CN103583558B - The aqueous emulsion of a kind of beta-cypermethrin and fenoxycarb and application - Google Patents
The aqueous emulsion of a kind of beta-cypermethrin and fenoxycarb and application Download PDFInfo
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- CN103583558B CN103583558B CN201310592102.2A CN201310592102A CN103583558B CN 103583558 B CN103583558 B CN 103583558B CN 201310592102 A CN201310592102 A CN 201310592102A CN 103583558 B CN103583558 B CN 103583558B
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- Prior art keywords
- fenoxycarb
- cypermethrin
- beta
- aqueous emulsion
- application
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- HJUFTIJOISQSKQ-UHFFFAOYSA-N fenoxycarb Chemical compound C1=CC(OCCNC(=O)OCC)=CC=C1OC1=CC=CC=C1 HJUFTIJOISQSKQ-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 239000005898 Fenoxycarb Substances 0.000 title claims abstract description 45
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 title claims abstract description 43
- 239000000839 emulsion Substances 0.000 title claims abstract description 14
- 239000004480 active ingredient Substances 0.000 claims abstract description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 241001531327 Hyphantria cunea Species 0.000 claims description 7
- -1 polyoxyethylene formaldehyde Polymers 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000007859 condensation product Substances 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 241000607479 Yersinia pestis Species 0.000 abstract description 11
- 239000000203 mixture Substances 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 7
- 239000002917 insecticide Substances 0.000 abstract description 7
- 239000003905 agrochemical Substances 0.000 abstract description 5
- 239000002131 composite material Substances 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000003814 drug Substances 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 241000238631 Hexapoda Species 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 230000000749 insecticidal effect Effects 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- KAATUXNTWXVJKI-GGPKGHCWSA-N (1R)-trans-(alphaS)-cypermethrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-GGPKGHCWSA-N 0.000 description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 241000255901 Tortricidae Species 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 231100000194 ovacidal Toxicity 0.000 description 2
- 230000003151 ovacidal effect Effects 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 206010004194 Bed bug infestation Diseases 0.000 description 1
- PCBZRNYXXCIELG-WYFCWLEVSA-N COC1=CC=C(C[C@H](NC(=O)OC2CCCC3(C2)OOC2(O3)C3CC4CC(C3)CC2C4)C(=O)N[C@@H]2[C@@H](CO)O[C@H]([C@@H]2O)N2C=NC3=C2N=CN=C3N(C)C)C=C1 Chemical compound COC1=CC=C(C[C@H](NC(=O)OC2CCCC3(C2)OOC2(O3)C3CC4CC(C3)CC2C4)C(=O)N[C@@H]2[C@@H](CO)O[C@H]([C@@H]2O)N2C=NC3=C2N=CN=C3N(C)C)C=C1 PCBZRNYXXCIELG-WYFCWLEVSA-N 0.000 description 1
- 241000813617 Ceroplastes floridensis Species 0.000 description 1
- 241001327638 Cimex lectularius Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241001635274 Cydia pomonella Species 0.000 description 1
- 241000012249 Dendrolimus spectabilis Species 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000270322 Lepidosauria Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 241000382353 Pupa Species 0.000 description 1
- 241000124033 Salix Species 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 230000001887 anti-feedant effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- GZXSDYYWLZERLF-UHFFFAOYSA-N ethyl n-ethylcarbamate Chemical compound CCNC(=O)OCC GZXSDYYWLZERLF-UHFFFAOYSA-N 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 230000003054 hormonal effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 229930014550 juvenile hormone Natural products 0.000 description 1
- 239000002949 juvenile hormone Substances 0.000 description 1
- 150000003633 juvenile hormone derivatives Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000001418 larval effect Effects 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000029052 metamorphosis Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000002981 neuropathic effect Effects 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field that agricultural chemical insecticide is composite, be specially aqueous emulsion and the application of a kind of beta-cypermethrin and fenoxycarb.Said composition active ingredient is beta-cypermethrin and fenoxycarb; wherein the weight ratio of beta-cypermethrin and fenoxycarb is; beta-cypermethrin: fenoxycarb=1:1-1:5; this compounded combination has effectively resisted the problem that pest resistance produces; farthest alleviate the problem of current pest resistance to insecticide; thus decrease the consumption of agricultural chemicals; also the impact for environment is alleviated; meet the trend of future society environmental protection, composition of the present invention receives best crop protection effect.
Description
Technical field
The invention belongs to the technical field that agricultural chemical insecticide is composite, be specially aqueous emulsion and the application of a kind of beta-cypermethrin and fenoxycarb.
Background technology
beta-cypermethrin
English name: theta-cypermethrin
Molecular formula: C
22h
19c
i2nO
3
Chemical name: (S) a-cyano group-3-phenoxy benzyl (1R, 3S)-3-(2,2-dichloro dialkylene)-2,2-dimethyl cyclopropane carboxylic acid ester and (R)-a-cyano group-3-phenoxy benzyl (1S, 3R)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's esters
Chemical classes: pyrethroid
Physicochemical property: outward appearance is white or light yellow crystalline powder, without visible exogenous impurity.1.219g/m during proportion 25 DEG C
3; Fusing point 78-81 DEG C; Vapour pressure (20 DEG C) 2.3 × (10 negative 7) Pa; Under normal temperature, in water, solvability is extremely low, dissolves in ketone, alcohols and aromatic hydrocarbon solvent.
Action character: theta-cypermethrin belongs to third generation pyrethroid insecticides, be mainly used in the control of the agriculture and forestry injurious insects such as field crop, economic crops, vegetables, fruit tree and the domestic hygiene insect such as vegetables, mosquito class bedbug and have that virus killing is efficient, wide spectrum, to people and animals' low toxicity, effect rapidly, the feature such as holding effect is long, have and tag and stomach toxicity, ovicidal, insect is had to the effects such as antifeedant activity, but all there is no systemic action.Resistance of rainwater washing against, has special efficacy to the insect that organophosphorous pesticide has reached resistance especially.Due to use for years, in addition with the cross resistance problem of organic phosphates, carbamates, make insect generally produce very strong pesticide resistance to such medicament, preventive effect is not equal to before.
fenoxycarb
[chemical name] [2-(4-phenoxy-phenoxy) ethyl] urethanes.
[physicochemical property] former medicine outward appearance is white to light yellow solid, fusing point 53 C ~ 54 DEG C.
Solvability when 25 DEG C: water 5.7mg/l, hexane 5 g/l), acetone, methyl alcohol, toluene >250g ,/l
Stability: stablize more than 2 years under room temperature condition, stablizing .5% pulvis outward appearance to light is free-pouring powder,
Acid-base value (in H2S04)≤0.3%.
English common name: fenoxycarb(BSI; ISO; ANSI);
The p-phenoxy-phenoxy of chemical name: 2-() ethyl carbamic acid ethyl ester, ethyl [2-(4-phenoxphenoxy) ethyl] carbamate
Fenoxycarb has stomach toxicity and action of contace poison, and has insect growth regulator, IGR effect, desinsection wide spectrum; But its insecticidal action right and wrong are neuropathic, show as and have strong juvenile hormone activity to various insects, ovicidal can be caused, suppress the metamorphosis in adult stage and casting off a skin of larval phase, to cause after larva friend or pupa time dead, the lasting period is long, harmless to beneficial organism.Can be used for preventing and treating sanitary insect pest, forestry pest, storage pest and agricultural pests.
But its action effect is also very single, after large-scale application, resistance risk is also very high.
Summary of the invention
The object of the present invention is to provide a kind of aqueous emulsion and the application thereof that have beta-cypermethrin and fenoxycarb, said composition active ingredient is beta-cypermethrin and fenoxycarb, wherein the weight ratio of beta-cypermethrin and fenoxycarb is, beta-cypermethrin: fenoxycarb=1:1-1:5, this compounded combination has effectively resisted the problem that pest resistance produces, farthest alleviate the problem of current pest resistance to insecticide, thus decrease the consumption of agricultural chemicals, also the impact for environment is alleviated, meet the trend of future society environmental protection, composition of the present invention receives best crop protection effect.
Technical scheme of the present invention is:
An aqueous emulsion for beta-cypermethrin and fenoxycarb, active ingredient is beta-cypermethrin and fenoxycarb, and wherein the weight ratio of beta-cypermethrin and fenoxycarb is, beta-cypermethrin: fenoxycarb=1:1-1:5.
As preferably, the weight ratio of beta-cypermethrin and fenoxycarb is, beta-cypermethrin: fenoxycarb=1:2-1:3.
The aqueous emulsion of beta-cypermethrin of the present invention and fenoxycarb, it consists of following component by weight percentage:
Beta-cypermethrin 1-5%,
Fenoxycarb 10-25%,
Solvent 10-15%,
Defoamer 1-4%,
Emulsifier 5-10%,
Thickener 2-5%,
Antifreezing agent 4-8%,
Surplus is water.
Further preferably,
The aqueous emulsion of beta-cypermethrin of the present invention and fenoxycarb, it consists of following component by weight percentage:
Beta-cypermethrin 5%,
Fenoxycarb 15%,
Solvent 12%,
Defoamer 3%,
Emulsifier 7%,
Thickener 3%,
Antifreezing agent 6%,
Surplus is water.
Described solvent is the one in toluene, methylated soya oil, the rapeseed oil that methylates, mineral oil, dimethylbenzene, 150# solvent naphtha or 200# solvent naphtha.
Described defoamer is selected from: the one in silicone oil, silicone compound.
Described emulsifier is nonionic or anionic.Wherein, the emulsifier of nonionic is as phenethyl phenol polyethenoxy polyethenoxy ether, alkylphenol polyoxyethylene formaldehyde condensation products, fatty alcohol-polyoxyethylene ether or alkylphenol polyoxyethylene phosphate; The emulsifier of anionic is as alkyl benzene calcium sulfonate, sodium alkyl benzene sulfonate or C8-C20 sodium alkyl sulfate.Concrete example is as serial in agriculture breast 1600#, NP is serial, 700# is serial, 400# is serial.
Described thickener is selected from: the one in Magnesiumaluminumsilicate, cyanethyl cellulose, polyvinyl alcohol.
Described antifreezing agent is selected from: the one in ethylene glycol, glycerine.
The aqueous emulsion of beta-cypermethrin of the present invention and fenoxycarb, the wood louse on control cotton field, orchard, vegetable garden and ornamental plants, a red-spotted lizard class, leaf roller, the pine caterpillars of control woods trees, fall webworm, looper, willow boat moth, codling moth; Be particularly useful for preventing and treating fall webworm.
Beneficial effect of the present invention is:
Said composition is complex insecticidal composition, compared with single product, there is the feature of binary Pesticidal combination, significantly enhance insecticidal effect, delay the generation of pest resistance to insecticide, especially special efficacy is had to thrips, and expand effective active control spectrum, there is speed fast, lasting period is long, consumption is low, eco-friendly feature, the more important thing is, this compounded combination has effectively resisted the problem that pest resistance produces, farthest alleviate the problem of current pest resistance to insecticide, thus decrease the consumption of agricultural chemicals, also the impact for environment is alleviated, meet the trend of future society environmental protection.The control efficiency of composition of the present invention is especially good to control fall webworm, mainly by the result of the synergistic function between each component.
Study the compound synergic of composition of the present invention, test adopts fall webworm.
Calculate virulence equation and lethal concentration of 50 LC50 by method of least squares, calculate toxicity index and the mixed co-toxicity coefficient (CTC value) of medicament according to the abundant method of Sun Yun.
Table 1 different ratio relation is to the toxicity test result of fall webworm
| Process | LC50（PPM） | Co-toxicity coefficient |
| Beta-cypermethrin 1: fenoxycarb 1 | 0.855 | 529.8 |
| Beta-cypermethrin 1: fenoxycarb 2 | 0.727 | 733.8 |
| Beta-cypermethrin 1: fenoxycarb 3 | 0.632 | 835.7 |
| Beta-cypermethrin 1: fenoxycarb 5 | 0.717 | 613.6 |
| Beta-cypermethrin | 21.03 | |
| Fenoxycarb | 0.56 |
As can be seen from Table 1, beta-cypermethrin and fenoxycarb composite, has very high synergistic effect, especially beta-cypermethrin: during fenoxycarb=1:2-1:3, synergistic effect is more obvious.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described in detail.
embodiment 1
20% aqueous emulsion: the composition of beta-cypermethrin and fenoxycarb
Beta-cypermethrin 5%,
Fenoxycarb 15%,
Methylate rapeseed oil 12%,
Silicone oil 3%,
Alkylphenol polyoxyethylene formaldehyde condensation products 7%,
Cyanethyl cellulose 3%,
Glycerine 6%,
Surplus is water.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control fall webworm:
Co-toxicity coefficient is: 859.5;
By 6000 times of thin up sprayings, after medicine, 7 days control efficiency are that 99.1%, 5% beta-cypermethrin suspending agent dilutes 500 times and 15% fenoxycarb missible oil dilutes 3000 times, use with same method respectively, after medicine 7 days, control efficiency was respectively 77.5% and 73.9%, significant difference.
embodiment 2
6% aqueous emulsion: the composition of beta-cypermethrin and fenoxycarb
Beta-cypermethrin 1%,
Fenoxycarb 5%,
Dimethylbenzene 10%,
Silicone compound 1%,
Phenethyl phenol polyethenoxy polyethenoxy ether 10%,
Polyvinyl alcohol 2%,
Ethylene glycol 8%,
Surplus is water.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control leaf roller:
Co-toxicity coefficient is: 770.3;
By 4000 times of thin up sprayings, after medicine, 7 days control efficiency are that 96.60%, 1% beta-cypermethrin suspending agent dilutes 200 times and 5% fenoxycarb missible oil dilutes 1000 times, use with same method respectively, after medicine 7 days, control efficiency was respectively 73.2% and 67.7%, significant difference.
embodiment 3
30% aqueous emulsion: the composition of beta-cypermethrin and fenoxycarb
Beta-cypermethrin 5%,
Fenoxycarb 25%,
Toluene 15%,
Silicone compound 4%,
Fatty alcohol-polyoxyethylene ether 5%,
Magnesiumaluminumsilicate 5%,
Glycerine 5%,
Surplus is water.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control ceroplastes floridensis:
Co-toxicity coefficient is: 790.1;
By 6000 times of thin up sprayings, after medicine, 7 days control efficiency are that 97.5%, 5% beta-cypermethrin suspending agent dilutes 500 times and 25% fenoxycarb missible oil dilutes 2000 times, use with same method respectively, after medicine 7 days, control efficiency was respectively 76.9% and 70.3%, significant difference.
Claims (2)
1. an aqueous emulsion for beta-cypermethrin and fenoxycarb, active ingredient is beta-cypermethrin and fenoxycarb, and it consists of following component by weight percentage:
Beta-cypermethrin 5%,
Fenoxycarb 15%,
Methylate rapeseed oil 12%,
Silicone oil 3%,
Alkylphenol polyoxyethylene formaldehyde condensation products 7%,
Cyanethyl cellulose 3%,
Glycerine 6%,
Surplus is water.
2. the aqueous emulsion of beta-cypermethrin according to claim 1 and fenoxycarb is for preventing and treating the application of fall webworm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310592102.2A CN103583558B (en) | 2013-11-22 | 2013-11-22 | The aqueous emulsion of a kind of beta-cypermethrin and fenoxycarb and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310592102.2A CN103583558B (en) | 2013-11-22 | 2013-11-22 | The aqueous emulsion of a kind of beta-cypermethrin and fenoxycarb and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103583558A CN103583558A (en) | 2014-02-19 |
| CN103583558B true CN103583558B (en) | 2015-10-21 |
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|---|---|---|---|
| CN201310592102.2A Expired - Fee Related CN103583558B (en) | 2013-11-22 | 2013-11-22 | The aqueous emulsion of a kind of beta-cypermethrin and fenoxycarb and application |
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| CN107136079B (en) * | 2017-05-12 | 2020-01-07 | 扬州大学 | Cyhalofop-butyl emulsion in water and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4024163A (en) * | 1972-05-25 | 1977-05-17 | National Research Development Corporation | Insecticides |
| US5004822A (en) * | 1971-12-21 | 1991-04-02 | National Research Development Corporation | Insecticides |
| CN1305715A (en) * | 2001-02-28 | 2001-08-01 | 郑州沙隆达伟新农药有限公司 | Insecticide composition |
-
2013
- 2013-11-22 CN CN201310592102.2A patent/CN103583558B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5004822A (en) * | 1971-12-21 | 1991-04-02 | National Research Development Corporation | Insecticides |
| US4024163A (en) * | 1972-05-25 | 1977-05-17 | National Research Development Corporation | Insecticides |
| CN1305715A (en) * | 2001-02-28 | 2001-08-01 | 郑州沙隆达伟新农药有限公司 | Insecticide composition |
Non-Patent Citations (1)
| Title |
|---|
| 反式高效氯氰菊酯及药效简介;钱小敏 张近高;《中华卫生杀虫药械》;20020515;第8卷(第2期);第69-70页 * |
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| CN103583558A (en) | 2014-02-19 |
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