CN103651527B - A kind of water dispersible granules and application containing spiral shell worm ethyl ester - Google Patents
A kind of water dispersible granules and application containing spiral shell worm ethyl ester Download PDFInfo
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- CN103651527B CN103651527B CN201310661579.1A CN201310661579A CN103651527B CN 103651527 B CN103651527 B CN 103651527B CN 201310661579 A CN201310661579 A CN 201310661579A CN 103651527 B CN103651527 B CN 103651527B
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- CN
- China
- Prior art keywords
- ethyl ester
- spiral shell
- shell worm
- worm ethyl
- cypermethrin
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- 125000004494 ethyl ester group Chemical group 0.000 title claims abstract description 50
- 239000004562 water dispersible granule Substances 0.000 title claims abstract description 14
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical group CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims abstract description 36
- 239000004480 active ingredient Substances 0.000 claims abstract description 6
- 241001672694 Citrus reticulata Species 0.000 claims description 8
- 241000258937 Hemiptera Species 0.000 claims description 8
- 241001465977 Coccoidea Species 0.000 claims description 3
- 241001454293 Tetranychus urticae Species 0.000 claims description 3
- 239000000203 mixture Substances 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 7
- 239000002917 insecticide Substances 0.000 abstract description 7
- 241000607479 Yersinia pestis Species 0.000 abstract description 5
- 239000003905 agrochemical Substances 0.000 abstract description 5
- 239000002131 composite material Substances 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000003814 drug Substances 0.000 description 11
- 241000238631 Hexapoda Species 0.000 description 7
- 239000005995 Aluminium silicate Substances 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 5
- 235000012211 aluminium silicate Nutrition 0.000 description 5
- 210000000481 breast Anatomy 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- -1 polyoxyethylene Polymers 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- KAATUXNTWXVJKI-GGPKGHCWSA-N (1R)-trans-(alphaS)-cypermethrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-GGPKGHCWSA-N 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 206010004194 Bed bug infestation Diseases 0.000 description 1
- 235000000318 Bindesalat Nutrition 0.000 description 1
- 244000106835 Bindesalat Species 0.000 description 1
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- 241001327638 Cimex lectularius Species 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000001887 anti-feedant effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000009571 larval growth Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 231100000194 ovacidal Toxicity 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The invention belongs to the technical field that agricultural chemical insecticide is composite, be specially a kind of water dispersible granules and the application that contain spiral shell worm ethyl ester, said composition active ingredient is beta-cypermethrin and spiral shell worm ethyl ester, wherein the weight ratio of beta-cypermethrin and spiral shell worm ethyl ester is, beta-cypermethrin: spiral shell worm ethyl ester=1:1-1:10, farthest alleviate the problem of current pest resistance to insecticide, thus decrease the consumption of agricultural chemicals, also the impact for environment is alleviated, meet the trend of future society environmental protection, composition of the present invention receives best crop protection effect.
Description
Technical field
The invention belongs to the technical field that agricultural chemical insecticide is composite, be specially a kind of water dispersible granules and the application that contain spiral shell worm ethyl ester.
Background technology
Beta-cypermethrin
English name: theta-cypermethrin
Molecular formula: C
22h
19c
i2nO
3
Chemical name: (S) a-cyano group-3-phenoxy benzyl (1R, 3S)-3-(2,2-dichloro dialkylene)-2,2-dimethyl cyclopropane carboxylic acid ester and (R)-a-cyano group-3-phenoxy benzyl (1S, 3R)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's esters
Chemical classes: pyrethroid
Physicochemical property: outward appearance is white or light yellow crystalline powder, without visible exogenous impurity.1.219g/m during proportion 25 DEG C
3; Fusing point 78-81 DEG C; Vapour pressure (20 DEG C) 2.3 × (10 negative 7) Pa; Under normal temperature, in water, solvability is extremely low, dissolves in ketone, alcohols and aromatic hydrocarbon solvent.
Action character: theta-cypermethrin belongs to third generation pyrethroid insecticides, be mainly used in the control of the agriculture and forestry injurious insects such as field crop, economic crops, vegetables, fruit tree and the domestic hygiene insect such as vegetables, mosquito class bedbug and have that virus killing is efficient, wide spectrum, to people and animals' low toxicity, effect rapidly, the feature such as holding effect is long, have and tag and stomach toxicity, ovicidal, insect is had to the effects such as antifeedant activity, but all there is no systemic action.Resistance of rainwater washing against, has special efficacy to the insect that organophosphorous pesticide has reached resistance especially.Due to use for years, in addition with the cross resistance problem of organic phosphates, carbamates, make insect generally produce very strong pesticide resistance to such medicament, preventive effect is not equal to before.
Spiral shell worm ethyl ester
Molecular formula is: C
21h
27nO
5
Spiral shell worm ethyl ester has unique function Characteristics, is one of modern pesticides so far with two-way Uptake and translocation performance.This compound upwards can move down in whole plant corpus, arrives at blade face and bark, thus control is as on romaine lettuce and Chinese cabbage internal lobe, and the corticole insect of fruit.The interior absorption of this uniqueness can protect newborn stem, leaf and root, prevents ovum and the larval growth of insect.Its another feature is that the lasting period is long, can provide the effective control reaching 8 weeks.
But its action effect is also very single, after large-scale application, resistance risk is also very high.
Summary of the invention
The object of the present invention is to provide a kind of water dispersible granules and the application thereof that contain spiral shell worm ethyl ester; said composition active ingredient is beta-cypermethrin and spiral shell worm ethyl ester; wherein the weight ratio of beta-cypermethrin and spiral shell worm ethyl ester is; beta-cypermethrin: spiral shell worm ethyl ester=1:5-1:10; farthest alleviate the problem of current pest resistance to insecticide; thus decrease the consumption of agricultural chemicals; also the impact for environment is alleviated; meet the trend of future society environmental protection, composition of the present invention receives best crop protection effect.
Technical scheme of the present invention is:
A water dispersible granules containing spiral shell worm ethyl ester, active ingredient is beta-cypermethrin and spiral shell worm ethyl ester, and wherein the weight ratio of beta-cypermethrin and spiral shell worm ethyl ester is, beta-cypermethrin: spiral shell worm ethyl ester=1:1-1:10.
As preferably, the weight ratio of beta-cypermethrin and spiral shell worm ethyl ester is, beta-cypermethrin: spiral shell worm ethyl ester=1:2-1:4.
Water dispersible granules containing spiral shell worm ethyl ester of the present invention, it consists of following component by weight percentage:
Beta-cypermethrin 1-50%,
Spiral shell worm ethyl ester 1-50%,
Agriculture breast 400# 4-7%;
Laminated crystal of sodium disilicate 1-5%;
Alkylphenol polyoxyethylene 5-10%;
Sodium carboxymethyl starch 2-20%;
Kaolin surplus.
As preferably, the water dispersible granules containing spiral shell worm ethyl ester of the present invention, it consists of following component by weight percentage:
Beta-cypermethrin 5-10%,
Spiral shell worm ethyl ester 10-40%,
Agriculture breast 400# 4-7%;
Laminated crystal of sodium disilicate 1-5%;
Alkylphenol polyoxyethylene 5-10%;
Sodium carboxymethyl starch 2-20%;
Kaolin surplus.
Wherein, the total weight percentage of described active ingredient is 30 ~ 60%.
Water dispersible granules containing spiral shell worm ethyl ester of the present invention, for preventing and treating mealybug, two spotted spider mite, mandarin tree scale insect, is particularly useful for control mandarin tree scale insect.
Beneficial effect of the present invention is:
Said composition is compound water dispersible granule composition, compared with single product, there is the feature of binary composition, significantly enhance effect, delay the generation of pest resistance to insecticide, and expand effective active control spectrum, have speed fast, the lasting period is long, consumption is low, eco-friendly feature, the more important thing is, this compounded combination has effectively resisted the problem that pest resistance produces, farthest alleviate the problem of current pest resistance to insecticide, thus decrease the consumption of agricultural chemicals, also alleviate the impact for environment, meet the trend of future society environmental protection.The control efficiency of composition of the present invention is especially good to control mandarin tree scale insect, mainly by the result of the synergistic function between each component.
Study the compound synergic of composition of the present invention, test adopts the mandarin tree scale insect in field.
Toxicity index and the mixed co-toxicity coefficient (CTC value) of medicament is calculated according to the abundant method of Sun Yun.
Table 1 different ratio relation is to the toxicity test result of mandarin tree scale insect
| Process | Co-toxicity coefficient |
| Beta-cypermethrin 1: spiral shell worm ethyl ester 1 | 213.6 |
| Beta-cypermethrin 1: spiral shell worm ethyl ester 2 | 298.5 |
| Beta-cypermethrin 1: spiral shell worm ethyl ester 4 | 290.7 |
| Beta-cypermethrin 1: spiral shell worm ethyl ester 5 | 202.7 |
| Beta-cypermethrin 1: spiral shell worm ethyl ester 10 | 120.5 |
| Beta-cypermethrin | |
| Spiral shell worm ethyl ester |
As can be seen from Table 1, beta-cypermethrin and spiral shell worm ethyl ester composite, has very high synergistic effect, especially beta-cypermethrin: during spiral shell worm ethyl ester=1:2-1:4, synergistic effect is more obvious.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The composition of 30% beta-cypermethrin and spiral shell worm ethyl ester
Beta-cypermethrin 15%,
Spiral shell worm ethyl ester 15%,
Agriculture breast 400# 7%;
Laminated crystal of sodium disilicate 4%;
Alkylphenol polyoxyethylene 10%;
Sodium carboxymethyl starch 15%;
Kaolin surplus.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control mandarin tree scale insect:
Co-toxicity coefficient is: 210.6;
By 4000 times of thin up sprayings, after medicine, 30 days control efficiency are that 96.5%, 15% beta-cypermethrin suspending agent dilutes 500 times and 15% spiral shell worm ethyl ester missible oil dilutes 500 times, use with same method respectively, after medicine 30 days, control efficiency was respectively 72.3% and 69.6%, significant difference.
Embodiment 2
The composition of 50% beta-cypermethrin and spiral shell worm ethyl ester
Beta-cypermethrin 10%,
Spiral shell worm ethyl ester 40%,
Agriculture breast 400# 4%;
Laminated crystal of sodium disilicate 5%;
Alkylphenol polyoxyethylene 5%;
Sodium carboxymethyl starch 20%;
Kaolin surplus.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control mealybug:
Co-toxicity coefficient is: 290.8;
By 5000 times of thin up sprayings, after medicine, 30 days control efficiency are that 99.1%, 10% beta-cypermethrin suspending agent dilutes 500 times and 40% spiral shell worm ethyl ester missible oil dilutes 2000 times, use with same method respectively, after medicine 30 days, control efficiency was respectively 69.8% and 73.4%, significant difference.
Embodiment 3
The composition of 60% beta-cypermethrin and spiral shell worm ethyl ester
Beta-cypermethrin 20%,
Spiral shell worm ethyl ester 40%,
Agriculture breast 400# 7%;
Laminated crystal of sodium disilicate 1%;
Alkylphenol polyoxyethylene 8%;
Sodium carboxymethyl starch 5%;
Kaolin surplus.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control two spotted spider mite:
Co-toxicity coefficient is: 299.7;
By 6000 times of thin up sprayings, after medicine, 30 days control efficiency are that 99.3%, 20% beta-cypermethrin suspending agent dilutes 1000 times and 40% spiral shell worm ethyl ester missible oil dilutes 2000 times, use with same method respectively, after medicine 30 days, control efficiency was respectively 69.1% and 74.4%, significant difference.
Claims (4)
1. the water dispersible granules containing spiral shell worm ethyl ester, active ingredient is beta-cypermethrin and spiral shell worm ethyl ester, and wherein the weight ratio of beta-cypermethrin and spiral shell worm ethyl ester is, beta-cypermethrin: spiral shell worm ethyl ester=1:1-1:10; Wherein, the total weight percentage of described active ingredient is 30 ~ 60%.
2. the water dispersible granules containing spiral shell worm ethyl ester according to claim 1, it is characterized in that, the weight ratio of described beta-cypermethrin and spiral shell worm ethyl ester is, beta-cypermethrin: spiral shell worm ethyl ester=1:2-1:4.
3. the water dispersible granules containing spiral shell worm ethyl ester according to the arbitrary claim of claim 1-2 is for preventing and treating mealybug, two spotted spider mite, mandarin tree scale insect.
4. the water dispersible granules containing spiral shell worm ethyl ester according to claim 3 is for preventing and treating mandarin tree scale insect.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310661579.1A CN103651527B (en) | 2013-12-06 | 2013-12-06 | A kind of water dispersible granules and application containing spiral shell worm ethyl ester |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310661579.1A CN103651527B (en) | 2013-12-06 | 2013-12-06 | A kind of water dispersible granules and application containing spiral shell worm ethyl ester |
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| Publication Number | Publication Date |
|---|---|
| CN103651527A CN103651527A (en) | 2014-03-26 |
| CN103651527B true CN103651527B (en) | 2015-08-19 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104705318B (en) * | 2015-03-23 | 2018-02-16 | 广东中迅农科股份有限公司 | A kind of Pesticidal combination containing rosin acid sodium and spiral shell worm ethyl ester |
| CN105475311A (en) * | 2016-01-19 | 2016-04-13 | 陕西西大华特科技实业有限公司 | Spirotetramat containing granules, application and preparation method of spirotetramat containing granules |
| CN108294045A (en) * | 2018-03-15 | 2018-07-20 | 重庆中邦药业（集团）有限公司 | One vegetative insecticide composition, preparation and its application |
| CN109197884A (en) * | 2018-08-31 | 2019-01-15 | 南通江山农药化工股份有限公司 | Spiral shell worm ethyl ester insecticide, purposes and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101796949A (en) * | 2009-12-31 | 2010-08-11 | 青岛星牌作物科学有限公司 | Plant insecticidal protective agent and application thereof |
| CN102379299A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing spirotetramat |
-
2013
- 2013-12-06 CN CN201310661579.1A patent/CN103651527B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101796949A (en) * | 2009-12-31 | 2010-08-11 | 青岛星牌作物科学有限公司 | Plant insecticidal protective agent and application thereof |
| CN102379299A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing spirotetramat |
Non-Patent Citations (2)
| Title |
|---|
| 贾晓红,张国才.4.5%高效氯氰菊酯乳油中高效氯氰菊酯含量的分析.《化学标准化与质量监督》.1999,(第5期),第27-28页. * |
| 黄润秋,等.差向异构化立体有择合成高效顺反式氯氰菊酯.《农药》.1990,第29卷(第2期),第16-21页. * |
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