CN102308789A - Preparation and applications of novel composite atomizing agent with deratization function - Google Patents
Preparation and applications of novel composite atomizing agent with deratization function Download PDFInfo
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Abstract
The invention relates to preparation and applications of a novel composite atomizing agent with a deratization function. The atomizing agent comprises the following components in percentage by weight: 0.1%-15% of novel insecticide and rodenticide, 10%-30% of surface active agent, 0%-40% of atomizing agent, 1%-10% of cosolvent and the balance of water. The invention aims to provide the preparation of the novel composite atomizing agent with a deratization function. The preparation comprises the steps of: mixing and stirring the novel insecticide and rodenticide, the cosolvent and the surface active agent in percentage by weight for one hour, thus a mixed substance A is prepared; mixing and stirring the mixed substance A and 50% of water in percentage by weight for one hour, thus a mixed substance B is prepared; mixing and stirring the atomizing agent and the residual 50% of water in percentage by weight for one hour, thus a mixed substance C is prepared; and mixing and stirring the mixed substance B and the mixed substance C for one hour, then standing for one hour, measuring the content of the mixed substances, and packaging the qualified mixed substances, thus a qualified product is obtained. The novel composite atomizing agent with the deratization function has the characteristics that the atomizing agent is harmless to human and animals, can not generate harmful substances, does not pollute environment, is safe and environmentally-friendly, has no stimulation to skin mucosa, has no corrosion to articles and fabrics, has no irritating smell, is colorless, is not influenced by the environment, organic matters, acid, alkali, and other physical and chemical factors, has long durability and low cost, and the like.
Description
Technical field
The invention belongs to the product scope that kills mouse; Relate to a kind of NEW TYPE OF COMPOSITE Alevaire with the function of killing mouse, the composition that especially contains new type disinsection rat-bane, surfactant, Alevaire, cosolvent is as preparation and application with compound Alevaire of the function of killing mouse.
Background technology
For a long time, extensively adopted anticoagulation kill mouse bait formulation and fumigant etc. at the product scope that kills mouse always.
Anticoagulation kill mouse bait formulation be mostly diphacinone-Na, Bromadiolone, kill its battle, big grand etc.
Diphacinone-Na is claimed Diphacinone again, is mainly used in ground such as urban and rural residents' dwelling house, grain depot, factory, car, ship, harbour and kills home mouse, also can be used for dry land, paddy field, forest zone, grassland and kill field rodent, but effect slowly.
The High Effect Raticide that Bromadiolone is a kind of good palatability, toxicity is big, the target spectrum is wide.It not only possess first generation anticoagulations such as diphacinone-Na, coumatetralyl kill mouse the bait formulation effect slowly, be difficult for causing that muroid realizes, annihilates easily the characteristics of bandicoot in surperise; But also having the strong outstanding advantage of acute toxicity, single dose uses and can both prevent and kill off effectively various mouse.Simultaneously, it can also be killed effectively the first generation anticoagulation bait formulation that kills mouse is produced the bandicoot of resistance.Aquatiles such as fish, aquatic insect there is moderate toxicity.These article are high toxin preparation, and eye is had excitant, flammable.
Killing its battle is novel second generation anticoagulant property rodenticide, its unique formula, and palatability is good, is easy to mouse and gets food rapidly.Unique particle poison bait can accurately be controlled consumption, cuts the waste, and can not produce secondary poisoning, to people and Environmental security.
Big swelling claims that again the bromo biphenyl mouse is grand, and pure article are yellow-white or pale powder, and are water insoluble; Dissolve in ethanol, acetone etc.; To severe toxicity such as domestic animal, poultry, fish there is little poison, for second generation anticoagulation kills the mouse bait formulation; Be a kind of of present anticoagulant toxic maximum, have the two-fold advantage of acute and chronic rodenticide.Good palatability can not produce the food refusal effect, can kill the first generation anticoagulation muroid that bait formulation develops immunity to drugs that kills mouse.
But in use there is following shortcoming:
1, be the bait formulation preparation, directly dispenser is sprayed, and has limited range of application;
2, strong toxicity has harmfulness to other animals;
3, bait formulation preparation, contaminated environment is eaten by mistake easily;
4, make mouse that pesticide resistance arranged for a long time, influence killing effect.
Mostly fumigant is Celfume and vikane etc.
Celfume is a kind of liquid of colorless and odorless; It has strong fumigation action, can be efficient, kill various pests wide spectrum, soil is had very strong penetration capacity; Can be penetrated in the organism that rots to decompose, thereby reach the purpose of deinsectization, diseases prevention, weeding.Along with closing on of World Earth Day, this methyl bromide fumigation agent that is widely used has caused global concern.Since the forties in 20th century, just be widely used by various countries always.Because it has plurality of advantages, thereby very popular; Caused many environment and soil issues because of it again, thus controversial.Rise the nineties in 20th century; Countries in the world government all is tending towards stopping using this fumigant from security consideration; Also halted by United Nations Environment Programme for the previous period, it is a kind of material of ozone layer depletion, according to " Montreal Protocol Copenhagen amendment "; Developed country eliminated in 2005, and developing country also will eliminate in 2015.
Vikane is no color or smell gas at normal temperatures and pressures; Have that diffusion permeability is strong, broad spectrum disinfestation, dosage are economized, residual quantity is low, desinsection speed fast, the gas time of loosing is short, low temperature is easy to use, to germination rate characteristics such as influence and toxicity is not lower, be applied to the survive the winter control of insect, the tree moth dryness insect that lives of warehouse, freighter, container and building, reservoir dam, termite control and gardens more and more widely.China has just begun to manufacture experimently vikane the beginning of the eighties.But U.S.'s scientist's current research shows, can become a kind of strong effect greenhouse gases after being dispersed into air, and it endangers greater than the previous judgement of scientist, and its acute toxic action mainly damages central nervous system, causes convulsions.Environment there is harm, can pollutes water body.It is reported that it is 4800 times of one kilogram of carbonic acid gas that one kilogram of vikane is discharged in the atmosphere effect to global warming, but it is increasing with annual 5% speed.
Summary of the invention
The objective of the invention is to provides a kind of NEW TYPE OF COMPOSITE Alevaire with the function of killing mouse to the various drawbacks of existing rat-bane with for solving the technical problem that exists in the known technology; Especially with the composition of new type disinsection rat-bane, surfactant, Alevaire, cosolvent as a kind of preparation and application with compound Alevaire of the function of killing mouse, it has characteristics such as safety, efficient, wide spectrum, convenient, low toxicity, environmental protection.
One of the object of the invention provides a kind of NEW TYPE OF COMPOSITE Alevaire with the function of killing mouse; Especially a kind of composition with new type disinsection rat-bane, surfactant, Alevaire, cosolvent is as the preparation of the compound Alevaire with the function of killing mouse, and the compound Alevaire with the function of killing mouse of the present invention contains following component by mass percent:
| Component | Mass percent % |
| The new type disinsection rat-bane | 0.1~15 |
| Surfactant | 10~30 |
| Alevaire | 0~40 |
| Cosolvent | 1~10 |
| Water | Surplus |
New type disinsection rat-bane described in the component is selected from: seven fluorine methothrins, seven fluorine methyl ethers go permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to remove one or more the mixture in permethrin etc.
Seven fluorine methothrins wherein, chemical name: 2,3,5,6-tetrafluoro-4-methoxyl methyl carbobenzoxy-3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
17H
15ClF
7O
3Molecular weight: the 448.6th, a kind of novel pyrethroid pesticide is mainly used in hygienic insecticides such as preparation aerosol and propellant, with pests such as control cockroach, mosquito, ant, flea, dirt mite, silverfish, cricket, spider, mouse; Have the very strong suction and the ability of tagging; Have the stronger ability of killing than tetrafluoro methothrin, be superior to seven fluorobenzene chrysanthemum esters, structural formula is following:
Wherein seven fluorine methyl ethers remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxyl methyl carbobenzoxy ester, molecular formula: C
18H
17F
7O
3, molecular weight: 414.1, belong to novel pyrethroid pesticide, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Wherein seven fluorine methoxies remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxy benzyl ester, molecular formula: C
17H
15F
7O
3, molecular weight: 400.1, belong to novel pyrethroid pesticide, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Wherein seven fluorine remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methyl benzyl ester, molecular formula: C
17H
15F
7O
2, molecular weight: 384.1, belong to novel pyrethroid pesticide, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Wherein seven fluorine go first to remove permethrin, chemical name: 3-(3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-ptfe benzyl, molecular formula: C
16H
13F
7O
2, molecular weight: 370.1, belong to novel pyrethroid pesticide, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Seven fluorine methoxy chrysanthemum esters wherein, chemical name: 3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methoxy benzyl ester, molecular formula: C
17H
15ClF
7O
3, molecular weight: 434.6, belong to novel pyrethroid pesticide, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Seven fluorine remove first chrysanthemum ester, chemical name: 3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid-2,3,5,6-tetrafluoro-4-methyl benzyl ester, molecular formula: C
16H
13ClF
7O
2, molecular weight: 434.6, belong to novel pyrethroid pesticide, have the very strong suction and the ability of tagging, can prevent and treat pests such as cockroach, mosquito, ant, flea, cricket, spider, mouse, structural formula is following:
Surfactant described in the component is selected from: (TX/NP)-and one or more mixture in n, OP-10, AE0-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc.
(TX/NP)-n wherein, chemical name: NPE, have been widely used at washing agent, printing and dyeing, chemical industry, good penetration, emulsification, dispersion, antiacid, alkali resistant, anti-hard water, anti-reduction, oxidation resistance are arranged; Wherein n is 3,4,6 among (TX/NP)-n; 7,10,15.
OP-10 wherein; Chemical name: APES; Main with the emulsifier on the used as pesticides, also be the good finishing agent of textile industry, antifoaming agent, washing agent, dispersant, emulsifier, softening agent, dyeing assistant, fibre finishing, crude oil demulsifier etc.
AE0-n wherein; Chemical name: AEO; Chemical composition: natural fatty alcohol and ethylene oxide adduct, wherein the n among the AE0-n is 3 or 9, AEO-3 can make water-in-oil emulsifier; AEO-9 is mainly used in Wool detergent, woolen industry degreasing agent, fabric detergent with the liquid detergent active component, and general industry is as emulsifier.
Isomery alcohol APEO wherein, chemical composition: isomery alcohol and polymers of ethylene oxide belong to nonionic surface active agent; Structural formula: RO-(C2H4O) n H: (general R is C8, C11, C13); Performance: these article are colourless or weak yellow liquid, and emulsifying capacity is strong, and surface-active is high; Anti-hard water, the washing performance is strong, and chemical stability and Environmental compatibility are good in the pH value scope of broad.Can be used as dispersant, wetting agent, bleeding agent, washing agent, be widely used in family expenses and industrial washing field, leather is had tangible degreasing; Be specially adapted to do emulsifier, better performances.
Wherein isomery alcohol polyoxyethylene poly-oxygen propylene aether is to react in proportion with oxirane, expoxy propane with isomery alcohol to form, and is one and has 100% biodegradable novel, low bubble, efficient, environment-friendly type non-ionic surface active agent.Good, acidproof, alkaline-resisting, anti-oxidant with various surfactants, auxiliary agent, additive, solvent compatibility.Characteristics: have excellent emulsification, dispersibility; Have excellent permeation property and alkali tolerance; Have excellent washing, dirt-removing power; Extremely low foam belongs to ultralow bubble interfacial agent, does not use antifoaming agent, does not therefore have silicon spot problem; Nontoxic, non-stimulated, free from extraneous odour, nonflammable explosive, safe in utilization.
Alevaire described in the component is selected from: the ethylene glycol APEO; 1, the 2-dihydroxypropane; The mixture of one or more in 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.
Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.It has passed through the U.S. FDA authentication, meets American Pharmacopeia (USP), NF (NF), and Food Chemistry code (FCC) standard is widely used in the production of industries such as food, pharmacy, feed, personal care articles, chemistry.It is the water white transparency thick liquid, and it is sweet to distinguish the flavor of, and has hygroscopicity, and is miscible with water, lower aliphatic alcohols, glycerine, acetic acid, acetone, can be used as solvent, dispersant, lubricant, emulsifier etc. and is used for cosmetics, agricultural chemicals, food, medicine and other fields.
1; The 2-dihydroxypropane is the stable water imbibition liquid of colourless thickness, and almost tasteless odorless is with water, ethanol and multiple immiscible organic solvent; As gas-chromatography fixer, solvent, antifreeze, plasticizer, dehydrating agent, carrier solvent, wetting agent, NMF, anticaking agent, antioxidant, surface-active, stabilizing agent, thickener, emulsifier, processing aid; It classifies food processing aid as among the GB 2760-96, and its aqueous solution is effective antifreeze, can be used as NMF in the cosmetics; Softening agent, solvent etc.
Trihydroxy propane outward appearance is the water white transparency thick liquid; Odorless, tasteless, have hygroscopicity, humectation property, a property of softening; It is neutral that the aqueous solution is; Can mix arbitrarily with water, ethanol, methyl alcohol, have good freeze-proof, be widely used in industries such as weaving, printing and dyeing, papermaking, printing, washing agent, daily use chemicals, system wine, food, cigarette, glassine paper, enamel, oil, electronics, rubber, plastics, process hides, chemistry, chemical fibre.Main as NMF, humectant, hygroscopic agent, lubricant, softening agent, softening agent, thickener, plasticizer, thinner, antifreezing agent etc.
The triethylene-glycol outward appearance is that no color or smell has the hygroscopicity thick liquid, can be miscible with water, ethanol, benzene, toluene, be insoluble in ethers, and be insoluble to benzinum, have hygroscopicity, have the character of pure and mild ether.As solvent, extractant, desiccant, air disinfection agent etc.The toxicity data are little poison, LD
50(rat oral) 16.8ml/kg. is to eyes and skin nonirritant.
Cosolvent described in the component is selected from: 95% ethanol.
Water described in the component is deionized water.
Each component is role in the present invention:
New type disinsection rat-bane described in the component is novel suction and contact killing type medicament, has and knocks down fast and the quick-acting lethal effects of killing, and to mucocutaneous nonirritant, to metal and fabric non-corrosiveness, does not receive organic substance influence, good stability;
Surfactant described in the component plays emulsification and dissolution;
Cosolvent described in the component plays dissolution and antifreeze effect, plays synergistic effect simultaneously;
Alevaire described in the component plays good dispersion, atomizing, synergy and antifreeze effect, to mucocutaneous non-stimulated, good stability is harmless to article, to metal and fabric non-corrosiveness.
The NEW TYPE OF COMPOSITE Alevaire that the present invention is a kind of to have the function of killing mouse is the proportioning of following mass percent most preferably:
| ?Component | Mass percent % |
| The new type disinsection rat-bane | 1~10 |
| Surfactant | 15~25 |
| Alevaire | 5~35 |
| Cosolvent | 2~8 |
| Water | Surplus |
New type disinsection rat-bane described in the component is selected from: seven fluorine methothrins, seven fluorine methyl ethers go permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to remove one or more the mixture in permethrin etc.
Surfactant described in the component is selected from: (TX/NP)-one or more mixture in n, OP-10, AE0-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc., wherein the n among (TX/NP)-n is 3,4; 6; 7,10,15; N among the AEO-n is 3 or 9.
Cosolvent described in the component is selected from: 95% ethanol.
Alevaire described in the component is selected from: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
Water described in the component is: deionized water.
Another object of the present invention is, a kind of compound method with NEW TYPE OF COMPOSITE Alevaire of the function of killing mouse is provided, it mainly be new type disinsection rat-bane, surfactant, Alevaire, cosolvent and water through mix, reaction, stir, leave standstill formulated:
The compound method of the above-mentioned compound Alevaire with the function of killing mouse that contains the mass percent component is following:
1, new type disinsection rat-bane, cosolvent are mixed stirring with surfactant by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, above-mentioned Alevaire is mixed stirring with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
The object of the invention also comprises provides above-mentioned application with NEW TYPE OF COMPOSITE Alevaire of the function of killing mouse:
1, through the multi-functional atomizer (patent No.: 201020662097.X) with the Portable atomizer (patent No.: 201020682031.7) be applied to the deratization of the environment of public health field, food processing field and medicine and hygiene fields, can effectively prevent and eliminate pests such as mouse;
2, through the multi-functional atomizer (patent No.: 201020662097.X) with the Portable atomizer (patent No.: 201020682031.7) be applied to the internal container of inspection and quarantine system; The deratization of railway carriage, cabin, automotive interior can effectively prevent and remove pests such as mouse;
3, through the multi-functional atomizer (patent No.: 201020662097.X) with the Portable atomizer (patent No.: 201020682031.7) be applied to the environment deratization in livestock and poultry cultivation field, can effectively prevent and remove pests such as mouse.
Combination matching between each component of NEW TYPE OF COMPOSITE Alevaire with the function of killing mouse of the present invention has following advantage and good effect:
1, harmless to people, animal, can not produce harmful substance, do not pollute the environment safety and environmental protection;
2, non-stimulated to skin and mucosa, article and fabric there are not corrosivity;
3, have no irritating odor, colourless, do not receive the influence of environment, organic matter, acid, alkali and other physics, chemical factor.
The experimental study that NEW TYPE OF COMPOSITE Alevaire product with the function of killing mouse according to the invention is carried out:
The lethality rate contrast (cooperative synergism effect experiment) of the disinfestation and deratization composition of experimental example 1 said component and the agent of one-component disinfestation and deratization:
1, the prescription of one-component disinfestation and deratization agent described in the component and the agent of component disinfestation and deratization is formed:
| Component | Prescription |
| A | Be seven fluorine methothrins |
| B | Be that seven fluorine methyl ethers remove permethrin |
| A+B | The combination of consumption (or content) separately separately for A and B |
3, result of the test:
| Component | To home mouse 24H lethality rate |
| A | ＞ 70% |
| B | ＞ 70% |
| A+B | ＞ 95% |
Investigate by above-mentioned experimental technique; When disinfestation and deratization agent that will be wherein is selected from the seven fluorine methoxy chrysanthemum esters, the seven fluorine methoxies that go except that seven fluorine methothrins, seven fluorine methyl ethers the permethrin and goes permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to remove one or more the mixture in the permethrin etc.; Also obtained effect like the same Synergistic of experimental example 1 (cooperative synergism effect experiment); Promptly ideal with killing mouse of A+B; Simultaneously; The combining form of the A+B of described product is being investigated killing in the process home mouse; The killing effect that has equally also shown the good Synergistic of A+B combination, special feature promptly of the present invention be, after the disinfestation and deratization agent in the component goes permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to go one or more the mixture Pesticidal combination combination in the permethrin etc. by seven fluorine methothrins, seven fluorine methyl ethers; It has the outstanding activity of killing, and this activity is to be predicted out by the killing action of known single component.
The killing effect of 2 pairs of mouse of Test Example:
Test Example 3 certain port container (volume: 33.2m3) to the on-the-spot killing effect of mouse:
Embodiment
Embodiment 1
| Component | Mass percent % |
| Seven fluorine methothrins | 1~5 |
| OP-10 | 15~25 |
| 95% ethanol | 2~8 |
| 1, the 2-dihydroxypropane | 5~20 |
| Trihydroxy propane | 5~20 |
| Water | Surplus |
1, seven fluorine methothrins, 95% ethanol are mixed stirring with OP-10 by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 1,2-dihydroxypropane, trihydroxy propane mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 2
| Component | Mass percent % |
| Seven fluorine methyl ethers remove permethrin | 1~5 |
| TX-10 | 15~25 |
| 95% ethanol | 2~8 |
| 1, the 2-dihydroxypropane | 5~20 |
| Trihydroxy propane | 5~20 |
| Water | Surplus |
1, goes permethrin, 95% ethanol to mix to stir by above-mentioned mass percent seven fluorine methyl ethers and be mixed with compounding substances A in 1 hour with TX-10;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 1,2-dihydroxypropane, trihydroxy propane mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 3
| Component | Mass percent % |
| Seven fluorine methyl ethers remove permethrin | 1~5 |
| AEO-3 | 15~25 |
| 95% ethanol | 2~8 |
| 1, the 2-dihydroxypropane | 5~20 |
| Trihydroxy propane | 5~20 |
| Water | Surplus |
1, goes permethrin, 95% ethanol to mix to stir by above-mentioned mass percent seven fluorine methyl ethers and be mixed with compounding substances A in 1 hour with AEO-3;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 1,2-dihydroxypropane, trihydroxy propane mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 4
| Component | Mass percent % |
| Seven fluorine remove first chrysanthemum ester | 1.5~3 |
| Seven fluorine methyl ethers remove permethrin | 1~5 |
| NP-10 | 15~25 |
| Ethylene glycol APEO 200 | 5~20 |
| Triethylene-glycol | 5~20 |
| 95% ethanol | 3~7 |
| Water | Surplus |
1, goes first chrysanthemum ester, seven fluorine methyl ethers to go permethrin, 95% ethanol to mix to stir by above-mentioned mass percent in seven fluorine and be mixed with compounding substances A in 1 hour with NP-10;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, ethylene glycol APEO 200, triethylene-glycol are mixed stirring with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 5
| Component | Mass percent % |
| Seven fluorine remove permethrin | 1.5~3 |
| Seven fluorine methoxy chrysanthemum esters | 1~5 |
| OP-10 | 5~25 |
| TX-7 | 5~25 |
| Ethylene glycol APEO 400 | 5~20 |
| Triethylene-glycol | 5~20 |
| 95% ethanol | 4~8 |
| Water | Surplus |
1, goes permethrin, 95% ethanol to mix to stir by above-mentioned mass percent in seven fluorine methoxy chrysanthemum esters, seven fluorine and be mixed with compounding substances A in 1 hour with OP-10, TX-7;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, ethylene glycol APEO 400, triethylene-glycol are mixed stirring with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 6
| Component | Mass percent % |
| Seven fluorine methothrins | 0.5~2.5 |
| Seven fluorine methyl ethers remove permethrin | 0.5~2.5 |
| OP-10 | 5~25 |
| AEO-9 | 5~25 |
| 1, the 2-dihydroxypropane | 5~15 |
| Trihydroxy propane | 5~15 |
| 95% ethanol | 5~8 |
| Water | Surplus |
1, goes permethrin, 95% ethanol to mix to stir by above-mentioned mass percent seven fluorine methothrins, seven fluorine methyl ethers and be mixed with compounding substances A in 1 hour with OP-10, AEO-9;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 1,2-dihydroxypropane, trihydroxy propane mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 7
| Component | Mass percent % |
| Seven fluorine methothrins | 0.5~2.5 |
| Seven fluorine methyl ethers remove permethrin | 0.5~2.5 |
| Seven fluorine remove permethrin | 0.5~2.5 |
| Isomery alcohol APEO | 15~25 |
| Tetraethylene-glycol | 5~25 |
| 95% ethanol | 5~8 |
| Water | Surplus |
1, goes permethrin, inclined to one side tefluthrin, 95% ethanol to mix to stir by above-mentioned mass percent seven fluorine methothrins, seven fluorine methyl ethers and be mixed with compounding substances A in 1 hour with isomery alcohol APEO;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, tetraethylene-glycol is mixed stirring with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 8
| Component | Mass percent % |
| Seven fluorine remove first chrysanthemum ester | 1~5 |
| Seven fluorine methyl ethers remove permethrin | 1~5 |
| Isomery alcohol APEO | 5~15 |
| OP-10 | 5~15 |
| NP-10 | 5~15 |
| Tetraethylene-glycol | 10~30 |
| 95% ethanol | 5~8 |
| Water | Surplus |
1, goes first chrysanthemum ester, seven fluorine methyl ethers to go permethrin, 95% ethanol to mix to stir by above-mentioned mass percent in seven fluorine and be mixed with compounding substances A in 1 hour with isomery alcohol APEO, OP-10, NP-10;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, tetraethylene-glycol is mixed stirring with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances C in 1 hour;
4, said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 9
| Component | Mass percent % |
| Seven fluorine methothrins | 0.5~2.5 |
| Seven fluorine methyl ethers remove permethrin | 0.5~2.5 |
| Seven fluorine remove first chrysanthemum ester | 0.5~2.5 |
| Seven fluorine go first to remove permethrin | 0.5~2.5 |
| AEO-3 | 5~15 |
| NP-15 | 5~15 |
| OP-10 | 5~15 |
| 2-ethyl-2-(methylol)-1,3 propane diols | 5~15 |
| 1, the 2-dihydroxypropane | 5~15 |
| Trihydroxy propane | 5~15 |
| 95% ethanol | 5~8 |
| Water | Surplus |
1, goes permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, 95% ethanol to mix to stir by above-mentioned mass percent seven fluorine methothrins, seven fluorine methyl ethers and be mixed with compounding substances A in 1 hour with AEO-3, NP-15, OP-10;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 2-ethyl-2-(methylol)-1,3 propane diols, 1,2-dihydroxypropane, trihydroxy propane mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 10
| Component | Mass percent % |
| Seven fluorine methothrins | 0.5~1.5 |
| Seven fluorine methyl ethers remove permethrin | 0.5~1.5 |
| Seven fluorine remove first chrysanthemum ester | 0.5~1.5 |
| Seven fluorine go first to remove permethrin | 0.5~1.5 |
| Seven fluorine remove permethrin | 0.5~1.5 |
| Seven fluorine methoxy chrysanthemum esters | 0.5~1.5 |
| TX-15 | 15~25 |
| 2-ethyl-2-(methylol)-1,3 propane diols | 5~15 |
| 1, the 2-dihydroxypropane | 5~15 |
| Trihydroxy propane | 5~15 |
| 95% ethanol | 5~8 |
| Water | Surplus |
1, goes permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to go permethrin, seven fluorine methoxy chrysanthemum esters, 95% ethanol to mix to stir by above-mentioned mass percent seven fluorine methothrins, seven fluorine methyl ethers and be mixed with compounding substances A in 1 hour with TX-15;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 2-ethyl-2-(methylol)-1,3 propane diols, 1,2-dihydroxypropane, trihydroxy propane mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
The present invention does further elaboration through above embodiment, but does not limit the scope of the invention.
The present invention is with the various variations of described scope of soverlay technique scheme and claim scope; Under the prerequisite that does not depart from technical scheme of the present invention, any improvement that those skilled in the art that the present invention did are realized easily all belongs to the present invention's scope required for protection.
Claims (9)
1. NEW TYPE OF COMPOSITE Alevaire with the function of killing mouse is characterized in that comprising following component by mass percent:
。
2. the NEW TYPE OF COMPOSITE Alevaire with the function of killing mouse as claimed in claim 1 is characterized in that comprising following most preferably component by mass percent:
。
3. the described NEW TYPE OF COMPOSITE Alevaire with the function of killing mouse of claim 1 is characterized in that described new type disinsection rat-bane is selected from: seven fluorine methothrins, seven fluorine methyl ethers go permethrin, seven fluorine methoxy chrysanthemum esters, seven fluorine methoxies to go permethrin, seven fluorine to go first chrysanthemum ester, seven fluorine to go first to go permethrin, seven fluorine to remove one or more the mixture in permethrin etc.
4. the NEW TYPE OF COMPOSITE Alevaire with the function of killing mouse as claimed in claim 1; It is characterized in that described surfactant is selected from: (TX/NP)-one or more mixture in n, OP-10, AE0-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc., wherein the n among (TX/NP)-n is 3,4; 6; 7,10,15; N among the AEO-n is 3 or 9.
5. the NEW TYPE OF COMPOSITE Alevaire with the function of killing mouse as claimed in claim 1; It is characterized in that described Alevaire is selected from: ethylene glycol APEO, 1; The mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
6. the NEW TYPE OF COMPOSITE Alevaire with the function of killing mouse as claimed in claim 1 is characterized in that described cosolvent is selected from: 95% ethanol.
7. the NEW TYPE OF COMPOSITE Alevaire with the function of killing mouse as claimed in claim 1 is characterized in that described water is: deionized water.
8. like the described arbitrary preparation of claim 1-7, it is characterized in that: new type disinsection rat-bane, cosolvent are mixed to stir being mixed with compounding substances A in 1 hour by above-mentioned mass percent with surfactant with NEW TYPE OF COMPOSITE Alevaire of the function of killing mouse; Said mixture matter A is mixed stirring be mixed with compounding substances B in 1 hour with the water of above-mentioned mass percent 50%; Above-mentioned Alevaire is mixed stirring be mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%; Said mixture matter B is mixed stirring 1 hour with said mixture matter C, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
9. like the described arbitrary application of claim 1-7 with NEW TYPE OF COMPOSITE Alevaire of the function of killing mouse; It is characterized in that: be applied to the deratization of the environment of public health field, food processing field and medicine and hygiene fields through multi-functional atomizer and Portable atomizer, can effectively prevent and eliminate pests such as mouse; Be applied to the internal container of inspection and quarantine system through multi-functional atomizer and Portable atomizer, the deratization of railway carriage, cabin, automotive interior can effectively prevent and remove pests such as mouse; Cross multi-functional atomizer and Portable atomizer and be applied to the environment deratization in livestock and poultry cultivation field, can effectively prevent and remove pests such as mouse.
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| CN201110125893A CN102308789A (en) | 2011-05-16 | 2011-05-16 | Preparation and applications of novel composite atomizing agent with deratization function |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201110125893A CN102308789A (en) | 2011-05-16 | 2011-05-16 | Preparation and applications of novel composite atomizing agent with deratization function |
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|---|---|---|---|---|
| CN1071551A (en) * | 1991-10-21 | 1993-05-05 | 河北省肃宁县商业局圳宁精细化工厂 | Multi-effect atomizing insect and moth repelling agent |
| US20020147179A1 (en) * | 2000-12-15 | 2002-10-10 | Munagavalasa Murthy S. | Insect repellant formulation deliverable by piezoelectric device |
| CN101637178A (en) * | 2009-06-05 | 2010-02-03 | 江苏扬农化工股份有限公司 | Pesticide spray |
| CN101755827A (en) * | 2009-10-29 | 2010-06-30 | 深圳诺普信农化股份有限公司 | Insecticidal composition with synergy effect |
| CN101897342A (en) * | 2010-06-04 | 2010-12-01 | 贵阳柏丝特化工有限公司 | Preparation of insecticide solution and application thereof |
| CN102037977A (en) * | 2011-01-18 | 2011-05-04 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing thiacloprid amide and synthetic pyrethroid insecticide |
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1071551A (en) * | 1991-10-21 | 1993-05-05 | 河北省肃宁县商业局圳宁精细化工厂 | Multi-effect atomizing insect and moth repelling agent |
| US20020147179A1 (en) * | 2000-12-15 | 2002-10-10 | Munagavalasa Murthy S. | Insect repellant formulation deliverable by piezoelectric device |
| CN101637178A (en) * | 2009-06-05 | 2010-02-03 | 江苏扬农化工股份有限公司 | Pesticide spray |
| CN101755827A (en) * | 2009-10-29 | 2010-06-30 | 深圳诺普信农化股份有限公司 | Insecticidal composition with synergy effect |
| CN101897342A (en) * | 2010-06-04 | 2010-12-01 | 贵阳柏丝特化工有限公司 | Preparation of insecticide solution and application thereof |
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Application publication date: 20120111 |