CN103704246B - Synergistic pesticide composition and application thereof - Google Patents
Synergistic pesticide composition and application thereof Download PDFInfo
- Publication number
- CN103704246B CN103704246B CN201310663631.7A CN201310663631A CN103704246B CN 103704246 B CN103704246 B CN 103704246B CN 201310663631 A CN201310663631 A CN 201310663631A CN 103704246 B CN103704246 B CN 103704246B
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- China
- Prior art keywords
- cypermethrin
- beta
- thiocyclam
- insecticidal composition
- synergistic insecticidal
- Prior art date
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- 239000010457 zeolite Substances 0.000 description 1
Abstract
The invention belongs to the technical field of compound pesticides, and specifically relates to a synergistic pesticide composition and an application thereof. Effective components of the synergistic pesticide composition comprise theta-cypermethrin and a nereistoxin pesticide, wherein the nereistoxin pesticide is one of monosultap, dimehypo, cartap and thiocyclam. The compound combination can effectively resist the problems of resistance generation of pests, alleviate the problem of present pest resistance to pesticides at the greatest extent, thereby reducing use amount of the pesticides, alleviating influences of the pesticides on the environment and fitting a trend of social environment protection in the further. The composition provided by the invention can achieve an optimal crop protection effect.
Description
Technical field
The invention belongs to the technical field that agricultural chemical insecticide is composite, be specially a kind of Synergistic insecticidal composition and application.
Background technology
sandworm toxin insecticide
According to the chemical constitution of nereistoxin, a series of analog making agricultural insecticide of bio-mimetic syntheses, as cartap, dimehypo, Cupric sulfate, thiocyclam etc., being referred to as sandworm toxin insecticide, is also human development successful first kind animal sources insecticide.
To insect, there is very strong tagging and stomach poison function, also there is certain interior suction and fumigation action, lethality is had to adult, larva, ovum, its site of action is cholinergic synapse, check neural normal delivery and make the nerve of insect not produce reaction to external irritant, when contacting pests or after taking food medicament, polypide is drowse, paralysis very soon, until dead, but polypide poisoning after there is no spasm or overwrought symptom.But its action effect is also very single, after large-scale application, resistance risk is also very high.
beta-cypermethrin
English name: theta-cypermethrin
Molecular formula: C
22h
19c
i2nO
3
Chemical name: (S) a-cyano group-3-phenoxy benzyl (1R, 3S)-3-(2,2-dichloro dialkylene)-2,2-dimethyl cyclopropane carboxylic acid ester and (R)-a-cyano group-3-phenoxy benzyl (1S, 3R)-3-(2,2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid's esters
Chemical classes: pyrethroid
Physicochemical property: outward appearance is white or light yellow crystalline powder, without visible exogenous impurity.1.219g/m during proportion 25 DEG C
3; Fusing point 78-81 DEG C; Vapour pressure (20 DEG C) 2.3 × (10 negative 7) Pa; Under normal temperature, in water, solvability is extremely low, dissolves in ketone, alcohols and aromatic hydrocarbon solvent.
Action character: theta-cypermethrin belongs to third generation pyrethroid insecticides, be mainly used in the control of the agriculture and forestry injurious insects such as field crop, economic crops, vegetables, fruit tree and the domestic hygiene insect such as vegetables, mosquito class bedbug and have that virus killing is efficient, wide spectrum, to people and animals' low toxicity, effect rapidly, the feature such as holding effect is long, have and tag and stomach toxicity, ovicidal, insect is had to the effects such as antifeedant activity, but all there is no systemic action.Resistance of rainwater washing against, has special efficacy to the insect that organophosphorous pesticide has reached resistance especially.Due to use for years, in addition with the cross resistance problem of organic phosphates, carbamates, make insect generally produce very strong pesticide resistance to such medicament, preventive effect is not equal to before.
Summary of the invention
The object of the present invention is to provide a kind of Synergistic insecticidal composition, active ingredient comprises beta-cypermethrin and sandworm toxin insecticide, wherein, described sandworm toxin insecticide is Cupric sulfate, dimehypo, cartap, one in thiocyclam, this compounded combination has effectively resisted the problem that pest resistance produces, farthest alleviate the problem of current pest resistance to insecticide, thus decrease the consumption of agricultural chemicals, also the impact for environment is alleviated, meet the trend of future society environmental protection, composition of the present invention receives best crop protection effect.
Technical scheme of the present invention is:
A kind of Synergistic insecticidal composition, active ingredient comprises beta-cypermethrin and sandworm toxin insecticide, and wherein, described sandworm toxin insecticide is the one in Cupric sulfate, dimehypo, cartap, thiocyclam.
As preferably, the total weight percentage of described active ingredient is 10 ~ 90%.
As preferably, the total weight percentage of described active ingredient is 50 ~ 80%.
Wherein the weight ratio of beta-cypermethrin and Cupric sulfate is, beta-cypermethrin: Cupric sulfate=5:1.
Wherein the weight ratio of beta-cypermethrin and dimehypo is, beta-cypermethrin: dimehypo=7:1.
Wherein the weight ratio of beta-cypermethrin and cartap is, beta-cypermethrin: cartap=1:10.
Wherein the weight ratio of beta-cypermethrin and thiocyclam is, beta-cypermethrin: thiocyclam=20:1.
The composition of beta-cypermethrin of the present invention and chlorfenapyr, adds auxiliary agent and excipients, makes various preparation, comprises wetting powder, suspending agent, water dispersible granules, aqueous emulsion or missible oil; Be preferably aqueous emulsion.
Described auxiliary agent and excipients comprise: solvent, emulsifier, antifreeze, defoamer, thickener, carrier or filler, dispersant.
Described solvent is at least one in toluene, turpentine oil, methylated soya oil, the rapeseed oil that methylates, mineral oil, dimethylbenzene, 150# solvent naphtha or 200# solvent naphtha.
Described emulsifier be phenethyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy polyethenoxy ether, castor oil polyoxyethylene ether, alkylphenol polyoxyethylene formaldehyde condensation products or alkylphenol-polyethenoxy polyethenoxy ether, triphen ethyl phenol polyoxyethylene ether phosphate, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, calcium dodecyl benzene sulfonate, at least one.
Described dispersant is triphenyl vinyl phenol polyoxyethylene ether phosphate, alkaryl phenol polyethenoxy ether sulfate, castor oil polyoxyethylene ether phosphate, naphthalenesulfonateformaldehyde formaldehyde condensation compound sodium salt, alkylphenol polyoxyethylene phosphate, rosin segmented APEO polyoxypropylene ether sulfonate, triphen ethyl phenol polyoxyethylene ether phosphate, aliphatic alcohol polyoxyvinethene phosphate, to hydroxyphenyl lignin sulfonic acid sodium salt, fatty acid amide N methyl taurine salt, maleic acid disodium salt, at least one in acrylate homopolymer sodium salt calcium lignosulfonate or dialkyl succinylsuccinate sulfonated ester.
Described wetting agent is at least one in alkylphenol polyoxyethylene, naphthalene sulfonate, lauryl sodium sulfate, fatty alcohol-polyoxyethylene ether or alkyl sulfate.
Described antifreezing agent is at least one in ethylene glycol, propane diols, glycerine or urea.
Described suspending agent is at least one in diatomite, bentonite, white carbon, aluminium-magnesium silicate, xanthans, carboxymethyl cellulose or polyvinyl alcohol.
Described preservative is the one in benzoic acid, Sodium Benzoate, sodium Diacetate, glutaraldehyde, Kathon CG, potassium sorbate, formaldehyde, BIT.
Described thickener is xanthans, aluminium-magnesium silicate, sodium carboxymethylcellulose or polyvinyl alcohol, kaolin, bentonite, white carbon, gelatin, gum Arabic.
Described defoamer is higher alcohols, tributyl phosphate, polysiloxanes.
Described carrier, filler are selected from: one or more in precipitated calcium carbonate, attapulgite, kaolin, diatomite, bentonite, zeolite, quartz sand.
Synergistic insecticidal composition of the present invention, for preventing and treating multiple defoliator in the various crop such as paddy rice, vegetables, sugarcane, fruit tree, tea tree, borer pest, as aphid, leafhopper, plant hopper, thrips, beet armyworm, prodenia litura, Americal rice leaf miner, trialeurodes vaporariorum, cotton bollworm, cabbage caterpillar, large trypetid, liriomyza bryoniae, rice fulgorid, the wild snout moth's larva of beans, unguiculus mite, rice leaf roller, striped rice borer, paddy stem borer.
Beneficial effect of the present invention is:
Said composition is complex insecticidal composition, compared with single product, there is the feature of binary Pesticidal combination, significantly enhance desinsection, ovicidal effect, delay the generation of pest resistance to insecticide, and expand effective active control spectrum, there is speed fast, lasting period is long, consumption is low, eco-friendly feature, the more important thing is, this compounded combination has effectively resisted the problem that pest resistance produces, farthest alleviate the problem of current pest resistance to insecticide, thus decrease the consumption of agricultural chemicals, also the impact for environment is alleviated, meet the trend of future society environmental protection, composition of the present invention receives best crop protection effect.
Study the compound synergic of composition of the present invention, test adopts the beet armyworm in field, for test after raising.
Concrete grammar is: adopting commercially available former medicine to carry out composite is required preparation.Examination worm is the beet armyworm pupa picking up from field, indoor feeding four generation, select the second instar larvae of growth uniformity, access is put in the culture dish of the diameter 10 centimetres of cabbage leaf (black leaf Chinese cabbage, outermost layer blade), and every ware connects 40, often process connects three wares, spray under SOPSI pressure with POTT spray tower, each spray ware, every ware spraying liquid 3 milliliters.General each process arranges 1-7 concentration gradient.The culture dish processed puts into 25 DEG C, cultivates in 12H/l2H illumination box, within 48 hours, checks survival borer population, calculates Revision insect recluced rate.Blank spray equivalent clear water.Toxicity index and the mixed co-toxicity coefficient (CTC value) of medicament is calculated according to the abundant method of Sun Yun.
Table 1 different ratio relation is to the toxicity test result of beet armyworm
| Process | Co-toxicity coefficient |
| Beta-cypermethrin 5: Cupric sulfate 1 | 270.7 |
| Beta-cypermethrin 7: dimehypo 1 | 301.2 |
| Beta-cypermethrin 1: cartap 10 | 246.1 |
| Beta-cypermethrin 20: thiocyclam 1 | 251.6 |
| Beta-cypermethrin | |
| Cupric sulfate | |
| Dimehypo | |
| Cartap | |
| Thiocyclam |
As can be seen from Table 1, beta-cypermethrin and chlorfenapyr composite, co-toxicity coefficient is far longer than 120, has very high synergistic effect.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described in detail.
embodiment 1
60% aqueous emulsion:
Beta-cypermethrin 10%,
Cupric sulfate 50%,
Agriculture breast 500
#4%,
Propyl alcohol 10%,
Ethylene glycol 5%,
Silicone oil 2%,
Xanthans 0.5%,
Surplus is water.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to the aphid on control cotton:
Co-toxicity coefficient is: 230.5;
By 6000 times of thin up sprayings, after medicine, 15 days control efficiency are that 98.9%, 10% beta-cypermethrin suspending agent dilutes 2000 times and 50% chlorfenapyr missible oil dilutes 4000 times, use with same method respectively, after medicine 15 days, control efficiency was respectively 80.1% and 71.2%, significant difference.
embodiment 2
80% aqueous emulsion:
Beta-cypermethrin 70%,
Dimehypo 10%,
Polyoxyethylene nonylphenol ether 10%,
Ethylene glycol 15%,
Glycerine 2%,
Silicone compound 1%,
Cyanethyl cellulose 3%,
Surplus is water.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control unguiculus mite:
Co-toxicity coefficient is: 220.6;
By 8000 times of thin up sprayings, after medicine, 15 days control efficiency are that 97.9%, 70% beta-cypermethrin suspending agent dilutes 5000 times and 10% chlorfenapyr missible oil dilutes 3000 times, use with same method respectively, after medicine 15 days, control efficiency was respectively 77.5% and 70.2%, significant difference.
embodiment 3
55% wetting powder:
Beta-cypermethrin 5%,
Cartap 50%,
Diatomite 6%,
Sodium methylene bis-naphthalene sulfonate 10%,
White carbon 3%,
Poly-naphthalene formaldehyde sulfonate salt 2%,
Surplus is bentonite.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control cabbage caterpillar:
Co-toxicity coefficient is: 199.2;
By 6000 times of thin up sprayings, after medicine, 15 days control efficiency are that 98.3%, 5% beta-cypermethrin suspending agent dilutes 400 times and 50% chlorfenapyr missible oil dilutes 3000 times, use with same method respectively, after medicine 15 days, control efficiency was respectively 79.9% and 69.3%, significant difference.
embodiment 4
63% aqueous emulsion:
Beta-cypermethrin 60%,
Thiocyclam 3%,
Castor oil polyoxyethylene ether 8%,
Dimethylbenzene 12%,
Glycerine 3%,
CS-10 aliphatic alcohols compound 1.5%,
Magnesiumaluminumsilicate 2%,
Surplus is water.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to control trialeurodes vaporariorum:
Co-toxicity coefficient is: 225.1;
By 8000 times of thin up sprayings, after medicine, 15 days control efficiency are that 98.9%, 60% beta-cypermethrin suspending agent dilutes 5000 times and 3% chlorfenapyr missible oil dilutes 600 times, use with same method respectively, after medicine 15 days, control efficiency was respectively 77.5% and 68.9%, significant difference.
Claims (4)
1. a Synergistic insecticidal composition, active ingredient comprises beta-cypermethrin and sandworm toxin insecticide, wherein, described sandworm toxin insecticide is thiocyclam, it is characterized in that, wherein the weight ratio of beta-cypermethrin and thiocyclam is, beta-cypermethrin: thiocyclam=20:1.
2. Synergistic insecticidal composition according to claim 1, is characterized in that, comprises wetting powder, suspending agent, water dispersible granules, aqueous emulsion or missible oil.
3. Synergistic insecticidal composition according to claim 2, is characterized in that, is aqueous emulsion.
4. the Synergistic insecticidal composition according to the arbitrary claim of claim 1-3, for preventing and treating multiple defoliator in paddy rice, vegetables, sugarcane, fruit tree, tea tree various crop, borer pest, is specially aphid, leafhopper, plant hopper, thrips, beet armyworm, prodenia litura, trialeurodes vaporariorum, cotton bollworm, cabbage caterpillar, large trypetid, liriomyza bryoniae, the wild snout moth's larva of beans, unguiculus mite.
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