CN102308845A - Preparation and applications of atomizing agent with pesticide and deratization functions - Google Patents
Preparation and applications of atomizing agent with pesticide and deratization functions Download PDFInfo
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- CN102308845A CN102308845A CN201110132173A CN201110132173A CN102308845A CN 102308845 A CN102308845 A CN 102308845A CN 201110132173 A CN201110132173 A CN 201110132173A CN 201110132173 A CN201110132173 A CN 201110132173A CN 102308845 A CN102308845 A CN 102308845A
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Abstract
The invention relates to preparation and applications of an atomizing agent with pesticide and deratization functions. The atomizing agent comprises the following components in percentage by weight: 0.1-15% of pesticidal composition, 0.1-15% of novel deratization composition, 10-40% of surface active agent, 1%-40% of atomizing agent, 1-10% of cosolvent and the balance of water. The atomizing agent provided by the invention has the characteristics that the atomizing agent is harmless to human and animals, can not generate harmful substances, can not pollute the environment, and is safe and environmentally-friendly, has no irritation to skin mucous membrane, has no corrosiveness to particles and fabrics, has no irritating smell, is colorless, is not influenced by the environment, organic matters, acid, alkali, and other physical and chemical factors, has long durability and low cost, and the like.
Description
Technical field
The invention belongs to desinsection and kill mouse product scope; Relate to a kind of the have desinsection and the function Alevaire that kills mouse, wherein contain of preparation and the application of the composition of Pesticidal combination, novel mouse-killing composition, surfactant, Alevaire, cosolvent as control pest multipotency Alevaire.
Background technology
For a long time, extensively adopt at the desinsection and the product scope that kills mouse always and mostly be contact insecticide, fumigant and the anticoagulation bait formulation etc. that kills mouse.
Mostly contact insecticide is the pyrethroid medicament, like Permanone, tetramethrin, decis, flucythrinate, cypermethrin etc.
Permanone has stronger tagging and stomach poison function, has that the power of knocking down is strong, the fireballing characteristics of desinsection.More stable to light, also slower to the pest resistance development under equal service condition, efficient to lepidopterous larvae.Can be used for various pests such as crop control cabbage caterpillar, aphid, cotton bollworm, pink bollworm, cotten aphid, green plant bug, striped flea-beetle, peach fruit borer, phyllocnistis citrella stainton, potato ladybug, tea geometrid, tea caterpillar, the thin moth of tea such as vegetables, tealeaves, fruit tree, cotton, sanitary insect pests such as mosquito, fly, flea, cockroach, louse are also had good effect.
Tetramethrin is a kind of powerful synthetic pesticide, and sanitary insect pests such as mosquito, fly are had quick down effect, but the poor performance that causes death has anabiosis, and use therefore will be mixed with the medicament of other good disinsection effect.This medicine has certain effect of driveing to blattaria, perch is run out under the effect of blattaria at tetramethrin at dark place and receives the poisoning of other insecticides and causes death.This medicine is that world health organisation recommendations is used for one of sanitarian main insecticide, but result of use is not obvious separately.
Decis has another name called " decis ", is the highest a kind of of virulence in the present chrysanthemum ester insecticide.Insecticidal spectrum is wide; Effective to various pests such as Lepidoptera, orthoptera, thrips, Semiptera, diptera, coleopteras, but very low or invalid basically to preventive effects such as mite class, scale insect, mirid pentatomids, also can stimulate the breeding of mite class; When the worm mite is concurrent, use with specialized acaricide.Decis belongs to the poison class of poisoning.The skin contact can cause irritation, red papule occurs.During acute poisoning, the lighter has headache, dizziness, feels sick, vomiting, poor appetite, weak, and weight person muscle bundle also can occur and tremble and twitch, and the WHO hazard rating is the II level, medium harmfulness.
Flucythrinate is claimed flucythrinate again, belongs to pyrethrin pesticide, is the moderate toxicity insecticide, the mode of action with tag, stomach toxicity is main, do not have stifling and systemic action, insecticidal spectrum is wide, drug effect is rapid.Can use with general insecticide, bactericide, its biologically active is lower than by Influence of Temperature and kills chrysanthemum ester and chlorobenzene chrysanthemum ester, and the WHO hazard rating is the II level, medium harmfulness.
Cypermethrin is claimed struggle again, belongs to the chrysanthemum esters medicine, is the moderate toxicity insecticide, and insecticidal spectrum is wide, and drug effect is rapid, and the WHO hazard rating is the II level, medium harmfulness.
The long-term use of above-mentioned pyrethroid medicament makes sanitary insect pest such as insects such as cockroach, mosquitos and flies improve greatly the pesticide resistance of this type of medicament, has occurred the problem that control efficiency generally reduces in recent years.
Mostly fumigant is Celfume and vikane.
Celfume is a kind of liquid of colorless and odorless; It has strong fumigation action, can be efficient, kill various pests wide spectrum, soil is had very strong penetration capacity; Can be penetrated in the organism that rots to decompose, thereby reach the purpose of deinsectization, diseases prevention, weeding.Along with closing on of World Earth Day, this methyl bromide fumigation agent that is widely used has caused global concern.Since the forties in 20th century, just be widely used by various countries always.Because it has plurality of advantages, thereby very popular; Caused many environment and soil issues because of it again, thus controversial.Rise the nineties in 20th century; Countries in the world government all is tending towards stopping using this fumigant from security consideration; Also halted by United Nations Environment Programme for the previous period, it is a kind of material of ozone layer depletion, according to " Montreal Protocol Copenhagen amendment "; Developed country eliminated in 2005, and developing country also will eliminate in 2015.
Vikane is no color or smell gas at normal temperatures and pressures; Have that diffusion permeability is strong, broad spectrum disinfestation, dosage are economized, residual quantity is low, desinsection speed fast, the gas time of loosing is short, low temperature is easy to use, to germination rate characteristics such as influence and toxicity is not lower, be applied to the survive the winter control of insect, the tree moth dryness insect that lives of warehouse, freighter, container and building, reservoir dam, termite control and gardens more and more widely.China has just begun to manufacture experimently vikane the beginning of the eighties.But U.S.'s scientist's current research shows, can become a kind of strong effect greenhouse gases after being dispersed into air, and it endangers greater than the previous judgement of scientist, and its acute toxic action mainly damages central nervous system, causes convulsions.Environment there is harm, can pollutes water body.It is reported that it is 4800 times of one kilogram of carbonic acid gas that one kilogram of vikane is discharged in the atmosphere effect to global warming, but it is increasing with annual 5% speed.
Anticoagulation kill mouse bait formulation be mostly diphacinone-Na, Bromadiolone, kill its battle, big grand etc.
Diphacinone-Na is claimed Diphacinone again, is mainly used in ground such as urban and rural residents' dwelling house, grain depot, factory, car, ship, harbour and kills home mouse, also can be used for dry land, paddy field, forest zone, grassland and kill field rodent, but effect slowly.
The High Effect Raticide that Bromadiolone is a kind of good palatability, toxicity is big, the target spectrum is wide; It not only possess first generation anticoagulations such as diphacinone-Na, coumatetralyl kill mouse the bait formulation effect slowly, be difficult for causing that muroid realizes, annihilates easily the characteristics of bandicoot in surperise; But also having the strong outstanding advantage of acute toxicity, single dose uses and can both prevent and kill off effectively various mouse.Simultaneously, it can also be killed effectively the first generation anticoagulation bait formulation that kills mouse is produced the bandicoot of resistance.Aquatiles such as fish, aquatic insect there is moderate toxicity.These article are high toxin preparation, and eye is had excitant, flammable.
Killing its battle is novel second generation anticoagulant property rodenticide, its unique formula, and palatability is good, is easy to mouse and gets food rapidly.Unique particle poison bait can accurately be controlled consumption, cuts the waste, and can not produce secondary poisoning, to people and Environmental security.
Big swelling claims that again the bromo biphenyl mouse is grand, and pure article are yellow-white or pale powder, and are water insoluble; Dissolve in ethanol, acetone etc.; To severe toxicity such as domestic animal, poultry, fish there is little poison, be second generation anti-coagulant rodenticide; Be a kind of of present anticoagulant toxic maximum, have the two-fold advantage of acute and chronic rodenticide.Good palatability can not produce the food refusal effect, can kill the muroid that first generation anticoagulation rodenticide is produced resistance.
But in use there is following shortcoming:
1, rat-bane is the bait formulation preparation, and directly dispenser is sprayed, and has limited range of application;
2, strong toxicity has harmfulness to other animal;
3, bait formulation formulation products, contaminated environment is eaten by mistake easily;
4, make muroid that pesticide resistance arranged for a long time, influence killing effect.
Summary of the invention
The objective of the invention is to have desinsection and the function Alevaire that kills mouse to the various drawbacks of PCO medicaments such as existing insecticide, rat-bane with for the technical problem that exists in the solution known technology provides a kind of; Especially the composition with Pesticidal combination, novel mouse-killing composition, surfactant, Alevaire, cosolvent has desinsection and the preparation and the application of the function Alevaire that kills mouse as a kind of, and it has characteristics such as safety, efficient, wide spectrum, convenient, low toxicity, environmental protection.
One of the object of the invention provides a kind of the have desinsection and the function Alevaire that kills mouse; Especially a kind of composition with Pesticidal combination, novel rat-bane, surfactant, Alevaire, cosolvent is as a kind of preparation that has desinsection and kill mouse the function Alevaire, and of the present invention a kind ofly have desinsection and contain following component by mass percent with the function Alevaire that kills mouse:
| Component | Mass percent % |
| Pesticidal combination | 0.1~15 |
| Novel mouse-killing composition | 0.1~15 |
| Surfactant | 10~40 |
| Alevaire | 1~40 |
| Cosolvent | 1~10 |
| Water | Surplus |
Pesticidal combination described in the component is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
Es-EXTHIN wherein, chemical name: dextrorotation-trans-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid-(R, S)-2-methyl-3-pi-allyl-4-oxo-ring penta-2-alkenyl esters, molecular formula: C
19H
26O
3, molecular weight: 302.41, be the former medicine of a kind of wide spectrum pyrethroid, for upsetting the contact killing type never poison of aixs cylinder conduction; Act on insect and cause the violent paralysis effect of ordering, reclining falls, and until death, very strong tagging and repellent action is arranged; The power of knocking down is stronger, and it is strong 2 times that its insecticidal toxicity is executed allethrin than the right side, and knocks down the active tetramethrin that surpasses; Mainly be used for preventing and treating flying pests such as mosquito, fly, mosquito, fly, wasp, cockroach, flea, ant are had special effect, structural formula is following:
S-bioallethrin wherein, chemical name: (1R)-trans-chrysanthemate-(S)-and 2-methyl-3-pi-allyl-4-oxo-ring penta-2-alkenyl esters, molecular formula: C
19H
26O
3, molecular weight: 302.41, be a kind of wide spectrum pyrethroid insecticides, very strong tagging and repellent action arranged, the power of knocking down is stronger, and insecticidal toxicity is 4.9 times of allethrin, and structural formula is following:
。
The trans phenothrin of wherein rich dextrorotation is claimed d-phenothrin again, chemical name: (1R)-trans-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic)-cyclopropane-carboxylic acid-3-phenoxy benzyl ester, molecular formula: C
23H
26O
3, molecular weight: 350.45, these article are unique nontoxic products in the pyrethroid, are that the unique allowance of the U.S. is used for the insecticide that civil aviaton uses, and are one of insecticides of world health organisation recommendations.These article have for insect tags and stomach poison function, and insecticidal spectrum is wide, high 8.5 ~ 20 times than the Dalmatian chrysanthemum class to the deadly power of insect, can be widely used in the control of household, warehousing, public health, industrial area insect.
Tetrafluoro methothrin wherein, chemical name: 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid 2,3,5,6-tetrafluoro-4-(methoxy) benzyl ester, molecular formula: C
19H
22F
4O
3, molecular weight: the 374.37th, suck and the contact killing type insecticide agent, knock down and kill activity to what sanitary insect pests such as mosquito, fly had a brilliance.In the experimental concentration scope; The acute toxicity and chronic toxicity of tetrafluoro methothrin is extremely low, and teratogenesis, carcinogenic do not observe, to Aedes aegypti, housefly, Groton bug, that a curtain casemaking clothes moth is knocked down speed is fast; Consumption is little; Be suitable for the hygienic biocide goods, belong to broad spectrum pesticide, ability effectively preventing sanitary insect pest and storage insect; Dipteral insect such as mosquito class there are quick knockdown effect, and cockroach, bedbug are had good residual effect.
Transfluthrin wherein, chemical name: 2,3,5, the 6-ptfe benzyl (1R, 3S)-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
15H
12Cl
2F
4O
2, molecular weight: 371.16, this article desinsection wide spectrum, ability effectively preventing sanitary insect pest and storage insect; Dipteral insect such as mosquito class there are quick knockdown effect, and cockroach, bedbug are had good residual effect.
Seven fluorobenzene chrysanthemum esters wherein.Chemical name: 2,3,5,6-tetrafluoro-4-methyl-benzyl (Z)-(1RS, 3RS)-3-(2-chloro-2,3,3-trifluoropropyl-1-thiazolinyl)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
17H
14ClF
7O
2, molecular weight: 418.73, these article belong to pyrethroid insecticides, are soil insecticides, can prevent and treat coleoptera and the Lepidoptera and some Diptera pest that perch in soil well, than transfluthrin stronger killing action are arranged.
Novel mouse-killing composition described in the component is selected from: seven fluorine methothrins, seven fluorine methyl ethers go permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to remove one or more the mixture in permethrin etc.
Seven fluorine methothrins wherein, chemical name: 2,3,5,6-tetrafluoro-4-methoxyl methyl carbobenzoxy-3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
17H
15ClF
7O
3Molecular weight: the 448.6th, a type agricultural chemicals is killed in a kind of novel disappearing, and is mainly used in hygienic insecticides such as preparation aerosol and propellant, with pests such as control cockroach, mosquito, ant, flea, dirt mite, silverfish, cricket, spider, mouse; Have the very strong suction and the ability of tagging, structural formula is following:
Wherein seven fluorine methyl ethers remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxyl methyl carbobenzoxy ester, molecular formula: C
18H
17F
7O
3, molecular weight: 414.1, belong to novel disappearing and kill a type agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Wherein seven fluorine methoxies remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxy benzyl ester, molecular formula: C
17H
15F
7O
3, molecular weight: 400.1, belong to novel disappearing and kill a type agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Wherein seven fluorine remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methyl benzyl ester, molecular formula: C
17H
15F
7O
2, molecular weight: 384.1, belong to novel disappearing and kill a type agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Wherein seven fluorine go first to remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-ptfe benzyl, molecular formula: C
16H
13F
7O
2, molecular weight: 370.1, belong to novel disappearing and kill a type agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Seven fluorine methoxy chrysanthemum esters wherein, chemical name: 3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxy benzyl ester, molecular formula: C
17H
15ClF
7O
3, molecular weight: 434.6, belong to novel disappearing and kill a type agricultural chemicals, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Wherein seven fluorine remove first chrysanthemum ester, chemical name: 3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methyl benzyl ester, molecular formula: C
16H
13ClF
7O
2, molecular weight: 434.6, belong to novel pyrethroid pesticide, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Surfactant described in the component is selected from: (TX/NP)-and one or more mixture in n, OP-10, AEO-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc.
(TX/NP)-n wherein, chemical name: NPE, have been widely used at washing agent, printing and dyeing, chemical industry, good penetration, emulsification, dispersion, antiacid, alkali resistant, anti-hard water, anti-reduction, oxidation resistance are arranged; (TX/NP)-n among the n is 3,4,6; 7,10,15..
OP-10 wherein; Chemical name: APES; Main with the emulsifier on the used as pesticides, also be the good finishing agent of textile industry, antifoaming agent, washing agent, dispersant, emulsifier, softening agent, dyeing assistant, fibre finishing, crude oil demulsifier etc.
AEO-n wherein, chemical name: AEO, chemical composition: natural fatty alcohol and oxirane synthetic; Wherein the n among the AEO-n is 3 or 9; AEO-3 can make water-in-oil emulsifier, and AEO-9 is mainly used in Wool detergent, woolen industry degreasing agent, and general industry is used emulsifier.
Isomery alcohol APEO wherein, chemical composition: isomery alcohol and polymers of ethylene oxide belong to nonionic surface active agent; Structural formula: RO-(C2H4O) n H: (general R is C8, C11, C13); Performance: these article are colourless or weak yellow liquid, and emulsifying capacity is strong, and surface-active is high; Anti-hard water, the washing performance is strong, and chemical stability and Environmental compatibility are good in the pH value scope of broad.Can be used as dispersant, wetting agent, bleeding agent, washing agent, be widely used in family expenses and industrial washing field, leather is had tangible degreasing; Be specially adapted to do emulsifier, better performances.
Wherein isomery alcohol polyoxyethylene poly-oxygen propylene aether is to react in proportion with oxirane, expoxy propane with isomery alcohol to form, and is one and has 100% biodegradable novel, low bubble, efficient, environment-friendly type non-ionic surface active agent.Good, acidproof, alkaline-resisting, anti-oxidant with various surfactants, auxiliary agent, additive, solvent compatibility.Characteristics: have excellent emulsification, dispersibility; Have excellent permeation property and alkali tolerance; Have excellent washing, dirt-removing power; Extremely low foam belongs to ultralow bubble interfacial agent, does not use antifoaming agent, does not therefore have silicon spot problem; Nontoxic, non-stimulated, free from extraneous odour, nonflammable explosive, safe in utilization.
Alevaire described in the component is selected from: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.
Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.It has passed through the U.S. FDA authentication, meets American Pharmacopeia (USP), NF (NF), and Food Chemistry code (FCC) standard is widely used in the production of industries such as food, pharmacy, feed, personal care articles, chemistry.It is the water white transparency thick liquid, and it is sweet to distinguish the flavor of, and has hygroscopicity, and is miscible with water, lower aliphatic alcohols, glycerine, acetic acid, acetone, can be used as solvent, dispersant, lubricant, emulsifier etc. and is used for cosmetics, agricultural chemicals, food, medicine and other fields.
Wherein 1; The 2-dihydroxypropane is the stable water imbibition liquid of colourless thickness, and almost tasteless odorless is with water, ethanol and multiple immiscible organic solvent; As gas-chromatography fixer, solvent, antifreeze, plasticizer, dehydrating agent, carrier solvent, wetting agent, NMF, anticaking agent, antioxidant, surface-active, stabilizing agent, thickener, emulsifier, processing aid; It classifies food processing aid as among the GB 2760-96, and its aqueous solution is effective antifreeze, can be used as NMF in the cosmetics; Softening agent, solvent etc.
Wherein trihydroxy propane outward appearance is the water white transparency thick liquid; Odorless, tasteless, have hygroscopicity, humectation property, a property of softening; It is neutral that the aqueous solution is; Can mix arbitrarily with water, ethanol, methyl alcohol, have good freeze-proof, be widely used in industries such as weaving, printing and dyeing, papermaking, printing, washing agent, daily use chemicals, system wine, food, cigarette, glassine paper, enamel, oil, electronics, rubber, plastics, process hides, chemistry, chemical fibre.Main as NMF, humectant, hygroscopic agent, lubricant, softening agent, softening agent, thickener, plasticizer, thinner, antifreezing agent etc.
Wherein the triethylene-glycol outward appearance is that no color or smell has the hygroscopicity thick liquid, can be miscible with water, ethanol, benzene, toluene, be insoluble in ethers, and be insoluble to benzinum, have hygroscopicity, have the character of pure and mild ether.As solvent, extractant, desiccant, air disinfection agent etc.The toxicity data are little poison, LD
50(rat oral) 16.8ml/kg. is to eyes and skin nonirritant.
Cosolvent described in the component is selected from: 95% ethanol.
Water described in the component is: deionized water.
Each component is role in the present invention:
Pesticidal combination described in the component for sucking and the contact killing type insecticide agent, has and knocks down fast and the quick-acting lethal effects of killing, and to mucocutaneous nonirritant, to metal and fabric non-corrosiveness, receives organic substance influence slight, good stability;
Thanks rat-bane described in the component,, have and knock down fast and the quick-acting lethal effects of killing, metal and fabric are not had corrosion, good stability for sucking and the preparation of tagging;
Surfactant described in the component plays emulsification, dissolved constituent;
Alevaire described in the component plays good dispersion, atomizing, synergy and antifreeze effect, to mucocutaneous non-stimulated, good stability is harmless to article, to metal and fabric non-corrosiveness;
Cosolvent described in the component plays dissolving and antifreeze effect, plays synergistic effect simultaneously.
The present invention has the desinsection and the most preferably proportioning of following mass percent of function Alevaire that kills mouse:
| ?Component | Mass percent % |
| Pesticidal combination | 1~10 |
| Novel mouse-killing composition | 1~10 |
| Surfactant | 15~35 |
| Alevaire | 5~35 |
| Cosolvent | 2~8 |
| Water | Surplus |
Pesticidal combination described in the component is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
Novel mouse-killing composition described in the component is selected from: seven fluorine methothrins, seven fluorine methyl ethers go permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to remove permethrin, the mixture of one or more in the tefluthrin etc. partially.
Surfactant described in the component is selected from: (TX/NP)-one or more mixture in n, OP-10, AEO-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc., wherein the n among (TX/NP)-n is 3,4; 6; 7,10,15; N among the AEO-n is 3 or 9.
Alevaire described in the component is: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
Cosolvent described in the component is selected from: 95% ethanol.
Water described in the component is: deionized water.
Another object of the present invention is; Provide a kind of and have desinsection and kill mouse the compound method of function Alevaire, it mainly be adopt Pesticidal combination, novel mouse-killing composition, surfactant, Alevaire, cosolvent and water through mix, reaction, stir, leave standstill and be prepared from:
Above-mentioned contain the mass percent component to have a desinsection following with the compound method of function multipotency Alevaire of killing mouse:
1, Pesticidal combination and surfactant were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, novel mouse-killing composition and cosolvent were mixed with compounding substances B in 1 hour by above-mentioned mass percent mixing stirring;
3, said mixture matter A, said mixture matter B are mixed stirring 1 hour with the Alevaire and the water of above-mentioned mass percent, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
The object of the invention also comprises provides above-mentioned application with the desinsection and the function Alevaire that kills mouse:
1, through multi-functional atomizer (patent No.: 201020662097.X) with the Portable Alevaire (patent No.: 201020682031.7) be applied to public health field, food processing field and medicine and hygiene fields environment and air desinsection and kill mouse, can effectively prevent and kill pests such as mosquitos and flies, cockroach, mouse;
2, through multi-functional atomizer (patent No.: 201020662097.X) with the Portable Alevaire (patent No.: 201020682031.7) be applied to the inspection and quarantine system internal container, railway carriage, cabin, aircraft passenger compartment, aircraft hold, automotive interior air and environment desinsection and kill mouse, can effectively prevent and kill pests such as mosquitos and flies, cockroach, mouse;
3, through the multi-functional atomizer (patent No.: 201020662097.X) with the Portable Alevaire (patent No.: 201020682031.7) be applied to the desinsection of the environment in livestock and poultry cultivation field, indoor and air and killing mouse, can effectively prevent and kill pests such as mosquitos and flies, cockroach, mouse.
Of the present invention have desinsection and each component of the function Alevaire that kills mouse between combination matching have the effect of Synergistic, and have following advantage and good effect:
1, harmless to people, animal, can not produce harmful substance, do not pollute the environment safety and environmental protection;
2, non-stimulated to skin and mucosa, article and fabric there are not corrosivity;
3, have no irritating odor, colourless, do not receive the influence of environment, organic matter, acid, alkali and other physics, chemical factor.
Have the desinsection and an experimental study that function Alevaire product carries out that kills mouse to according to the invention:
The Pesticidal combination of experimental example 1 said component and the lethality rate of one-component insecticide contrast (cooperative synergism effect experiment):
1, the prescription of one-component insecticide described in the component and component Pesticidal combination is formed:
| Component | Prescription |
| A | Be the Es-EXTHIN |
| B | Be the trans phenothrin of rich dextrorotation |
| A+B | The combination of consumption (or content) separately separately for A and B |
2, result of the test:
| Component | To American cockroach 24H lethality rate |
| A | ＞ 70% |
| B | ＞ 70% |
| A+B | ＞ 95% |
Investigate by above-mentioned experimental technique; When Pesticidal combination that will be wherein is selected from one or more the mixture in the S-bioallethrin except that the Es-EXTHIN, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.; Also obtained effect like the same Synergistic of experimental example 1 (cooperative synergism effect experiment); Promptly ideal with the desinsection of A+B; Simultaneously; The combining form of the A+B of described product is being investigated killing in the process American cockroach, mosquitos and flies etc.; The killing effect that has equally also shown the good Synergistic of A+B combination, special feature promptly of the present invention be, the Pesticidal combination in the component by one or more the mixture combination in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc. after; It has the outstanding activity of killing, and this activity is to be predicted out by the killing action of known single component.
The novel mouse-killing composition of experimental example 2 said components and the lethality rate of one-component insecticide contrast (cooperative synergism effect experiment):
1, the prescription of the mouse-killing composition of one-component rat-bane described in the component and component is formed:
| Component | Prescription |
| A | Be seven fluorine methothrins |
| B | Be that seven fluorine methyl ethers remove permethrin |
| A+B | The combination of consumption (or content) separately separately for A and B |
3, result of the test:
| Component | To home mouse 24H lethality rate |
| A | ＞ 70% |
| B | ＞ 70% |
| A+B | ＞ 95% |
Investigate by above-mentioned experimental technique; When disinfestation and deratization agent that will be wherein is selected from the seven fluorine methoxy chrysanthemum esters, the seven fluorine methoxies that go except that seven fluorine methothrins, seven fluorine methyl ethers the permethrin and goes permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to remove one or more the mixture in the permethrin etc.; Also obtained effect like the same Synergistic of experimental example 1 (cooperative synergism effect experiment); Promptly ideal with killing mouse of A+B; Simultaneously; The combining form of the A+B of described product is being investigated killing in the process home mouse; The killing effect that has equally also shown the good Synergistic of A+B combination, special feature promptly of the present invention be, after the novel mouse-killing composition in the component goes permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to go one or more the mixture Pesticidal combination combination in the permethrin etc. by seven fluorine methothrins, seven fluorine methyl ethers; It has the outstanding activity of killing, and this activity is to be predicted out by the killing action of known single component.
The killing effect of 3 pairs of American cockroaches of experimental example, culex, housefly, mouse:
Test Example 4 certain port container (volume: 33.2m3) to the on-the-spot killing effect of American cockroach, culex, housefly:
Embodiment
Embodiment 1
| Component | Mass percent % |
| The Es-EXTHIN | 1~5 |
| The trans phenothrin of rich dextrorotation | 1~5 |
| Seven fluorine methothrins | 1~5 |
| OP-10 | 15~30 |
| 1, the 2-dihydroxypropane | 5~25 |
| Trihydroxy propane | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, Es-EXTHIN, the trans phenothrin of rich dextrorotation and OP-10 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, seven fluorine methothrins and 95% ethanol were mixed with compounding substances B in 1 hour by above-mentioned mass percent mixing stirring;
3, with 1 of said mixture matter A, said mixture matter B and above-mentioned mass percent; 2-dihydroxypropane, trihydroxy propane and water mix stirring 1 hour, leave standstill 1 hour again, and mixed mixture is carried out assay; Qualified mixture is packed, be qualified products.
Embodiment 2
| Component | Mass percent % |
| The Es-EXTHIN | 1~5 |
| The trans phenothrin of rich dextrorotation | 1~5 |
| Seven fluorine methoxy chrysanthemum esters | 1~5 |
| TX-10 | 15~30 |
| 1, the 2-dihydroxypropane | 5~25 |
| Trihydroxy propane | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, Es-EXTHIN, the trans phenothrin of rich dextrorotation and TX-10 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, seven fluorine methoxy chrysanthemum esters and 95% ethanol were mixed with compounding substances B in 1 hour by above-mentioned mass percent mixing stirring;
3, with 1 of said mixture matter A, said mixture matter B and above-mentioned mass percent; 2-dihydroxypropane, trihydroxy propane and water mix stirring 1 hour, leave standstill 1 hour again, and mixed mixture is carried out assay; Qualified mixture is packed, be qualified products.
Embodiment 3
| Component | Mass percent % |
| Seven fluorine methyl ethers remove permethrin | 1~5 |
| Seven fluorobenzene chrysanthemum esters | 1~5 |
| Seven fluorine methothrins | 1~5 |
| NP-10 | 15~30 |
| Ethylene glycol APEO 200 | 5~25 |
| Triethylene-glycol | 5~25 |
| 95% ethanol | 3~6 |
| Water | Surplus |
1, seven fluorobenzene chrysanthemum esters and NP-10 were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, go permethrin and 95% ethanol to mix to stir seven fluorine methothrins, seven fluorine methyl ethers and be mixed with compounding substances B in 1 hour by above-mentioned mass percent;
3, said mixture matter A, said mixture matter B are mixed stirring 1 hour with triethylene-glycol, ethylene glycol APEO 200 and the water of above-mentioned mass percent; Left standstill again 1 hour; Mixed mixture is carried out assay; Qualified mixture is packed, be qualified products.
Embodiment 4
| Component | Mass percent % |
| The tetrafluoro methothrin | 1~5 |
| Seven fluorobenzene chrysanthemum esters | 1~5 |
| The S-bioallethrin | 1~5 |
| Seven fluorine methothrins | 1~5 |
| Seven fluorine remove permethrin | 1~5 |
| Isomery alcohol APEO | 15~30 |
| Ethylene glycol APEO 200 | 5~25 |
| Triethylene-glycol | 5~25 |
| 95% ethanol | 3~6 |
| Water | Surplus |
1, tetrafluoro methothrin, seven fluorobenzene chrysanthemum esters, S-bioallethrin and isomery alcohol APEO are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, go permethrin and 95% ethanol to mix to stir in seven fluorine methothrins, seven fluorine and be mixed with compounding substances B in 1 hour by above-mentioned mass percent;
3, said mixture matter A, said mixture matter B are mixed stirring 1 hour with triethylene-glycol, ethylene glycol APEO 200 and the water of above-mentioned mass percent; Left standstill again 1 hour; Mixed mixture is carried out assay; Qualified mixture is packed, be qualified products.
Embodiment 5
| Component | Mass percent % |
| The tetrafluoro methothrin | 1~5 |
| Seven fluorine methoxy chrysanthemum esters | 1~5 |
| TX-7 | 15~30 |
| 1, the 2-dihydroxypropane | 5~30 |
| 95% ethanol | 4~7 |
| Water | Surplus |
1, tetrafluoro methothrin and TX-7 were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, seven fluorine methoxy chrysanthemum esters and 95% ethanol were mixed with compounding substances B in 1 hour by above-mentioned mass percent mixing stirring;
3, with 1 of said mixture matter A, said mixture matter B and above-mentioned mass percent; 2-dihydroxypropane and water mix stirring 1 hour, leave standstill 1 hour again, and mixed mixture is carried out assay; Qualified mixture is packed, be qualified products.
Embodiment 6
| Component | Mass percent % |
| The trans phenothrin of rich dextrorotation | 1~5 |
| Seven fluorine go first to remove permethrin | 1~5 |
| AEO-3 | 15~30 |
| Trihydroxy propane | 5~30 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, trans phenothrin of rich dextrorotation and AEO-3 were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, go first to go permethrin and 95% ethanol to mix to stir in seven fluorine and be mixed with compounding substances B in 1 hour by above-mentioned mass percent;
3, said mixture matter A, said mixture matter B are mixed stirring 1 hour with the trihydroxy propane and the water of above-mentioned mass percent; Left standstill again 1 hour; Mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 7
| Component | Mass percent % |
| Seven fluorobenzene chrysanthemum esters | 1~5 |
| Seven fluorine remove first chrysanthemum ester | 1~5 |
| OP-10 | 15~30 |
| Ethylene glycol APEO 200 | 5~25 |
| Triethylene-glycol | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, seven fluorobenzene chrysanthemum esters and OP-10 were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, go first chrysanthemum ester to mix stirring with the above-mentioned mass percent of 95% ethanol in seven fluorine and be mixed with compounding substances B in 1 hour;
3, said mixture matter A, said mixture matter B are mixed stirring 1 hour with ethylene glycol APEO 200, triethylene-glycol and the water of above-mentioned mass percent; Left standstill again 1 hour; Mixed mixture is carried out assay; Qualified mixture is packed, be qualified products.
Embodiment 8
| Component | Mass percent % |
| Seven fluorobenzene chrysanthemum esters | 1~5 |
| Seven fluorine remove permethrin | 1~5 |
| NP-10 | 10~20 |
| OP-10 | 10~20 |
| Ethylene glycol APEO 400 | 5~25 |
| Triethylene-glycol | 5~25 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, seven fluorobenzene chrysanthemum esters and NP-10, OP-10 were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, go permethrin and 95% ethanol to mix to stir in seven fluorine and be mixed with compounding substances B in 1 hour by above-mentioned mass percent;
3, said mixture matter A, said mixture matter B are mixed stirring 1 hour with ethylene glycol APEO 400, triethylene-glycol and the water of above-mentioned mass percent; Left standstill again 1 hour; Mixed mixture is carried out assay; Qualified mixture is packed, be qualified products.
Embodiment 9
| ?Component | Mass percent % |
| The S-bioallethrin | 1~5 |
| Seven fluorine methyl ethers remove permethrin | 1~5 |
| TX-15 | 10~20 |
| AEO-3 | 10~20 |
| Triethylene-glycol | 5~30 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, S-bioallethrin and TX-15, AEO-3 were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, go permethrin and 95% ethanol to mix to stir seven fluorine methyl ethers and be mixed with compounding substances B in 1 hour by above-mentioned mass percent;
3, said mixture matter A, said mixture matter B are mixed stirring 1 hour with the triethylene-glycol and the water of above-mentioned mass percent, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
The present invention does further elaboration through above embodiment, but does not limit the scope of the invention.
The present invention is with the various variations of described scope of soverlay technique scheme and claim scope; Under the prerequisite that does not depart from technical scheme of the present invention, any improvement that those skilled in the art that the present invention did are realized easily all belongs to the present invention's scope required for protection.
Claims (10)
1. one kind has desinsection and kills mouse the function Alevaire, it is characterized in that comprising following component by mass percent:
。
2. have desinsection and kill mouse the function Alevaire like what claim 1 was told, it is characterized in that comprising following most preferably component by mass percent:
。
3. as claimed in claim 1 have desinsection and kill mouse the function Alevaire, it is characterized in that described Pesticidal combination is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
4. as claimed in claim 1 have the desinsection and a function Alevaire that kills mouse, and it is characterized in that described novel mouse-killing composition is selected from: seven fluorine methothrins, seven fluorine methyl ethers go permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to remove one or more the mixture in the permethrin etc.
5. as claimed in claim 1 have desinsection and kill mouse the function Alevaire; It is characterized in that described surfactant is selected from: (TX/NP)-one or more mixture in n, OP-10, AEO-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc., wherein the n among (TX/NP)-n is 3,4; 6; 7,10,15; N among the AEO-n is 3 or 9.
6. as claimed in claim 1 have desinsection and kill mouse the function Alevaire; It is characterized in that described Alevaire is selected from: ethylene glycol APEO, 1; The mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
7. as claimed in claim 1 have desinsection and kill mouse the function Alevaire, it is characterized in that described cosolvent is selected from: 95% ethanol.
8. as claimed in claim 1 have desinsection and kill mouse the function Alevaire, it is characterized in that described water is: deionized water.
9. one kind arbitraryly has desinsection and kills mouse the preparation of function Alevaire as claim 1-8 is described, it is characterized in that: Pesticidal combination is mixed stirring with surfactant by above-mentioned mass percent be mixed with compounding substances A in 1 hour; Novel mouse-killing composition and cosolvent were mixed with compounding substances B in 1 hour by above-mentioned mass percent mixing stirring; Said mixture matter A, said mixture matter B are mixed stirring 1 hour with the Alevaire and the water of above-mentioned mass percent, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
10.
A kind of like the described arbitrary application of claim 1-8 with the desinsection and the function Alevaire that kills mouse; It is characterized in that: be applied to through multi-functional atomizer and Portable atomizer public health field, food processing field and medicine and hygiene fields environment and air desinsection and kill mouse, can effectively prevent and kill pests such as mosquitos and flies, cockroach, mouse; Be applied to through multi-functional atomizer and Portable atomizer the inspection and quarantine system internal container, railway carriage, cabin, aircraft passenger compartment, aircraft hold, automotive interior air and environment desinsection and kill mouse, can effectively prevent and kill pests such as mosquitos and flies, cockroach, mouse; Be applied to the desinsection of the environment in livestock and poultry cultivation field, indoor and air and kill mouse through multi-functional atomizer and Portable atomizer, can effectively prevent and kill pests such as mosquitos and flies, cockroach, mouse.
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| CN201110132173A CN102308845A (en) | 2011-05-22 | 2011-05-22 | Preparation and applications of atomizing agent with pesticide and deratization functions |
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| CN201110132173A CN102308845A (en) | 2011-05-22 | 2011-05-22 | Preparation and applications of atomizing agent with pesticide and deratization functions |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106212501A (en) * | 2016-07-21 | 2016-12-14 | 启东明光企业管理有限公司 | Disinfestation and deratization complexing agent |
| CN108124862A (en) * | 2017-12-21 | 2018-06-08 | 江西省农业科学院植物保护研究所 | Synergistic auxiliary agent of pesticide for killing borers and use method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101897342A (en) * | 2010-06-04 | 2010-12-01 | 贵阳柏丝特化工有限公司 | Preparation of insecticide solution and application thereof |
| CN101985412A (en) * | 2010-09-17 | 2011-03-16 | 覃终 | Preparation and application of compound smoke agent |
-
2011
- 2011-05-22 CN CN201110132173A patent/CN102308845A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101897342A (en) * | 2010-06-04 | 2010-12-01 | 贵阳柏丝特化工有限公司 | Preparation of insecticide solution and application thereof |
| CN101985412A (en) * | 2010-09-17 | 2011-03-16 | 覃终 | Preparation and application of compound smoke agent |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106212501A (en) * | 2016-07-21 | 2016-12-14 | 启东明光企业管理有限公司 | Disinfestation and deratization complexing agent |
| CN108124862A (en) * | 2017-12-21 | 2018-06-08 | 江西省农业科学院植物保护研究所 | Synergistic auxiliary agent of pesticide for killing borers and use method thereof |
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Application publication date: 20120111 |