CN102308844A - Preparation and applications of pesticidal atomizing agent - Google Patents
Preparation and applications of pesticidal atomizing agent Download PDFInfo
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- CN102308844A CN102308844A CN201110127499A CN201110127499A CN102308844A CN 102308844 A CN102308844 A CN 102308844A CN 201110127499 A CN201110127499 A CN 201110127499A CN 201110127499 A CN201110127499 A CN 201110127499A CN 102308844 A CN102308844 A CN 102308844A
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Abstract
The invention relates to preparation and applications of a pesticidal atomizing agent. The pesticidal atomizing agent comprises the following components in percentage by weight: 0.5-15% of pesticidal composition, 5-40% of surface active agent, 5%-40% of atomizing agent, and the balance of water. The invention aims to provide the preparation of the pesticidal atomizing agent. The preparation comprises the steps of mixing and stirring the pesticidal composition and surface active agent in percentage by weight for one hour, thus a mixed substance A is prepared; mixing and stirring the mixed substance A and 50% of water in percentage by weight for one hour, thus a mixed substance B is prepared; mixing and stirring the atomizing agent and the residual 50% of water in percentage by weight for one hour, thus a mixed substance C is prepared; and mixing and stirring the mixed substance B and the mixed substance C for one hour, then standing for one hour, measuring the content of the mixed substances, and packaging the qualified mixed substances, thus a qualified product is obtained. The pesticidal atomizing agent has the characteristics that the atomizing agent is harmless to human and animals, can not generate harmful substances, can not pollute the environment, is safe and environmentally-friendly, has no irritation to skin mucous membrane, has no corrosiveness to articles and fabrics, has no irritating smell, and is colorless, is not influenced by the environment, organic matters, acid, alkali, and other physical and chemical factors, has long durability and low cost, and the like.
Description
Technical field
The invention belongs to the desinsection product scope, relate to a kind of desinsection Alevaire, especially contain of preparation and the application of the composition of Pesticidal combination, surfactant, Alevaire as the desinsection Alevaire.
Background technology
For a long time, be mostly the pyrethroid medicament at the employed insecticide of health and pest prevention and control field, like Permanone, tetramethrin, decis, flucythrinate, cypermethrin etc.
Permanone has stronger tagging and stomach poison function, has that the power of knocking down is strong, the fireballing characteristics of desinsection.More stable to light, also slower to the pest resistance development under equal service condition, efficient to lepidopterous larvae.Can be used for various pests such as crop control cabbage caterpillar, aphid, cotton bollworm, pink bollworm, cotten aphid, green plant bug, striped flea-beetle, peach fruit borer, phyllocnistis citrella stainton, potato ladybug, tea geometrid, tea caterpillar, the thin moth of tea such as vegetables, tealeaves, fruit tree, cotton, sanitary insect pests such as mosquito, fly, flea, cockroach, louse are also had good effect.
Tetramethrin is a kind of powerful synthetic pesticide, belongs to pyrethroid.Sanitary insect pests such as mosquito, fly are had quick down effect, but the poor performance that causes death has anabiosis, use therefore will be mixed with the medicament of other good disinsection effect.This medicine has certain effect of driveing to blattaria, perch is run out under the effect of blattaria at tetramethrin at dark place and receives the poisoning of other insecticides and causes death.This medicine is that world health organisation recommendations is used for one of sanitarian main insecticide, but result of use is not obvious separately.
Decis has another name called " decis ", is the highest a kind of of virulence in the present chrysanthemum ester insecticide.Insecticidal spectrum is wide; Effective to various pests such as Lepidoptera, orthoptera, thrips, Semiptera, diptera, coleopteras, but very low or invalid basically to preventive effects such as mite class, scale insect, mirid pentatomids, also can stimulate the breeding of mite class; When the worm mite is concurrent, use with specialized acaricide.Decis belongs to the poison class of poisoning.The skin contact can cause irritation, red papule occurs.During acute poisoning, the lighter has headache, dizziness, feels sick, vomiting, poor appetite, weak, and weight person muscle bundle also can occur and tremble and twitch, and the WHO hazard rating is the II level, medium harmfulness.
Flucythrinate is claimed flucythrinate again, belongs to pyrethrin pesticide, is the moderate toxicity insecticide, the mode of action with tag, stomach toxicity is main, do not have stifling and systemic action, insecticidal spectrum is wide, drug effect is rapid.Can use with general insecticide, bactericide, its biologically active is lower than by Influence of Temperature and kills chrysanthemum ester and chlorobenzene chrysanthemum ester, and the WHO hazard rating is the II level, medium harmfulness.
Cypermethrin is claimed struggle again, belongs to the chrysanthemum esters medicine, is the moderate toxicity insecticide, and insecticidal spectrum is wide, and drug effect is rapid, and the WHO hazard rating is the II level, medium harmfulness.
The long-term use of above-mentioned pyrethroid medicament makes sanitary insect pest such as insects such as cockroach, mosquitos and flies improve greatly the pesticide resistance of this type of medicament, the generally reduction of control efficiency occurred.
Summary of the invention
The objective of the invention is to provides a kind of preparation and application of desinsection Alevaire to the various drawbacks of existing insecticide with for solving the technical problem that exists in the known technology; Especially with preparation and the application as the desinsection Alevaire of the composition of Pesticidal combination, surfactant, Alevaire, it has characteristics such as safety, efficient, wide spectrum, low toxicity, environmental protection.
One of the object of the invention provides a kind of desinsection Alevaire, and especially a kind of composition with Pesticidal combination, surfactant, Alevaire is as the preparation of desinsection Alevaire, and composite insecticidal Alevaire of the present invention contains following component by mass percent:
| Component | Mass percent % |
| Pesticidal combination | 0.5~15 |
| Surfactant | 5~40 |
| Alevaire | 5~40 |
| Water | Surplus |
Pesticidal combination described in the component is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
Es-EXTHIN wherein, chemical name: dextrorotation-trans-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid-(R, S)-2-methyl-3-pi-allyl-4-oxo-ring penta-2-alkenyl esters, molecular formula: C
19H
26O
3, molecular weight: 302.41, be the former medicine of a kind of wide spectrum pyrethroid, for upsetting the contact killing type never poison of aixs cylinder conduction; Act on insect and cause the violent paralysis effect of ordering, reclining falls, and until death, very strong tagging and repellent action is arranged; The power of knocking down is stronger, and it is strong 2 times that its insecticidal toxicity is executed allethrin than the right side, and knocks down the active tetramethrin that surpasses; Mainly be used for preventing and treating flying pests such as mosquito, fly, mosquito, fly, wasp, cockroach, flea, ant are had special effect, structural formula is following:
。
S-bioallethrin wherein, chemical name: (1R)-trans-chrysanthemate-(S)-and 2-methyl-3-pi-allyl-4-oxo-ring penta-2-alkenyl esters, molecular formula: C
19H
26O
3, molecular weight: 302.41, be a kind of wide spectrum pyrethroid insecticides, very strong tagging and repellent action arranged, the power of knocking down is stronger, and insecticidal toxicity is 4.9 times of allethrin, and structural formula is following:
The trans phenothrin of wherein rich dextrorotation is claimed d-phenothrin again, chemical name: (1R)-trans-2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic)-cyclopropane-carboxylic acid-3-phenoxy benzyl ester, molecular formula: C
23H
26O
3, molecular weight: 350.45, these article are unique nontoxic products in the pyrethroid, are that the unique allowance of the U.S. is used for the insecticide that civil aviaton uses, and are one of insecticides of world health organisation recommendations.These article have for insect tags and stomach poison function, and insecticidal spectrum is wide, high 8.5 ~ 20 times than the Dalmatian chrysanthemum class to the deadly power of insect, can be widely used in the control of household, warehousing, public health, industrial area insect, and structural formula is following:
。
Tetrafluoro methothrin wherein, chemical name: 2,2-dimethyl-3-(2-methyl isophthalic acid-acrylic) cyclopropane-carboxylic acid 2,3,5,6-tetrafluoro-4-(methoxy) benzyl ester, molecular formula: C
19H
22F
4O
3, molecular weight: the 374.37th, suck and the contact killing type insecticide agent, knock down and kill activity to what sanitary insect pests such as mosquito, fly had a brilliance.In the experimental concentration scope; The acute toxicity and chronic toxicity of tetrafluoro methothrin is extremely low, and teratogenesis, carcinogenic do not observe, to Aedes aegypti, housefly, Groton bug, that a curtain casemaking clothes moth is knocked down speed is fast; Consumption is little; Be suitable for the hygienic biocide goods, belong to broad spectrum pesticide, ability effectively preventing sanitary insect pest and storage insect; Dipteral insect such as mosquito class are had quick knockdown effect, and cockroach, bedbug are had good residual effect, structural formula is following:
。
Transfluthrin wherein, chemical name: 2,3,5, the 6-ptfe benzyl (1R, 3S)-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
15H
12Cl
2F
4O
2, molecular weight: 371.16, this article desinsection wide spectrum, ability effectively preventing sanitary insect pest and storage insect; Dipteral insect such as mosquito class are had quick knockdown effect, and cockroach, bedbug are had good residual effect, structural formula is following:
。
Seven fluorobenzene chrysanthemum esters wherein.Chemical name: 2,3,5,6-tetrafluoro-4-methyl-benzyl (Z)-(1RS, 3RS)-3-(2-chloro-2,3,3-trifluoropropyl-1-thiazolinyl)-2,2-dimethyl cyclopropane carboxylic acid ester, molecular formula: C
17H
14ClF
7O
2, molecular weight: 418.73, these article belong to pyrethroid insecticides, are soil insecticides, can prevent and treat coleoptera and the Lepidoptera and some Diptera pest that perch in soil well, than transfluthrin stronger killing action are arranged, and structural formula is following:
Surfactant described in the component is selected from: (TX/NP)-and one or more mixture in n, OP-10, AEO-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc.
(TX/NP)-n wherein, chemical name: NPE, have been widely used at washing agent, printing and dyeing, chemical industry, good penetration, emulsification, dispersion, antiacid, alkali resistant, anti-hard water, anti-reduction, oxidation resistance are arranged; (TX/NP)-n among the n is 3,4,6; 7,10,15..
OP-10 wherein; Chemical name: APES; Main with the emulsifier on the used as pesticides, also be the good finishing agent of textile industry, antifoaming agent, washing agent, dispersant, emulsifier, softening agent, dyeing assistant, fibre finishing, crude oil demulsifier etc.
AEO-n wherein, chemical name: AEO, chemical composition: natural fatty alcohol and oxirane synthetic; N among the AEO-n is 3 or 9; AEO-3 can make water-in-oil emulsifier, and AEO-9 is mainly used in Wool detergent, woolen industry degreasing agent, and general industry is used emulsifier.
Isomery alcohol APEO wherein, chemical composition: isomery alcohol and polymers of ethylene oxide belong to nonionic surface active agent; Structural formula: RO-(C2H4O) n H: (general R is C8, C11, C13); Performance: these article are colourless or weak yellow liquid, and emulsifying capacity is strong, and surface-active is high; Anti-hard water, the washing performance is strong, and chemical stability and Environmental compatibility are good in the pH value scope of broad.Can be used as dispersant, wetting agent, bleeding agent, washing agent, be widely used in family expenses and industrial washing field, leather is had tangible degreasing; Be specially adapted to do emulsifier, better performances.
Wherein isomery alcohol polyoxyethylene poly-oxygen propylene aether is to react in proportion with oxirane, expoxy propane with isomery alcohol to form, and is one and has 100% biodegradable novel, low bubble, efficient, environment-friendly type non-ionic surface active agent.Good, acidproof, alkaline-resisting, anti-oxidant with various surfactants, auxiliary agent, additive, solvent compatibility.Characteristics: have excellent emulsification, dispersibility; Have excellent permeation property and alkali tolerance; Have excellent washing, dirt-removing power; Extremely low foam belongs to ultralow bubble interfacial agent, does not use antifoaming agent, does not therefore have silicon spot problem; Nontoxic, non-stimulated, free from extraneous odour, nonflammable explosive, safe in utilization.
Alevaire described in the component is selected from: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.
Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.It has passed through the U.S. FDA authentication, meets American Pharmacopeia (USP), NF (NF), and Food Chemistry code (FCC) standard is widely used in the production of industries such as food, pharmacy, feed, personal care articles, chemistry.It is the water white transparency thick liquid, and it is sweet to distinguish the flavor of, and has hygroscopicity, and is miscible with water, lower aliphatic alcohols, glycerine, acetic acid, acetone, can be used as solvent, dispersant, lubricant, emulsifier etc. and is used for cosmetics, agricultural chemicals, food, medicine and other fields.
Wherein 1; The 2-dihydroxypropane is the stable water imbibition liquid of colourless thickness, and almost tasteless odorless is with water, ethanol and multiple immiscible organic solvent; As gas-chromatography fixer, solvent, antifreeze, plasticizer, dehydrating agent, carrier solvent, wetting agent, NMF, anticaking agent, antioxidant, surface-active, stabilizing agent, thickener, emulsifier, processing aid; It classifies food processing aid as among the GB 2760-96, and its aqueous solution is effective antifreeze, can be used as NMF in the cosmetics; Softening agent, solvent etc.
Wherein trihydroxy propane outward appearance is the water white transparency thick liquid; Odorless, tasteless, have hygroscopicity, humectation property, a property of softening; It is neutral that the aqueous solution is; Can mix arbitrarily with water, ethanol, methyl alcohol, have good freeze-proof, be widely used in industries such as weaving, printing and dyeing, papermaking, printing, washing agent, daily use chemicals, system wine, food, cigarette, glassine paper, enamel, oil, electronics, rubber, plastics, process hides, chemistry, chemical fibre.Main as NMF, humectant, hygroscopic agent, lubricant, softening agent, softening agent, thickener, plasticizer, thinner, antifreezing agent etc.
Wherein the triethylene-glycol outward appearance is that no color or smell has the hygroscopicity thick liquid, can be miscible with water, ethanol, benzene, toluene, be insoluble in ethers, and be insoluble to benzinum, have hygroscopicity, have the character of pure and mild ether.As solvent, extractant, desiccant, air disinfection agent etc.The toxicity data are little poison, LD
50(rat oral) 16.8ml/kg. is to eyes and skin nonirritant.
Water described in the component is: deionized water.
Each component is role in the present invention:
Pesticidal combination described in the component for sucking and the contact killing type insecticide agent, has and knocks down fast and quick-acting killing actions, to mucocutaneous nonirritant, to metal and fabric non-corrosiveness, does not receive organic substance influence, good stability;
Surfactant described in the component plays emulsification, the dissolving Pesticidal combination;
Alevaire described in the component plays good dispersion, atomizing, synergy and antifreeze effect, to mucocutaneous non-stimulated, good stability is harmless to article, to metal and fabric non-corrosiveness.
Desinsection Alevaire of the present invention is the proportioning of following mass percent most preferably:
| Component | Mass percent % |
| Pesticidal combination | 1.5~13 |
| Surfactant | 10~30 |
| Alevaire | 10~35 |
| Water | Surplus |
Pesticidal combination described in the component is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
Surfactant described in the component is selected from: (TX/NP)-one or more mixture in n, OP-10, AEO-n, isomery alcohol APEO, the isomery alcohol polyoxyethylene poly-oxygen propylene aether etc., wherein the n among (TX/NP)-n is 3,4; 6; 7,10,15; N among the AEO-n is 3 or 9.
Alevaire described in the component is selected from: ethylene glycol APEO, 1, the mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
Water described in the component is: deionized water.
Another object of the present invention is, a kind of compound method of desinsection Alevaire is provided, it mainly be adopt Pesticidal combination, surfactant, Alevaire and water through mix, reaction, stir, leave standstill formulated.
The compound method of the above-mentioned desinsection Alevaire that contains the mass percent component is following:
1, Pesticidal combination and surfactant were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, the Alevaire of above-mentioned mass percent is mixed with the water of above-mentioned mass percent remaining 50% to stir be mixed with compounding substances C in 1 hour;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
The object of the invention also comprises the application that above-mentioned desinsection Alevaire is provided:
1, through the multi-functional ultra micron atomizer (patent No.: 201020662097.X) and the Portable (patent No.: 201020682031.7) be applied to the environment of public health field, food processing field and medicine and hygiene fields and the desinsection of air, can effectively prevent and kill harmful insects such as mosquitos and flies, cockroach;
2, through the multi-functional ultra micron atomizer (patent No.: 201020662097.X) and the Portable (patent No.: 201020682031.7) be applied to the internal container of inspection and quarantine system; The air of railway carriage, cabin, automotive interior and the desinsection of environment can effectively prevent and kill harmful insects such as mosquitos and flies, cockroach;
3, through the multi-functional ultra micron atomizer (patent No.: 201020662097.X) and the Portable (patent No.: 201020682031.7) be applied to the environment in livestock and poultry cultivation field, the desinsection of indoor and air, can effectively prevent and kill harmful insects such as mosquitos and flies, cockroach.
Combination matching between each component of desinsection Alevaire of the present invention has following advantage and good effect:
1, harmless to people, animal, can not produce harmful substance, do not pollute the environment safety and environmental protection;
2, non-stimulated to skin and mucosa, article and fabric there are not corrosivity;
3, have no irritating odor, colourless, do not receive the influence of environment, organic matter, acid, alkali and other physics, chemical factor.
The experimental study that desinsection Alevaire product according to the invention is carried out:
The Pesticidal combination of experimental example 1 said component and the lethality rate of one-component insecticide contrast (cooperative synergism effect experiment):
1, the prescription of one-component insecticide described in the component and component Pesticidal combination is formed:
| Component | Prescription |
| A | Be the Es-EXTHIN |
| B | Be the trans phenothrin of rich dextrorotation |
| A+B | The combination of consumption (or content) separately separately for A and B |
2, result of the test:
| Component | To American cockroach 24H lethality rate |
| A | ＞ 70% |
| B | ＞ 70% |
| A+B | ＞ 95% |
Investigate by above-mentioned experimental technique; When Pesticidal combination that will be wherein is selected from one or more the mixture in the S-bioallethrin except that the Es-EXTHIN, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.; Also obtained effect like the same Synergistic of experimental example 1 (cooperative synergism effect experiment); Promptly ideal with the desinsection of A+B; Simultaneously; The combining form of the A+B of described product is being investigated killing in the process American cockroach, mosquitos and flies etc.; The killing effect that has equally also shown the good Synergistic of A+B combination, special feature promptly of the present invention be, the Pesticidal combination in the component by one or more the mixture combination in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc. after; It has the outstanding activity of killing, and this activity is to be predicted out by the killing action of known single component.
The killing effect of 2 pairs of American cockroaches of experimental example, culex, housefly:
Test Example 3 certain port container (volume: 33.2m3) to the on-the-spot killing effect of American cockroach, culex, housefly:
Embodiment
Embodiment 1
| Component | Mass percent % |
| The Es-EXTHIN | 0.1~5 |
| The trans phenothrin of rich dextrorotation | 0.1~5 |
| OP-10 | 15~25 |
| Ethylene glycol APEO 200 | 5~20 |
| Trihydroxy propane | 5~20 |
| Water | Surplus |
1, Es-EXTHIN, the trans phenothrin of rich dextrorotation and OP-10 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, ethylene glycol APEO 200, the trihydroxy propane of above-mentioned mass percent is mixed with the water of above-mentioned mass percent remaining 50% to stir be mixed with compounding substances C in 1 hour;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 2
| Component | Mass percent % |
| The Es-EXTHIN | 0.1~5 |
| The trans phenothrin of rich dextrorotation | 0.1~5 |
| TX-10 | 15~25 |
| 1, the 2-dihydroxypropane | 5~20 |
| Trihydroxy propane | 5~20 |
| Water | Surplus |
1, Es-EXTHIN, the trans phenothrin of rich dextrorotation and TX-10 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 1 of above-mentioned mass percent, 2-dihydroxypropane, trihydroxy propane mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 3
| Component | Mass percent % |
| The Es-EXTHIN | 0.1~5 |
| Seven fluorobenzene chrysanthemum esters | 0.1~5 |
| NP-10 | 15~25 |
| 2-ethyl-2-(methylol)-1,3 propane diols | 5~20 |
| Trihydroxy propane | 5~20 |
| Water | Surplus |
1, Es-EXTHIN, seven fluorobenzene chrysanthemum esters and NP-10 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3,2-ethyl-2-(methylol)-1,3 propane diols, the trihydroxy propane of above-mentioned mass percent is mixed with the water of above-mentioned mass percent remaining 50% to stir be mixed with compounding substances C in 1 hour;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 4
| Component | Mass percent % |
| The tetrafluoro methothrin | 0.1~5 |
| Seven fluorobenzene chrysanthemum esters | 0.1~5 |
| AEO-3 | 15~25 |
| 1, the 2-dihydroxypropane | 5~20 |
| Trihydroxy propane | 5~20 |
| Water | Surplus |
1, tetrafluoro methothrin, seven fluorobenzene chrysanthemum esters and AEO-3 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 1 of above-mentioned mass percent, 2-dihydroxypropane and trihydroxy propane mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 5
| Component | Mass percent % |
| The Es-EXTHIN | 2~10 |
| OP-10 | 5~15 |
| TX-7 | 5~15 |
| 1, the 2-dihydroxypropane | 5~20 |
| Triethylene-glycol | 5~20 |
| Water | Surplus |
1, Es-EXTHIN and OP-10, TX-7 were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 1 of above-mentioned mass percent, 2-dihydroxypropane and triethylene-glycol mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 6
| Component | Mass percent % |
| Transfluthrin | 0.1~5 |
| Seven fluorobenzene chrysanthemum esters | 0.1~5 |
| Isomery alcohol APEO | 15~25 |
| 1, the 2-dihydroxypropane | 5~20 |
| Triethylene-glycol | 5~20 |
| Water | Surplus |
1, transfluthrin, seven fluorobenzene chrysanthemum esters and isomery alcohol oxygen vinethene are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 1 of above-mentioned mass percent, 2-dihydroxypropane, triethylene-glycol mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 7
| Component | Mass percent % |
| The Es-EXTHIN | 0.5~8 |
| The S-bioallethrin | 0.5~8 |
| NP-7 | 15~25 |
| Ethylene glycol APEO 400 | 5~20 |
| Trihydroxy propane | 5~20 |
| Water | Surplus |
1, Es-EXTHIN, S-bioallethrin and NP-7 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, ethylene glycol APEO 400, the trihydroxy propane of above-mentioned mass percent is mixed with the water of above-mentioned mass percent remaining 50% to stir be mixed with compounding substances C in 1 hour;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 8
| Component | Mass percent % |
| Transfluthrin | 2~8 |
| TX-15 | 15~25 |
| Trihydroxy propane | 10~30 |
| Water | Surplus |
1, transfluthrin and TX-15 were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, the trihydroxy propane of above-mentioned mass percent is mixed with the water of above-mentioned mass percent remaining 50% to stir be mixed with compounding substances C in 1 hour;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed
Mixture carries out assay, and qualified mixture is packed, and is qualified products.
Embodiment 9
| Component | Mass percent % |
| Seven fluorobenzene chrysanthemum esters | 0.1~5 |
| Transfluthrin | 0.1~5 |
| The Es-EXTHIN | 0.1~5 |
| The trans phenothrin of rich dextrorotation | 0.1~5 |
| TX-10 | 15~25 |
| 1, the 2-dihydroxypropane | 5~20 |
| Trihydroxy propane | 5~15 |
| Water | Surplus |
1, seven fluorobenzene chrysanthemum esters, transfluthrin, Es-EXTHIN, the trans phenothrin of rich dextrorotation and TX-10 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 1 of above-mentioned mass percent, 2-dihydroxypropane, trihydroxy propane mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed
Mixture carries out assay, and qualified mixture is packed, and is qualified products.
Embodiment 10
| Component | Mass percent % |
| The Es-EXTHIN | 0.1~5 |
| The trans phenothrin of rich dextrorotation | 0.1~5 |
| Seven fluorobenzene chrysanthemum esters | 0.1~5 |
| OP-10 | 15~25 |
| 1, the 2-dihydroxypropane | 5~15 |
| Trihydroxy propane | 5~20 |
| Water | Surplus |
1, seven fluorobenzene chrysanthemum esters, Es-EXTHIN, the trans phenothrin of rich dextrorotation and OP-10 are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 1 of above-mentioned mass percent, 2-dihydroxypropane and trihydroxy propane mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Embodiment 11
| Component | Mass percent % |
| The Es-EXTHIN | 0.1~5 |
| The S-bioallethrin | 0.1~5 |
| Transfluthrin | 0.1~5 |
| The trans phenothrin of rich dextrorotation | 0.1~5 |
| Transfluthrin | 0.1~5 |
| Seven fluorobenzene chrysanthemum esters | 0.1~5 |
| OP-10 | 5~15 |
| NP-10 | 5~15 |
| Isomery alcohol APEO | 5~15 |
| 1, the 2-dihydroxypropane | 5~15 |
| Trihydroxy propane | 5~20 |
| Triethylene-glycol | 5~15 |
| Water | Surplus |
1, seven fluorobenzene chrysanthemum esters, Es-EXTHIN, transfluthrin, transfluthrin, S-bioallethrin, the trans phenothrin of rich dextrorotation and OP-10, NP-10, isomery alcohol APEO are mixed stirring by above-mentioned mass percent and be mixed with compounding substances A in 1 hour;
2, said mixture matter A is mixed stirring with the water of above-mentioned mass percent 50% and be mixed with compounding substances B in 1 hour;
3, with 1 of above-mentioned mass percent, 2-dihydroxypropane, triethylene-glycol and trihydroxy propane mix stirring and were mixed with compounding substances C in 1 hour with the water of above-mentioned mass percent remaining 50%;
4, with said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
The present invention does further elaboration through above embodiment, but does not limit the scope of the invention.
The present invention is with the various variations of described scope of soverlay technique scheme and claim scope; Under the prerequisite that does not depart from technical scheme of the present invention, any improvement that those skilled in the art that the present invention did are realized easily all belongs to the present invention's scope required for protection.
Claims (8)
1. desinsection Alevaire is characterized in that comprising following component by mass percent:
。
2. desinsection Alevaire as claimed in claim 1 is characterized in that comprising following most preferably component by mass percent:
。
3. desinsection Alevaire as claimed in claim 1 is characterized in that described insecticide is selected from: the mixture of one or more in Es-EXTHIN, S-bioallethrin, the trans phenothrin of rich dextrorotation, tetrafluoro methothrin, transfluthrin, the seven fluorobenzene chrysanthemum esters etc.
4. desinsection Alevaire as claimed in claim 1 is characterized in that described surfactant is selected from: the mixture of one or more in NPE, APES, the AEO (AE0) etc.
5. desinsection Alevaire as claimed in claim 1; It is characterized in that described Alevaire is selected from: ethylene glycol APEO, 1; The mixture of one or more in 2-dihydroxypropane, 2-ethyl-2-(methylol)-1,3 propane diols, trihydroxy propane, triethylene-glycol, the tetraethylene-glycol etc.; Wherein the ethylene glycol APEO is an ethylene glycol APEO 200,400,600.
6. desinsection Alevaire as claimed in claim 1 is characterized in that described water is: deionized water.
7. like the preparation of the described arbitrary desinsection Alevaire of claim 1-6, it is characterized in that: insecticide and surfactant were mixed with compounding substances A in 1 hour by above-mentioned mass percent mixing stirring; Said mixture matter A is mixed stirring be mixed with compounding substances B in 1 hour with the water of above-mentioned mass percent 50%; The Alevaire of above-mentioned mass percent mixed with the water of above-mentioned mass percent remaining 50% to stir be mixed with compounding substances C in 1 hour; With said mixture matter B and said mixture matter C stirring reaction 1 hour, left standstill again 1 hour, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
8. like the application of the described arbitrary desinsection Alevaire of claim 1-6; It is characterized in that: be applied to the environment of public health field, food processing field and medicine and hygiene fields and the desinsection of air through multi-functional atomizer and Portable atomizer, can effectively prevent and kill harmful insects such as mosquitos and flies, cockroach; Be applied to the internal container of inspection and quarantine system through multi-functional atomizer and Portable atomizer, the air of railway carriage, cabin, automotive interior and the desinsection of environment can effectively prevent and kill harmful insects such as mosquitos and flies, cockroach; Be applied to the environment in livestock and poultry cultivation field, the desinsection of indoor and air through multi-functional atomizer and Portable atomizer, can effectively prevent and kill harmful insects such as mosquitos and flies, cockroach.
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| CN201110127499A CN102308844A (en) | 2011-05-17 | 2011-05-17 | Preparation and applications of pesticidal atomizing agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110127499A CN102308844A (en) | 2011-05-17 | 2011-05-17 | Preparation and applications of pesticidal atomizing agent |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102308790A (en) * | 2011-05-19 | 2012-01-11 | 覃终 | Preparation and applications of composite atomizing agent |
| CN111034716A (en) * | 2018-10-11 | 2020-04-21 | 江苏功成生物科技有限公司 | Normal-temperature volatile type insecticidal spray composition and application thereof |
| CN115067312A (en) * | 2022-06-29 | 2022-09-20 | 广西壮族自治区农业科学院 | Method for preventing and treating red imported fire ants by using ultramicron atomization technology |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101897342A (en) * | 2010-06-04 | 2010-12-01 | 贵阳柏丝特化工有限公司 | Preparation of insecticide solution and application thereof |
| CN101985412A (en) * | 2010-09-17 | 2011-03-16 | 覃终 | Preparation and application of compound smoke agent |
-
2011
- 2011-05-17 CN CN201110127499A patent/CN102308844A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101897342A (en) * | 2010-06-04 | 2010-12-01 | 贵阳柏丝特化工有限公司 | Preparation of insecticide solution and application thereof |
| CN101985412A (en) * | 2010-09-17 | 2011-03-16 | 覃终 | Preparation and application of compound smoke agent |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102308790A (en) * | 2011-05-19 | 2012-01-11 | 覃终 | Preparation and applications of composite atomizing agent |
| CN111034716A (en) * | 2018-10-11 | 2020-04-21 | 江苏功成生物科技有限公司 | Normal-temperature volatile type insecticidal spray composition and application thereof |
| CN115067312A (en) * | 2022-06-29 | 2022-09-20 | 广西壮族自治区农业科学院 | Method for preventing and treating red imported fire ants by using ultramicron atomization technology |
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Application publication date: 20120111 |