition is formed:
| Component | Prescription |
| A | Be the dodecyl dimethyl ethylbenzylammonium chloride |
| B | Be poly hexamethylene biguanide |
| A+B | The combination of consumption (or content) separately separately for A and B |
2, experimental result:
| Component | Content | 1min kills logarithm value to Escherichia coli |
| A (quaternary ammonium compound) | 100ppm | ＞ 1.2 |
| B (guanidine compound) | 100ppm | ＞ 1.0 |
| A+B | ? | ＞ 3.0 |
Investigate by above-mentioned experimental technique; (wherein the n in the n-zephiran is 8-18 when quaternary ammonium compound that will be wherein is selected from one or more mixture in benzalkonium bromide, benzalkonium chloride, n-zephiran, n-alkyl dimethyl ethylbenzylammonium chloride and the two n-alkyl-dimethyl ammonium chloride except that the dodecyl dimethyl ethylbenzylammonium chloride; N in two n-alkyl-dimethyl ammonium chlorides is 8-14, and the n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18); Guanidine compound is selected from polyhexamethylene guanide, gather and encircle guanidine, gather one or more the mixture in [2-(2-ethyoxyl)-ethyoxyl second fat] guanidine; Or when being selected from the mixture of above-mentioned guanidine compound and poly hexamethylene biguanide; Also obtained effect like the same Synergistic of experimental example 1 (cooperative synergism effect experiment); Promptly ideal with the sterilization effect of A+B; Simultaneously, the combining form of the A+B of described product investigating the killing in the process of bacterial propagule, mycobacterium, virus, fungi etc., has equally also been shown the Disinfection Effect of the good Synergistic of A+B combination; Be that special feature of the present invention is; After one or more the mixture combination of sanitizing composition in the component by quaternary ammonium compound, guanidine compound, it is active that it has outstanding disinfection, and this activity is to be predicted out by the bactericidal action of known single component.
The Pesticidal combination of experimental example 2 said components and the lethality rate of one-component insecticide contrast (cooperative synergism effect experiment):
1, the prescription of one-component insecticide described in the component and component Pesticidal combination is formed:
| Component | Prescription |
| A | Be the S-bioallethrin |
| B | Be transfluthrin |
| A+B | The combination of consumption (or content) separately separately for A and B |
2, result of the test:
| Component | To American cockroach 24H lethality rate |
| A | ＞ 70% |
| B | ＞ 70% |
| A+B | ＞ 95% |
Investigate by above-mentioned experimental technique; When Pesticidal combination that will be wherein is selected from one or more the mixture in S-bioallethrin, the Es-EXTHIN the transfluthrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, seven fluorobenzene chrysanthemum esters etc.; Also obtained effect like the same Synergistic of experimental example 1 (cooperative synergism effect experiment); Promptly ideal with the desinsection of A+B; Simultaneously; The combining form of the A+B of described product is being investigated killing in the process American cockroach, mosquitos and flies etc.; The killing effect that has equally also shown the good Synergistic of A+B combination, special feature promptly of the present invention be, the Pesticidal combination in the component by one or more the mixture combination in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc. after; It has the outstanding activity of killing, and this activity is to be predicted out by the killing action of known single component.
The novel mouse-killing composition of experimental example 3 said components and the lethality rate of one-component insecticide contrast (cooperative synergism effect experiment):
1, the prescription of the mouse-killing composition of one-component rat-bane described in the component and component is formed:
| Component | Prescription |
| A | Be seven fluorine methothrins |
| B | Be that seven fluorine methyl ethers remove permethrin |
| A+B | The combination of consumption (or content) separately separately for A and B |
2, result of the test:
| Component | To home mouse 24H lethality rate |
| A | ＞ 70% |
| B | ＞ 70% |
| A+B | ＞ 95% |
Investigate by above-mentioned experimental technique; When disinfestation and deratization agent that will be wherein is selected from the seven fluorine methoxy chrysanthemum esters, the seven fluorine methoxies that go except that seven fluorine methothrins, seven fluorine methyl ethers the permethrin and goes permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to remove one or more the mixture in the permethrin etc.; Also obtained effect like the same Synergistic of experimental example 1 (cooperative synergism effect experiment); Promptly ideal with killing mouse of A+B; Simultaneously; The combining form of the A+B of described product is being investigated killing in the process home mouse; The killing effect that has equally also shown the good Synergistic of A+B combination, special feature promptly of the present invention be, after the novel mouse-killing composition in the component goes permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to go one or more the mixture combination in the permethrin etc. by seven fluorine methothrins, seven fluorine methyl ethers; It has the outstanding activity of killing, and this activity is to be predicted out by the killing action of known single component.
The killing effect of 4 pairs of American cockroaches of experimental example, culex, housefly, mouse:
The killing effect of 5 pairs of staphylococcus aureuses of experimental example (ATCC 6538), Escherichia coli (8099), Candida albicans (ATCC10231):
The killing effect of 6 pairs of verdigris vacations of experimental example unicellular (ATCC15542):
?。
The air that experimental example 7 is done in certain hospital and the field trial of body surface:
Experimental example 8 certain port container (volume: 33.2m3) to the on-the-spot killing effect of American cockroach, culex, housefly:
Embodiment
Embodiment 1
| Component | Mass percent % |
| Dodecyl benzyl dimethyl ammonium chloride | 0.1~3 |
| The dodecyl dimethyl ethylbenzylammonium chloride | 0.1~3 |
| Two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chlorides | 0.1~3 |
| Two octyldimethyl ammonium chlorides | 0.1~3 |
| Octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride | 0.1~3 |
| The Es-EXTHIN | 0.1~3 |
| The trans phenothrin of rich dextrorotation | 1~5 |
| Seven fluorine methothrins | 1~5 |
| TX-10 | 15~30 |
| 1, the 2-dihydroxypropane | 5~25 |
| Trihydroxy propane | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, Es-EXTHIN, the trans phenothrin of rich dextrorotation, seven fluorine methothrins, alkane TX-10 and 95% ethanol are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl ethylbenzylammonium chloride, two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride, two octyldimethyl ammonium chloride, octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 2
| Component | Mass percent % |
| Cetalkonium chloride | 0.1~3 |
| Benzalkonium bromide | 0.1~3 |
| Myristyl dimethyl ethyl benzyl ammonium chloride | 0.1~3 |
| Octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride | 0.1~3 |
| The tetrafluoro methothrin | 1~5 |
| Seven fluorobenzene chrysanthemum esters | 1~5 |
| Seven fluorine methothrins | 1~5 |
| Seven fluorine methyl ethers remove permethrin | 1~5 |
| OP-10 | 15~30 |
| Ethylene glycol APEO 200 | 5~25 |
| Triethylene-glycol | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, goes permethrin, OP-10 and 95% ethanol to mix to stir tetrafluoro methothrin, seven fluorobenzene chrysanthemum esters, seven fluorine methothrins, seven fluorine methyl ethers and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, cetalkonium chloride, benzalkonium bromide, myristyl dimethyl ethyl benzyl ammonium chloride, octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride and ethylene glycol APEO 200, triethylene-glycol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 3
| Component | Mass percent % |
| Polyhexamethylene guanide | 0.1~5 |
| Hexamethylene | 0.1~5 |
| The S-EXTHIN | 1~5 |
| The trans phenothrin of rich dextrorotation | 1~5 |
| Seven fluorine methothrins | 1~5 |
| Seven fluorine methyl ethers remove permethrin | 1~5 |
| NP-10 | 15~30 |
| 1, the 2-dihydroxypropane | 5~25 |
| Trihydroxy propane | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, goes permethrin, NP-10 and 95% ethanol to mix to stir S-EXTHIN, the trans phenothrin of rich dextrorotation, seven fluorine methothrins, seven fluorine methyl ethers and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with polyhexamethylene guanide, hexamethylene and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 4
| Component | Mass percent % |
| Benzalkonium bromide | 0.1~5 |
| Benzalkonium chloride | 0.1~5 |
| The tetrafluoro phenothrin | 1~5 |
| Seven fluorobenzene chrysanthemum esters | 1~5 |
| Seven fluorine remove first chrysanthemum ester | 1~5 |
| Seven fluorine go first to remove permethrin | 1~5 |
| AEO-3 | 15~30 |
| 1, the 2-dihydroxypropane | 5~25 |
| Trihydroxy propane | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, goes first chrysanthemum ester, seven fluorine to go first to go permethrin, AEO-3 and 95% ethanol to mix to stir in tetrafluoro phenothrin, seven fluorobenzene chrysanthemum esters, seven fluorine and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with benzalkonium bromide, benzalkonium chloride and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 5
| Component | Mass percent % |
| Polyhexamethylene guanide | 0.1~5 |
| Hexamethylene | 0.1~5 |
| The dodecyl dimethyl ethylbenzylammonium chloride | 0.1~5 |
| The tetrafluoro phenothrin | 0~2 |
| Transfluthrin | 0~2 |
| Seven fluorobenzene chrysanthemum esters | 0~2 |
| Seven fluorine remove permethrin | 0~3 |
| Seven fluorine remove first chrysanthemum ester | 0~3 |
| Seven fluorine go first to remove permethrin | 0~3 |
| Isomery alcohol APEO | 15~30 |
| 1, the 2-dihydroxypropane | 5~25 |
| Trihydroxy propane | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, goes permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, isomery alcohol APEO and 95% ethanol to mix to stir in tetrafluoro phenothrin, transfluthrin, seven fluorobenzene chrysanthemum esters, seven fluorine and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with hexamethylene, polyhexamethylene guanide, dodecyl dimethyl ethylbenzylammonium chloride and 1,2-dihydroxypropane, trihydroxy propane mix stirring by above-mentioned mass percent and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 6
| Component | Mass percent % |
| Benzalkonium bromide | 0.1~5 |
| Benzalkonium chloride | 0.1~5 |
| Hexamethylene | 0.1~5 |
| Polyhexamethylene guanide | 0.1~5 |
| The tetrafluoro phenothrin | 0~2 |
| Transfluthrin | 0~2 |
| Seven fluorobenzene chrysanthemum esters | 0~2 |
| The S-bioallethrin | 0~2 |
| Seven fluorine remove permethrin | 0~3 |
| Seven fluorine remove first chrysanthemum ester | 0~3 |
| Seven fluorine go first to remove permethrin | 0~3 |
| Seven fluorine methoxy chrysanthemum esters | 0~3 |
| NP-7 | 15~30 |
| Ethylene glycol APEO 400 | 5~25 |
| Triethylene-glycol | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, goes permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine methoxy chrysanthemum esters, NP-7 and 95% ethanol to mix to stir in tetrafluoro phenothrin, transfluthrin, seven fluorobenzene chrysanthemum esters, S-bioallethrin, seven fluorine and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, benzalkonium bromide, benzalkonium chloride, hexamethylene, polyhexamethylene guanide and ethylene glycol APEO 400, triethylene-glycol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 7
| Component | Mass percent % |
| Benzalkonium bromide | 0.1~5 |
| Benzalkonium chloride | 0.1~5 |
| The dodecyl dimethyl ethylbenzylammonium chloride | 0.1~5 |
| The myristyl dimethyl benzyl ammonium chloride | 0.1~5 |
| Octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride | 0.1~5 |
| The tetrafluoro phenothrin | 0~2 |
| Transfluthrin | 0~2 |
| Seven fluorobenzene chrysanthemum esters | 0~2 |
| The S-bioallethrin | 0~2 |
| The Es-EXTHIN | 0~2 |
| Seven fluorine remove permethrin | 0~3 |
| Seven fluorine remove first chrysanthemum ester | 0~3 |
| Seven fluorine go first to remove permethrin | 0~3 |
| Seven fluorine methoxy chrysanthemum esters | 0~3 |
| Seven fluorine methothrins | 0~3 |
| OP-10 | 15~30 |
| 2-ethyl-2-(methylol)-1,3 propane diols | 5~25 |
| Tetraethylene-glycol | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, goes permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methothrins, OP-10 and 95% ethanol to mix to stir in tetrafluoro phenothrin, transfluthrin, seven fluorobenzene chrysanthemum esters, S-bioallethrin, Es-EXTHIN, seven fluorine and be mixed with compounding substances A in 1 hour by above-mentioned mass percent;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, benzalkonium bromide, benzalkonium chloride, dodecyl dimethyl ethylbenzylammonium chloride, myristyl dimethyl benzyl ammonium chloride, octyl group certain herbaceous plants with big flowers base alkyl dimethyl ammonium chloride and 2-ethyl-2-(methylol)-1,3 propane diols, tetraethylene-glycol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 8
| Component | Mass percent % |
| The dodecyl dimethyl ethylbenzylammonium chloride | 1~6 |
| Seven fluorobenzene chrysanthemum esters | 1~8 |
| Seven fluorine methoxy chrysanthemum esters | 1~8 |
| Isomery alcohol APEO | 15~30 |
| 2-ethyl-2-(methylol)-1,3 propane diols | 15~35 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, seven fluorobenzene chrysanthemum esters, seven fluorine methoxy chrysanthemum esters, isomery alcohol APEO and 95% ethanol are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, dodecyl dimethyl ethylbenzylammonium chloride and 2-ethyl-2-(methylol)-1,3 propane diols are mixed with the water of above-mentioned mass percent remaining 50% to stir by above-mentioned mass percent be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 9
| Component | Mass percent % |
| Hexamethylene | 1~6 |
| Seven fluorobenzene chrysanthemum esters | 1~8 |
| Seven fluorine methoxy chrysanthemum esters | 1~8 |
| Isomery alcohol APEO | 15~30 |
| 2-ethyl-2-(methylol)-1,3 propane diols | 15~35 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, seven fluorobenzene chrysanthemum esters, seven fluorine methoxy chrysanthemum esters, isomery alcohol APEO and 95% ethanol are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, hexamethylene and 2-ethyl-2-(methylol)-1,3 propane diols are mixed with the water of above-mentioned mass percent remaining 50% to stir by above-mentioned mass percent be mixed with compounding substances C in 1 hour;
4, said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
The present invention does further elaboration through above embodiment, but does not limit the scope of the invention.
The present invention is with the various variations of described scope of soverlay technique scheme and claim scope; Under the prerequisite that does not depart from technical scheme of the present invention, any improvement that those skilled in the art that the present invention did are realized easily all belongs to the present invention's scope required for protection.
Claims (10)
1. be used for sealed container control pest multipotency Alevaire, it is characterized in that comprising following component by mass percent:
。
2. the sealed container control pest multipotency Alevaire that is used for as claimed in claim 1; It is characterized in that described disinfection composition is selected from: the mixture of one or more of quaternary ammonium compound, guanidine compound, quaternary ammonium compound comprise one or more mixture of benzalkonium bromide, benzalkonium chloride, n-zephiran, n-alkyl dimethyl ethylbenzylammonium chloride and two n-zephirans; Guanidine compound comprises polyhexamethylene guanide, poly hexamethylene biguanide, gather and encircle guanidine, gather one or more the mixture in [2-(2-ethyoxyl)-ethyoxyl second fat] guanidine; Or one or more mixture of above-mentioned each guanidine compound pharmaceutically acceptable salt (wherein the n in the n-zephiran is 8 ~ 18; N in two n-alkyl-dimethyl ammonium chlorides is 8 ~ 14, and the n in the n-alkyl dimethyl ethylbenzylammonium chloride is 12 ~ 18).
3. the sealed container control pest multipotency Alevaire that is used for as claimed in claim 1 is characterized in that described Pesticidal combination is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
4. the sealed container control pest multipotency Alevaire that is used for as claimed in claim 1 is characterized in that described novel mouse-killing composition is selected from: seven fluorine methothrins, seven fluorine methyl ethers go permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to remove one or more the mixture in the permethrin etc.
5. the sealed container control pest multipotency Alevaire that is used for as claimed in claim 1; It is characterized in that described surfactant is selected from: (TX/NP)-one or more mixture in n, OP-10, AEO-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc., wherein the n among (TX/NP)-n is 3,4; 6; 7,10,15; N among the AEO-n is 3 or 9.
6. the sealed container control pest multipotency Alevaire that is used for as claimed in claim 1; It is characterized in that described Alevaire is selected from: ethylene glycol APEO, 1; The mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
7. the sealed container control pest multipotency Alevaire that is used for as claimed in claim 1 is characterized in that described cosolvent is selected from: 95% ethanol.
8. the sealed container control pest multipotency Alevaire that is used for as claimed in claim 1 is characterized in that described water is: deionized water.
9. like the described arbitrary preparation that is used for sealed container control pest multipotency Alevaire of claim 1-8, it is characterized in that: Pesticidal combination, novel mouse-killing composition, surfactant and cosolvent are mixed to stir being mixed with compounding substances A in 1 hour by above-mentioned mass percent; Said mixture matter A is mixed stirring be mixed with compounding substances B in 1 hour with the water of above-mentioned mass percent 50%; Disinfection composition and Alevaire mixed with the water of above-mentioned mass percent remaining 50% to stir by above-mentioned mass percent be mixed with compounding substances C in 1 hour; Said mixture matter B and said mixture matter C are mixed stirring 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
10. like the described arbitrary application that is used for sealed container control pest multipotency Alevaire of claim 1-8; It is characterized in that: be applied to disinfection, the desinsection in sealed container space and PCO such as kill mouse through multi-functional atomizer and Portable atomizer, can effectively prevent and pests such as pathogenic microbe killing, mosquitos and flies, cockroach, mouse.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011101277395A CN102334502A (en) | 2011-05-18 | 2011-05-18 | Preparation and application of multifunctional atomization agent for controlling pests in sealed container |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103210950A (en) * | 2013-04-26 | 2013-07-24 | 王福建 | Disinfection and pest-killing mixture |
| CN103285415A (en) * | 2012-02-23 | 2013-09-11 | 朱启亮 | Method for clearing peculiar smell and pollutants in car |
| CN103767079A (en) * | 2014-01-21 | 2014-05-07 | 深圳市凯神科技股份有限公司 | Electronic cigarette oil solvent |
| CN106879621A (en) * | 2017-03-24 | 2017-06-23 | 五赫兹（厦门）医疗用品有限公司 | A kind of composite disinfectant of long-acting high security |
| CN107899386A (en) * | 2017-10-31 | 2018-04-13 | 茂名清华创富环保有限公司 | A kind of Indoor Air Pollution Purification method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102210300A (en) * | 2011-05-15 | 2011-10-12 | 覃终 | Preparation and application of multifunctional atomizing agent for preventing and controlling pests of inspection and quarantine system |
| CN102334501A (en) * | 2011-05-17 | 2012-02-01 | 覃终 | Preparation and application of multifunctional atomization agent for controlling pests |
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2011
- 2011-05-18 CN CN2011101277395A patent/CN102334502A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102210300A (en) * | 2011-05-15 | 2011-10-12 | 覃终 | Preparation and application of multifunctional atomizing agent for preventing and controlling pests of inspection and quarantine system |
| CN102334501A (en) * | 2011-05-17 | 2012-02-01 | 覃终 | Preparation and application of multifunctional atomization agent for controlling pests |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103285415A (en) * | 2012-02-23 | 2013-09-11 | 朱启亮 | Method for clearing peculiar smell and pollutants in car |
| CN103210950A (en) * | 2013-04-26 | 2013-07-24 | 王福建 | Disinfection and pest-killing mixture |
| CN103210950B (en) * | 2013-04-26 | 2014-03-26 | 王福建 | Disinfection and pest-killing mixture |
| CN103767079A (en) * | 2014-01-21 | 2014-05-07 | 深圳市凯神科技股份有限公司 | Electronic cigarette oil solvent |
| CN106879621A (en) * | 2017-03-24 | 2017-06-23 | 五赫兹（厦门）医疗用品有限公司 | A kind of composite disinfectant of long-acting high security |
| CN106879621B (en) * | 2017-03-24 | 2020-01-31 | 五赫兹（厦门）医疗用品有限公司 | long-acting high-safety composite disinfectant |
| CN107899386A (en) * | 2017-10-31 | 2018-04-13 | 茂名清华创富环保有限公司 | A kind of Indoor Air Pollution Purification method |
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Application publication date: 20120201 |